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First-principles calculations of electronic structure and optical and elastic properties of the novel ABX3-type LaWN3 perovskite structure

RSC Adv., 2020, 10,17317-17326
DOI: 10.1039/C9RA10735E, Paper
Open Access
Xing Liu, Jia Fu, Guangming Chen
Using first-principles calculation, the stable R3c LaWN3 as a new ABX3-type advanced perovskite structure is designed in the plan of the material genome initiative (MGI), which helps to widen the nowadays nitride perovskite material's application.
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Deposition of an ultra-thin polyaniline coating on a TiO2 surface by vapor phase polymerization for electrochemical glucose sensing and photocatalytic degradation

RSC Adv., 2020, 10,17387-17395
DOI: 10.1039/D0RA01571G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sibani Majumdar, Debajyoti Mahanta
Here, we have synthesized an ultra-thin coating of polyaniline on a TiO2 nanoparticle surface (PANI–TiO2) using a simple vapor phase polymerization method.
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One pot fabrication of fluorescein functionalized manganese dioxide for fluorescence “Turn OFF–ON” sensing of hydrogen peroxide in water and cosmetic samples

RSC Adv., 2020, 10,17506-17514
DOI: 10.1039/D0RA01980A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hassan Refat H. Ali, Ahmed I. Hassan, Yasser F. Hassan, Mohamed M. El-Wekil
The fluorometric nanoprobe was fabricated via doping of fluorescein dye in MnO2 nanosheets (FLS/MnO2 NS) via facile co-precipitation method. It was used for analysis of H2O2 in different matrices through liberation of FLS after reduction of MnO2 NS.
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Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes

RSC Adv., 2020, 10,17404-17407
DOI: 10.1039/D0RA03536J, Paper
Open Access
Yi Chen, Liqing Ai, Yongming Li, Caihong Xu
A borohydride catalyzed Si–H/Si–Cl redistribution system was established to prepare hydrochlorosilanes facilely and efficiently.
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Synthesis and gas permeation properties of thermally rearranged poly(ether-benzoxazole)s with low rearrangement temperatures

RSC Adv., 2020, 10,17461-17472
DOI: 10.1039/D0RA00145G, Paper
Open Access
Yunhua Lu, Jianhua Zhang, Guoyong Xiao, Lin Li, Mengjie Hou, Junyi Hu, Tonghua Wang
A series of poly(ether-benzoxazole)(PEBO) for gas separation were prepared from 9,9-bis[4-(4-amino-3-hydroxylphenoxy)phenyl]fluorene based hydroxyl-containing poly(ether-imide)s (HPEIs) with low rearrangement temperatures.
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A dopamine electrochemical sensor based on a platinum–silver graphene nanocomposite modified electrode

RSC Adv., 2020, 10,17336-17344
DOI: 10.1039/C9RA11056A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nadzirah Sofia Anuar, Wan Jeffrey Basirun, Md. Shalauddin, Shamima Akhter
A platinum–silver graphene nanocomposite was synthesized and characterized. A nanocomposite modified electrode was fabricated in order to investigate the electrochemical detection of dopamine.
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The influence of structural gradients in large pore organosilica materials on the capabilities for hosting cellular communities

RSC Adv., 2020, 10,17327-17335
DOI: 10.1039/D0RA00927J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hannah Bronner, Anna-Katharina Holzer, Alexander Finke, Marius Kunkel, Andreas Marx, Marcel Leist, Sebastian Polarz
Chemical and structural gradients in biofunctionalized organosilica–polymer nanocomposites control cell adhesion properties and open perspectives for artificial cellular community systems.
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Development of novel N-(6-methanesulfonyl-benzothiazol-2-yl)-3-(4-substituted-piperazin-1-yl)-propionamides with cholinesterase inhibition, anti-β-amyloid aggregation, neuroprotection and cognition enhancing properties for the therapy of Alzheimer's d

RSC Adv., 2020, 10,17602-17619
DOI: 10.1039/D0RA00663G, Paper
Open Access
Chandra Bhushan Mishra, Shruti Shalini, Siddharth Gusain, Amresh Prakash, Jyoti Kumari, Shikha Kumari, Anita Kumari Yadav, Andrew M. Lynn, Manisha Tiwari
A novel series of benzothiazole–piperazine hybrids were rationally designed, synthesized, and evaluated as multifunctional ligands against Alzheimer's disease (AD).
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Enhanced thermal stability, hydrophobicity, UV radiation resistance, and antibacterial properties of wool fabric treated with p-aminobenzenesulphonic acid

RSC Adv., 2020, 10,17515-17523
DOI: 10.1039/D0RA02267E, Paper
Open Access
Mohammad Mahbubul Hassan
The treatment with para-aminobenzenesulphonic acid produced a multifunctional wool fabric with enhanced hydrophobicity, thermal stability, UV resistance, and antibacterial properties.
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Polypyrrole modified magnetic reduced graphene oxide composites: synthesis, characterization and application for selective lead adsorption

RSC Adv., 2020, 10,17524-17533
DOI: 10.1039/D0RA01546F, Paper
Open Access
Zhanmeng Liu, Zhimin Gao, Lichun Xu, Fengping Hu
Compared to Fe3O4/rGO, the PPy-FG composites showed desirable adsorption capacity and selectivity for Pb(II) from water.
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Elimination of humic acid in water: comparison of UV/PDS and UV/PMS

RSC Adv., 2020, 10,17627-17634
DOI: 10.1039/D0RA01787F, Paper
Open Access
Shoufeng Tang, Jiachen Tang, Deling Yuan, Zetao Wang, Yating Zhang, Yandi Rao
In this work, UV-activated persulphate treatment (UV/PDS and UV/PMS) was found to be an effective method for HA removal.
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Selective modification of Ti6Al4V surfaces for biomedical applications

RSC Adv., 2020, 10,17642-17652
DOI: 10.1039/C9RA11000C, Paper
Open Access
Gabriela Melo Rodriguez, James Bowen, Mischa Zelzer, Artemis Stamboulis
The surface of a medical implant is required to interact favourably with ions, biomolecules and cells in vivo, commonly resulting in the formation of the extracellular matrix.
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Cobalt–carbon/silica nanocomposites prepared by pyrolysis of a cobalt 2,2'-bipyridine terephthalate complex for remediation of cationic dyes

RSC Adv., 2020, 10,17660-17672
DOI: 10.1039/D0RA02752A, Paper
Open Access
Nusaybah Alotaibi, Hassan H. Hammud, Ranjith Kumar Karnati, Syed Ghazanfar Hussain, Javed Mazher, Thirumurugan Prakasam
A cobalt–carbon@silica nanocomposite was synthesized from a cobalt 2,2'-bipyridine terephthalate complex and its adsorption behavior towards crystal violet dye was tested using batch and column techniques.
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Ultrathin δ-MnO2 nanoflakes with Na+ intercalation as a high-capacity cathode for aqueous zinc-ion batteries

RSC Adv., 2020, 10,17702-17712
DOI: 10.1039/D0RA02556A, Paper
Open Access
Haijun Peng, Huiqing Fan, Chenhui Yang, Yapeng Tian, Chao Wang, Jianan Sui
Sodium-ion intercalated δ-MnO2 nanoflakes are applied in an aqueous rechargeable zinc battery cathode with high energy density and excellent durable stability.
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A facile method for preparing Yb3+-doped perovskite nanocrystals with ultra-stable near-infrared light emission

RSC Adv., 2020, 10,17635-17641
DOI: 10.1039/D0RA01897J, Paper
Open Access
Chunqian Zhang, Aidi Zhang, Taoran Liu, Lin Zhou, Jun Zheng, Yuhua Zuo, Yongqi He, Juhao Li
A facile method for fabricating CsPbBr3:Yb3+@SiO2 NCs which guarantees high PLQY and excellent stability at the same time.
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Dip-coating decoration of Ag2O nanoparticles on SnO2 nanowires for high-performance H2S gas sensors

RSC Adv., 2020, 10,17713-17723
DOI: 10.1039/D0RA02266G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tran Thi Ngoc Hoa, Nguyen Van Duy, Chu Manh Hung, Nguyen Van Hieu, Ho Huu Hau, Nguyen Duc Hoa
Ag2O nanoparticles decorated on the surface of on-chip growth SnO2 nanowires by a dip-coating method possessed excellent sensing performance for H2S gas.
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Correction: Role of polysilicon in poly-Si/SiOx passivating contacts for high-efficiency silicon solar cells

RSC Adv., 2020, 10,17571-17571
DOI: 10.1039/D0RA90049D, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
HyunJung Park, Soohyun Bae, Se Jin Park, Ji Yeon Hyun, Chang Hyun Lee, Dongjin Choi, Dongkyun Kang, Hyebin Han, Yoonmook Kang, Hae-Seok Lee, Donghwan Kim
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Correction: Synthesis of α,β-unsaturated esters of perfluoropolyalkylethers (PFPAEs) based on hexafluoropropylene oxide units for photopolymerization

RSC Adv., 2020, 10,17416-17417
DOI: 10.1039/D0RA90036B, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Céline Bonneaud, Mélanie Decostanzi, Julia Burgess, Giuseppe Trusiano, Trevor Burgess, Roberta Bongiovanni, Christine Joly-Duhamel, Chadron M. Friesen
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Effect of temperature and large guest molecules on the C–H symmetric stretching vibrational frequencies of methane in structure H and I clathrate hydrates

RSC Adv., 2020, 10,17473-17478
DOI: 10.1039/D0RA02748K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Go Fuseya, Satoshi Takeya, Akihiro Hachikubo
Temperature effect on C–H symmetric stretching frequencies of CH4 in water cages of sI and sH clathrate hydrates were clarified.
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One-pot oxime ligation from peptides bearing thiazolidine and aminooxyacetyl groups

RSC Adv., 2020, 10,17681-17685
DOI: 10.1039/D0RA03235B, Paper
Open Access
Stéphane Duflocq, Jingjing Zhou, Florent Huguenot, Michel Vidal, Wang-Qing Liu
Pd(II), acidic hydrolysis and iodine lead to one-pot oxime ligation from peptides bearing thiazolidine and aminooxyacetyl groups.
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Position-locking of volatile reaction products by atmosphere and capping layers slows down photodecomposition of methylammonium lead triiodide perovskite

RSC Adv., 2020, 10,17534-17542
DOI: 10.1039/D0RA03572F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fengshuo Zu, Thorsten Schultz, Christian M. Wolff, Dongguen Shin, Lennart Frohloff, Dieter Neher, Patrick Amsalem, Norbert Koch
Gas pressure and capping layers under ultrahigh vacuum prevent methylammonium lead triiodide photo-degradation due to efficient back-reaction of volatile compounds.
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The synergistic influence of polyethyleneimine-grafted graphene oxide and iodide for the protection of steel in acidizing conditions

RSC Adv., 2020, 10,17739-17751
DOI: 10.1039/D0RA00864H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
K. R. Ansari, Dheeraj Singh Chauhan, M. A. Quraishi, A. Y. Adesina, Tawfik A. Saleh
Herein, graphene oxide (GO) was chemically functionalized with polyethyleneimine (PEI) in a single step to obtain PEI-GO, which was characterized via FTIR spectroscopy, SEM, and TEM.
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Boosting performances of triboelectric nanogenerators by optimizing dielectric properties and thickness of electrification layer

RSC Adv., 2020, 10,17752-17759
DOI: 10.1039/D0RA02181D, Paper
Open Access
Xiaofang Kang, Chongxiang Pan, Yanghui Chen, Xiong Pu
Enhanced output performances of a triboelectric nanogenerator (TENG) are achieved by optimizing the high-dielectric-constant filler content in the electrification layer and decreasing its thickness.
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Work function modification of PEDOT:PSS by mixing with barium acetylacetonate

RSC Adv., 2020, 10,17673-17680
DOI: 10.1039/D0RA02575E, Paper
Open Access
K. L. Woon, W. S. Wong, N. Chanlek, H. Nakajima, S. Tunmee, V. S. Lee, A. Ariffin, P. Songsiriritthigul
Modification of poly(3,4-ethylenedioxythiophene)polystyrene sulfonate as electron injection layer.
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Enhancing the performance of LARP-synthesized CsPbBr3 nanocrystal LEDs by employing a dual hole injection layer

RSC Adv., 2020, 10,17653-17659
DOI: 10.1039/D0RA02622K, Paper
Open Access
Dingyan Xu, Qun Wan, Siyao Wu, Yu Zhao, Xinglei Xu, Liang Li, Gufeng He
The current and power efficiencies of CsPbBr3 NC LEDs are improved 1.5 and 1.8 times by employing a dual HAT-CN/MoO3 hole injection layer.
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Elongated conductive structures in detonation soot of high explosives

RSC Adv., 2020, 10,17620-17626
DOI: 10.1039/D0RA01393E, Paper
Open Access
Nataliya P. Satonkina, Alexander P. Ershov, Alexey O. Kashkarov, Ivan A. Rubtsov
Micrographs of transmission electron microscopy of saved detonation products of benzotrifuroxane at different scales.
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A novel series of phenolic temozolomide (TMZ) esters with 4 to 5-fold increased potency, compared to TMZ, against glioma cells irrespective of MGMT expression

RSC Adv., 2020, 10,17561-17570
DOI: 10.1039/D0RA02686G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Leroy Shervington, Oliver Ingham, Amal Shervington
The standard of care treatment for patients diagnosed with glioblastoma multiforme (GBM) is temozolomide (TMZ).
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A highly sensitive, selective and renewable carbon paste electrode based on a unique acyclic diamide ionophore for the potentiometric determination of lead ions in polluted water samples

RSC Adv., 2020, 10,17552-17560
DOI: 10.1039/D0RA01435D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. A. Zayed, Walaa H. Mahmoud, Ashraf A. Abbas, Aya E. Ali, Gehad G. Mohamed
Due to the toxicity of lead(II) to all living organisms destroying the central nervous system and leading to circulatory system and brain disorders, the development of effective and selective lead(II) ionophores for its detection is very important.
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Electrochemical reduction of CO2 to ethylene on Cu/CuxO-GO composites in aqueous solution

RSC Adv., 2020, 10,17572-17581
DOI: 10.1039/D0RA02754E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nusrat Rashid, Mohsin Ahmad Bhat, U. K. Goutam, Pravin Popinand Ingole
Herein, we present fabrication of graphene oxide supported Cu/CuxO nano-electrodeposits which efficiently and selectively can electroreduce CO2 into ethylene with a faradaic efficiency of 34% and conversion rate of 194 mmol g−1 h−1 at −0.985 V vs. RHE.
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Correction: Influence of co-cultures of Streptococcus thermophilus and probiotic lactobacilli on quality and antioxidant capacity parameters of lactose-free fermented dairy beverages containing Syzygium cumini (L.) Skeels pulp

RSC Adv., 2020, 10,16905-16905
DOI: 10.1039/D0RA90046J, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sabrina Laís Alves Garcia, Gabriel Monteiro da Silva, Juliana Maria Svendsen Medeiros, Anna Paula Rocha de Queiroga, Blenda Brito de Queiroz, Daniely Rayane Bezerra de Farias, Joyceana Oliveira Correia, Eliane Rolim Florentino, Flávia Carolina Alonso Buriti
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A poly(allylamine hydrochloride)/poly(styrene sulfonate) microcapsule-coated cotton fabric for stimulus-responsive textiles

RSC Adv., 2020, 10,17731-17738
DOI: 10.1039/D0RA02474K, Paper
Open Access
Zhiqi Zhao, Qiujin Li, Jixian Gong, Zheng Li, Jianfei Zhang
This study reports a stimulus-responsive fabric incorporating a combination of microcapsules, containing polyelectrolytes poly(allylamine hydrochloride) (PAH) and poly(styrene sulfonate) sodium salt (PSS), formed via a layer-by-layer (LBL) approach.
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Computational study on the polymerization reaction of D-aminopeptidase for the synthesis of D-peptides

RSC Adv., 2020, 10,17582-17592
DOI: 10.1039/D0RA01138J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Joan Gimenez-Dejoz, Kousuke Tsuchiya, Ayaka Tateishi, Yoko Motoda, Takanori Kigawa, Yasuhisa Asano, Keiji Numata
We studied the molecular mechanism of D-aminopeptidase for the synthesis of polypeptides incorporating D-amino acids.
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Preparation of phosphorus-doped porous carbon for high performance supercapacitors by one-step carbonization

RSC Adv., 2020, 10,17768-17776
DOI: 10.1039/D0RA02398A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Guanfeng Lin, Qiong Wang, Xuan Yang, Zhenghan Cai, Yongzhi Xiong, Biao Huang
P-doped porous carbon can be prepared by one-step carbonization using biomass sawdust impregnated with a small amount of phosphoric acid.
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Dependence on co-adsorbed water in the reforming reaction of ethanol on a Rh(111) surface

RSC Adv., 2020, 10,17787-17794
DOI: 10.1039/D0RA02015J, Paper
Open Access
Yu-Yao Hsia, Po-Cheng Chien, Lu-Hsin Lee, Yu-Ling Lai, Li-Chung Yu, Yao-Jane Hsu, Jeng-Han Wang, Meng-Fan Luo
Adsorbed ethanol molecules penetrated readily through pre-adsorbed water to react at the Rh surface; they decomposed at a promoted probability.
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Ni stabilized rock-salt structured CoO; Co1−xNixO: tuning of eg electrons to develop a novel OER catalyst

RSC Adv., 2020, 10,17845-17853
DOI: 10.1039/D0RA03050C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rakesh Mondal, Himanshu Ratnawat, Sarvesh Kumar, Anil Kumar, Preetam Singh
Incorporation of Ni into CoO lattices helps to stabilize the rock salt structure and modulate the eg electrons to develop superior OER and ORR electrocatalysts.
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Effect of Zn doping on phase transition and electronic structures of Heusler-type Pd2Cr-based alloys: from normal to all-d-metal Heusler

RSC Adv., 2020, 10,17829-17835
DOI: 10.1039/D0RA02951C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiaotian Wang, Mengxin Wu, Tie Yang, Rabah Khenata
By first-principles calculations, for Heusler alloys Pd2CrZ (Z = Al, Ga, In, Tl, Si, Sn, P, As, Sb, Bi, Se, Te, Zn), the effect of Zn doping on their phase transition and electronic structure has been studied in this work.
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Microwave roasting of blast furnace slag for carbon dioxide mineralization and energy analysis

RSC Adv., 2020, 10,17836-17844
DOI: 10.1039/D0RA02846K, Paper
Open Access
Zike Han, Jianqiu Gao, Xizhi Yuan, Yanjun Zhong, Xiaodong Ma, Zhiyuan Chen, Dongmei Luo, Ye Wang
This paper highlights the potential of microwave roasting in solid-waste treatment and carbon dioxide storage.
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Enhanced methane gas storage in the form of hydrates: role of the confined water molecules in silica powders

RSC Adv., 2020, 10,17795-17804
DOI: 10.1039/D0RA01754J, Paper
Open Access
Pinnelli S. R. Prasad, Burla Sai Kiran, Kandadai Sowjanya
Rapid and efficient methane hydrate conversions by utilising the water molecules confined in intra- and inter-granular space of silica powders.
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Synthesis, characterization and corrosion inhibition behavior of 2-aminofluorene bis-Schiff bases in circulating cooling water

RSC Adv., 2020, 10,17816-17828
DOI: 10.1039/D0RA01903H, Paper
Open Access
Wenchang Wei, Zheng Liu, Chuxin Liang, Guo-Cheng Han, Jiaxing Han, Shufen Zhang
Two new bis-Schiff bases, namely 2-bromoisophthalaldehyde-2-aminofluorene (M1) and glutaraldehyde 2-aminofluorene (M2) were synthesized and were characterized, the potentiodynamic polarization curve confirmed that they were anode type inhibitors.
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Facile synthesis of a direct Z-scheme BiOCl–phosphotungstic acid heterojunction for the improved photodegradation of tetracycline

RSC Adv., 2020, 10,17369-17376
DOI: 10.1039/D0RA02396E, Paper
Open Access
Haijuan Tong, Bingfang Shi, Shulin Zhao
A one-step hydrothermal approach for synthesizing BiOCl–phosphotungstic acid (BiOCl–HPW) heterojunctions is proposed. The prepared BiOCl–HPW heterojunction exhibited good stability and photocatalytic activity.
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Correction: Narrowing band gap and enhanced visible-light absorption of metal-doped non-toxic CsSnCl3 metal halides for potential optoelectronic applications

RSC Adv., 2020, 10,17869-17869
DOI: 10.1039/D0RA90054K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakiul Islam, A. K. M. Akther Hossain
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Effect of new carbonyl cyanide aromatic hydrazones on biofilm inhibition against methicillin resistant Staphylococcus aureus

RSC Adv., 2020, 10,17854-17861
DOI: 10.1039/D0RA03124K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xueer Lu, Ziwen Zhang, Yingying Xu, Jun Lu, Wenjian Tang, Jing Zhang
2e and 2j with strong p-NO2 and p-CF3 at phenyl ring had the lowest MICs against S. aureus and MRSA. 2e displayed unaided or synergistic efficacy against MRSA, especially combined with ofloxacin. EM revealed that 2e destroys biofilms and cell membranes.
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Research on the controllable degradation of N-methylamido and dialkylamino substituted at the 5th position of the benzene ring in chlorsulfuron in acidic soil

RSC Adv., 2020, 10,17870-17880
DOI: 10.1039/D0RA00811G, Paper
Open Access
Fan-Fei Meng, Lei Wu, Yu-Cheng Gu, Sha Zhou, Yong-Hong Li, Ming-Gui Chen, Shaa Zhou, Yang-Yang Zhao, Yi Ma, Zheng-Ming Li
These results will provide valuable information to discover tailored SU with controllable degradation properties to meet the needs of individual crops.
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Nitrogen-doped RuS2 nanoparticles containing in situ reduced Ru as an efficient electrocatalyst for hydrogen evolution

RSC Adv., 2020, 10,17862-17868
DOI: 10.1039/D0RA02530E, Paper
Open Access
Yan Xu, Xiaoping Gao, Jingyan Zhang, Daqiang Gao
The reasonable design that N-doping and in situ reduced Ru metal enhances the performance of N-RuS2/Ru for HER.
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Lithium metal deposition/dissolution under uniaxial pressure with high-rigidity layered polyethylene separator

RSC Adv., 2020, 10,17805-17815
DOI: 10.1039/D0RA02788J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shogo Kanamori, Mitsuhiro Matsumoto, Sou Taminato, Daisuke Mori, Yasuo Takeda, Hoe Jin Hah, Takashi Takeuchi, Nobuyuki Imanishi
The use of a high rigidity separator and application of an appropriate amount of pressure are effective approaches to control lithium metal growth and improve its cycle performance.
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Synthesis of heteroatom-containing pyrrolidine derivatives based on Ti(O-iPr)4 and EtMgBr-catalyzed carbocyclization of allylpropargyl amines with Et2Zn

RSC Adv., 2020, 10,17881-17891
DOI: 10.1039/D0RA02677H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rita N. Kadikova, Ilfir R. Ramazanov, Azat M. Gabdullin, Oleg S. Mozgovoj, Usein M. Dzhemilev
The Ti(O-iPr)4 and EtMgBr-catalyzed regio and stereoselective carbocyclization of N-allyl-substituted 2-alkynylamines with Et2Zn, followed by deuterolysis or hydrolysis, affords the corresponding methylenepyrrolidine derivatives in high yields.
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Glossary format definition list

Bruce Lawson recently asked for ways to style a definition list in the common glossary format. This is one way to do it.

Bruce’s original post – css challenge – describes what he is after: a “glossary style” appearance with the term on the left and the definitions on the right. Some terms will have multiple definitions, definitions of varying length, and each new term should appear on a new line. A definition list is semantically correct for this kind of information, so there was to be no fiddling around with the HTML, and the browser requirements were for it to work in all modern browsers and IE 6+.

You can skip straight to the demo where some additional classes are included in the HTML in order to highlight each term-definition association.

The basic HTML

The basic HTML structure is a simple definition list and nothing more. There are some short, long, and multiple definitions for each term.

<h1>Styling definition lists</h1>
<dl>
  <dt>Cheese</dt>
  <dd>
    <p>Velit esse cillum dolore in reprehenderit in voluptate duis aute irure dolor. Consectetur adipisicing elit, excepteur sint occaecat sunt in culpa. Velit esse cillum dolore eu fugiat nulla pariatur. Ut aliquip ex ea commodo consequat.</p>
    <p>Mollit anim id est laborum. Ut enim ad minim veniam, consectetur adipisicing elit, ullamco laboris nisi. Lorem ipsum dolor sit amet, sunt in culpa quis nostrud exercitation.</p>
  </dd>
  <dd>yummy!</dd>

  <dt>Building flexibility through spreading knowledge and self-organization, exploiting the productive lifecycle to experience a profound paradigm shift. Through the adoption of a proactive stance, the astute manager can adopt a position at the vanguard.</dt>
  <dd>balderdash</dd>;
  <dd>poppycock</dd>

  <dt>Aardvark</dt>
  <dd>never hurt anyone</dd>
</dl>

The styles

In order to get the required appearance in all browsers I had to use negative margins and a few conditional styles to get IE7 and IE6 to play along.

For the purposes of the demo I’ve placed all the styles in <style> blocks in the head of the document.

<style>
   dl {padding-left:300px;}
   dt {clear:both; float:left; width:260px; padding:10px; margin:0 0 2em -300px; font-weight:bold; color:#686663;}
   dd {float:left; width:100%; padding:10px 0; margin:0 0 2em;}
</styl>
<!--[if lte IE 7]>
<style>
   dt {display:inline; margin-bottom:0;}
   dd {float:none; width:auto;}
</style>
<![endif]-->

That’s it. The widths of the <dt> can be set in ems or percentages if the layout requires. The complete code is available in the demo and you are free to use this code.




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Hoverfly on a pink flower




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Thoughts on some new HTML5 elements

In the last few months there has been increased discussion about some of the new elements that have been introduced in the HTML5 draft specification. This entry is primarily a counter argument to some of the comments that I disagree with.

The most recent and high-profile comments in regard to parts of the HTML5 specification come from The HTML5 Super Friends in an article entitled Guide to HTML5 Hiccups. It lays out their concerns with the HTML5 draft specification as it stood at the time of its writing and I am largely going to focus on the issues they have discussed.

The article and section elements

The first argument that I disagree with is that the article and section elements are redundant and, therefore, that the article element should be dropped.

article and section are identical except that article allows a pubdate attribute. We would suggest that article be dropped and section be adapted to allow an optional pubdate attribute or, even better, more explicit metadata.

The article and section elements are not identical according the to HTML5 draft specification. Here is what it says about the section element as of 13 September 2009:

The section element represents a generic document or application section. A section, in this context, is a thematic grouping of content, typically with a heading, possibly with a footer.

Now contrast that with what it says about the the article element:

The article element represents a section of a page that consists of a composition that forms an independent part of a document, page, application, or site.

An article element is “independent” in the sense that its contents could stand alone, for example in syndication, or as a interchangeable component on a user-configurable portal page.

That is a clear distinction that resists the reading of article and section being “identical”. The article element has a specific purpose: to mark parts of a document that form an independent composition that may be appropriate for syndication. It is a special kind of sectioning element that performs an essential role that is lacking in the semantics of the generic section element. This generic element serves only to thematically group content. That grouping may occur at the document level, within an independent article, or within a footer.

The article element has unique semantics and practical use. There is a fundamental conceptual difference between stand-alone compositions and sections of compositions, documents, or pages and this difference should be recognised and catered for in the specification. Websites regularly employ microformats and you don’t have to look far to see independent compositions currently marked up with class="hentry" or find links to individual blog comments and twitter updates. There is clearly a need for an easy way to define independent compositions and that is met with the introduction of the article element in HTML5.

What may be needed is a stronger clarification and definition of the article element to minimise the potential for this distinction to be overlooked and to highlight the differences from a generic document section.

The hgroup element

The hgroup element is a relatively recent addition to the draft specification. It is defined as serving a fairly specific purpose:

The hgroup element represents the heading of a section. The element is used to group a set of h1h6 elements when the heading has multiple levels, such as subheadings, alternative titles, or taglines.

The element works to associate headings together so that the highest ranked heading descendant (if present) of the hgroup element is used as its text in document outlines and summary. Other heading descendants are treated as subheadings and are left out of outlines.

The HTML5 Super Friends have this to say about the hgroup element:

We don’t see the added value of this element and would instead add a boolean attribute to the heading element which allows content authors to specify if that particular heading should be included in the outline.

Bruce Lawson has similar concerns and proposes another alternative – removing the need for a wrapping element and defining a new element specifically for marking up subtitles:

I agree that hgroup is clumsy and likely to be misused. Rather than wrap an h1 and its h2 subtitle in hgroup to keep the subtitle out of the outlining algorithm, I would prefer to use

<header>
<h1>My blog</h1>
<subtitle>My wit and wisdom</subtitle>
</header>

as I think that;s easier to understand than a heading-that’s-not-a-heading, and it removes a wrapping element.

I disagree with these criticisms of the hgroup element and consider the proposed alternatives to be more problematic, less intuitive, less flexible, and further removed from the way in which authors currently markup subheadings.

The way that many authors are currently marking up subheadings is by using headings of various ranks and in various orders depending on whether the subheading or qualifying heading needs to appear above or below the main page heading. A subheading is still, conceptually, a heading of sorts and it cannot be accurately marked up with a paragraph or any other currently available element.

Allowing the addition of a boolean attribute to heading elements has several problems.

  1. A boolean attribute may be less intuitive for authors than the hgroup element. The hgroup element relies upon and produces an association between all the headings it contains. Since headings and subheadings occur together and derive their meaning from each other, it is semantic to wrap these headings in an element. We know that the highest ranked heading contains the string to be used in the outline and that the other headings serve as ranked subheadings to this primary heading. A boolean attribute is only associated with the element that it is a part of. We can create no association between the element and adjacent elements. This is related to the next issue.

  2. The hgroup itself acts as heading content while a boolean attribute would act only to remove headings from the outline. The hgroup element only removes the descendant headings that are those not of the highest rank. The boolean attribute shifts the burden onto the author to decide which headings should be marked for removal from the outline, rather than providing an element to wrap a collection of headings without authors having to be concerned with (or aware of) issues of outlining.

What about Bruce Lawson’s idea for a subtitle element? I believe that, irrespective of the what this element were actually called, it suffers from similar problems to the idea of using a boolean attribute. There is nothing to prevent the use of a subtitle element away from a heading, it creates no association with other elements, and it does not allow for ranking of subheadings.

One of my key points in relation to criticism of the hgroup element is that subheadings draw their meaning from context. A subheading (as opposed to a section heading) is only a sub-heading if it is associated with a higher ranking heading. Remove the higher ranking heading and what was once a subheading is likely to be understood as a heading.

The strength of the hgroup element over the two alternative suggestions I have referenced is that it is the only proposal that defines a subheading as contextual. I think that it is the most intuitive proposal (although perhaps none of them are particularly inuitive) – the name of the element is self-descriptive and encapsulates the contextual relationship and adjacent positioning of its child elements — and matches most closely with the way that subheadings are currently marked up on many websites.

The aside element

The HTML5 Super Friends are of the opinion that the aside element is not worth including in the specification:

The use cases for aside are too limited to warrant its inclusion in the specification. We were also concerned about potentially duplicating content within an aside.

However, the specification itself provides some fairly compelling uses for the element:

The element can be used for typographical effects like pull quotes or sidebars, for advertising, for groups of nav elements, and for other content that is considered separate from the main content of the page.

Authors might use the aside element for their blogrolls, for marking up adverts ranging from google ads on blogs to large banners on enterprise websites, for expanding on themes within an article or providing an extended definition of a term, for pull quotes, and anything else “tangentially related to the content around the aside element, and which could be considered separate from that content”.

Most of these uses would not involve duplication of content. Using the aside element for pull quotes would produce some instances of content duplication. However, this is not really a problem for users who are used to content being duplicated in this way in newspapers and magazines. It would not take much for search engines to adapt to deal with short amounts of duplicate content contained within an aside either. While I appreciate the point about duplicate content I’m not yet convinced that it is actually problematic.

The legend element

The current specification defines the legend element as providing an explanatory caption for the contents of its parent element. The parent element may be a fieldset, figure or details element. However, Remy Sharp‘s article entitled legend not such a legend anymore shows why it is not practical to use legend for the new elements details and figure – because it is not backwards compatible with current browsers and effectively unusable outside of a fieldset because of the inability to style the element.

In this case, forging a new element is most appropriate rather than trying to use an element like label which will only create confusion with little advantage.

Summary

I have discussed my reasons for disagreeing with certain feedback on the HTML5 draft specification. I have yet to be convinced that the article, hgroup, or aside elements should be dropped from the specification because it seems to me that they have necessary uses and advantages over alternatives.




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New HTML5 elements: summary & figcaption

Over the weekend two new HTML5 elements – summary and figcaption – were added to the draft specification. The introduction of summary and figcaption marks the acceptance that new elements are needed to act as captions or legends for the details and figure elements. The addition of the figcaption element finally begins to clear up the difficulty in marking-up figure element captions and looks to cement the place of the figure element in the HTML5 specification. The summary element does much the same for the details element but the very nature of the details element itself means that its future is not yet clear.

The figcaption element

This new element acts as the optional caption or legend for any content contained within its parent figure element.

If there is no figcaption element within a figure element then there is no caption for the rest of its content. If there is a figcaption element then it must be the first or last child of the figure element and only the first figcaption element (should there be more than one child figcaption of the parent figure element) represents a caption.

The figure element is used to mark up any self-contained content that may be referenced from the main flow of a document but could also be removed from the primary content (for example, to an appendix) without affecting its flow. This makes it suitable for various types of content ranging from graphs and data tables to photographs and code blocks.

<p><a href="#fig-ftse">Figure 1</a> shows the extent of the collapse in the markets and how recovery has been slow.</p>

<figure id="fig-ftse">
  <figcaption>Figure 1. The value of the FTSE 100 Index from 1999&ndash;2009.</figcaption>
  <img src="ftse-100-index-graph.jpg" alt="The index hit a record high at the end of 1999 and experienced two significant drops in the following last decade.">
</figure>

<p>This latest financial crisis hasn't stopped Alex from writing music and his latest track is actually worth listening to.</p>

<figure>
  <audio src="what-am-i-doing.mp3" controls></audio>
  <figcaption><cite>What am I doing?</cite> by Alex Brown</figcaption>
</figure>

The creation of the figcaption element is an important step forward for the HTML5 draft specification as it finally provides a reliable means to markup the caption for content that is best marked up as a figure. Previous attempts to use the legend element, the caption element, and the dt and dd elements had failed due to a lack of backwards compatibility when it came to styling these elements with CSS.

The summary element

This new element represents a summary, caption, or legend for any content contained within its parent details element.

The summary element must be the first child of a details element and if there is no summary element present then the user agent should provide its own. The reason for this is because the details element has a specific function – to markup additional information and allow the user to toggle the visibility of the additional information. Although it is not specified in the specification, it is expected that the summary element will act as the control that toggles the open-closed status of the contents of the parent details element.

<details>
  <summary>Technical details.</summary>
  <dl>
    <dt>Bit rate:</dt> <dd>190KB/s</dd>
    <dt>Filename:</dt> <dd>drum-and-bass-mix.mp3</dd>
    <dt>Duration:</dt> <dd>01:02:34</dd>
    <dt>File size:</dt> <dd>78.9MB</dd>
  </dl>
</details>

The introduction of the summary element seems to secure the future of the details element and the new behaviour that it affords, for now. When user agents begin to add support for the details element you won’t need JavaScript, or even CSS, to have expanding or collapsing sections in an HTML document.

The future of the details element

There will continue to be some debate over the inclusion of behaviour in an HTML specification especially given the widespread use of JavaScript to provide the expand-collapse functionality that details describes.

The details element writes some quite significant behaviour into an HTML document and I can see it being abused to provide generic expand-collapse functionality throughout a document. It is also not entirely clear what purpose the details element actually serves other than being an attempt to bypass the need for JavaScript or CSS to expand or collapse sections of a document.

There has been a general softening of the rough distinction between content, presentation, and behaviour. JavaScript libraries are being used to patch holes in browser CSS and HTML5 support, the CSS3 modules introduce plenty of behaviour that was previously only possibly with JavaScript, and the HTML5 specification is also introducing functionality and behaviour that previously required the use of JavaScript.

The future survival of the details element, and the behaviour associated with it, may well depend on browser implementations and author applications over the coming months.