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para-Selective arylation and alkenylation of monosubstituted arenes using thianthrene S-oxide as a transient mediator

Chem. Commun., 2020, 56,5058-5061
DOI: 10.1039/D0CC00641F, Communication
Xiao-Yue Chen, Xiao-Xue Nie, Yichen Wu, Peng Wang
Using thianthrene S-oxide (TTSO) as a transient mediator, para-arylation and alkenylation of mono-substituted arenes have been demonstrated via a para-selective thianthrenation/Pd-catalyzed thio-Suzuki–Miyaura coupling sequence under mild conditions.
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Electrochemically generated N-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines

Chem. Commun., 2020, 56,5010-5013
DOI: 10.1039/C9CC09869K, Communication
Binbin Huang, Chao Yang, Jia Zhou, Wujiong Xia
This study presents a straightforward protocol for approaching N-sulphonylamidines via an electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines.
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Nitrosoarene-catalyzed regioselective aromatic C–H sulfinylation with thiols under aerobic conditions

Chem. Commun., 2020, 56,5054-5057
DOI: 10.1039/D0CC01188F, Communication
Suman Pradhan, Sandeep Patel, Indranil Chatterjee
Aromatic amines and (hetero)arenes, such as indoles and pyrroles, are regioselectively sulfinylated under mild aerobic conditions using nitrosoarenes as a redox-catalyst.
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1,6-Conjugate addition initiated formal [4+2] annulation of p-quinone methides with sulfonyl allenols: a unique access to spiro[5.5]undeca-1,4-dien-3-one scaffolds

Chem. Commun., 2020, 56,5022-5025
DOI: 10.1039/D0CC01005G, Communication
Ganesh S. Ghotekar, Sachin R. Shirsath, Aslam C. Shaikh, M. Muthukrishnan
An expedient one-pot synthesis of carbocyclic spiro[5.5]undeca-1,4-dien-3-ones via 1,6-conjugate addition initiated formal [4+2] annulation sequences by employing p-quinone methides and sulfonyl allenols.
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Synthetic method, growth mechanism and electrochemical properties of PbSnS2 nanosheets for supercapacitors

Chem. Commun., 2020, 56,5062-5065
DOI: 10.1039/D0CC01011A, Communication
Yuhan Zeng, Hehe Huang, Shenhu Huang, Tongtong Jiang, Zekai Fang, Lin Li, Yuming Dai
Facile hydrothermally synthesized PbSnS2 nanosheets with various morphologies were developed to obtain high performance electrode materials for supercapacitors.
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Correlating alkyl chain length with defect passivation efficacy in perovskite solar cells

Chem. Commun., 2020, 56,5006-5009
DOI: 10.1039/D0CC01197E, Communication
Wenhuai Feng, Chengxi Zhang, Jun-Xing Zhong, Liming Ding, Wu-Qiang Wu
Anchoring of amine ligands with different alkyl chain lengths on perovskites mitigates non-radiative charge recombination in perovskite solar cells.
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High performance zinc stannate photoanodes in dye sensitized solar cells with cobalt complex mediators

Chem. Commun., 2020, 56,5042-5045
DOI: 10.1039/D0CC01219J, Communication
Lingling Tao, Zhe Sun, Lei Chen, Mao Liang, Song Xue
The combination of a zinc stannate photoanode and cobalt complex electrolyte in DSCs yields an impressive power conversion efficiency of 8.1%.
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Solvent-driven migration of highly polar monomers into hydrophobic PDMS produces a thick graft layer via subsurface initiated ATRP for efficient antibiofouling

Chem. Commun., 2020, 56,5030-5033
DOI: 10.1039/D0CC00768D, Communication
Xin Yu, Yang Yang, Wufang Yang, Xungai Wang, Xin Liu, Feng Zhou, Yan Zhao
Organic solvents that possess affinity towards both polar monomers and hydrophobic PDMS play a “driving” role in the diffusion of polar monomers into the subsurface of the PDMS substrate.
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The synergy between the CsPbBr3 nanoparticle surface and the organic ligand becomes manifest in a demanding carbon–carbon coupling reaction

Chem. Commun., 2020, 56,5026-5029
DOI: 10.1039/D0CC01339K, Communication
Ignacio Rosa-Pardo, Carla Casadevall, Luciana Schmidt, Miguel Claros, Raquel E. Galian, Julio Lloret-Fillol, Julia Pérez-Prieto
The cooperative action between the CsPbBr3 surface and capping makes the photoredox homo-/cross-coupling of benzyl bromides under mild conditions possible.
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Synthesis of functionalized tetrahydropyrans via cascade cycloaddition involving silyloxyallyl cation intermediates

Chem. Commun., 2020, 56,5034-5037
DOI: 10.1039/D0CC01796E, Communication
Fatimat O. Badmus, Joshua A. Malone, Frank R. Fronczek, Rendy Kartika
An expedient synthesis of highly substituted tetrahydrobenzofuran via an unsymmetrical silyloxyallyl cation is reported.
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Modulation of an intermediate layer between NiCoP and Ni foam substrate in a microwire array electrode for enhancing the hydrogen-evolution reaction

Chem. Commun., 2020, 56,4990-4993
DOI: 10.1039/D0CC01488E, Communication
Dan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, Jun Lv
A strategy involving modulating the intermediate layer of an electrode was developed to promote the electrocatalysis kinetics of the electrode and therefore enhance its performance.
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Modified cation-exchange membrane for phosphate recovery in an electrochemically assisted adsorption–desorption process

Chem. Commun., 2020, 56,5046-5049
DOI: 10.1039/C9CC09563B, Communication
Kostadin V. Petrov, Laura Paltrinieri, Lukasz Poltorak, Louis C. P. M. de Smet, Ernst J. R. Sudhölter
A novel ion separation methodology using a cation-exchange membrane modified with iron oxide nanoparticles (Fe3O4 NPs) coated with polyhexamethylene guanidine (PHMG) is proposed.
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Ring-opening iodination and bromination of unstrained cycloalkanols through β-scission of alkoxy radicals

Chem. Commun., 2020, 56,5002-5005
DOI: 10.1039/D0CC01720E, Communication
Jiang-Ling Shi, Yuankai Wang, Zixuan Wang, Bowen Dou, Jianbo Wang
Ring-opening iodination or bromination of unstrained cycloalkanols with NaI or NaBr and PhI(OAc)2 under visible light irradiation is developed.
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Highly selective hydrosilylation of equilibrating allylic azides

Chem. Commun., 2020, 56,5038-5041
DOI: 10.1039/D0CC01316A, Communication
Ruzhang Liu, Zhen Wei, Juan Wang, Yongmei Liu, Huaiguo Xue
Pt-catalyzed hydrosilylation of equilibrating allylic azides provides 3-azidopropansilanes with high chemoselectivity, regioselectivity, and excellent functional group tolerance.
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All solid state electrochromic devices based on the LiF electrolyte

Chem. Commun., 2020, 56,5018-5021
DOI: 10.1039/D0CC00697A, Communication
Xi Chen, Shuliang Dou, Wenjie Li, Dongqi Liu, Yongfu Zhang, Yingming Zhao, Yao Li, Jiupeng Zhao, Xiang Zhang
A high performance ECD with a structure of glass/ITO/WO3/LiF/NiO/ITO has been prepared by electron beam and resistance evaporation methods.
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Catalytic asymmetric synthesis of diazabicyclo[3.1.0]hexanes by 1,3-dipolar cycloaddition of azomethine ylides with azirines

Chem. Commun., 2020, 56,5050-5053
DOI: 10.1039/D0CC01061H, Communication
Alba Molina, Sergio Díaz-Tendero, Javier Adrio, Juan C. Carretero
A practical CuI/(R)-Fesulphos catalyzed 1,3-dipolar cycloaddition of azomethine ylides with azirines has been developed to produce highly valuable enantioenriched diazabicyclo[3.1.0]hexanes.
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Al centre-powered graphitic nanozyme with high catalytic efficiency for pH-independent chemodynamic therapy of cancer

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01331E, Communication
Jun Li, Ke Yi, Yanli Lei, Zhihe Qing, Zhen Zou, Yuedong Zhang, Haiyan Sun, Ronghua Yang
In this work, an Al centre-powered graphitic nanozyme (Fe/Al-GNE) was developed for chemodynamic cancer therapy, which afforded pH-independent catalytic activity and high reaction kinetics.
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Improving the structural and cyclic stabilities of P2-type Na0.67MnO2 cathode material via Cu and Ti co-substitution for sodium ion batteries

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01442G, Communication
Xueping Zhang, Feilong Qiu, Kezhu Jiang, Ping He, Min Han, Shaohua Guo, Haoshen Zhou
An air-stable Na0.67Mn0.7Cu0.15Ti0.15O2 (NMCT) has been synthesized using a solid-state method. And it showed the excellent performance as a cathode material for sodium ion batteries.
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Facile construction of double network cross-linked luminescent supramolecular elastomer from hydrosilylation and pillar[5]arene host–guest recognition

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02214D, Communication
Rong Fu, Junying Zhang, Shaojie Liu, Xing-Dong XU, Shengyu Feng
Reticulated copolymer hosts pillar[5]arene crosslinked with poly(dimethylsiloxane) (PDMS) were synthesized for the facile construction of double network crosslinked elastomer upon noncovalently cross-linking with tetraphenyethylene (TPE)-based tetratopic guests through host-guest interactions....
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Photo-regulated supramolecular star with a pillar[6]arene-coated metal-organic polyhedron (MOP) core

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00536C, Communication
Xiang Hao, ZeJian Leng, Dan Sun, Feng Peng, Akram Yasin
We herein report a 12-armed photo-responsive supramolecular star centered by a pillar[6]arene-coated M6L12 metal-organic polyhedron (MOP) via core-first approach.
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Control of microenvironment around enzymes by hydrogels

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01332C, Communication
Yuichiro Kobayashi, Kenji Kohara, Yusuke Kiuchi, Hiroki Onoda, Osami Shoji, Hiroyasu Yamaguchi
We prepared enzyme immobilized hydrogels and investigated the effects of the cross-linking density and polymer properties on their oxidation reaction rate. The oxidation rate of enzyme immobilized hydrogels increased as...
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Is breaking of a hydrogen bond enough to lead to drug resistance?

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02164D, Communication
María José Dávila-Rodríguez, Thales Souza Freire, Erik Lindahl, Ignez Caracelli, Júlio Zukerman-Schpector, Ran Friedman
Drug resistance is a serious problem in cancer, viral, bacterial, fungal and parasitic diseases. Examination of crystal structures of protein-drug complexes is often not enough to explain why a certain...
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A combined viscosity-restricted intramolecular motion and mitochondrial targeting leads to selective tumor visualization

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02943B, Communication
Le Yu, Jun Feng Zhang, Mingle Li, Dewei Jiang, Ying Zhou, Peter Verwilst, Jong Seung Kim
We report a novel fluorescent molecular conjugate V-M1 enabling an accurate visualization of tumor tissues. The emission wavelength of V-M1 exceeds 650 nm, well within the near-infrared therapeutic window. Tumor...
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Efficient generation of sulfate radicals in Fe (II)/S (IV) system induced by WS2 nanosheets and examined by its intrinsic chemiluminescence

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01999B, Communication
Tong Sun, Yingying Su, Houjing Liu, Hongjie Song, Yi Lv
In this study, more 〖SO〗_4^( ∙-) and strong intrinsic chemiluminescence (CL) can be achieved through activating sulphite (〖SO〗_3^( 2-)) with ferrous ions (Fe2+) on the WS2 nanosheets with the thickness...
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Rh(III)-catalyzed sequential ortho- C–H oxidative arylation/cyclization of sulfoxonium ylides with quinones toward 2-hydroxy-dibenzo[b,d]pyran-6-ones

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00176G, Communication
Yaqun Dong, Jin-Tao Yu, Song Sun, Jiang Cheng
A rhodium(III)-catalyzed ortho- C−H functionalization of sulfoxonium ylides followed by intramolecular annulation reactions with quinones is described, where the carbonyl in sulfoxonium ylides served as a chelation group. This protocol...
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Electrospray Ionization: an efficient approach to deposit polymetallic molecular switches onto gold surfaces

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01906B, Communication
Amina Benchohra, Christophe Méthivier, david kreher, Jessem Landoulsi, rodrigue lescouezec
Electrospray ionization (EI) deposition is proven efficient in obtaining monolayers of a polymetallic charge transfer complex onto gold surfaces. The molecule’s integrity is monitored by PM-IRRAS and XPS. This approach...
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Superstructural diversity in salt-cocrystals: higher-order hydrogen-bonded assemblies formed using U-shaped dications and with assistance of π(-)−π stacking

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02671A, Communication
Shweta P. Yelgaonkar, Daniyal Kiani, Jonas Baltrusaitis, Len R MacGillivray
Salt cocrystals with components that assemble by hydrogen bonds and aromatic anion-molecule stacks (π(−)−π stacks) are reported. U-shaped bipyridines and an isocoumarin carboxylic acid self-assemble to form 5-, 6-, and...
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Engineering of Decameric D-fructose-6-phosphate Aldolase A by Combinatorial Modulation of Inter- and Intra-subunit Interactions

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02437F, Communication
Xiaohong Yang, Lian Wu, Aipeng Li, Lidan Ye, Jiahai Zhou, Hongwei Yu
Combinatorial modulation of inter- and intra-subunit interactions on decameric D-fructose-6-phosphate aldolase A (FSAA) generated a triple-site variant I31T/Q59T/I195Q FSAA with 27 to 278-fold activity improvement towards target heteroaromatic aldehydes. X-ray...
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A directing group assisted ruthenium catalyzed approach to access meta nitrated phenol

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02851G, Communication
Sheuli Sasmal, Soumya Kumar Sinha, Goutam Kumar Lahiri, Debrabrata Maiti
A meta selective C‒H nitration of phenol derivatives have been developed using a Ru-catalyzed σ-activation strategy. Cu(NO3)2.3H2O has been employed as the nitrating source while Ru3(CO)12 was found to be...
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Integration of ultra-high-pressure liquid chromatography-tandem mass spectrometry with machine learning for identifying fatty acid metabolite biomarkers of ischemic stroke

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02329A, Communication
Lijian Zhang, Fei Ma, Ao Qi, Lulu Liu, Junjie Zhang, Simin Xu, Qisheng Zhong, Yusen Chen, Chun-yang Zhang, Chun Cai
We report for the first time the integration of ultra-high-pressure liquid chromatography-tandem mass spectrometry with machine learning for identifying fatty acid metabolite biomarkers of ischemic stroke. Especially, we develop an...
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Rotation of a helical coordination polymer by mechanical grinding

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02158J, Communication
Bibhuti Bhusan Rath, Goutam Kumar Kole, Samuel Alexander Morris, Jagadese J. Vittal
Mechanical grinding causes anisotropic cell volume expansion, which facilitates the misaligned arms containing olefin functional groups in the neighbouring strands of the photo-inert helical coordination polymer to align to undergo [2+2] cycloaddition reaction.
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Helicity of a polyacetylene directed by molecular recognition of biscalixarene and fullerene

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02506B, Communication
Takehiro Hirao, Yoshiki Iwabe, Naoyuki Hisano, Takeharu HAINO
Chiral biscalixarenes and a C60-appended polyphenylacetylene have been synthesized. The chiral biscalixarene encapsulated the C60 unit of the phenylpolyacetylene, which induced the preferred helicity of the polyacetylene.
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Monitoring Protein Ubiquitination and SUMOylation in real-time by NMR

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02252G, Communication
Batul Ismail Habibullah, Vasvi Tripathi, Parag Surana, Ranabir Das
Ubiquitin (Ub) is a highly conserved 76-amino acid polypeptide that is abundant throughout the eukaryotes. The covalent conjugation of Ub and Ub polymers to substrate proteins governs a variety of...
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Living pictures : perspectives on the film poster in India / edited by David Blamey & Robert D'Souza ; [writers, Sara Dickey ... et al.]




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Pro CSS for high traffic Websites / Antony Kennedy, Inayaili de León

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Mobile Web 2.0 : developing and delivering services to mobile devices / edited by Syed A. Ahson, Mohammad Ilyas




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Scalability rules : 50 principles for scaling Web sites / Martin L. Abbott, Michael T. Fisher

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HTML : a beginner's guide / Wendy Willard

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How to do everything with Dreamweaver 8 / Michael Meadhra

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How to do everything with Flash 8 / Bonnie Blake, Doug Sahlin

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Typography = Typographie = Typographie : when, who, how / edited by Friedrich Friedl, Nicolaus Ott, Bernard Stein; text Philipp Luidl




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The animation book : a complete guide to animated filmmaking--from flip-books to sound cartoons to 3-D animation / Kit Laybourne ; preface by George Griffin ; introduction by John Canemaker

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Typo survival kit for all type emergencies / Jill Yeland

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Cartoon animation / by Preston Blair

Blair, Preston




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50 digital ideas you really need to know / Tom Chatfield

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3D math primer for graphics and game development / Fletcher Dunn, Ian Parberry

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GPU computing gems / [edited by] Wen-mei W. Hwu




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Graphics shaders : theory and practice / Mike Bailey, Steve Cunningham

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The enigma of web interfaces : cultural aspects of web site design / by Linda Lim Mei Luan

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Head first mobile web / Lyza Danger Gardner, Jason Grigsby

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