on Highly covalent metal–ligand π bonding in chelated bis- and tris(iminoxolene) complexes of osmium and ruthenium By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT01287D, PaperJacqueline Gianino, Seth N. BrownDescribing the π bonding in ruthenium and osmium iminoxolenes as highly covalent allows one to experimentally dissect the electron distribution in these compounds.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Copolymerization of CHO/CO2 catalyzed by a series of aluminum amino-phenolate complexes and insights into structure–activity relationships By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00726A, PaperHart Plommer, Laura Stein, Jennifer N. Murphy, Nduka Ikpo, Nelaine Mora-Diez, Francesca M. KertonFive aluminum catalysts demonstrated different selectivity and activity during reactions of carbon dioxide and epoxides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Self-assembly of mixed-valent and heterometallic metallocycles: efficient catalyst for oxidation of alcohols to aldehydes with ambient air By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01340D, CommunicationYa-Liang Lai, Xue-Zhi Wang, Rui-Rong Dai, Yong-Liang Huang, Xian-Chao Zhou, Xiao-Ping Zhou, Dan LiTwo mixed-valent CuII/CuI and two heterometallic CuII/AgI metallocycles have been synthesized by the assembly of designed metalloligands and CuI/AgI ions, respectively. The CuII/CuI metallocycle can catalyze oxidation of alcohols to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Water-locking molecule-assisted fabrication of natural-inspired Mg(OH)2 for high-efficient and economical uranium capture By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT00618A, PaperHengbin Xu, Zhenyuan Bai, Milin Zhang, Jun Wang, Yongde Yan, Min Qiu, Jiaming ChenWith the depletion of uranium terrestrial deposits, researchers have focused on the development of adsorbents to extract radioactive uranium from seawater/wastewater. However, there are still considerable challenges to manipulate this...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Accelerating charge transfer in ultrafine NiFe-LDHs/CB interface during electrocatalyst activation process for water oxidation By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT00824A, PaperMengke Cai, Qinglin Liu, Yiyue Zhao, Zhenyu Wang, Yinle Li, Guangqin LiOwing to coordinating of intriguing activity and conductivity, the hybrid compositions of layered double hydroxides (LDHs) and carbon-based materials have been extensively and widely applied to evolve oxygen gas for...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Modulation of the driving forces for adsorption on MIL-101 analogues by decoration with sulfonic acid functional groups: superior selective adsorption of hazardous anionic dyes By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00978D, PaperJi-Min Yang, Wei Zhang, Run-Zhi Zhang, Meng-Xuan TongMIL-101-SO3H analogues functionalized with –SO3H groups exhibited superior CR, MO and AC adsorption capacities because of their distinct adsorption mechanisms.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Structural, spectroscopic and electronic properties of a family of bi-octahedral Ru25+/6+ complexes with a bridging 2,5-di(2-pyridyl)pyrrolide ligand By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01325K, PaperShi-Rui Kang, Qin Zi Zhou, Chang-Fang Xiong, Bin Liu, John E. McGrady, Mohammed Obies, Chao Liu, Piao He, Xiao-Yi YiA family of Ru2 dimers, [Ru2(μ-κ2N,N’:κ2N’,N’’-dpp)2(μ-X)(X)2]q+ (X = Cl, Br, q = 0 and X = I, q = 1) is synthesized from a [Ru2(OAc)4Cl] paddlewheel starting material. The neutral...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on An ultra-effective pathway for fully removing the oxygen components of graphene oxide by a flame-assisted microwave process By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01483D, CommunicationXuefeng Zou, Qin Hu, Hengxiu Yang, Feng Chen, Bin Xiang, Xinyue Liang, Qibing Wu, Hujun ShenHere we report an ultra-effective, reliable pathway to reduce GO into graphene by an about 4-seconds flame-assisted microwave process. A holey graphene with a C/O atom ratio of 31.1, a...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Temperature-dependent hysteretic two-step spin crossover in two-dimensional Hofmann-type compounds By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT00866D, PaperJun Tao, Yue Li, Min Liu, Zi-Shuo YaoHofmann-type spin-crossover (SCO) frameworks attract much attention due to their predictable structures and diverse SCO behaviours. In this paper, we report two isostructural two-dimensional (2D) Hofmann-type SCO frameworks [FeII(ppe)2MII(CN)4]·3H2O (ppe...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Color Tuning in Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) Phosphors via Cation Substitution By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01130D, PaperHuiling Zhang, Dengwen Yuan, Xiaoyun Mi, Xiuling Liu, Jun LinA series of Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) phosphors were prepared via high-temperature solid-state reaction process. The X-ray diffraction and Rietveld refinements were used to verify the incorporations of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on 1,2-Insertion Reactions of Alkynes into Ge–C Bonds of Arylbromogermylene By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01223H, PaperTomohiro Sugahara, Arturo Espinosa Ferao, Alicia Rey, Jing-Dong Guo, Shin Aoyama, Kazunobu Igawa, Katsuhiko Tomooka, Takahiro Sasamori, Daisuke Hashizume, Shigeru Nagase, Norihiro Tokitoh1,2-insertion reactions of alkynes into the Ge–C bonds in dibromodigermenes afford stable crystalline bromovinylgermylenes. In contrast to previously reported Lewis-base-supported vinylgermylenes, the bromovinylgermylene obtained from reaction of the bromogermylene with...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Multicolor tunable luminescence and energy transfer of core-shell structured SiO2@Gd2O3 microspheres co-activated with Dy3+/Eu3+ under single UV excitation By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT00735H, PaperJie Chen, Yixin Gao, Haifeng Jiang, Yan Liu, Zhaohui JinOptimizing structure and varing doped ions are two main strategies to obtain excellent luminescence performance. Spherical morphology is considered to be the most ideal phosphor structure due to the least...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on The role of the excited state dynamic of the antenna ligand in the Lanthanide sensitization mechanism By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01132K, PaperMaría Joaquina Beltrán Leiva, Eduardo Solis Céspedes, Dayan Paez-HernandezA fragmentation scheme combined with a series of theoretical approximations like TD-DFT, and multiconfigurational CASSCF/NEVPT2 methods, have been used to describe the photophysical phenomena associated with the antenna effect and...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Probing the limits of linker substitution in aluminum MOFs through water vapor sorption studies: Mixed-MOF instead of mixed-linker CAU-23 and MIL-160 materials By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01044H, PaperCarsten Schlüsener, Dustin Nils Jordan, Mergime Xhinovci, Tobie J. Matemb Ma Ntep, Alexa Schmitz, Beatriz Giesen, Christoph JaniakWe report the systematic study on the possibility of forming mixed-linker MOFs spanning between the aluminum metal-organic frameworks CAU-23 and MIL-160 with their 2,5-thiophenedicarboxylate (TDC) and 2,5 furandicarboxylate (FDC) linkers,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Luminescent organic dyes containing a phenanthro[9,10-D]imidazole core and [Ir(N^C)(N^N)]+ complexes based on the cyclometalating and diimine ligands of this type By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00568A, PaperAnastasia I. Solomatina, Kirill M. Kuznetsov, Vladislav V. Gurzhiy, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov, Sergey P. TunikNew N^N and N^C luminescent ligands with solvatochromic behavior and their iridium complexes were synthesized, characterized and investigated.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on MnO2 flowery nanocomposites for efficient and fast removal of mercury(II) from aqueous solution: a facile strategy and mechanistic interpretation By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT01054E, PaperSankar Das, Arnab Samanta, Kanika Kole, Gautam Gangopadhyay, Subhra JanaMnO2 flowery nanocomposites were explored as a novel and cost effective nanoadsorbent for the fast and efficient extraction of toxic inorganic contaminants from aqueous solution.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Three diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2: influences of co-substitution on the crystal structure By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT01070G, PaperMing Wen, Cong Hu, Hongping Wu, Zhihua Yang, Xiaohong Wu, Shilie PanWe reported the synthesis, structure, characterization and first-principles calculations of diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2, and studied the influences of co-substitution on the crystal structure.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Influence of magnetic dilution on relaxation processes in a solid solution comprising tetrahedral Co/ZnII complexes By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT01058H, PaperMagdalena Ceglarska, Olaf Stefańczyk, Shin-ichi Ohkoshi, Anna M. Majcher-FitasDilution with diamagnetic species in a SIM solid solution leads to an increase in relaxation times at low temperatures and monotonously reduces the probability of quantum tunneling of magnetization and the direct process.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Dehydrogenation of amines in aryl-amine functionalized pincer-like nitrogen-donor redox non-innocent ligands via ligand reduction on a Ni(II) template By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00466A, PaperManas Khatua, Bappaditya Goswami, Subhas SamantaA Ni(II)-template directed dehydrogenative imine formation reaction via ligand reduction leading to the formation of new pincer-like azo imine ligands is described.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Recent advances in coordination-driven polymeric gel materials: design and applications By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00863J, FrontierPapri Sutar, Tapas Kumar MajiIn this article, we reviewed recent advances in coordination-driven polymeric gels and highlighted their design and applications in various fields.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Effects of ligand substituents on the single-molecule magnetic behavior of quinonoid-bridged dicobalt compounds By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00033G, PaperXiao-Quan Zhu, Wen-Hai Cao, Shao-Dong Su, Xin-Tao Wu, Tian-Lu ShengThe SMM behavior weakens until its disappearance with the substituent changing from Br, H to OMe in the quinonoid-bridged dicobalt compounds [(N4Co)2LX](ClO4)2, (X = H, Cl, Br, and OMe).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Amorphous Ni–Fe–Se hollow nanospheres electrodeposited on nickel foam as a highly active and bifunctional catalyst for alkaline water splitting By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/C9DT04755G, PaperXuerui Yi, Xiaobo He, Fengxiang Yin, Biaohua Chen, Guoru Li, Huaqiang YinThe electrodeposition of amorphous Ni–Fe–Se hollow nanospheres as a highly efficient bifunctional catalyst for the sustainable production of hydrogen.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Metal–metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt–Ag bonds By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT01227K, CommunicationNatsuki Yabune, Hiroshi Nakajima, Takanori NishiokaA triplatinum complex with chelating NHC ligands reacts with Ag(I) and affords a heptanuclear cluster bearing four Ag–Pt bonds.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Selenotungstates incorporating organophosphonate ligands and metal ions: synthesis, characterization, magnetism and catalytic efficiency in Knoevenagel condensation reaction By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT00444H, PaperJingyang Niu, Hui Kong, Peipei He, Zongfei Yang, Qiaofei Xu, Jiawei Wang, Ran Ban, Pengtao Ma, Jingping WangThree sandwich-type TM-containing (TM = transition metal) organophosphonate-based polyoxotungstate clusters, [TM(H2O)4(SeW6O21)2{Co(OOCCH2NCH2PO3)2}3]12– (TM = Co, Ni), have been successfully synthesized, which is the first reported TMs-containing organophosphonate-based selenotungstates. They were structurally...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Luminescent lanthanide complexes with a pyridine-bis(carboxamide)-bithiophene sensitizer showing wavelength-dependent singlet oxygen generation By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT01034K, PaperKatherine R. Johnson, Sebastian B. Vittardi, Manuel A. Gracia-Nava, Jeffrey J. Rack, Ana de Bettencourt-DiasA new pyridine-bis(carboxamide)-based ligand with a bithiophene pendant, 2Tcbx, was synthesized.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Tin based organic-inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01401J, PaperZhenhong Wei, Xiuli You, Jiaojiao YaoOrganic−inorganic hybrid materials with perovskite structure have recently attracted tremendous interest due to their structural tunability and rich functional properties, such as phase transition and photoelectric properties. Within this context,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Oxacalix[4]arene Derived Dual Sensing Fluorescence Probe for the Detection of As (V) and Cr (VI) Oxyanions in Aqueous Media By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT00452A, PaperShuvankar Dey, Anshu Kumar, Pradip Mondal, Krunal M. Modi, Deepak Chopra, Vinod K. JainAn oxacalix[4]arene-Ce (III) complex viz. L-Ce(III) has been introduced for selective detection of As (V) and Cr (VI) oxyanions in aqueous medium. Binding mode of L-Ce(III) + AsO43-/ CrO42- was...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Double addition of phenylacetylene onto the mixed bridge phosphinito–phosphanido Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)](Pt–Pt) By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00923G, PaperStefano Todisco, Mario Latronico, Vito Gallo, Nazzareno Re, Alessandro Marrone, Iogann Tolbatov, Piero MastrorilliDouble addition of phenylacetylene onto the Pt(I)–Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)] (Pt–Pt) affords the η1-alkenyl-μ,η1:η2-alkynyl complex [(η1-trans-(Ph)HCCH)(PHCy2)Pt(μ-PCy2)(μ,η1:η2-PhCC)Pt{κP-P(O)Cy2}(PHCy2)].To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on A molecular boron cluster-based chromophore with dual emission By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00826E, PaperKierstyn P. Anderson, Mary A. Waddington, Gary J. Balaich, Julia M. Stauber, Nicholas A. Bernier, Justin R. Caram, Peter I. Djurovich, Alexander M. SpokoynyBromination of the luminescent borane, anti-B18H22, via electrophilic substitution using AlCl3 and Br2, yields the monosubstituted derivative 4-Br-anti-B18H21 as an air-stable crystalline solid.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Crystal structure, chemical bonding, and electrical and thermal transport in Sc5Rh6Sn18 By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00324G, PaperManuel Feig, Lev Akselrud, Walter Schnelle, Vadim Dyadkin, Dmitry Chernyshov, Alim Ormeci, Paul Simon, Andreas Leithe-Jasper, Roman GumeniukSingle crystals of the superconductor Sc5Rh6Sn18 were grown from Sn-flux.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) as necroptosis and ferroptosis inducers By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00168F, PaperDaniel Baecker, Benjamin N. Ma, Jessica Sagasser, Lukas Schultz, Carina Hörschläger, Maria Weinreich, Lucy Steiner, Brigitte Kircher, Ronald GustAmide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) were synthesized and characterized as necroptosis and ferroptosis inducers using the acute myeloid leukemia cell line HL-60.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Reactive metallocene cations as sensitive indicators of gas-phase oxygen and water By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00798F, PaperAnuj Joshi, Sofia Donnecke, Ori Granot, Dongju Shin, Scott Collins, Irina Paci, J. Scott McIndoeGas-phase oxidation of air-sensitive organometallic compounds does not proceed to a significant extent in mass spectrometric analysis unless a vacant coordination site is generated, making nitrogen generators a suitable source of desolvation gas.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Heat-resistant Pb(II)-based X-ray scintillating metal-organic frameworks for sensitive dosage detection via the aggregation-induced luminescent chromophore By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT00974A, CommunicationJian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng, Guo-Cong GuoThe synergy of unusual X-aggregation induced luminescent chromophores and heavy Pb(II) ions has facilitated excellent X-ray scintillation of two structurally similar Pb-SMOFs, which are heat-resistant due to solvent-free lattices. Owing...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Spin-frustration with two quasi-degenerated spin states of a copper(II) heptanuclear complex obtained from an amino acid ligand By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/C9DT04501E, PaperCatiúcia Rodrigues Marcelino Oliveira Matos, Henrique Silva Jr, Dayenny D’Amato, Guilherme Guedes, Glaucio Braga Ferreira, Odivaldo Cambraia Alves, Filipe Barra de Almeida, Sergio Pinheiro, Acácio Souza, Flavio Garcia, Célia Machado RonconiThe Cu(II) heptanuclear complex (Cu7atac) was synthesised using the hydrated amino acid ligand 2-(5-amino-1H-1,2,4-triazol-3-yl)acetic acid (Hatac.H2O). Single crystal X-ray diffraction analysis revealed a μ3-hydroxo bridged Cu(II) heptanuclear complex, consisting of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Photophysical, photodynamical, redox properties and BSA-interactions of novel isomeric tetra-cationic peripheral palladium(II)-bipyridyl porphyrins By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01063D, PaperFabiano S Santos, Carolina H. da Silveira, Fabio Souza Nunes, Daniele Ferreira, Henrique Victória, Klaus Krambrock, Otávio Augusto Chaves, Fabiano Severo Rodembusch, Bernardo Almeida IglesiasNew isomeric tetra-cationic porphyrins containing peripheral [Pd(bpy)Cl]+ units attached at pyridyl substituents were synthetized and fully characterized. The porphyrins present an intense Soret band located in the blue spectral region...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Impacts of hydrogen bonding interactions with Np(V/VI)O2Cl4 complexes: vibrational spectroscopy, redox behavior, and computational analysis By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00848F, PaperMikaela M. Pyrch, Jennifer L. Bjorklund, James M. Williams, Daniel L. Parr IV, Sara E. Mason, Johna Leddy, Tori Z. ForbesCrystallization of neptunyl(V) tetrachlorides over neptunyl(VI) species occurs simultaneously with charge assisted hydrogen bonding in our solid state materials, which we explored by DFT calculations, cyclic voltammograms, and Raman spectroscopy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on The differential magnetic relaxation behaviours of slightly distorted triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compounds By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00990C, PaperAn-Qi Xue, Yang-Yu Liu, Jia-Xin Li, Yan Zhang, Yin-Shan Meng, Wen-Hua Zhu, Yi-Quan Zhang, Hao-Ling Sun, Fei Wang, Guan-Xia Qiu, Lu-Yu Liang, Xiang Wang, Song GaoDifferential magnetic properties were observed for triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compound.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Rhenium and technetium-complexed silicon rhodamines as near-infrared imaging probes for bimodal SPECT- and optical imaging By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01084G, CommunicationThines Kanagasundaram, Carsten Sven Kramer, Eszter Boros, Klaus KopkaRadiolabelled fluorescent dyes are decisive for bimodal imaging and currently in demand for scintigraphic and optical imaging. This powerful method allows the combination of nuclear imaging (e.g. SPECT-imaging) and optical...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on A Review: Recent Advances in Preparations and Applications of Heteroatom-Doped Carbon Quantum Dots By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01004A, PerspectiveXiaoli Kou, Shicui Jiang, Soo-Jin Park, Long-Yue MengCarbon quantum dots (CQDs) are widely used in optoelectronic catalysis, biological imaging, and ion probes owing to their low toxicity, stable photoluminescence, and ease of chemical modification. However, the low...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Highly cytotoxic gold(I)-phosphane dithiocarbamate complexes trigger an ER stress-dependent immune response in ovarian cancer cells By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01411G, PaperHai Van Le, Maria Babak, Muhammad Ali Ehsan, Mohammad Altaf , Lisa Reichert, Artem Gushchin, Wee Han Ang, Anvarhusein IsabOvarian cancer is a highly aggressive disease which is treated by surgery and platinum chemotherapy. However, a significant proportion of treated patients develop resistance to platinum treatment resulting in tumor...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Platinum Complexes of a Boron-Rich Diphosphine Ligand By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT00963F, PaperMarcus W. Drover, Eric G Bowes, Maeve C Dufour, Lindsay Lesperance-NantauHerein, we describe the preparation, characterization, and reactivity of two PtIIbis-hydrocarbyl complexes containing the 1,2-bis(di(3-dicyclohexylboraneyl)propylphosphino)ethane (P2BCy4) ligand. These scaffolds are readily accessed from four-fold hydroboration of 1,2-bis(diallylphosphino)ethane PtII precursors....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on Dual-fixations of europium cation and TEMPO species on metal-organic frameworks for aerobic oxidation of alcohols By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01324B, PaperSeongwoo Kim, Jooyeon Lee, Sungeun Jeoung, Hoi Ri Moon, Min KimThe efficient and selective aerobic oxidation of alcohols has been investigated with judicious combinations of europium-incorporated and/or TEMPO ((2,2,6,6-tetramethylpiperidin-1-yl)oxyl)-functionalized zirconium-based porous metal-organic frameworks (MOFs). Although MOFs are well-known catalytic platform...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
on What is a “third place,” and do you have one? By www.berkshirepublishing.com Published On :: Fri, 01 Nov 2019 11:05:34 +0000 The term “happy place” is not in the Oxford English Dictionary (though “happy slap” is), but I’ve been hearing the term a lot. There’s even a new shop in Great Barrington called HappyPlace Berkshires. I first dismissed it as therapeutic slang, but discovered that the concept actually goes back to the Greeks: a utopia is The post What is a “third place,” and do you have one? appeared first on Berkshire Publishing. Full Article Berkshire Blog China Community third places
on COVID-19 is here (& where has all the toilet paper gone?) By www.berkshirepublishing.com Published On :: Tue, 31 Mar 2020 09:19:45 +0000 We lived through the ‘80s. We lived through the ‘90s. We lived through the ‘00s. We lived through the ‘10s. And we’ve lived through March. Most of us, that is, have lived. I’m still coming to terms with what is happening. It’s like grief. I go about my day, getting absorbed in work, or a The post COVID-19 is here (& where has all the toilet paper gone?) appeared first on Berkshire Publishing. Full Article Berkshire Blog
on Do exclusionary rules ensure a fair trial?: a comparative perspective on evidentiary rules / Sabine Gless, Thomas Richter, editors By library.mit.edu Published On :: Sun, 21 Jul 2019 09:24:23 EDT Online Resource Full Article
on Selma and the Liuzzo murder trials: the first modern civil rights convictions / by James P. Turner By library.mit.edu Published On :: Sun, 21 Jul 2019 09:24:23 EDT Dewey Library - KF224.K7 T87 2018 Full Article
on First: Sandra Day O'Connor / Evan Thomas By library.mit.edu Published On :: Sun, 28 Jul 2019 10:20:39 EDT Dewey Library - KF8745.O25 T46 2019 Full Article
on Our selfish tax laws: toward tax reform that mirrors our better selves / Anthony C. Infanti By library.mit.edu Published On :: Sun, 28 Jul 2019 10:20:39 EDT Dewey Library - KF6289.I49 2018 Full Article
on The World Bank policy for projects on international waterways: an historical and legal analysis / Salman M.A. Salman By library.mit.edu Published On :: Sun, 28 Jul 2019 10:20:39 EDT Online Resource Full Article
on Many nations under many gods: public land management and American Indian sacred sites / Todd Allin Morman By library.mit.edu Published On :: Sun, 28 Jul 2019 10:20:39 EDT Rotch Library - KF5605.M67 2018 Full Article
