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Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06581F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lijun You, Daniel Roth, Lutz Greb
A structural constraint approach at a P–P bond is presented that enables the phosphinophosphination of alkynes, alkenes, and carbonyls with high regio- and diastereoselectivity. The apolar nature of the P–P bond facilitates a concerted mechanism.
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Regioselectivity switches between anthraquinone precursor fissions involved in bioactive xanthone biosynthesis

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06369D, Edge Article
Open Access
Xiao Jing Lv, Chun Zhi Ai, Li Rong Zhang, Xiu Xiu Ma, Juan Juan Zhang, Jia Peng Zhu, Ren Xiang Tan
BruN and BTG13 cleave chrysophanol hydroquinone into monodictyphenone and cephalanone F, respectively, with the regioselectivities found tunable via the key amino acid (AA) substitution strategy.
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Diphosphaenones: Beyond the Phosphorus Analogue of Enones

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06462C, Edge Article
Open Access
Jieli Lin, Shihua Liu, Shunlin Zheng, Hansjörg Grützmacher, Cheng-Yong Su, Zhongshu Li
Phosphaenones, like their carbon analogue enones (C=C–C=O), are promising building blocks for synthetic chemistry and materials science. However, in contrast to the α- and β-phosphaenones, structurally and spectroscopically well-defined diphosphaenones...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tailoring Hierarchical MnO2 Nanostructures on Self-Supporting Cathodes for High-Mass-Loading Zinc-Ion Batteries

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06182A, Edge Article
Open Access
Weijie Zheng, Zhibiao Cui, Cong Liu, Libei Yuan, Shengsong Li, Lilin Lin, Tao Meng, Liangui Yang, Yexiang Tong, Dong Shu
Aqueous zinc-ion batteries (AZIBs) with MnO2 cathodes have promising application prospects, however, their performance is hindered by their low efficiency and insufficient life. By leveraging the nanomicellar properties of cetyltrimethylammonium...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06403H, Edge Article
Open Access
Dan-Dan Zhou, Chun-Li Hu, Xin-Wei Zhang, Jiang-Gao Mao, Fang Kong
Successful synthesis of centrosymmetric Ga(Te3O7)Br and non-centrosymmetric M2(OH)(TeO3)(Te2O5)X (M = Al, Ga; X = Br, Cl) using a depolymerization strategy.
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Pathway control in metallosupramolecular polymerization of a monoalkynylplatinum(II) terpyridine complex through competitive complex formation

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06083K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Minhye Kim, Heekyoung Choi, Minjoo Kim, Seonghan Kim, Seohyeon Yun, Eunji Lee, Jaeheung Cho, Sung Ho Jung, Jong Hwa Jung
The modification of metalloligands based on bis-type amideterpyridine platinum(II) complexes not only induces the formation of helical supramolecular polymers but also introduces a kinetic trapping strategy in competitive conditions.
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Pronounced Electronic Modulation of Geometrically-Regulated Metalloenediyne Cyclization

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05396F, Edge Article
Open Access
Sarah E. Lindahl, Erin M. Metzger, Chun-Hsing Chen, Maren Pink, Jeff Zaleski
Using a diverse array of thermally robust phosphine enediyne ligands (dxpeb, X = Ph, Ph-pOCH3, Ph-pCF3, Ph-m2CH3, Ph-m2CF3, iPr, Cy, and tBu) a novel suite of cisplatin-like Pt(II) metalloenediynes (3,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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13/09:26 EST Minor Flood Warning for the Bremer River and Warrill Creek




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Low notes for film trade

How do box office revenues get affected with the recent move to discontinue old Rs. 500 and Rs. 1,000 notes? Deborah Cornelious asks trade experts




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Back to Basics: What should you know about Exchange Traded Funds?

Navigating the intricacies of ETF-investing involves understanding the disparity between an ETF’s market price and its Net Asset Value (NAV)




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Past performance not a guarantee for future returns

Sectoral funds usually are cyclical, which means their performance can swing significantly




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Markets correlate with economic performance, not political dispensation: Ashish Somaiyaa, CEO, WhiteOak Capital AMC

Ashish Somaiyaa, CEO, WhiteOak Capital AMC, on the impact of elections on the market and more




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North prefers equity, South less of it, East and West a mix

Pan-India, the diversity ties in with the fact that B30 cities are aggressive on equity compared to T30




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Why this consumption thematic fund is an attractive investment now

Nippon India Consumption fund has been a consistent outperformer across market cycles




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Mutual Funds and NRIs: If you are a non-resident Indian, here is how you can partake in the India growth story

If you’re a Non-Resident Indian eyeing India’s growth story, here are the basics that matter




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Not devoid of stock ideas, though markets aren’t cheap: Neelesh Surana, CIO, Mirae Asset Mutual Fund

Open to spinning off passive fund business under MF Lite, says Swarup Mohanty, Vice-Chairman and CEO, Mirae Asset Investment Managers




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Kotak Nifty Midcap 50 Index Fund: Just another Midcap Index Fund?

Only the second fund to give exposure to the Nifty Midcap 50 Index, how does it differ from other funds giving exposure to Midcaps?




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SBI Innovative Opportunities Fund: What you should know

The recently-launched fund, open till August 12, is a high risk and unknown rewards scenario




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What you need to know about SWP

Guide to withdrawing a fixed sum from MF investments at regular intervals for a fixed period




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Back to Basics: Have you filed in nomination for your MF?

Non-submission of ‘choice of nomination’ shall not result in freezing of MF folios for existing investors. But, you have more to lose not doing it




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Recent tweaks by SEBI in norms pertaining to nominations

A brief explainer on the amendments pertaining to investors recently brought in




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Why not considering liquid ETFs might be an opportunity cost

Liquid ETFs, trading on both NSE and BSE, predominantly invest in TREPS, which ensures daily returns, very low volatility, no interest or credit risk.




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India warns 'least common denominator' model of UNSC reforms could derail major change




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India warns 'least common denominator' model of UNSC reforms could derail major change




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Global leader PM Modi deserves Nobel Peace prize: Ace investor Mark Mobius




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Baku climate talks: India not attending World Leaders Climate Action Summit




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Andrews McMeel Cookbooks Nominated for IACP Awards

Two Andrews McMeel Publishing 2008 cookbooks have been named finalists in the 2009 International Association of Culinary Professionals Cookbook Awards:

The Art and Soul of Baking
By Sur La Table with Cindy Mushet
Baking Category

Things Cooks Love: Ingredients. Implements. Recipes.
By Sur La Table with Marie Simmons
General Category

The winners in each of the thirteen categories, as well as the Cookbook of the Year,
will be announced April 4 at IACP’s annual international conference in Denver.




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The Art & Soul of Baking Named James Beard Nominee

The Art & Soul of Baking has been named a nominee in the James Beard Foundation Awards 2009 in the Books: Baking Category

The James Beard Foundation Awards shine a spotlight on the best and brightest talent in the food and beverage industry.

The winners will be announced May 4th at a Black Tie Ceremony in New York

The Art and Soul of Baking guides readers through the world of baking, where alluring aromas of chocolate, vanilla, and cinnamon fill the air and tempt the palate. Culinary authority Sur La Table teams with professional pastry chef and baking instructor Cindy Mushet to create the ultimate book for bakers. The Art and Soul of Baking demystifies the friendly science of baking through delicious recipes and photography sequences that illustrate proper techniques for carmelizing sugar, or working with croissant dough.



  • The Art and Soul of Baking

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Towards real-time myocardial infarction diagnosis: a convergence of machine learning and ion-exchange membrane technologies leveraging miRNA signatures

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00640B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiang Ren, Ruyu Zhou, George Ronan, S. Gulberk Ozcebe, Jiaying Ji, Satyajyoti Senapati, Keith L. March, Eileen Handberg, David Anderson, Carl J. Pepine, Hsueh-Chia Chang, Fang Liu, Pinar Zorlutuna
Rapid diagnosis of acute myocardial infarction (AMI) is crucial for optimal patient management.
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Applying Low Levels of Strain to Model Nascent Phenomenon of Retinal Pathologies

Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D4LC00205A, Paper
Chase Paterson, Elizabeth Vargis
Age-related macular degeneration (AMD) is a leading cause of vision loss in the elderly. A better understanding of the mechanisms of the disease, especially at early stages, could elucidate new...
The content of this RSS Feed (c) The Royal Society of Chemistry




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A nanofluidic exchanger for harvesting saline gradient energy

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00544A, Paper
Saranath Sripriya, Cyril Picard, Vincent Larrey, Frank Fournel, Elisabeth Charlaix
Optimising, by tailored flows, the coupled ion transport in the proximity of selective nanopores multiplies by 300 the recovered osmotic power.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dual-drive acoustic micromixer for rapid nucleation and ultrafast growth of perovskite nanoparticles

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00721B, Paper
Zhifang Liu, Yuwen Lu, Wei Tan, Guorui Zhu
An acoustic micromixer driven by bubbles and sharp edges, controlling the nucleation and growth of perovskite nanoparticles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Discretised microfluidics for noninvasive health monitoring using sweat sensing

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00763H, Paper
Open Access
Emma J. M. Moonen, Walther Verberne, Eduard Pelssers, Jason Heikenfeld, Jaap M. J. den Toonder
We present the first wearable device with integrated electrowetting, which collects and transports sweat from single glands and measures sweat rate for extremely low sweat rate. This enables non-invasive biomarker monitoring of hospitalized patients.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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An imaging scheme to study the flow dynamics of co-flow regimes in microfluidics: implications for nanoprecipitation

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00652F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wali Inam, Anton Vladyka, Joanna W. Pylvänäinen, Junel Solis, Dado Tokic, Pasi Kankaanpää, Hongbo Zhang
Herein, by presenting a novel imaging-based scheme for analyzing fluid interactions in co-flow regimes, we identify oscillatory and chaotic flow behaviors to optimize nanoprecipitation through controlled fluid manipulation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Microstring-engineered tension tissues: a novel platform for replicating tissue mechanics and advancing mechanobiology

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00753K, Paper
Zixing Zhou, Tingting Li, Wei Cai, Xiaobin Zhu, Zuoqi Zhang, Guoyou Huang
A simple, cost-effective approach for fabricating soft microstring chips that enables precise engineering of tension tissues (METTs), advancing research in mechanobiology and biomedical applications.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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SERS-based pump-free microfluidic chip sensor for highly sensitive competitive immunoassay of cortisol in human sweat

Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D4LC00858H, Paper
Siyue Xiong, Chushu Zhu, Chengxuan Wang, Peitao Dong, Xuezhong Wu
Cortisol, known as the "stress hormone," is secreted by the adrenal cortex. Measuring cortisol levels in body fluids is essential for evaluating stress levels, adrenal function, hormone imbalances, and psychological...
The content of this RSS Feed (c) The Royal Society of Chemistry




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KITE gives technological edge to coverage of State school sports meet




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No child will be left out of school sports meet in future, says Sivankutty




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Kerala High Court quashes criminal case against filmmaker Sreekumar Menon




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CKCL, private players help fill gaps in non-biodegradable waste management in Ernakulam




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Media rights cannot be restricted: Kerala High Court

Expression by the media of any definitive opinion regarding the guilt or innocence of a party in an ongoing criminal investigation will not get protection under Article 19(1)(a), observes an HC bench




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Not afraid of any probe, says Mamkootathil




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Perumbavoor Urban Cooperative Society to witness novel election as aggrieved investors set to field panel to seize control

Election for 11-member board set for November 24 after cooperative faces financial crisis due to alleged fraud in loan valuations and sanctions




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HC allows medical termination of pregnancy of minor rape survivor

Division Bench passed the order while allowing an appeal filed against a single judge’s order declining permission. Medical board said that termination of pregnancy was most appropriate




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All set for Tazhathangadi Boat race on November 16




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No separate categories of schools in adjudging winners, clarifies Minister




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IBM’s new GenAI Innovation Centre to open doors to all looking to experiment with its AI platform




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Champions Way primed to deliver in the Governor’s Cup




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Shubankar takes the honours in Governor’s Cup




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Excellent Lass, Ashwa Vedha, Shamrock, Mandarino and The Leader shine