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[ASAP] Synthesis of Stable, High-SOMO Zwitterionic Radicals: Enabling Intermolecular Electron Transfer between Naphthalenediimides

Organic Letters
DOI: 10.1021/acs.orglett.0c01263




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[ASAP] Chiral Binaphthyl Box-Copper-Catalyzed Enantioselective Tandem Michael–Ketalization Annulations for Optically Active Aryl and Heteroaryl Fused Bicyclicnonanes

Organic Letters
DOI: 10.1021/acs.orglett.0c01221




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[ASAP] Ruthenium-Catalyzed Asymmetric <italic toggle="yes">N</italic>-Acyl Nitrene Transfer Reaction: Imidation of Sulfide

Organic Letters
DOI: 10.1021/acs.orglett.0c01373




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[ASAP] Self-Catalyzed Rapid Synthesis of <italic toggle="yes">N</italic>-Acylated/<italic toggle="yes">N</italic>-Formylated a-Aminoketones and <italic toggle="yes">N</italic>-Hydroxymethyl

Organic Letters
DOI: 10.1021/acs.orglett.0c01206




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[ASAP] Acylation of Aryl Halides and a-Bromo Acetates with Aldehydes Enabled by Nickel/TBADT Cocatalysis

Organic Letters
DOI: 10.1021/acs.orglett.0c01121




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[ASAP] Carbocation versus Carbene Controlled Chemoselectivity: DFT Study on Gold- and Silver-Catalyzed Alkylation/Cyclopropanation of Indoles with Vinyl Diazoesters

Organic Letters
DOI: 10.1021/acs.orglett.0c01476




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[ASAP] K<sub>2</sub>S as Sulfur Source and DMSO as Carbon Source for the Synthesis of 2-Unsubstituted Benzothiazoles

Organic Letters
DOI: 10.1021/acs.orglett.0c00994




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[ASAP] Palladium-Catalyzed Cascade Decarboxylative Amination/6-<italic toggle="yes">endo-dig</italic> Benzannulation of <italic toggle="yes">o</italic>-Alkynylarylketones with <italic toggle="yes"&g

Organic Letters
DOI: 10.1021/acs.orglett.0c01183




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[ASAP] Organocatalytic Regiodivergent Ring Expansion of Cyclobutanones for the Enantioselective Synthesis of Azepino[1,2-<italic toggle="yes">a</italic>]indoles and Cyclohepta[<italic toggle="yes">b</italic>]ind

Organic Letters
DOI: 10.1021/acs.orglett.0c01406




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[ASAP] Hydrogenation or Dehydrogenation of N-Containing Heterocycles Catalyzed by a Single Manganese Complex

Organic Letters
DOI: 10.1021/acs.orglett.0c01273




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[ASAP] Catalytic, Enantioselective C2-Functionalization of 3-Aminobenzofurans Using N-Heterocyclic Carbenes

Organic Letters
DOI: 10.1021/acs.orglett.0c01112




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[ASAP] Nickel-Catalyzed Cyclization Strategy for the Synthesis of Pyrroloquinolines, Indoloquinolines, and Indoloisoquinolines

Organic Letters
DOI: 10.1021/acs.orglett.0c01055




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[ASAP] Enantioselective Copper-Catalyzed Remote C(sp<sup>3</sup>)–H Alkynylation of Linear Primary Sulfonamides

Organic Letters
DOI: 10.1021/acs.orglett.0c01325




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[ASAP] Nickel(II)-Catalyzed Addition of Aryl-, Alkenyl-, and Alkylboronic Acids to Alkenylazaarenes

Organic Letters
DOI: 10.1021/acs.orglett.0c01425




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[ASAP] Designing Homogeneous Copper-Free Sonogashira Reaction through a Prism of Pd–Pd Transmetalation

Organic Letters
DOI: 10.1021/acs.orglett.0c01227




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[ASAP] Total Synthesis of Echinomycin and Its Analogues

Organic Letters
DOI: 10.1021/acs.orglett.0c01268




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[ASAP] Sequential Visible-Light and <italic toggle="yes">N</italic>-Heterocyclic Carbene Catalysis: Stereoselective Synthesis of Tetrahydropyrano[2,3-<italic toggle="yes">b</italic>]indoles

Organic Letters
DOI: 10.1021/acs.orglett.0c01447




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[ASAP] Synthesis of Spiroisoxazolines via an Oximation/Dearomatization Cascade under Air

Organic Letters
DOI: 10.1021/acs.orglett.0c01429




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[ASAP] Columnar Organization of Carbo[5]helicene Directed by Peripheral Steric Perturbation

Organic Letters
DOI: 10.1021/acs.orglett.0c01421




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[ASAP] Copper-Catalyzed 1,2-Aminocyanation of Unactivated Alkenes via Cyano Migration

Organic Letters
DOI: 10.1021/acs.orglett.0c01217




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[ASAP] Phosphorus(III)-Mediated, Tandem Deoxygenative Geminal Chlorofluorination of 1,2-Diketones

Organic Letters
DOI: 10.1021/acs.orglett.0c01258




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[ASAP] Copper-Mediated DNA-Compatible One-Pot Click Reactions of Alkynes with Aryl Borates and TMS-N<sub>3</sub>

Organic Letters
DOI: 10.1021/acs.orglett.0c01219




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[ASAP] Studies of the Enantiocontrolled Synthesis of the C(10)–C(25) Subunit of Amphidinolide C

Organic Letters
DOI: 10.1021/acs.orglett.0c01177




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[ASAP] Palladium-Catalyzed Regio- and Stereoselective Cross-Coupling of Vinylethylene Carbonates with Ketimine Esters to Generate (<italic toggle="yes">Z</italic>)-Tri- and Tetra-substituted Allylic Amino Acid Derivatives

Organic Letters
DOI: 10.1021/acs.orglett.0c01211




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[ASAP] Addition to “Selective Methylation of Amides, <italic toggle="yes">N</italic>-Heterocycles, Thiols, and Alcohols with Tetramethylammonium Fluoride”

Organic Letters
DOI: 10.1021/acs.orglett.0c01524




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[ASAP] Nickel-Catalyzed Formal Aminocarbonylation of Secondary Benzyl Chlorides with Isocyanides

Organic Letters
DOI: 10.1021/acs.orglett.0c01284




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[ASAP] Benzo- and Thieno-Annulated Tetracenes: A One-Pot Synthesis via Cross-Dehydrogenative Annulation

Organic Letters
DOI: 10.1021/acs.orglett.0c01244




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[ASAP] Rh(I)-Catalyzed C6-Selective Decarbonylative Alkylation of 2-Pyridones with Alkyl Carboxylic Acids and Anhydrides

Organic Letters
DOI: 10.1021/acs.orglett.0c01277




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Relevant Details Missing as Cameron Strang Returns

The Christian magazine had halted publication without informing subscribers and has shared little about its founder’s sabbatical.

Last month, Relevant Podcast listeners heard a familiar voice in their earbuds: founder Cameron Strang, returning to the show’s lineup—and to leadership at Relevant Media Group—six months after stepping away due to public criticism from former employees.

Though Relevant promised to be transparent with its efforts to address Strang’s alleged racial insensitivity and difficult leadership style, it did not bring up the process again until the April 10 update announcing his return as CEO.

In the meantime, the bimonthly Christian magazine had not sent out an issue to its 27,000 paid subscribers since Strang left in September, leaving fans to wonder about its future.

Strang told listeners that he’s “excited to be back” for a new era at Relevant as it prepares to revamp and expand its podcast offerings, transition to a yearly print publication, and relaunch its website, all under an advisory board newly enlisted to oversee leadership of the 10-person staff.

Relevant’s loyal followers, some of whom have been around for its entire 20-year history, are excited to hear Strang’s voice again. But as much as they hope to see the kind of progress the company has promised and prayed for, a few have questioned the lack of communication.

“When the print issues stopped coming, I was disappointed but figured the company was trying to figure out how to move forward. I suspected they had lost a lot of advertisers & revenue,” wrote Erin Bird, an Iowa pastor, in a Twitter thread responding to the April update. “I’ve patiently walked thru this w/ you, actually prayed for you guys (& those hurt), & was hoping to see a repentance from Cameron that would show the world ...

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After SAT and ACT Cancel, Registrations Soar for Classical Education Exam

An alternative college admissions test, used by some Christian schools, draws a record 50,000 students.

The Classic Learning Test (CLT), a niche college entrance exam aspiring to bring a sense of virtue to standardized tests, saw a 1,000 percent increase in registrations over its short history when the SAT and ACT canceled testing for the remainder of the school year due to COVID-19.

“Because we are able to administer the test remotely, we’re kind of the only game in town,” said Jeremy Tate, who created the CLT four years ago amid a renaissance in Classical education, including among Christians.

At its first administration in June 2016, 47 students took the CLT. With the bump in registration, 50,000 students will take its suite of tests—the CLT, and the CLT-8 and CLT-10, designed for lower grades—during the 2019-2020 academic year. That’s more than double last year’s total.

Though not a Christian company, CLT references figures including John Henry Newman and C. S. Lewis in its promotional materials and stresses the moral, formational dimension to education. The exam has been popular among classical Christian schools, which educate over 40,000 students in the US, and homeschoolers, who make up about 40 percent of CLT test-takers.

So far, 178 colleges and universities in the US accept the exam, mostly Catholic and Protestant schools. For other institutions, the CLT can serve as a supplemental assessment.

The College Board and ACT Inc., the companies that administer the SAT and ACT, respectively, have canceled or postponed in-person testing until the fall, leading many colleges to make the admissions exams an optional part of their applications. In 2018, around 2 million students took the SAT and 1.9 million took the ACT.

While some registrants may turn to the CLT this year for the convenience ...

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Why We Opened a Christian University in Iraq Amid ISIS’ Genocide

CT interviews Stephen Rasche on Erbil’s Catholic presence, the need for Christian unity, and why Christians will “no longer be shy” with the gospel.

For 25 years, Stephen Rasche was a “bare knuckles” international lawyer. But in 2010, he offered his services to the Chaldean Catholic Church of Erbil in Iraqi Kurdistan and has increasingly dedicated his life to the preservation of this ancient community.

Under the leadership of Archbishop Bashar Matti Warda, in 2015 Rasche helped found the Catholic University of Erbil, where he serves as vice chancellor. Also the director of its Institute for Ancient and Threatened Christianity, Rasche lived this title as ISIS ravaged Iraq’s Christian homelands in the Nineveh Plains and many believers fled to Erbil.

After testifying on their behalf before the United Nations and the US Congress, Rasche allows them to represent themselves in his recent book, The Disappearing People: The Tragic Fate of Christians in the Middle East. The book has won a diverse range of endorsements, from leaders such as Matthew Hassan Kukah, bishop of the Catholic Diocese of Sokoto, Nigeria; Yahya Cholil Staquf, general secretary of Nahdlatul Ulama, the largest Muslim organization in the world; and Thomas Farr, president of the Religious Freedom Institute.

The US State Department’s Office of International Religious Freedom reports that less than 250,000 Christians are living in Iraq, most in Kurdistan or on the Nineveh Plains. Two-thirds belong to the Chaldean Catholic Church.

CT interviewed Rasche about the logic of establishing a university during a genocide, how its Catholic identity functions in a Muslim society, and his enduring optimism for Christianity in Iraq.

What led you personally to invest your life in this endeavor?

In 2010, Bishop Warda had just been made archbishop, and I went to pay him a visit of respect, asking if there ...

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Died: Darrin Patrick, Who Used His Fall and Restoration to Help Struggling Pastors

(UPDATED) The St. Louis pastor spoke up about the difficulties faced by leaders and critiqued “celebrity culture” in ministry.

Darrin Patrick, a megachurch pastor, author, and speaker, has died.

Patrick was a teaching pastor at Seacoast Church, a multi-site megachurch based in Mount Pleasant, South Carolina, and the founding pastor of the Journey Church in St. Louis, where he lived.

In a Friday evening update, Seacoast Church stated: “Darrin was target shooting with a friend at the time of his death. An official cause of death has not been released but it appears to be a self-inflicted gunshot wound. No foul play is suspected.”

Patrick’s unexpected death came as a shock to friends and colleagues. Robby Gallaty, pastor of Long Hollow Baptist, in Hendersonville, Tennessee, said that Patrick was scheduled to speak at his church next weekend.

“I just talked to him Tuesday and Wednesday,” said Gallaty. “This is the second close friend I have lost in a year.”

Gallaty first met Patrick in 2015 and had invited him to speak the following year at a men’s ministry event at Long Hollow. Just before the event, he said, Patrick called and said he was leaving the ministry.

At the time, Patrick had been a rising star among Reformed evangelical circles and was serving as vice-president of the Acts 29 church planting network. He was fired from Journey for what church elders called misconduct including “inappropriate meetings, conversations, and phone calls with two women” and an abuse of power.

Despite Patrick’s fall from ministry, the two stayed friends. Patrick admitted his faults and got counseling. He went through a restoration process that lasted 26 months, according to a 2019 blog interview posted at Christianity Today. He returned to the ministry as a preacher but not as a senior pastor of a church. ...

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Life Insurance Corporation of India’s New Endowment Plan: Check benefits, other details of this policy

LIC's New Endowment Plan is a participating non-linked plan which offers an attractive combination of protection and saving features.




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NLC India TPS II, all about the company where boiler blast occurred in Neyveli

The power stations of the NLC integrated mining-cum-power generating company are located at Neyveli in Cuddalore.




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Ratan Tata invests in 17-year-old kid's pharma start-up Generic Aadhaar

Generic Aadhaar supplies quality generic drugs from reputed manufacturers at up to 80 per cent lesser cost and other medicines 20-30 per cent cheaper.




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BMW launches 8 Series Gran Coupe at Rs 1.3 crore, M8 Coupe at Rs 2.15 crore in India

The BMW 8 Series Gran Coupe is powered by a 3-litre, 6-cylinder in-line BSVI petrol engine. This is the most luxurious sports coupe ever built by BMW, the company said in a statement




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Invest Rs 10,000 and earn Rs 30,000 per month by starting pickle making business

For pickle making business you will be required to obtain a license. 




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CBI court extends Kapil Wadhawan, Dheeraj Wadhawan's custody in Yes Bank scam till May 10

The businessmen-brothers are facing charges of financial irregularities in cases filed by both Enforcement Directorate (ED) and CBI.




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Service charges for Post office savings a/c, issue of duplicate passport and more

Here are some details of service charges that the Post Office charges you.




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Dharmendra Pradhan hints at new gas policy, says low oil prices no answer

Pradhan also said that India favours reasonable prices that give some space to the producer countries.




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Nitin Gadkari asks traders to take loan in dollars, keep their balance sheets clean

The Union minister also offered them some remedies that are likely to earn money and will help them in increasing their business.




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Franklin Templeton issues apology to SEBI, says top executive's remark 'taken out of context'

Franklin Templeton Mutual Fund on Friday said it is making every effort to ensure an orderly and equitable exit to all investors affected by closure of six debt schemes, a day after it was asked by regulator sebi to focus on returning investors' money at the earliest.




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Free market and the reel world

Theatre owners need not fear OTT platforms and resort to protectionism. They can continue to be relevant even as tech disrupts




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An area of darkness

Power sector needs liquidity relief in Covid times



  • From the Viewsroom

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Europe: a natural history / Tim Flannery (with Luigi Boitani)

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The virtuous cyborg / Chris Bateman

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The apparitionists: a tale of phantoms, fraud, photography, and the man who captured Lincoln's ghost / Peter Manseau

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How to hide an empire: a history of the greater United States / Daniel Immerwahr

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The good neighbor: the life and work of Fred Rogers / Maxwell King

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The eight mountains: a novel / Paolo Cognetti ; translated by Simon Carnell and Erica Segre

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