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Fe/Fe3C particles encapsulated in hollow carbon nanoboxes for high performance zinc–air batteries

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02396J, Paper
Chuyun Huang, Wenyuan Zhang, Xuezhi Hu, Shiliang Fei, Fhulufhelo Nemangwele, Nnditshedzeni Eric Maluta, Yangsen Hu, Hui Lv, Pei Hu, Zhuo Peng
Zinc–air batteries are recognized for their environmental friendliness and high energy density; however, the slow kinetics of the oxygen reduction reaction (ORR) at the air electrode hinder their commercial viability.
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Chemistry of organometallic nucleic acid components: personal perspectives and prospects for the future

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02634A, Perspective
Mateusz Klarek, Konrad Kowalski
Article summarizes over 12 years of studies on organometallic nucleic acid components in our laboratory. It outlines synthetic chemistry, redox, photophysical and biological properties alike. It also shows directions for future development.
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Morphology-dependent Li+ ion dynamics in X-ray amorphous and crystalline Li3PS4 prepared by solvent-assisted synthesis

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02636E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jonas Spychala, Christoph Mandl, Katharina Hogrefe, H. Martin R. Wilkening, Bernhard Gadermaier
Ionic conductivity of Li3PS4 if synthesized by a solvent-assisted method strongly depends on overall and surface morphology. Amorphous Li3PS4 shows a rather high conductivity which is only slightly enhanced when going to the (nano-)crystalline form.
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Switchable, chiral aluminium catalysts for ring opening polymerisations

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02831G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David T. Jenkins, Elizabeth C. Trodden, John M. Andresen, Stephen M. Mansell, Ruaraidh D. McIntosh
A switchable, solvent-free catalytic system was developed in which Al catalysts selectively initiate either the formation of polyether or polycarbonate through the application of a PPNCl (bis(triphenylphosphine)iminium chloride) cocatalyst.
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Ionic-liquid Functionalized Metal-organic Framework and Its High Performance Solid Electrolyte for Lithium-ion Conduction

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02756F, Paper
Xiang Kun Cui, Yu Ding, Li Feng, Li Ming Chen, Yang Mei Hu, Hui Chen, Chong-Qing Wan
Herein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...
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A highly sensitive ratiometric optical thermometer based on Sr2MgWO6 double perovskite doped with Dy3+ exploiting thermally coupled and uncoupled levels

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02940B, Paper
Thi Hong Quan Vu, Bartosz Bondzior, Dagmara Stefanska, Shovan Dan, Przemysław Jacek Dereń
The increasing demand for highly sensitive optical thermometers operating within a wide temperature range necessitates the development of new phosphors. In this work, the potential of temperature sensing performance of...
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Advances in metal–organic frameworks for optically selective alkaline phosphatase activity monitoring: a perspective

Dalton Trans., 2024, 53,17742-17755
DOI: 10.1039/D4DT01727G, Perspective
Eduarda Andrade, Filipe A. Almeida Paz, Flávio Figueira
MOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.
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Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting

Dalton Trans., 2024, 53,17918-17933
DOI: 10.1039/D4DT02542C, Paper
Krishnendu M. Nair, Pavithra Shankar, Selvaraju Thangavelu
Electrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.
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Construction of oxygen-rich vacancies and heterojunctions coupled with different morphologies of CeO2/mesoporous TiO2 framework structures for efficient photocatalytic CO2 reduction performance

Dalton Trans., 2024, 53,17963-17975
DOI: 10.1039/D4DT02014F, Paper
Morigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin Zhao
Construction of oxygen-rich vacancies and heterojunction-coupled CeO2/mesoporous TiO2 framework structures with different morphologies and efficient photocatalytic CO2 reduction performance.
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Fluorescent molecular systems based on carborane-perylenediimide conjugates

Dalton Trans., 2024, 53,17841-17851
DOI: 10.1039/D4DT02477J, Paper
Open Access
Ruben Rodriguez-Madrid, Sohini Sinha, Laura Parejo, Jordi Hernando, Rosario Núñez
o-Carborane–perylenediimide conjugates exhibit exceptional fluorescence properties in solution, while red-light excimer emission is observed in their aggregated forms and in dispersible nanoparticles.
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Ruthenium, copper and ruthenium–copper complexes of an unsymmetrical phosphino pyridyl 1,8-naphthyridine PNNN ligand

Dalton Trans., 2024, 53,18037-18046
DOI: 10.1039/D4DT02755H, Paper
Jingyun Wu, Michael A. Stevens, Michael G. Gardiner, Annie L. Colebatch
A new unsymmetrical dinucleating PNNN ligand is reported, the versatility of which is demonstrated by formation of heterobimetallic, homobimetallic and monometallic complexes.
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Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance

Dalton Trans., 2024, 53,17948-17962
DOI: 10.1039/D4DT02118E, Paper
Anandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel Elumalai
We disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.
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Unprecedented C–F bond cleavage in perfluoronaphthalene during cobaltocene reduction

Dalton Trans., 2024, 53,17789-17793
DOI: 10.1039/D4DT02791D, Communication
Gargi Kundu, Debjit Pramanik, Soumya Ranjan Dash, Ravi Kumar, Mayur Sangole, Srinu Tothadi, Aryya Ghosh, Kumar Vanka, Kirandeep Singh, Sakya S. Sen
The reduction of octafluoronapthalene by cobaltocene in preence of NHC led to a distinct Co(I) species with the cleavage of the C–F bond and the formation of Co–C bond.
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Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02703E, Paper
Vilakkathala U. Krishnapriya, Cherumuttathu H. Suresh
Dinitrogen activation has long been a challenging goal in chemistry. Tailored superbase phosphines offer a promising approach to overcome this challenge by going beyond the traditional triple bond.
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Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO2) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
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Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02508C, Paper
Justin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van Stipdonk
A series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.
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Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02655A, Paper
Z. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun Xu
Four BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...
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Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02573C, Frontier
Prashanta Pal, Mahasweta Nandi
Two dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...
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Study of CanUO2(CO3)3(4–2n)– complexes using CE-ICP-MS with polyetheretherketone (PEEK) capillaries

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02781G, Paper
Ruopei Sun, Erwan Dupuis, Jean Aupiais, Pascal Reiller
The formation constants of CanUO2(CO3)3(4–2n)– complexes have been determined directly using capillary electrophoresis coupled with inductively coupled plasma mass spectrometry (CE-ICP-MS) in 0.1 M NaCl and at room temperature. Instead...
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Are Coal Producers doing an OPEC?



  • Siddhartha P Saikia

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Price pooling mantra: Wake up to expensive electricity



  • Siddhartha P Saikia

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Pencilled in

The writing stick has all but disappeared, flaunted only by a few sections




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The dark side of digital dependence

The dreaded blue screen can throw life out gear in the most unlikeliest of places




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Confessions of an impractical person

How one ignored the imperfection of life by finding solace in the perfection of art




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Permeating partiarchy

It’s no longer about confining women to the kitchen; it subtly disguises itself as praise for how well women juggle careers and family




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NanoRaman: correlated tip-enhanced optical spectroscopy and scanning-probe microscopy

Register now: 8 March 2018
A webinar sponsored by HORIBA Scientific




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Developing the world's first full-body PET scanner

Simon Cherry explains why the EXPLORER project will revolutionize medical imaging




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Heavy fog affects 21 flights at Kempegowda International Airport in Devanahalli in Bengaluru

There were more than 15 delays, and six flights diverted




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Appeal to Karnataka government to officially celebrate Shankar Nag’s birthday as ‘Driver’s Day’

Several auto drivers’ unions made an appeal to Transport Minister Ramalinga Reddy




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BJP MLA B.P. Yatnal walks out of event after crowd objects to political speech over mention of Waqf land row

Mr. Yatnal raised the issue of waqf during an Allammaprabhu temple event




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ANF conducts combing operations in Sringeri




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State-level mock Parliament competition for high school and PU students in Shivamogga tomorrow




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Sandur bypolls: Ballari Deputy Commissioner appeals to voters to exercise franchise




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Shepherds, craftspersons to participate in ‘Kurubki’ event in Bengaluru




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Movement of suspected Maoists in Chikkamagaluru: Jayapura police register case, seize three rifles




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Integrated motivational interviewing and cognitive behavioral therapy (ICBT) [electronic resource] : a practitioners guide / Joseph Hyde, Maria Torres, Win Turner, R. Lyle Cooper.

Hoboken, New Jersey : John Wiley & Sons, Inc., [2024]




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Why people smoke [electronic resource] : an innovative approach to treating tobacco dependence / Frank T. Leone and Sarah Evers-Casey ; with illustrations by Joey Leone.

Philadelphia : University of Pennsylvania Press, [2023]




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Maha CM asks officials to provide compensation for farm losses due to unseasonal rains




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People have seen our work... Devendra Fadnavis exudes confidence in Mahayuti alliance retaining power in Maharashtra




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Maha: Under PMBJP, Nalasopara residents buying cheaper medicines; thank PM Modi




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Padmini Kolhapure, Shreyas Talpade urge people to vote in Maharashtra Assembly elections




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Samson says support from captain Suryakumar, coach Gambhir helped him overcome doubt over his ability after failures

“I received a lot of phone calls from Gautam bhai and Surya, telling me what to work on,” says the Kerala batter, after his century against South Africa




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Deserving finalists Calicut and Forca Kochi to battle it out for Super League Kerala crown

When the two sides met in the league phase, Calicut won a match (1-0) while the other was drawn (1-1)




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Chennai Grandmasters | Chithambaram downs Arjun, throws the title race wide open

With this win, Chithambaram (3.5) has joined Iranian Tabatabaei (3.5) to trail leaders Arjun (4) and Aronian (4) by just half a point




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Football king Calicut takes home Super League Kerala crown

The host downs Forca Kochi 2-1 to win the inaugural edition of the tournament much to the delight of the crowd




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McSweeney to open, Inglis also handed maiden Test call up for BGT opener

Nathan McSweeney had emerged as a strong contender for the opener's spot, earning backing from the likes of David Warner and Ricky Ponting




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Medvedev rages in opening ATP Finals defeat to Fritz

American Fritz leads the group ahead of that clash following a surprisingly straightforward win in Turin over world number four Medvedev who exploded with anger during his below-par display




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Bumrah to lead, Rahul likely to open in Perth if Rohit does not make it, says Gautam Gambhir

The second batch of the Indian players is leaving for Perth, but Rohit has stayed back. Uncertainty remains if Rohit will compete in the series-opener.




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Sindhu, Lakshya Sen hope to regain form at Kumamoto Masters Japan

P.V. Sindhu and Lakshya Sen have struggled to find their best form since disappointing performances at the Paris Olympics.




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Super League Kerala has scored a fine goal on debut

The beautiful game may no longer be a clear winner when it comes to the State’s most popular sports, and it could do with the fillip provided by the league