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Pyrenoimidazole fused phenanthridine derivatives with intense red excimer fluorescence in solid-state

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01223H, Paper
Joseph Ajantha, Shanmugam Karthik, Thirumanavelan Gandhi, Easwaramoorthi Shanmugam
A new series of polycyclic aromatic hydrocarbon (PAH), pyrenoimidazole (PyFPs) having different substituents were developed as fluorescence emitters for optoelectronic applications. The compounds were synthesized by means of transition metal-free,...
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Catalytic oxidation mechanisms of carbon monoxide over single and double vacancy Mn-embedded graphene

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01500H, Paper
Mingming Luo, Zhao Liang, Mingwei Chen, Shaik Gouse Peera, Chao Liu, Hui Yang, Xiaopeng Qi, Juan Liu, Tongxiang Liang
Single-atom catalysts (SACs) have been extensively investigated in recent times due to their highly dispersed atomic levels and the improved distribution of their metallic active sites, maximizing the specific activity...
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Photo-degradation of Porphyrin bounded hIAPP (1-37) Fibrils

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9NJ06082K, Paper
Yongxiu Song, Ping Li, Zhimin Zhang, Yin Wang, Zhefei Zhang, Lei Liu, Mingdong Dong
Amyloid deposits in pancreatic islets of type 2 diabetes mellitus (T2DM) is mainly comprised of human islet amyloid polypeptide (hIAPP), which is believed to be generated as a paracrine hormone...
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Hydrogenation of CO2 to LPG over CuZnZr/MeSAPO-34 Catalyst

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00907E, Paper
Peng Lu, Tong Mingliang, Emmerson Hondo, Linet Gapu Chizema, Ce Du, Qingxiang Ma, Shuting Mo, Chengxue Lu, Noritatsu Tsubaki
The utilization of CO2 to synthesize environmentally begnin liquid fuels offers a solution to replacing depleting petroleum resources. Herein, a ternary CuZnZr (CZZ) metal oxide catalyst and a SAPO-34 zeolite...
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Discovery of [1,2,4]triazolo[4,3-a]pyrazine derivatives bearing 4-oxo-pyridazinone moiety as potential c-Met kinase inhibitors

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00575D, Paper
Binliang Zhang, Xiaobo Liu, Hehua Xiong, Qian Zhang, Xin Sun, Zunhua Yang, Shan Xu, Pengwu Zheng, Wufu Zhu
Two series of [1,2,4]triazolo[4,3-a]pyrazine derivatives bearing 4-oxo-pyridazinone moiety (compounds 21a-l and 22a-l) were designed and evaluated for the IC50 values against three cancer cell lines (A549, MCF-7 and Hela) and...
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Cd(II) coordination compounds as heterogeneous catalysts for microwave-assisted peroxidative oxidation of toluene and 1-phenyletanol

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01408G, Paper
Manas Sutradhar, Tannistha Roy Barman, Elisabete Clara Bastos do Amaral Alegria, Hugo M Lapa, M. Fátima C. Guedes da Silva, Armando J. L. Pombeiro
The aroylhydrazone Schiff bases 2-hydroxy(2-hydroxybenzylidene)benzohydrazide (H2L1) and 2-amino(2-hydroxybenzylidene)benzohydrazide (H2L2) have been used to synthesize the new Cd(II) coordination polymer [Cd(-1ONO’:2O:3O’’-L1)(DMF)]n (1) and the dinuclear complex [Cd(1ONO’:2O-HL2)(OO’-Ac)]2·2DMF (2). Both 1 and...
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Preparation of MOFs Catalysts Simultaneously Modulated Metal Nodes and Ligands Via One-Pot Method for Optimizing Cycloaddition Reactions

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01086C, Letter
Peng Wang, Sha Wang, Wenlei Zhang, Xiaohan Li, Zhida Gu, Wenze Li, Shuang Zhao, Yu Fu
MOFs catalysts are farbricated in one-pot method by simultaneously adjusting metal nodes and ligands. Pore environments, Lewis acids (LAs) and Brønsted acids (BAs) are controlled when using BAs groups to...
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Non-Photoisomerizable Butterfly Shaped Tetrasubstituted Azobenzenes: Synthesis and Photophysical Studies

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01092H, Paper
Raman Arunachalam, Afeefah U Neelambra, Venugopal Karunakaran, Easwaramoorthi Shanmugam
The trans-azobenzene (AB) substituted derivatives with bulky carbazole (1), phenothiazine (2), and phenyl (3) have been synthesized to understand the effect of steric crowding around –N=N– linkage on the photoisomerization...
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Effect of number and different types of proton donors on excited-state intramolecular single and double proton transfer in bipyridine derivatives: theoretical insights

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01304H, Paper
Komsun Chaihan, Nawee Kungwan
Intra-HBs are strengthened upon photoexcitation, confirmed by red-shift in vibrational mode and topology analysis. Number and type of donors result in difference in photophysical properties. Occurrence of ESIPT depends on barrier and reaction energy.
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Fabrication of a 3D self-supporting Ni–P/Ni2P/CC composite and its robust hydrogen evolution reaction properties in alkaline solution

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00727G, Paper
Fan Yang, Shuqin Yang, Qianqian Niu, Siyue Huo, Zimo Song, Laizhou Song
The Ni–P/Ni2P/CC composite exhibits excellent alkaline HER properties derived from Ni–P filling the sites on the CC not occupied by Ni2P nanosheets.
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Bonding–antibonding state transition induces multiple electron modulations toward oxygen reduction reaction electrocatalysis

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00660B, Paper
Qi Zhang, Haixia Zhong, Can Chen, Juexian Cao, Liwen Yang, Xiaolin Wei
B doping induces the transformation from the bonding state to the antibonding state of an Ni–N bond, resulting in enhanced ORR activity.
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Synthesis of 3-halochromones with simple KX halogen sources enabled by in situ halide oxidation

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00825G, Paper
Yan Lin, Jie-Ping Wan, Yunyun Liu
An in situ oxidation strategy for generating molecular halogen has been developed for the synthesis of 3-halochromones by employing simple potassium halides as halogen sources.
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A nickel molybdenum oxide nanoarray as an efficient and stable electrocatalyst for overall water splitting

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01232G, Paper
Xiaoshuang Zhang, Hui Su, Xiaoqiang Du
Experimental and DFT calculation results show that the presence of oxygen vacancies can decrease the adsorption energy of intermediates at active sites and facilitate their adsorption, thus improving the catalytic properties.
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Catalytic transfer hydrogenation of biomass-derived levulinic acid to γ-valerolactone over Sn/Al-SBA-15 catalysts

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01288B, Paper
Sakthivel Kumaravel, Sivakumar Thiripuranthagan, Mani Durai, Elangovan Erusappan, Thanigaivel Vembuli
The synthesized inexpensive catalysts show high catalytic transfer hydrogenation activity at ambient N2 pressure under non-corrosive conditions. The Sn/Al-SBA-15 (25) catalyst exhibited the highest catalytic activity with 99% conversion of levulinic acid and 100% selectivity towards GVL.
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Synthesis of characteristic polyisoprenes using rationally designed iminopyridyl metal (Fe and Co) precatalysts: investigation of co-catalysts and steric influence on their catalytic activity

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00942C, Paper
Wenhua Lin, Liping Zhang, Hongyi Suo, Arumugam Vignesh, Nighat Yousuf, Xiang Hao, Wen-Hua Sun
A series of iminopyridyl ligand-based iron and cobalt complexes are utilized as catalysts in isoprene polymerization, in which the microstructure of resultant polyisoprenes was investigated.
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Imidazole diarylethene switches: an alternative to acid-gated photochromism

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00606H, Paper
Kang-Tai Xiong, Meng-Lian Li, Yue Jiang, Hai-Bing Xu, Ming-Hua Zeng
Improving the photoactivity of imidazole diarylethenes by modifying their response sites in imidazole instead of appended aryl units is accomplished.
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Narrow bandgap difluorobenzochalcogenadiazole-based polymers for high-performance organic thin-film transistors and polymer solar cells

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01006E, Paper
Shengbin Shi, Qiaogan Liao, Hang Wang, Guomin Xiao
A series of difluorobenzochalcogenadiazole-bithiophene copolymers are developed for high-performance organic semiconductors.
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Unraveling the helianane family: a complementary quantum mechanical study

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01396J, Paper
Lucas H. Martorano, Alessandra L. Valverde, Carlos Magno R. Ribeiro, Ana Carolina F. de Albuquerque, José Walkimar de M. Carneiro, Rodolfo G. Fiorot, Fernando M. dos Santos Junior
Comprehensive work suggesting the amendment of helianane to the open ring curcudiol by means of computational spectroscopy and thermodynamic reasons.
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Investigation of phosphogypsum valorization by the integration of the Merseburg method

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00387E, Paper
Ines Hammas-Nasri, Sarra Elgharbi, Mounir Ferhi, Karima Horchani-Naifer, Mokhtar Férid
The proposal of a method for converting the phosphogypsum waste (PG) remains the focus of many researchers since its quantity, growing considerably, is causing serious environmental problems.
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Water-soluble poly(N-isopropylacrylamide) nanoparticles grafted to trivalent lanthanide complexes as highly sensitive ratiometric nanothermometers

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01263G, Paper
Josiane Aparecida Sobrinho, Gilmar Araújo Brito Júnior, Italo Odone Mazali, Fernando Aparecido Sigoli
A new water-soluble, luminescent ratiometric nanothermometer with a tunable temperature-responsive range, high thermal sensitivity and good repeatability was designed and synthesized by grafting lanthanide complexes to pNIPAM polymeric nanoparticles.
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Hydrodecarboxylation of fatty acids into liquid hydrocarbons over a commercial Ru/C catalyst under mild conditions

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00730G, Letter
Zihao Zhang, Francis Okejiri, Yafei Li, Jing Li, Jie Fu
100% stearic acid conversion can be achieved at even 160 °C alongside a 90.1% yield of heptadecane.
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Proton conduction in two Cu/Zn dimer-based hydrogen-bonded supramolecular frameworks from imidazole multi-carboxylate

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01189D, Paper
Qingxu Wang, Zhejun Ye, Guoqing Shi, Kaimeng Guo, Gang Li
At 98% RH and 100 °C, two dimer-based HSFs show the best σ values of 3.13 × 10−4 S cm−1 for 1 and 0.55 × 10−4 S cm−1 for 2, which can be compared to the values of reported HSFs.
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Oligoaniline-functionalized polysiloxane/Prussian blue composite towards bifunctional electrochromic supercapacitors

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00736F, Paper
Yanyan Wang, Xiaoteng Jia, Meihua Zhu, Xincai Liu, Danming Chao
We report the preparation of a novel oligoaniline-functionalized polysiloxane/Prussian blue composite, which exhibits improved electrochromic properties and approving supercapacitor performance featuring charge storage indicating functionalization.
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Discrete and polymeric ensembles based on dinuclear molybdenum(VI) building blocks with adaptive carbohydrazide ligands: from the design to catalytic epoxidation

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01045F, Paper
Edi Topić, Jana Pisk, Dominique Agustin, Martin Jendrlin, Danijela Cvijanović, Višnja Vrdoljak, Mirta Rubčić
Discrete and polymeric ensembles based on dimolybdenum(VI) units with adaptive carbohydrazide ligands are described. The polymeric complexes are efficient catalysts for cyclooctene epoxidation under eco-friendly conditions.
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A novel nanosensor for detecting tetracycline based on fluorescent palladium nanoclusters

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9NJ06218A, Paper
Xiaoyan Du, Wenxia Dong, Zhongping Li, Guangming Wen, Meng Liu, Xiujun Fan
Tetracycline (TC) is considered one of the most widely used antibiotic medicines, which the global production and usage ranks the second highest in all antibiotics. In this work, palladium nanoclusters...
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Hydroamination of isocyanates and isothiocyanates by alkaline earth metal initiators supported by bulky iminopyrrolyl ligand

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01509A, Paper
Tarun Kanti Panda, Kulsum Bano, Srinivas Anga, Archana Jain, Hari Pada Nayek
A series of new heteroleptic alkaline earth (Ae) metal complexes of general formula [{(Ph2CHN=CH)2C4H2N}AeI(THF)3] {Ae = Ca (2), Sr (3), and Ba (4)} were synthesized via salt metathesis by reacting...
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Complexes of BiCl3 with hydrazone derived ligands: Möbius-like discrete metal chelate versus salt-like porous polymeric structure

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00930J, Paper
Damir Safin, Farhad Akbari Afkhami, Ghodrat Mahmoudi, Barbara Miroslaw, Fengrui Qu, Arunava Gupta, Antonio Frontera, Fedor Ivanovich Zubkov, Ennio Zangrando
In this work we have synthesized and characterized a new helical complex of BiCl3, namely [Bi(LI)Cl3], fabricated from an extremely bulky ligand 1,2-diphenyl-1,2-bis((phenyl(pyridin-2-yl)methylene)hydrazono)ethane (LI). The same reaction of BiCl3 with...
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Effect of the graphene sheets incorporation on physicochemical properties of nano-alumina

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9NJ06317J, Paper
Elena A. Trusova, Dmitry D Titov, Alex N Kirichenko, Michael Y Zorin
The colloidal processing method was suggested for obtaining of chemically homogeneous composite powder based on graphene and nano-alumina. The method allows integrating a hybrid structure by mixing components at nanoscale...
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Label-free colorimetric detection of serum cysteine using Ag-NPs probes for immanence of Be2+ ions

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00967A, Paper
Chandrababu Rejeeth, Alok Sharma, Varukattu Nipun babu, Rahul Gautam
Amino acids play a crucial role in a variety of significant metabolic processes and their homeostasis is essential for cell growth and survival. Cysteine (Cys) furnishes imperative information about peculiar...
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Facile functionalization of boron nitride (BN) for the development of high-performance asymmetric supercapacitors

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New J. Chem., 2020, Advance Article
DOI: 10.1039/C9NJ06284J, Paper
Chandan Kumar Maity, Sumanta Sahoo, Kartikey Verma, Ajaya Kumar Behera, Ganesh Chandra Nayak
Ternary composites based on functionalized BN, a carbonaceous material, and PANI are developed for real-time asymmetric supercapacitor application.
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Synthesis of eight isostructural 2D lanthanide coordination polymers assembled by rigid furan-2,5-dicarboxylic acid and flexible adipic acid as linkers and exploration of luminescent Eu/Tb polymers as efficient and sensitive sensors for nitroaromatic comp

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01018A, Paper
Zaib ul Nisa, Lobzang Tashi, Charanjeet Sen, Nargis Akhter Ashashi, Subash Chandra Sahoo, Haq Nawaz Sheikh
Eight isostructural coordination polymers were synthesized by a solvothermal method. The luminescent Eu/Tb polymers function as efficient sensors for nitroaromatics via turn-off mode.
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Recent progress and approaches on the synthesis of Mn-doped zinc oxide nanoparticles: A theoretical and experimental investigation on the photocatalytic performance

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01530J, Paper
Joyce Silva, Nivaldo Freire Andrade Neto, Marisa Carvalho Oliveira, Renan Pontes Ribeiro, S Lazaro, Yara Gomes, Carlos Paskocimas, Mauricio Bomio, Fabiana Motta
Transition metal-doped semiconductors are promising to conduct the future of environmental remediation from photocatalysis. In this study, the role of Mn-doping on the structural, electronic, morphological, optical, and photocatalytic properties...
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Novel nitro substituted formazan derivatives: Selective ratiometric and colorimetric chemosensors for fluoride anion sensing detectable by the naked eye

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01860K, Paper
Gulsen Turkoglu
Novel two formazan derivatives FNB and FDNB were synthesized from their corresponding phenylhydrazone and characterized by various spectroscopic methods. The sensing ability of these formazan sensors towards different anions was...
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Magnetite mesoporous silica nanoparticles embedded in carboxybetaine methacrylate for application in hyperthermia and drug delivery

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00939C, Paper
Hasan Keshavarz, Alireza Khavandi, Somaye Alamolhoda, M. Reza Naimi-Jamal
Magnetite mesoporous silica nanoparticles (MMSNs) are biocompatible and can easily deliver a drug to the target tissue, but there are two challenges: burst effect and protein corona.
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Iron and chromium MOFs as sustainable catalysts for transfer hydrogenation of carbonyl compounds and biomass conversions

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00552E, Paper
Punitharaj Vasanthakumar, Dharmalingam Sindhuja, Duraisamy Senthil Raja, Chia-Her Lin, Ramasamy Karvembu
Fe and Cr based MOFs (MIL-88B) act as efficient and reusable catalysts for transfer hydrogenation of carbonyl compounds including bio-derived substrates.
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Synthesis and herbicidal application of turpentine derivative p-menthene type secondary amines as sustainable agrochemicals

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00583E, Paper
Huanhuan Dong, Shichao Xu, Jing Wang, Hongmei Zhang, Yuxiang Chen, Liangwu Bi, Zhendong Zhao
Compound 3a showed excellent herbicidal activity against barnyard grass with IC50 = 7.0 mg L−1, and exhibited good selection for rice, wheat, and radish at 100 mg L−1.
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Surface modification of graphene oxide via noncovalent functionalization with porphyrins for selective photocatalytic oxidation of alcohols

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01141J, Paper
Tossapong Phuangburee, Dmytro Solonenko, Nukorn Plainpan, Patchanita Thamyongkit, Dietrich R. T. Zahn, Sakulsuk Unarunotai, Thawatchai Tuntulani, Pannee Leeladee
GO–porphyrin composites were simply prepared by a self-assembly process. The noncovalent interactions between the porphyrins and oxygen-containing functional groups on GO play a crucial role in controlling their photocatalytic activities.
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Bio-fabricated ZnO nanoparticles: direct sunlight-driven selective photodegradation, antibacterial activity, and thermoluminescence-emission characteristics

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01611J, Paper
Anupama R. Prasad, Anagha M., Shamsheera K. O., Abraham Joseph
Zinc oxide (ZnO) nanoparticles were prepared via a Gliricidia sepium leaf extract-assisted green synthetic route. Near-spherical and elongated nanoparticles were obtained according to morphology analysis.
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Synthesis of a new Ni complex supported on CoFe2O4 and its application as an efficient and green catalyst for the synthesis of bis(pyrazolyl)methane and polyhydroquinoline derivatives

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00223B, Paper
Taiebeh Tamoradi, Seyedeh Masoumeh Mousavi, Masoud Mohammadi
A novel and magnetic nanocatalyst was synthesized for the synthesis of multicomponent compounds.
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Ultrastable conductive microporous covalent triazine frameworks based on pyrene moieties provide high-performance CO2 uptake and supercapacitance

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01292K, Paper
Mohamed Gamal Mohamed, Ahmed F. M. EL-Mahdy, Yasuno Takashi, Shiao-Wei Kuo
Two pyrene-functionalized CTFs through ionothermal treatment TCNPy in the presence of molten zinc chloride at 500 °C, which displayed high-performance CO2 uptake and supercapacitance.
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Density Functional Theory Investigations on the Coordination of Pa(V) with N, N-dialkylamide

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00687D, Paper
Jun Ma, Chu-Ting Yang, Jun Han, Sheng Hu, Haizhu Yu, Xinggui Long
Density functional theory (DFT) method was used to study the coordination of a series of N, N-dialkylamides with Pa(V) to shed light on the inherent principals for screening amides extractants...
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A Size-Controlled Green Synthesis of Silver Nanoparticles by the Berry Extract of Sea Buckthorn and the Biological Activities

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01335H, Paper
Simin Wei, Yinghui Wang, Zhishu Tang, Jinhang Hu, Su Rui, Lin Jingjie, Zhou Tuan, Hui Guo, Wang Nan, Xu Rongrong
Green synthesis of silver nanoparticles (AgNPs) has been extensively studied by using a variety of plant extracts for the applications in biomedical sciences and engineering. However, there are no reports...
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Single-pot template-free synthesis of a glycerol-derived C–Si–Zr mesoporous composite catalyst for fuel additive production

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00523A, Paper
Saurabh Kumar, Nagabhatla Viswanadham, Sandeep K. Saxena, Arumugam Selvamani, Jitendra Diwakar, Ala’a H. Al-Muhtaseb
The C–Si–Zr material synthesized from bio-derived waste glycerol, ZrO(NO3)2 and TEOS exhibits excellent catalytic activity for tri-acetin production from low-value glycerol.
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Design, Synthesis and Evaluation of A Novel Glutamine Derivative (2S,4R)-2-amino-4-cyano-4-[18F]fluoro-butanoic acid

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00410C, Paper
song Liu, Renbo Wu, Yuli Sun, Karl Ploessl, Yan Zhang, Yajing Liu, zehui wu, Lin Zhu, H. F. Kung
Glutamine is an important source of nutrient for tumor proliferation. Designing new glutamine-metabolizing PET imaging agents is useful for tumor diagnosis and treatment. Herein, a novel glutamine derivative, (2S,4R)-2-amino-4-cyano-4-[18F]fluoro-butanoic acid,...
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Fast and easy conversion of ortho amidoaryldiselenides into the corresponding Ebselen-like derivatives driven by theoretical investigations.

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01605E, Paper
Vanessa Nascimento, Pâmella da Silva Cordeiro, Massimiliano Arca, Francesca Marini, Luca Sancineto, Antonio Luiz Braga, Vito Lippolis, Michio Iwaoka, Claudio Santi
DFT calculations performed on amidoaryldiselenides as electrophilic derivatives evidenced the presence of a prevalent Se···O weak interaction when selenium is bonded to a Se atom (diselenides), a Br atom (selenenyl...
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Linear dicarboxylate based pyridyl appended cobalt(II) coordination polymers in search of opto-electronic properties

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00567C, Paper
Faruk Ahmed, Joydeep Datta, Samim Khan, Basudeb Dutta, Sakhiul Islam, Sanobar Naaz, Partha Pratim Ray, Mohammad Hedayetullah Mir
Two new coordination polymers (CPs) [Co(adc)(4-ppy)(H2O)2]n, (1) and [Co(adc)(4-bppy)(H2O)2]n, (2) (H2adc = acetylenedicarboxylic acid, 4-ppy = 4-phenylpyridine and 4-bppy = 4-(4-bromophenyl)pyridine) have been synthesized and characterized by various techniques including...
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Trifluoromethyl functionalized polyindoles: Electrosyntheses, characterization, and improved capacitive performance

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00812E, Paper
Rui Wang, Yu Xue, Fengxing Jiang, Weiqiang Zhou, Jingkun Xu, Xuemin Duan, Danhua Zhu, Liming Xu, Yue Cai, Aiqin Liang
Fluorination of conjugated polymers has been explored as a viable strategy for enhancing the overall performance of corresponding polymers. In this work, two trifluoromethylated polyindoles (5-PFMIn and 6-PFMIn) are synthesized...
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Benchmarking the inversion barriers in σ3λ3-phosphorus compounds: a computational study

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01237H, Paper
Arturo Espinosa Ferao, Antonio García Alcaraz
The study of inversion barriers for ninety-four P(III)-containing compounds has been carried out using DFT calculations. Most of these compounds display a typical vertex (“umbrella”) transition state (TS) structure, whereas...
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Conjugated Small Organic Molecules: Synthesis and Characterization of 4- Arylpyrazole-decorated Dibenzothiophenes

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01887B, Paper
M. Bhanuchandra, Satyajit Panda, Ram Singh Jat, Amir Fayaz, Jony Saha, Ramalingam Thirumoorthi , Tapta Kanchan Roy
4-Arylpyrazole-decorated dibenzothiophenes have been synthesized. The synthesis involves the treatment of 2,8-dibromodibenzothiophene with pyrazole under Ullmann-type amination conditions for the dual C-N bond formation. The selective bromination of the resulting...
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A two-photon AIE fluorophore as a photosensitizer for highly efficient mitochondria-targeted photodynamic therapy

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00822B, Paper
Qunshou Kong, Boxuan Ma, Tao Yu, Cheng Hu, Gaocan Li, Qing Jiang, Yunbing Wang
Nowadays, photodynamic therapy (PDT) has become an effective way for cancer therapy. However, there are still some drawbacks for common photosensitizers including poor photostability, nonspecific targeting, poor penetration depth of...
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