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Cooperative phenomenon of vapochromism and proton conduction of luminescent Pt(II) complexes for the visualisation of proton conductivity

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DOI: 10.1039/D0FD00001A, Paper
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The luminescent and proton conductive Pt(II) complex [PtCl(tpy-o-py)]Cl and its HCl adduct [PtCl(tpy-o-pyH)]Cl2 (o-Pt and o-Pt·HCl, respectively; tpy-o-py = 2,2': 6',2''-terpyridine-6',2'''-pyridine) were synthesised and their crystal structures, vapochromic behaviour, and...
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Faraday Discuss., 2020, Accepted Manuscript
DOI: 10.1039/D0FD00004C, Paper
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Zr(IV) metal-organic frameworks (MOFs) UiO-68 and PCN-57, containing linkers triphenylene dicarboxylate (TPDC) and tetramethyl-triphenylene dicarboxylate (TTDC), respectively, were doped with an H shaped, tetracarboxylate linker that contains a [2]rotaxane molecular...
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The Role of Temperature and Adsorbate on Negative Gas Adsorption in the Mesoporous Metal-Organic Framework DUT-49

Faraday Discuss., 2020, Accepted Manuscript
DOI: 10.1039/D0FD00013B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Simon Krause, Jack D. Evans, Volodymyr Bon, Irene Senkovska, François-Xavier Coudert, Daniel M Többens, Dirk Wallacher, Nico Grimm, Stefan Kaskel
Unusual adsorption phenomena, such as breathing and negative gas adsorption (NGA), are rare and challenge our understanding of the thermodynamics of adsorption in deformable porous solids. In particular, NGA appears...
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