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Phase separation driven by production of architectural RNA transcripts

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/C9SM02458A, Paper
Tetsuya Yamamoto, Tomohiro Yamazaki, Tetsuro Hirose
We here use an extension of the Flory-Huggins theory to predict that the phase separation is driven by the production of architectural RNA (arcRNA) at a DNA locus with a...
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Proving and interpreting the spontaneous formation of bulk nanobubbles in aqueous organic solvent solutions: effects of solvent type and content

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00111B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ananda J. Jadhav, Mostafa Barigou
We show that the mixing of organic solvents with pure water leads to the spontaneous formation of bulk nanobubbles which exhibit long-term stability on the scale of months.
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Evaporation-induced alignment of nanorods in a thin film

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00482K, Paper
Narina Jung, Byung Mook Weon, Masao Doi
During solvent evaporation of a thin film, Brownian rod-shaped particles self-assemble into microstructures and their orientation arrangements change while their volume fractions increase. We study the phenomena using a simple...
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Diffusive transport of nanoscale objects through cell membranes: a computational perspective

Soft Matter, 2020, 16,3869-3881
DOI: 10.1039/C9SM02338K, Perspective
Ziyang Xu, Lijuan Gao, Pengyu Chen, Li-Tang Yan
Clarifying the diffusion dynamics of nanoscale objects with cell membrane is critical for revealing fundamental physics in biological systems. This perspective highlights the advances in computational and theoretical aspects of this emerging field.
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Structure and tensile properties of the forewing costal vein of the honeybee Apis mellifera

Soft Matter, 2020, 16,4057-4064
DOI: 10.1039/C9SM02364J, Paper
Yun Ma, Tianbao Ma, Jianguo Ning, Stanislav Gorb
Our paper reveals the functional morphology and tensile properties of the forewing costal vein of honeybees, reviews studies on wings and discusses outlooks for future research.
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Template-based fabrication of spatially organized 3D bioactive constructs using magnetic low-concentration gelation methacrylate (GelMA) microfibers

Soft Matter, 2020, 16,3902-3913
DOI: 10.1039/C9SM01945F, Paper
Tao Sun, Yibing Yao, Qing Shi, Huaping Wang, Paolo Dario, Junzhong Sun, Qiang Huang, Toshio Fukuda
A new template-based method to apply low-concentration GelMA microfibers as building blocks for higher-order cellular assembly.
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Role of molecular bend angle and biaxiality in the stabilization of the twist-bend nematic phase

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00078G, Communication
Wojciech Tomczyk, Lech Longa
Within mean-field theory for V-shaped molecules, we have investigated how the alteration of a molecule's structural features influence the stabilization of modulated and non-modulated nematic phases.
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Effects of sodium chloride on rheological behaviour of the gemini-like surfactants

Soft Matter, 2020, 16,4024-4031
DOI: 10.1039/D0SM00243G, Paper
Xinxin Li, Pengxiang Wang, Xiaoyu Hou, Fang Wang, Han Zhao, Bobo Zhou, Hongwen Zhang, Hongbin Yang, Wanli Kang
Effects of NaCl on the rheological behaviour of the gemini-like surfactants and the mechanism of the effects were investigated.
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Observation of transition cascades in sheared liquid crystalline polymers

Soft Matter, 2020, 16,3891-3901
DOI: 10.1039/D0SM00275E, Paper
Ryan J. Fox, M. Gregory Forest, Stephen J. Picken, Theo J. Dingemans
We observe anomalous shear thickening behavior of a lyotropic liquid crystalline polymer due to the dynamics of the nematic director.
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Surface buckling delamination patterns of film on soft spherical substrates

Soft Matter, 2020, 16,3952-3961
DOI: 10.1039/D0SM00122H, Paper
Kanako Emori, Yusaku Saito, Akio Yonezu, Liangliang Zhu, Xiangbiao Liao, Xi Chen
The morphological transition of film buckling-delamination in an elastomeric bilayer spherical shell system was studied experimentally and numerically. It was changed by the film thickness, Young's modulus, and interfacial adhesion condition, etc.
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Melting scenarios of two-dimensional Hertzian spheres with a single triangular lattice

Soft Matter, 2020, 16,3962-3972
DOI: 10.1039/C9SM02262G, Paper
E. N. Tsiok, E. A. Gaiduk, Yu. D. Fomin, V. N. Ryzhov
We present a molecular dynamics simulation study of the phase diagram and melting scenarios of two-dimensional Hertzian spheres with exponent 7/2.
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How clay particulates affect flow cessation and the coiling stability of yield stress-matched cementing suspensions

Soft Matter, 2020, 16,3929-3940
DOI: 10.1039/C9SM02414J, Paper
Iman Mehdipour, Hakan Atahan, Narayanan Neithalath, Mathieu Bauchy, Edward Garboczi, Gaurav Sant
Transition from closely-packed to fractally-architected structures with clay addition improves homogeneity and prevents local dewatering, thus enhancing coiling stability of layer-wise extruded cementing suspensions during 3D-printing.
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Gait-optimized locomotion of wave-driven soft sheets

Soft Matter, 2020, 16,3991-3999
DOI: 10.1039/C9SM02103E, Paper
Open Access
Pearson W. Miller, Jörn Dunkel
Inspired by the robust locomotion of limbless animals, the development of soft robots capable of moving by localized swelling, bending, and other deformation modes has become a target for soft matter research over the last decade.
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Rotation of a submerged finite cylinder moving down a soft incline

Soft Matter, 2020, 16,4000-4007
DOI: 10.1039/C9SM02344E, Paper
Baudouin Saintyves, Bhargav Rallabandi, Theo Jules, Jesse Ault, Thomas Salez, Clarissa Schönecker, Howard A. Stone, L. Mahadevan
A fluid-immersed solid cylinder moves along a soft incline and rotates at a rate that depends on its aspect ratio and the stiffness of the incline.
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Normal and shear forces between boundary sphingomyelin layers under aqueous conditions

Soft Matter, 2020, 16,3973-3980
DOI: 10.1039/D0SM00215A, Paper
Yifeng Cao, Nir Kampf, Weifeng Lin, Jacob Klein
Sphingomyelin boundary layers can maintain extremely low friction under high pressures both in water and at high salt concentration.
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Inverse leidenfrost drop manipulation using menisci

Soft Matter, 2020, 16,4043-4048
DOI: 10.1039/C9SM02363A, Paper
Anaïs Gauthier, Guillaume Lajoinie, Jacco H. Snoeijer, Devaraj van der Meer
The motion of droplets levitated above a liquid surface is controlled using the menisci rising against partially immersed walls.
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Structural properties of contractile gels based on light-driven molecular motors: a small-angle neutron and X-ray study

Soft Matter, 2020, 16,4008-4023
DOI: 10.1039/D0SM00031K, Paper
Giacomo Mariani, Jean-Rémy Colard-Itté, Emilie Moulin, Nicolas Giuseppone, Eric Buhler
The collective rotation of light-driven molecular motors actuates the structural changes and macroscopic contraction of the chemical gels.
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Bi-continuous orthorhombic soft matter phase made of polycatenar molecules

Soft Matter, 2020, 16,3882-3885
DOI: 10.1039/D0SM00331J, Communication
Joanna Matraszek, Damian Pociecha, Nataša Vaupotič, Mirosław Salamończyk, Martin Vogrin, Ewa Gorecka
A slight deformation of a double gyroid structure of a cubic Iād phase results in the formation of a phase with an orthorhombic Pcab symmetry. The phase seems to be an intermediate state towards a columnar phase made of helical pillars.
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Detachment work of prolate spheroidal particles from fluid droplets: role of viscous dissipation

Soft Matter, 2020, 16,4049-4056
DOI: 10.1039/C9SM02385B, Paper
Sergey V. Lishchuk, Rammile Ettelaie
The minimum possible work done upon removal of an elongated solid particle from the surface of a liquid droplet can be less than that for a sphere.
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Correction: Preparation of electrospray ALG/PDA–PVP nanocomposites and their application in cancer therapy

Soft Matter, 2020, 16,4074-4074
DOI: 10.1039/D0SM90064H, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yangjie Xu, Jiulong Zhao, Zhilun Zhang, Jing Zhang, Mingxian Huang, Shige Wang, Pei Xie
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Uniform conductivity in stretchable silicones via multiphase inclusions

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00383B, Paper
R. Adam Bilodeau, Amir Mohammadi Nasab, Dylan S. Shah, Rebecca Kramer-Bottiglio
A thin, stretchable (200% linear strain), multiphase (solid–liquid) silicone composite with uniform electrical conductivity, for Joule heating and high-deformation sensing.
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Modeling atomic force microscopy and shell mechanical properties estimation of coated microbubbles

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00300J, Paper
Alkmini Lytra, Vassilis Sboros, Antonios Giannakopoulos, Nikos Pelekasis
We present an extensive comparison with experimental data of our theoretical/numerical model for the static response of coated microbubbles (MBs) subject to compression from an atomic force microscope (afm). The...
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Assessing the Extent of Structural and Dynamic Modulation of Membrane Lipids due to Pore Forming Toxins: Insights from Molecular Dynamics Simulations

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00086H, Paper
Vadhana Varadarajan, Rajat Desikan, Ganapathy Ayappa
Infections in many virulent bacterial strains are triggered by the release of pore forming toxins (PFTs), which form oligomeric transmembrane pore complexes on the target plasma membrane. The spatial extent...
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Marangoni puffs: dramatically enhanced dissolution of droplets with an entrapped bubble

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00093K, Paper
José M. Encarnación Escobar, Jaap Nieland, Arie van Houselt, Xuehua Zhang, Detlef Lohse
We present a curious effect observed during the dissolution process of water-immersed long-chain alcohol drops with an entrapped bubble. When the drop-water interface and the air bubble contact each other, a rapid cyclic motion that accelerates the drop's dissolution is found. We name this eye-catching phenomenon puffing.
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Quantifying the non-equilibrium activity of an active colloid

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00398K, Paper
Sarah Eldeen, Ryan Muoio, Paris Blaisdell-Pijuan, Ngoc La, Mauricio Gomez, Alex Vidal, Wylie Ahmed
Active matter systems exhibit rich emergent behavior due to constant injection and dissipation of energy at the level of individual agents. We characterize the dissipation of single active colloids.
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Impact of wormlike micelles on nano and macroscopic structure of TEMPO-oxidized cellulose nanofibrils hydrogels

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00135J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marcelo A. da Silva, Vincenzo Calabrese, Julien Schmitt, Kazi M. Zakir Hossain, Saffron J Bryant, Najet Mahmoudi, Janet L Scott, Karen J Edler
In this work, we investigated the effect of adding surfactant mixtures on the rheological properties of TEMPO-oxidized cellulose nanofibrils (OCNF) saline dispersions. Three surfactant mixtures were studied: cocamidopropyl betaine (CAPB)/sodium...
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Bioactive scaffolds based on collagen filaments with tunable physico-chemical and biological features

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00233J, Paper
Ting Lu, Hong Hu, Yuanqi Li, Qingsong Jiang, Jinlei Su, Hai Lin, Yun Xiao, Xiangdong Zhu, Xingdong Zhang
Native tissues such as nerve bundles, blood vessels and tendons have extracellular matrices with a characteristic linear orientation, which cannot be fully achieved with the current technology for the development of regenerative biomaterials.
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Formation of Fibrillar Crystals Strongly Accelerates the Form II to I Transformation of Polybutene-1

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00572J, Paper
Jiaqi Zhang, Chang Liu, Xintong Zhao, Zhijie Zhang, Quan Chen
This study examines shear-induced formation of fibrillar form II crystals and subsequent form II to I transformation of an isotactic polybutene-1 sample through a combination of rheology, polarized optical microscope...
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Irreversible adsorption of polymer melts and nanoconfinement effects

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00361A, Review Article
Simone Napolitano
Since almost a decade, a growing experimental evidence has revealed a strong correlation between the properties of nanoconfined polymers and the number of chains irreversibly adsorbed onto nonrepulsive interfaces, e.g....
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Different-shaped micro-objects driven by active particle aggregations

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00160K, Paper
Chen Wang, Hongyuan Jiang
We study the dynamics of passive micro-objects in the active bath. The motion of micro-objects depends on the pattern of active particle aggregations.
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Liposomal adhesion via electrostatic interactions and osmotic deflation increase membrane tension and lipid diffusion coefficient

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00416B, Paper
Atsushi Oda, Chiho Watanabe, Natsumi Aoki, Miho Yanagisawa
Liposome–liposome adhesion by electrostatic interactions and osmotic contraction increase membrane tension and the lipid diffusion coefficient compared to isolated liposomes.
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Investigating the Role of Carbon Nanotubes (CNTs) in Piezoelectric Performance of PVDF/KNN based Flexible Electrospun Nanogenerator

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00438C, Paper
Satyaranjan Bairagi, Wazed Ali
In the present study, the effect of varying concentrations of carbon nanotube (CNT) on the piezoelectric performance of poly (vinylidene fluoride) (PVDF)/potassium sodium niobate (KNN) based electrospun nanocomposite has been...
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Color, Structure, and Rheology of a Diblock Bottlebrush Copolymer Solution

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00397B, Paper
Matthew A Wade, Dylan J Walsh, Ching-Wei Johnny Lee, Elizabeth G. Kelley, Katie Weigandt, Damien Guironnet, Simon A Rogers
A structure-property-process relation is established for a diblock bottlebrush copolymer solution, through a combination of rheo-neutron scattering, imaging, and rheological measurements. Polylactic acid-b-polystyrene diblock bottlebrush copolymers were dispersed in toluene...
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Developing Super Tough Gelatin-based Hydrogels by Incorporating Linear Poly(methacrylic Acid) to Facilitate Sacrificial Hydrogen Bonding

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00422G, Communication
Hui Jie Zhang, Li Ni Wang, Xuechuan Wang, Qingxin Han, Xiangyou You
Mechanically robust protein-based hydrogels are strongly desired but their construction remains a significant challenge. In this work, gelatin, together with methacrylic acid, is used to construct a novel hydrogen-bonded hydrogel...
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Classical and Non-Classical Melatonin Receptor Agonist-Directed Micellization of Bipyridinium-Based Supramolecular Amphiphiles in Water

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00424C, Paper
Zhimin Sun, Lihui Xi, Kai Zheng, Zhao Zhang, Kim Baldridge, Mark Anthony Olson
The addition of molecular recognition units into structures of amphiphiles is a means by which soft matter capable of undergoing template-directed micellization can be obtained. These supramolecular amphiphiles can bind...
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Polymorphism of asymmetric catalysts based on amphiphilic lipopeptides in solution

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00245C, Paper
Juliane N. B. D. Pelin, Charlotte J. C. Edwards-Gayle, Andrea M. Aguilar, Amanpreet Kaur, Ian W. Hamley, Wendel A. Alves
The self-assembly of model [P]RWG lipopeptides (P: L-proline, R: L-arginine, W: L-tryptophan, G: L-glycine), containing one or two aliphatic octadecyl (C18) chains in water and cyclohexanone/water solutions was examined. The enantiomeric selectivity was found to be related to the assembly of catalyst molecules.
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On the pressure dependence of the thermodynamical scaling exponent γ

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00254B, Paper
R. Casalini, T. C. Ransom
In materials with a constant scaling parameter γS, the Isomorph γI is found to vary with pressure, demonstrating γSγI.
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Binary mixtures of active and passive particles on a sphere

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00281J, Communication
Bao-quan Ai, Bu-yun Zhou, Xiao-miao Zhang
According to the competition between rotational diffusion and polar alignment, we find three distinct phases: a mixed phase and two different demixed phases.
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Effect of polar amino acid incorporation on Fmoc-diphenylalanine-based tetrapeptides

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00320D, Paper
Alexandra Daryl Ariawan, Biyun Sun, Jonathan Pawel Wojciechowski, Ian Lin, Eric Y Du, Sophia C Goodchild, Charles Gordon Cranfield, Lars M Ittner, Pall Thordarson, Adam David Martin
Peptide hydrogels show great promise as extracellular matrix mimics due to their tuneable, fibrous nature. Through incorporation of polar cationic, polar anionic or polar neutral amino acids into the Fmoc-diphenylalanine...
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Effects of Eigen and Actual Frequencies of Soft Elastic Surfaces on droplet Rebound from Stationary Flexible Feather Vanes

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00315H, Paper
Chengchun Zhang, Zhengyang Wu, Chun Shen, Yihua Zheng, LIANG YANG, Yan Liu, Luquan Ren
The aim of this paper is to investigate the effect of eigenfrequency and the actual frequency of the elastic surface for the droplet rebound. The elastic surface used in this...
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