y para-Selective arylation and alkenylation of monosubstituted arenes using thianthrene S-oxide as a transient mediator By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5058-5061DOI: 10.1039/D0CC00641F, CommunicationXiao-Yue Chen, Xiao-Xue Nie, Yichen Wu, Peng WangUsing thianthrene S-oxide (TTSO) as a transient mediator, para-arylation and alkenylation of mono-substituted arenes have been demonstrated via a para-selective thianthrenation/Pd-catalyzed thio-Suzuki–Miyaura coupling sequence under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Electrochemically generated N-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5010-5013DOI: 10.1039/C9CC09869K, CommunicationBinbin Huang, Chao Yang, Jia Zhou, Wujiong XiaThis study presents a straightforward protocol for approaching N-sulphonylamidines via an electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Nitrosoarene-catalyzed regioselective aromatic C–H sulfinylation with thiols under aerobic conditions By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5054-5057DOI: 10.1039/D0CC01188F, CommunicationSuman Pradhan, Sandeep Patel, Indranil ChatterjeeAromatic amines and (hetero)arenes, such as indoles and pyrroles, are regioselectively sulfinylated under mild aerobic conditions using nitrosoarenes as a redox-catalyst.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y 1,6-Conjugate addition initiated formal [4+2] annulation of p-quinone methides with sulfonyl allenols: a unique access to spiro[5.5]undeca-1,4-dien-3-one scaffolds By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5022-5025DOI: 10.1039/D0CC01005G, CommunicationGanesh S. Ghotekar, Sachin R. Shirsath, Aslam C. Shaikh, M. MuthukrishnanAn expedient one-pot synthesis of carbocyclic spiro[5.5]undeca-1,4-dien-3-ones via 1,6-conjugate addition initiated formal [4+2] annulation sequences by employing p-quinone methides and sulfonyl allenols.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Synthetic method, growth mechanism and electrochemical properties of PbSnS2 nanosheets for supercapacitors By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5062-5065DOI: 10.1039/D0CC01011A, CommunicationYuhan Zeng, Hehe Huang, Shenhu Huang, Tongtong Jiang, Zekai Fang, Lin Li, Yuming DaiFacile hydrothermally synthesized PbSnS2 nanosheets with various morphologies were developed to obtain high performance electrode materials for supercapacitors.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Correlating alkyl chain length with defect passivation efficacy in perovskite solar cells By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5006-5009DOI: 10.1039/D0CC01197E, CommunicationWenhuai Feng, Chengxi Zhang, Jun-Xing Zhong, Liming Ding, Wu-Qiang WuAnchoring of amine ligands with different alkyl chain lengths on perovskites mitigates non-radiative charge recombination in perovskite solar cells.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y High performance zinc stannate photoanodes in dye sensitized solar cells with cobalt complex mediators By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5042-5045DOI: 10.1039/D0CC01219J, CommunicationLingling Tao, Zhe Sun, Lei Chen, Mao Liang, Song XueThe combination of a zinc stannate photoanode and cobalt complex electrolyte in DSCs yields an impressive power conversion efficiency of 8.1%.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Solvent-driven migration of highly polar monomers into hydrophobic PDMS produces a thick graft layer via subsurface initiated ATRP for efficient antibiofouling By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5030-5033DOI: 10.1039/D0CC00768D, CommunicationXin Yu, Yang Yang, Wufang Yang, Xungai Wang, Xin Liu, Feng Zhou, Yan ZhaoOrganic solvents that possess affinity towards both polar monomers and hydrophobic PDMS play a “driving” role in the diffusion of polar monomers into the subsurface of the PDMS substrate.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y The synergy between the CsPbBr3 nanoparticle surface and the organic ligand becomes manifest in a demanding carbon–carbon coupling reaction By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5026-5029DOI: 10.1039/D0CC01339K, CommunicationIgnacio Rosa-Pardo, Carla Casadevall, Luciana Schmidt, Miguel Claros, Raquel E. Galian, Julio Lloret-Fillol, Julia Pérez-PrietoThe cooperative action between the CsPbBr3 surface and capping makes the photoredox homo-/cross-coupling of benzyl bromides under mild conditions possible.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Synthesis of functionalized tetrahydropyrans via cascade cycloaddition involving silyloxyallyl cation intermediates By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5034-5037DOI: 10.1039/D0CC01796E, CommunicationFatimat O. Badmus, Joshua A. Malone, Frank R. Fronczek, Rendy KartikaAn expedient synthesis of highly substituted tetrahydrobenzofuran via an unsymmetrical silyloxyallyl cation is reported.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Modulation of an intermediate layer between NiCoP and Ni foam substrate in a microwire array electrode for enhancing the hydrogen-evolution reaction By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,4990-4993DOI: 10.1039/D0CC01488E, CommunicationDan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, Jun LvA strategy involving modulating the intermediate layer of an electrode was developed to promote the electrocatalysis kinetics of the electrode and therefore enhance its performance.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Modified cation-exchange membrane for phosphate recovery in an electrochemically assisted adsorption–desorption process By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5046-5049DOI: 10.1039/C9CC09563B, CommunicationKostadin V. Petrov, Laura Paltrinieri, Lukasz Poltorak, Louis C. P. M. de Smet, Ernst J. R. SudhölterA novel ion separation methodology using a cation-exchange membrane modified with iron oxide nanoparticles (Fe3O4 NPs) coated with polyhexamethylene guanidine (PHMG) is proposed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Ring-opening iodination and bromination of unstrained cycloalkanols through β-scission of alkoxy radicals By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5002-5005DOI: 10.1039/D0CC01720E, CommunicationJiang-Ling Shi, Yuankai Wang, Zixuan Wang, Bowen Dou, Jianbo WangRing-opening iodination or bromination of unstrained cycloalkanols with NaI or NaBr and PhI(OAc)2 under visible light irradiation is developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Highly selective hydrosilylation of equilibrating allylic azides By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5038-5041DOI: 10.1039/D0CC01316A, CommunicationRuzhang Liu, Zhen Wei, Juan Wang, Yongmei Liu, Huaiguo XuePt-catalyzed hydrosilylation of equilibrating allylic azides provides 3-azidopropansilanes with high chemoselectivity, regioselectivity, and excellent functional group tolerance.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y All solid state electrochromic devices based on the LiF electrolyte By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5018-5021DOI: 10.1039/D0CC00697A, CommunicationXi Chen, Shuliang Dou, Wenjie Li, Dongqi Liu, Yongfu Zhang, Yingming Zhao, Yao Li, Jiupeng Zhao, Xiang ZhangA high performance ECD with a structure of glass/ITO/WO3/LiF/NiO/ITO has been prepared by electron beam and resistance evaporation methods.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Catalytic asymmetric synthesis of diazabicyclo[3.1.0]hexanes by 1,3-dipolar cycloaddition of azomethine ylides with azirines By feeds.rsc.org Published On :: Chem. Commun., 2020, 56,5050-5053DOI: 10.1039/D0CC01061H, CommunicationAlba Molina, Sergio Díaz-Tendero, Javier Adrio, Juan C. CarreteroA practical CuI/(R)-Fesulphos catalyzed 1,3-dipolar cycloaddition of azomethine ylides with azirines has been developed to produce highly valuable enantioenriched diazabicyclo[3.1.0]hexanes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Al centre-powered graphitic nanozyme with high catalytic efficiency for pH-independent chemodynamic therapy of cancer By feeds.rsc.org Published On :: Chem. Commun., 2020, Advance ArticleDOI: 10.1039/D0CC01331E, CommunicationJun Li, Ke Yi, Yanli Lei, Zhihe Qing, Zhen Zou, Yuedong Zhang, Haiyan Sun, Ronghua YangIn this work, an Al centre-powered graphitic nanozyme (Fe/Al-GNE) was developed for chemodynamic cancer therapy, which afforded pH-independent catalytic activity and high reaction kinetics.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Improving the structural and cyclic stabilities of P2-type Na0.67MnO2 cathode material via Cu and Ti co-substitution for sodium ion batteries By feeds.rsc.org Published On :: Chem. Commun., 2020, Advance ArticleDOI: 10.1039/D0CC01442G, CommunicationXueping Zhang, Feilong Qiu, Kezhu Jiang, Ping He, Min Han, Shaohua Guo, Haoshen ZhouAn air-stable Na0.67Mn0.7Cu0.15Ti0.15O2 (NMCT) has been synthesized using a solid-state method. And it showed the excellent performance as a cathode material for sodium ion batteries.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Facile construction of double network cross-linked luminescent supramolecular elastomer from hydrosilylation and pillar[5]arene host–guest recognition By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC02214D, CommunicationRong Fu, Junying Zhang, Shaojie Liu, Xing-Dong XU, Shengyu FengReticulated copolymer hosts pillar[5]arene crosslinked with poly(dimethylsiloxane) (PDMS) were synthesized for the facile construction of double network crosslinked elastomer upon noncovalently cross-linking with tetraphenyethylene (TPE)-based tetratopic guests through host-guest interactions....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Photo-regulated supramolecular star with a pillar[6]arene-coated metal-organic polyhedron (MOP) core By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC00536C, CommunicationXiang Hao, ZeJian Leng, Dan Sun, Feng Peng, Akram YasinWe herein report a 12-armed photo-responsive supramolecular star centered by a pillar[6]arene-coated M6L12 metal-organic polyhedron (MOP) via core-first approach.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Control of microenvironment around enzymes by hydrogels By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC01332C, CommunicationYuichiro Kobayashi, Kenji Kohara, Yusuke Kiuchi, Hiroki Onoda, Osami Shoji, Hiroyasu YamaguchiWe prepared enzyme immobilized hydrogels and investigated the effects of the cross-linking density and polymer properties on their oxidation reaction rate. The oxidation rate of enzyme immobilized hydrogels increased as...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Is breaking of a hydrogen bond enough to lead to drug resistance? By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC02164D, CommunicationMaría José Dávila-Rodríguez, Thales Souza Freire, Erik Lindahl, Ignez Caracelli, Júlio Zukerman-Schpector, Ran FriedmanDrug resistance is a serious problem in cancer, viral, bacterial, fungal and parasitic diseases. Examination of crystal structures of protein-drug complexes is often not enough to explain why a certain...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y A combined viscosity-restricted intramolecular motion and mitochondrial targeting leads to selective tumor visualization By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC02943B, CommunicationLe Yu, Jun Feng Zhang, Mingle Li, Dewei Jiang, Ying Zhou, Peter Verwilst, Jong Seung KimWe report a novel fluorescent molecular conjugate V-M1 enabling an accurate visualization of tumor tissues. The emission wavelength of V-M1 exceeds 650 nm, well within the near-infrared therapeutic window. Tumor...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Efficient generation of sulfate radicals in Fe (II)/S (IV) system induced by WS2 nanosheets and examined by its intrinsic chemiluminescence By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC01999B, CommunicationTong Sun, Yingying Su, Houjing Liu, Hongjie Song, Yi LvIn this study, more 〖SO〗_4^( ∙-) and strong intrinsic chemiluminescence (CL) can be achieved through activating sulphite (〖SO〗_3^( 2-)) with ferrous ions (Fe2+) on the WS2 nanosheets with the thickness...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Rh(III)-catalyzed sequential ortho- C–H oxidative arylation/cyclization of sulfoxonium ylides with quinones toward 2-hydroxy-dibenzo[b,d]pyran-6-ones By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC00176G, CommunicationYaqun Dong, Jin-Tao Yu, Song Sun, Jiang ChengA rhodium(III)-catalyzed ortho- C−H functionalization of sulfoxonium ylides followed by intramolecular annulation reactions with quinones is described, where the carbonyl in sulfoxonium ylides served as a chelation group. This protocol...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Electrospray Ionization: an efficient approach to deposit polymetallic molecular switches onto gold surfaces By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC01906B, CommunicationAmina Benchohra, Christophe Méthivier, david kreher, Jessem Landoulsi, rodrigue lescouezecElectrospray ionization (EI) deposition is proven efficient in obtaining monolayers of a polymetallic charge transfer complex onto gold surfaces. The molecule’s integrity is monitored by PM-IRRAS and XPS. This approach...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Superstructural diversity in salt-cocrystals: higher-order hydrogen-bonded assemblies formed using U-shaped dications and with assistance of π(-)−π stacking By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC02671A, CommunicationShweta P. Yelgaonkar, Daniyal Kiani, Jonas Baltrusaitis, Len R MacGillivraySalt cocrystals with components that assemble by hydrogen bonds and aromatic anion-molecule stacks (π(−)−π stacks) are reported. U-shaped bipyridines and an isocoumarin carboxylic acid self-assemble to form 5-, 6-, and...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Engineering of Decameric D-fructose-6-phosphate Aldolase A by Combinatorial Modulation of Inter- and Intra-subunit Interactions By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC02437F, CommunicationXiaohong Yang, Lian Wu, Aipeng Li, Lidan Ye, Jiahai Zhou, Hongwei YuCombinatorial modulation of inter- and intra-subunit interactions on decameric D-fructose-6-phosphate aldolase A (FSAA) generated a triple-site variant I31T/Q59T/I195Q FSAA with 27 to 278-fold activity improvement towards target heteroaromatic aldehydes. X-ray...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y A directing group assisted ruthenium catalyzed approach to access meta nitrated phenol By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC02851G, CommunicationSheuli Sasmal, Soumya Kumar Sinha, Goutam Kumar Lahiri, Debrabrata MaitiA meta selective C‒H nitration of phenol derivatives have been developed using a Ru-catalyzed σ-activation strategy. Cu(NO3)2.3H2O has been employed as the nitrating source while Ru3(CO)12 was found to be...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Integration of ultra-high-pressure liquid chromatography-tandem mass spectrometry with machine learning for identifying fatty acid metabolite biomarkers of ischemic stroke By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC02329A, CommunicationLijian Zhang, Fei Ma, Ao Qi, Lulu Liu, Junjie Zhang, Simin Xu, Qisheng Zhong, Yusen Chen, Chun-yang Zhang, Chun CaiWe report for the first time the integration of ultra-high-pressure liquid chromatography-tandem mass spectrometry with machine learning for identifying fatty acid metabolite biomarkers of ischemic stroke. Especially, we develop an...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Rotation of a helical coordination polymer by mechanical grinding By feeds.rsc.org Published On :: Chem. Commun., 2020, Advance ArticleDOI: 10.1039/D0CC02158J, CommunicationBibhuti Bhusan Rath, Goutam Kumar Kole, Samuel Alexander Morris, Jagadese J. VittalMechanical grinding causes anisotropic cell volume expansion, which facilitates the misaligned arms containing olefin functional groups in the neighbouring strands of the photo-inert helical coordination polymer to align to undergo [2+2] cycloaddition reaction.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Helicity of a polyacetylene directed by molecular recognition of biscalixarene and fullerene By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC02506B, CommunicationTakehiro Hirao, Yoshiki Iwabe, Naoyuki Hisano, Takeharu HAINOChiral biscalixarenes and a C60-appended polyphenylacetylene have been synthesized. The chiral biscalixarene encapsulated the C60 unit of the phenylpolyacetylene, which induced the preferred helicity of the polyacetylene.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Monitoring Protein Ubiquitination and SUMOylation in real-time by NMR By feeds.rsc.org Published On :: Chem. Commun., 2020, Accepted ManuscriptDOI: 10.1039/D0CC02252G, CommunicationBatul Ismail Habibullah, Vasvi Tripathi, Parag Surana, Ranabir DasUbiquitin (Ub) is a highly conserved 76-amino acid polypeptide that is abundant throughout the eukaryotes. The covalent conjugation of Ub and Ub polymers to substrate proteins governs a variety of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
y Living pictures : perspectives on the film poster in India / edited by David Blamey & Robert D'Souza ; [writers, Sara Dickey ... et al.] By prospero.murdoch.edu.au Published On :: Full Article
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