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Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation

Dalton Trans., 2024, 53,18047-18053
DOI: 10.1039/D4DT02567A, Paper
Hui Li, He Zheng
Insights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.
The content of this RSS Feed (c) The Royal Society of Chemistry




no

Ruthenium, copper and ruthenium–copper complexes of an unsymmetrical phosphino pyridyl 1,8-naphthyridine PNNN ligand

Dalton Trans., 2024, 53,18037-18046
DOI: 10.1039/D4DT02755H, Paper
Jingyun Wu, Michael A. Stevens, Michael G. Gardiner, Annie L. Colebatch
A new unsymmetrical dinucleating PNNN ligand is reported, the versatility of which is demonstrated by formation of heterobimetallic, homobimetallic and monometallic complexes.
The content of this RSS Feed (c) The Royal Society of Chemistry




no

Neutral mononuclear indium(III) photosensitizers for CO2 photoreduction

Dalton Trans., 2024, 53,17772-17776
DOI: 10.1039/D4DT02595D, Communication
Zaichao Zhang, Li-Zhi Fu, Piao He, Xiao-Yi Yi
Neutral mononuclear indium(III) complexes (In-1–In-3) containing 2,6-di(1H-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligands are employed as photosensitizers in photocatalytic CO2 reduction.
The content of this RSS Feed (c) The Royal Society of Chemistry




no

An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection

Dalton Trans., 2024, 53,17893-17901
DOI: 10.1039/D4DT02111H, Paper
Yunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo Lu
An acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.
The content of this RSS Feed (c) The Royal Society of Chemistry




no

Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols

Dalton Trans., 2024, 53,17976-17988
DOI: 10.1039/D4DT02355B, Paper
The Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang Tran
Various 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO2) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02508C, Paper
Justin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van Stipdonk
A series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02655A, Paper
Z. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun Xu
Four BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02573C, Frontier
Prashanta Pal, Mahasweta Nandi
Two dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Single-ion magnetism in novel Btp-based cobalt complexes of different charge

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02338B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gustavo Rama-Martínez, Marcelo Osorio-Celis, Yolanda Sabater-Algarra, Diego Sánchez-Brunete, Antonio L. Llamas-Saiz, Eugenia P. Quirós-Díez, M. Eugenio Vázquez, Miguel Vázquez López, María del Carmen Giménez López
By deprotonating Btp-derived ligands, precise control over counterions in the outer-coordination sphere is achieved in both neutral and charged anisotropic CoII complexes exhibiting field-induced single-ion magnetism.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




no

Media invited but not welcomed!



  • Siddhartha P Saikia

no

Tie the knot on extravagant weddings

In conducting the feast and ceremonies, families spend as if there is no tommorow




no

Do not live in the past

While cherishing memories, we also need to prepare ourselves for the present and future




no

Thriving technology, waning memory

Too many digital nannies are robbing us of the power of memory




no

Nothing has changed for women in India

From Nirbhaya to Abhaya, violence continue to be perpertrated against women in the country




no

Talking about menopause

Media explore gender disparity largely, but it has failed to explicitly probe this transformative stage in a woman’s life




no

A case for a welfare economy

More human development means more purchasing power and more demand for products




no

Celebrate menopause

Recognise it as the beginning of a new chapter in a woman’s life




no

NanoRaman: correlated tip-enhanced optical spectroscopy and scanning-probe microscopy

Register now: 8 March 2018
A webinar sponsored by HORIBA Scientific




no

Public campaigning for bypolls to end on November 11

The final day of public canvassing will see the Chief Minister and the Deputy Chief Minister besides top leaders of JD(S) and BJP seeking votes in Channapatna




no

Medical malpractice destroys profession’s nobility, says BLDE Vice-Chancellor




no

Model rocketry workshop launched to inspire young innovators in Bengaluru

The workshop is aimed at promoting innovation and technical expertise




no

Karnataka Minister Zameer Ahmed Khan kicks up another row with ‘racist’ remark about Union Minister H.D. Kumaraswamy

The Housing Minister is already facing flak for the wakf controversy that has snowballed into a big issue in Karnataka




no

Siddaramaiah to launch projects in Mysuru on November 12 and 13




no

Chunchankatte Jalapatotsava to be held on Nov. 30, Dec. 1




no

Karnataka School Examination and Assessment Board directs students from unauthorised schools not to register for SSLC exam this year




no

HMT forest land denotification: Forest Department issues notice to former and current officers




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Chief Minister Siddaramaiah has no moral right to seek resignation of Prime Minister Narendra Modi, says Union Minister

Pralhad Joshi was responding to a challenge by Mr. Siddaramaiah to the PM to prove charges of corruption in Karnataka or resign.




no

Bengaluru likely to receive light to moderate rainfall till November 15: IMD

It added that from November 13 to 15, fairly widespread with light to moderate rainfall is very likely to occur over south interior Karnataka and coastal Karnataka




no

Kalaburagi: Man sentenced to 20 years of imprisonment for sexually assaulting minor girl




no

Farmers demand revocation of decades-old waqf notices




no

Indigenous audibilities : music, heritage, and collections in the Americas / Amanda Minks.

New York, NY : Oxford University Press, [2024]




no

The neuroscience of psychotherapy [electronic resource] : healing the social brain / Louis J. Cozolino

[New York] : W. W. Norton & Company, Incorporated, 2024.




no

Why people smoke [electronic resource] : an innovative approach to treating tobacco dependence / Frank T. Leone and Sarah Evers-Casey ; with illustrations by Joey Leone.

Philadelphia : University of Pennsylvania Press, [2023]




no

Over nine crore voters to decide Maha's fate on Nov 20




no

Prioritise celebrating Diwali with lights to avoid noise and air pollution: BMC issues new guidelines for firecracker use during festivities




no

Nov 20 Maharashtra election: 4,140 candidates in fray; 2,938 withdraw nominations




no

High-tech snooping: Maha hoteliers say privacy of customers, celebs at risk




no

Morning Digest: NSCN-IM threatens armed violence for first time since 2015 agreement; Article 370 cannot be restored by anyone, says PM Modi, and more

Here is a select list of stories to start the day




no

Harmanpreet, Sreejesh bag top honours at FIH Star Awards

Indian captain Harmanpreet Singh led the scoring charts at the Paris Olympics with 10 goals; Sreejesh brought the curtains down on his career at the highest level, putting together an incredible Olympic campaign




no

ICC Champions Trophy: Team India not to play in Pakistan, declares BCCI

BCCI decision comes despite Pakistan Cricket Board offering special security arrangements, choice of venue; India favours having its matches outside Pakistan under hybrid model




no

Hour-mark goals see hosts Chennaiyin FC and Mumbai City FC share the honours

Chennaiyin captain Ryan Edwards scored the opening goal in the 60th minute, while Nathan Asher Rodrigues grabbed Mumbai’s equaliser in the 63rd




no

Gukesh smart enough not to take favourite tag seriously: Vishnu

So much so, even his opponent, reigning World champion Ding Liren, has talked up Gukesh, downplaying himself




no

With nothing to lose, India will be a dangerous side now, says Ajay Jadeja

Ajay Jadeja, emphasising India’s edge, said: “We may not reach the World Test Championship final, but I believe we can secure the series win.




no

Morning Digest: Unidentified terrorist killed in encounter in J&K’s Sopore; Biden, Trump to meet in the White House on November 13, and more

Here is a select list of stories to start the day




no

Bruno Fernandes scores brilliant goal in landmark game for Man United against Leicester

Bruno Fernandes has scored 84 goals in all competitions since joining United from Sporting Lisbon in 2020




no

Benjamin Bonzi fells Norrie in Metz for first ATP title

The 28-year-old Benjamin Bonzi had climbed to number 42 in the world in 2023 as he reached two ATP finals, but had not won a match in the main draw of an ATP event this year




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Ponting should be concerned about Australian cricket, not India's: Gautam Gambhir

Gambhir defends Kohli against Ponting’s criticism, emphasising confidence in Indian batters ahead of Australia series




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Bumrah to lead, Rahul likely to open in Perth if Rohit does not make it, says Gautam Gambhir

The second batch of the Indian players is leaving for Perth, but Rohit has stayed back. Uncertainty remains if Rohit will compete in the series-opener.