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Jan86 Posts

Jan86 Posts





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Reserve Bank of India

Reserve Bank of India




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Ministry of New and Renewable Energy

Ministry of New and Renewable Energy




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Manmohan Singh

Manmohan Singh




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12th Five-Year Plan

12th Five-Year Plan




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MANUFACTURING

MANUFACTURING




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Facile fabrication of a hybrid polymer electrolyte via initiator-free thiol–ene photopolymerization for high-performance all-solid-state lithium metal batteries

Polym. Chem., 2020, 11,2732-2739
DOI: 10.1039/D0PY00203H, Paper
Cai Zuo, Binghua Zhou, Ye Hyang Jo, Sibo Li, Gong Chen, Shaoqiao Li, Wen Luo, Dan He, Xingping Zhou, Zhigang Xue
The article reports the facile fabrication of a solid polymer electrolyte via initiator-free thiol–ene photopolymerization for all-solid-state lithium metal batteries.
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A polymerization-induced self-assembly process for all-styrenic nano-objects using the living anionic polymerization mechanism

Polym. Chem., 2020, 11,2635-2639
DOI: 10.1039/D0PY00296H, Communication
Chengcheng Zhou, Jian Wang, Peng Zhou, Guowei Wang
By combination of the living anionic polymerization (LAP) mechanism with the polymerization-induced self-assembly (PISA) technique, the all-styrenic diblock copolymer poly(p-tert-butylstyrene)-b-polystyrene (PtBS-b-PS) based LAP PISA was successfully developed.
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Tin(II) 2-ethylhexanoate catalysed methanolysis of end-of-life poly(lactide)

Polym. Chem., 2020, 11,2625-2629
DOI: 10.1039/D0PY00292E, Communication
Melanie Hofmann, Christoph Alberti, Felix Scheliga, Roderich R. R. Meißner, Stephan Enthaler
The depolymerisation of end-of-life poly(lactide) (PLA) goods was studied as part of the chemical recycling of PLA.
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Correction: Dynamic covalent polymer networks via combined nitroxide exchange reaction and nitroxide mediated polymerization

Polym. Chem., 2020, 11,2761-2761
DOI: 10.1039/D0PY90053B, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yixuan Jia, Yannick Matt, Qi An, Isabelle Wessely, Hatice Mutlu, Patrick Theato, Stefan Bräse, Audrey Llevot, Manuel Tsotsalas
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A covalently crosslinked silk fibroin hydrogel using enzymatic oxidation and chemoenzymatically synthesized copolypeptide crosslinkers consisting of a GPG tripeptide motif and tyrosine: control of gelation and resilience

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00187B, Paper
Hiromitsu Sogawa, Takuya Katashima, Keiji Numata
A covalently crosslinked silk fibroin hydrogel was successfully formed via an enzymatic crosslinking reaction using copolypeptides, which consist of a glycine–proline–glycine tripeptide motif and tyrosine, as linker molecules.
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Synthesis and enantioseparation of proline-derived helical polyacetylenes as chiral stationary phases for HPLC

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00205D, Paper
Ge Shi, Xiao Dai, Yue Zhou, Jie Zhang, Jun Shen, Xinhua Wan
Proline-derived aliphatically substituted polyacetylenes with stable helical conformations exhibit an excellent enantioseparation ability as chiral stationary phases of HPLC.
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Synthesis of star-shaped polyzwitterions with adjustable UCST and fast responsiveness by a facile RAFT polymerization

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00318B, Paper
Zhi Li, Hao Li, Zhonghe Sun, Botao Hao, Tung-Chun Lee, Anchao Feng, Liqun Zhang, San H. Thang
We describe crosslinking of polyzwitterions for the formation of novel star-shaped polymers with low polydispersities and dual-responsiveness using RAFT polymerization.
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Highly elastic, strong, and reprocessable cross-linked polyolefin elastomers enabled by boronic ester bonds

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00235F, Paper
Fei Yang, Li Pan, Zhe Ma, Yahui Lou, Yuanyuan Li, Yuesheng Li
Despite the development of new catalysts and synthetic strategies to prepare polyolefin elastomers (POEs), less progress has been made in balancing their elastomeric properties with processability and resistance to heat and solvents.
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Poly(alanine-nylon-alanine) as a bioplastic: chemoenzymatic synthesis, thermal properties and biological degradation effects

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00137F, Paper
Open Access
Prashant G. Gudeangadi, Kei Uchida, Ayaka Tateishi, Kayo Terada, Hiroyasu Masunaga, Kousuke Tsuchiya, Hitoshi Miyakawa, Keiji Numata
Poly(amino acids) such as polypeptides and proteins are attractive biomass-based polymers that potentially contribute to circular economy for plastic.
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Self-crosslinking smart hydrogels through direct complexation between benzoxaborole derivatives and diols from hyaluronic acid

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00308E, Paper
Tamiris Figueiredo, Yu Ogawa, Jing Jing, Vanina Cosenza, Isabelle Jeacomine, Johan D. M. Olsson, Thibaud Gerfaud, Jean-Guy Boiteau, Craig Harris, Rachel Auzély-Velty
By tailoring the structure of benzoxaborole (BOR), self-crosslinking hydrogels based on hyaluronic acid (HA) modified with BOR derivatives are obtained for the first time through the direct BOR-HA diol complexation at physiological pH.
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Photo-controlled RAFT polymerization mediated by organic/inorganic hybrid photoredox catalysts: enhanced catalytic efficiency

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00171F, Paper
Wulong Wang, Sheng Zhong, Guicheng Wang, Hongliang Cao, Yun Gao, Weian Zhang
Photo-controlled RAFT polymerization mediated by an organic/inorganic hybrid photoredox catalyst (ZnTPP–POSS) was performed and showed enhanced catalytic efficiency compared with the ZnTPP photocatalyst.
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Surfactant-free synthesis of layered double hydroxide-armored latex particles

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00140F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
X. G. Qiao, P.-Y. Dugas, V. Prevot, E. Bourgeat-Lami
MgAl-layered double hydroxide (LDH)-armored latexes were produced by Pickering emulsion polymerization of styrene using 2-hydroxyethyl methacrylate (HEMA) and methyl methacrylate (MMA) as auxiliary comonomers.
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Miniemulsion polymerization of styrene using carboxylated graphene quantum dots as surfactant

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00404A, Paper
Le N. M. Dinh, Lakshmi N. Ramana, Vipul Agarwal, Per B. Zetterlund
Carboxylated graphene quantum dots (cGQDs) were synthesized from dextrose and sulfuric acid via a hydrothermal process, and subsequently used as sole surfactant in miniemulsion polymerization of styrene.
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Synthesis of acrylamide-based block-copolymer brushes under flow: monitoring real-time growth and surface restructuring upon drying

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00219D, Paper
Open Access
Joydeb Mandal, Andrea Arcifa, Nicholas D. Spencer
Block-copolymer brushes of water-soluble acrylamides have been synthesised by SI-ATRP under continuous flow and their growth monitored in situ by means of a quartz-crystal microbalance with dissipation (QCM-D).
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Preparation of aryl polysulfonates via a highly efficient SuFEx click reaction, their controllable degradation and functionalized behavior

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00435A, Communication
Zhenlei Cao, Feng Zhou, Pei-Yang Gu, Dongyun Chen, Jinghui He, John R. Cappiello, Peng Wu, Qingfeng Xu, Jianmei Lu
Polysulfonates obtained from SuFEx click reaction can be degraded using DBU. The degradation process was further utilized to prepare functional polymers.
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Enhanced thermomechanical property of a self-healing polymer via self-assembly of a reversibly cross-linkable block copolymer

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00310G, Paper
Hyang Moo Lee, Suguna Perumal, Gi Young Kim, Jin Chul Kim, Young-Ryul Kim, Minsoo P. Kim, Hyunhyup Ko, Yecheol Rho, In Woo Cheong
Introduction of a self-healable block copolymer increases the mechanical property whilst maintaining self-healing efficiency.
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A general method to greatly enhance ultrasound-responsiveness for common polymeric assemblies

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00254B, Paper
Jinkang Dou, Ruiqi Yang, Kun Du, Li Jiang, Xiayun Huang, Daoyong Chen
Ultrasound-controlled drug release is a very promising technique for controlled drug delivery due to the unique advantages of ultrasound as the stimulus.
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Pillar[5]arene-based self-assembled linear supramolecular polymer driven by guest halogen–halogen interactions in solid and solution states

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00327A, Paper
Talal F. Al-Azemi, Mickey Vinodh
A pillar[5]arene-based linear supramolecular polymer mediated by guest halogen–halogen interactions (C–Br⋯Br–C) was studied in both the solution and solid states.
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Hydrogen-bonded supramolecular micelle-mediated drug delivery enhances the efficacy and safety of cancer chemotherapy

Polym. Chem., 2020, 11,2791-2798
DOI: 10.1039/D0PY00082E, Paper
Chih-Chia Cheng, Ya-Ting Sun, Ai-Wei Lee, Shan-You Huang, Wen-Lu Fan, Yu-Hsuan Chiao, Chih-Wei Chiu, Juin-Yih Lai
Multiple hydrogen-bonded supramolecular polymers tend to form stable spherical micelles with oppositely charged anticancer drugs in biological environments, which improves cellular drug uptake and more effectively induces apoptosis in cancer cells.
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Polymerization of dopamine accompanying its coupling to induce self-assembly of block copolymer and application in drug delivery

Polym. Chem., 2020, 11,2811-2821
DOI: 10.1039/D0PY00085J, Paper
Yudian Qiu, Zongyuan Zhu, Yalei Miao, Panke Zhang, Xu Jia, Zhongyi Liu, Xubo Zhao
The polymerization of dopamine and its coupling occur in succession, which synergistically induces the self-assembly of block copolymer to yield ordered structures, including micelles and vesicles.
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Mussel-inspired coordination functional polymer brushes-decorated rGO-stabilized silver nanoparticles composite for antibacterial application

Polym. Chem., 2020, 11,2822-2830
DOI: 10.1039/D0PY00180E, Paper
Shengnan Zhou, Haixun Ji, Linjing Liu, Sijia Feng, Yuqin Fu, Yu Yang, Changli Lü
A catechol-terminated coordination functional polymer-modified rGO supported AgNPs composite was fabricated. Grafted polymer brushes improve the material's hydrophilicity and dispersion stability of AgNPs on rGO, enhancing antibacterial activity.
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Simple improvements to Gilch synthesis and molecular weight modulation of MEH-PPV

Polym. Chem., 2020, 11,2831-2837
DOI: 10.1039/D0PY00072H, Paper
Riley O'shea, Wallace W. H. Wong
The solvent and temperature used in the Gilch synthesis of poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) were varied to achieve an improved set of reaction conditions.
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Vesicular assemblies of thermoresponsive amphiphilic polypeptide copolymers for guest encapsulation and release

Polym. Chem., 2020, 11,2889-2903
DOI: 10.1039/D0PY00135J, Paper
Mahammad Anas, Somdeb Jana, Tarun K. Mandal
Thermoresponsive amphiphilic polypeptide copolymers are synthesized via different polymerization techniques for their self-assembly into vesicular aggregates for guest encapsulation and release.
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Self-supported rhodium catalysts based on a microporous metal–organic framework for polymerization of phenylacetylene and its derivatives

Polym. Chem., 2020, 11,2904-2913
DOI: 10.1039/D0PY00170H, Paper
Li Zhang, Qingbin Cao, Fei Gao, Yuping Dong, Xiaofang Li
Highly efficient, cis-selective, stable, recyclable and reusable heterogeneous single-site MOF-supported rhodium catalysts polymerize PA and its derivatives, producing cis-transoidal PPAs and their functional derivatives having a helical configuration or AIE properties.
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Synthesis of a side-chain hole transporting polymer through Mitsunobu post-functionalization for efficient inverted perovskite solar cells

Polym. Chem., 2020, 11,2883-2888
DOI: 10.1039/D0PY00134A, Paper
Liuyuan Lan, Xiang Deng, Jie Zhang, Jingdong Luo, Alex K.-Y. Jen
Mitsunobu post-functionalization was utilized to construct a new efficient dopant-free side-chain hole transporting polymer for inverted perovskite solar cells, exhibiting a power conversion efficiency of 17.75% and a high fill factor over 81%.
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Synthesis of biscarboxylic acid functionalised EDTA mimicking polymers and their ability to form Zr(IV) chelation mediated nanostructures

Polym. Chem., 2020, 11,2799-2810
DOI: 10.1039/D0PY00304B, Paper
Meike N. Leiske, Julia A. Walker, Aadarash Zia, Nicholas L. Fletcher, Kristofer J. Thurecht, Thomas P. Davis, Kristian Kempe
We present a new biscarboxylic acid acrylate, which is used for the synthesis of double hydrophilic EDTA-mimicking block copolymers capable of self-assembly upon zirconium complexation.
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A high performance phenyl-free LED photoinitiator for cationic or hybrid photopolymerization and its application in LED cationic 3D printing

Polym. Chem., 2020, 11,2855-2863
DOI: 10.1039/D0PY00142B, Paper
Liqun Tang, Jun Nie, Xiaoqun Zhu
In this work, a high performance LED photoinitiator, 1,3-bis(1-methyl-1H-pyrrol-2-yl)prop-2-en-1-one (BMO), without a benzene ring was synthesized through a one-step aldehyde–ketone condensation reaction.
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Thermally triggerable, anchoring block copolymers for use in aqueous inkjet printing

Polym. Chem., 2020, 11,2869-2882
DOI: 10.1039/D0PY00244E, Paper
George E. Parkes, Helena J. Hutchins-Crawford, Claire Bourdin, Stuart Reynolds, Laura J. Leslie, Matthew J. Derry, Josephine L. Harries, Paul D. Topham
Towards the goal of shifting from toxic organic solvents to aqueous-based formulations in commercial inkjet printing, a series of well-defined amphiphilic block copolymers have been synthesized via RAFT polymerization.
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Mechanical activation of polymers containing two adjacent mechanophores

Polym. Chem., 2020, 11,2864-2868
DOI: 10.1039/D0PY00279H, Paper
Richard Stevenson, Min Zhang, Guillaume De Bo
Polymers containing two adjacent mechanophores cleave at the same as a single-mechanophore chains.
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Influence of surface charge on the formulation of elongated PEG-b-PDLLA nanoparticles

Polym. Chem., 2020, 11,2775-2780
DOI: 10.1039/D0PY00280A, Communication
Open Access
Roxane Ridolfo, David S. Williams, Jan C. M. van Hest
Amphiphilic PEG-PDLLA copolymers undergo assembly into polymersomes and can be transformed into tubular shapes using dialysis. By fine-tuning the shape change conditions also amine- and carboxylic acid modified polymersomes can now be effectively turned into tubes.
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Correction: A facile PEG/thiol-functionalized nanographene oxide carrier with an appropriate glutathione-responsive switch

Polym. Chem., 2020, 11,2923-2923
DOI: 10.1039/D0PY90048F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bingjie Hao, Wei Li, Sen Zhang, Ying Zhu, Yongjun Li, Aishun Ding, Xiaoyu Huang
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Biosignal-responsive polymer nanorods that specifically recognize hydrogen polysulfide (H2Sn) from reactive sulfur species

Polym. Chem., 2020, 11,2781-2785
DOI: 10.1039/D0PY00360C, Communication
Xi Liu, Wei Sang, Kunbing Ouyang, Qiang Yan
We report a new block copolymer bearing p-fluoronitrobenzoate (FNB) pendants that is capable of responding to the H2Sn biosignal in an extraordinarily selective and sensitive manner.
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Incorporating trifunctional 1,6-heptadiyne moiety into polyacetylene ionomer for improving its physical and conductive properties

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00109K, Paper
Hongfei Li, Hengchen Zhang, Xiaojuan Liao, Ruyi Sun, Meiran Xie
A trifunctional diyne comonomer can regulate the structure and optimize the physical state of polyacetylene ionomers, which exhibit a high ionic conductivity of 2.6 × 10−5–1.0 × 10−3 S cm−1 at 30 °C.
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Outstanding Reviewers for Polymer Chemistry in 2019

Polym. Chem., 2020, 11,2774-2774
DOI: 10.1039/D0PY90061C, Editorial

We would like to take this opportunity to highlight the Outstanding Reviewers for Polymer Chemistry in 2019, as selected by the editorial team for their significant contribution to the journal.
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Aromatic thioketone-mediated radical polymerization of methacrylates and the preparation of amphiphilic quasi-block copolymers

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00322K, Paper
Haoyu Yu, Jianwei Shao, Dong Chen, Li Wang, Wantai Yang
TfXT exhibits strong ability to control radical polymerization of methyl methacrylate and has been used in preparing amphiphilic quasi-block copolymer.
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Amide transformation as an efficient postpolymerization modification approach for the synthesis of functional polyacetylenes

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00398K, Paper
Juntao Ren, Heng Liu, Xuequan Zhang, Yanming Hu, Guangyuan Zhou, Toshio Masuda
Modification of a precursor polyacetylene with various amines and alcohols through amide transformation gives access to a series of functional polymers showing nonlinear optical, luminescence, enhanced surface energy, and redox active properties.
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Alternating ring-opening copolymerization of epoxides with saturated and unsaturated cyclic anhydrides: reduced viscosity poly(propylene fumarate) oligomers for use in cDLP 3D printing

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00453G, Paper
Yongjun Shin, Matthew L. Becker
A ring-opening copolymerization of propylene oxide with saturated and unsaturated anhydrides using Mg(BHT)2(THF)2 catalyst followed by an isomerization yields poly(propylene fumarate) (PPF) oligomers with improved properties for 3D printing.
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Sequential and alternating RAFT single unit monomer insertion: model trimers as the guide for discrete oligomer synthesis

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00390E, Paper
Ruizhe Liu, Lei Zhang, Zixuan Huang, Jiangtao Xu
A complete set of model trimers and their synthetic kinetics are established to guide the synthesis of diverse sequence-defined polymers.
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Hierarchical self-assembled nanostructures of lactone-derived thiobarbiturate homopolymers for stimuli-responsive delivery applications

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00367K, Paper
Piyali Mandal, Diptendu Patra, Raja Shunmugam
Hierarchical self-assembled nanostructures of lactone-derived thiobarbiturate homopolymers for stimuli-responsive delivery applications are shown.
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Self-assembly of strawberry-like organic–inorganic hybrid particle clusters with directionally distributed bimetal and facile transformation of the core and corona

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00237B, Paper
Shuxing Mei, Mingwang Pan, Juan Wang, Xiaopeng Zhang, Shaofeng Song, Chao Li, Gang Liu
Controllable structure of organic–inorganic hybrid particle clusters were successfully fabricated by self-assembly which derived from the strong interaction between carboxyl groups of the organic particles and amino groups of the inorganic particles.
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A 3D printed drug delivery implant formed from a dynamic supramolecular polyurethane formulation

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00068J, Paper
S. Salimi, Y. Wu, M. I. Evangelista Barreiros, A. A. Natfji, S. Khaled, R. Wildman, L. R. Hart, F. Greco, E. A. Clark, C. J. Roberts, W. Hayes
Prototype drug eluting implants have been 3D printed using a supramolecular polyurethane-PEG formulation. The implants are capable of releasing a pharmaceutical active with effective drug release over a period of up to 8.5 months.
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Multi-photon polymerization of bio-inspired, thymol-functionalized hybrid materials with biocompatible and antimicrobial activity

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00281J, Communication
Open Access
Kostas Parkatzidis, Maria Chatzinikolaidou, Eleftherios Koufakis, Maria Kaliva, Maria Farsari, Maria Vamvakaki
Thymyl-methacrylate functionalized, hybrid 3D scaffolds, fabricated by multi-photon lithography, exhibit excellent biocompatibility and antimicrobial action for bone and dental tissue engineering.
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Epoxy-functional diblock copolymer spheres, worms and vesicles via polymerization-induced self-assembly in mineral oil

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00380H, Paper
Philip J. Docherty, Chloé Girou, Matthew J. Derry, Steven P. Armes
Epoxy-functional poly(stearyl methacrylate)-poly(glycidyl methacrylate) spheres, worms or vesicles can be prepared by RAFT dispersion polymerization of glycidyl methacrylate in mineral oil at 70 °C.
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