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An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00343H, Research Article
Huirong Ma, Liangchen Liu, Yuluan Liao, Huatian Shi, Po Sun, Weibin Yu
The direct decomposition of nitromethane into nitrile compounds is a significant challenge due to the occurrence of severe side-reactions.
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Efficient doped and non-doped light-emitting diodes based on a TADF-emitting Cu4Br4 cluster

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00210E, Research Article
Xin Lu, Shao-Jie Wu, Ya-Shu Wang, Shan-Yue Wei, Lingyi Meng, Xi-He Huang, Xu-Lin Chen, Can-Zhong Lu
A sublimable Cu4Br4 cluster, chelated by bidentate N^P ligands with a donor–acceptor configuration, realizes highly efficient doped and non-doped cluster light-emitting diodes.
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Enhancing the separation of C2H4/C2H6 in customized MOR zeolites

Inorg. Chem. Front., 2024, 11,2427-2435
DOI: 10.1039/D4QI00236A, Research Article
Hongwei Chen, Binyu Wang, Bin Zhang, Yongheng Ren, Jiuhong Chen, Jiabao Gui, Xiufeng Shi, Wenfu Yan, Jinping Li, Libo Li
MOR zeolites synthesized with cost-effective, non-toxic materials enhance ethylene separation without Ag or Cu modification. The customized framework composition improves adsorptive properties economically.
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N-heterocyclic carbene-stabilized Cu9 clusters with combined thermally activated delayed fluorescence and phosphorescence

Inorg. Chem. Front., 2024, 11,2498-2507
DOI: 10.1039/D4QI00160E, Research Article
Lin-Mei Zhang, Mo Xie, Hui-Zhi Wei, Shang-Fu Yuan, Dong-Sheng Li, Tao Wu
Two NHC-stabilized Cu9 clusters showcase both TADF and direct phosphorescence in thermal equilibrium. The combined harvesting mechanism arises from the simultaneous presence of a small ΔE(S1 − T1) gap and relatively strong spin–orbit coupling.
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Recent progress in aluminum anodes for high-performance rechargeable aqueous Al-ion batteries

Inorg. Chem. Front., 2024, 11,2246-2259
DOI: 10.1039/D4QI00468J, Review Article
Le Li, Shaofeng Jia, Yue Shi, Conghui Wang, Hengwei Qiu, Yongqiang Ji, Minghui Cao, Dan Zhang
This review discusses the recent advances in the aluminum metal anodes, alloy anodes, and intercalated anodes used for rechargeable aqueous Al-ion batteries.
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Nanocarbon armor reinforced Ag particles to build a high-rate and long-lifespan aqueous Zn2+/Cl− dual-ion battery

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00499J, Research Article
Wenbo Guo, Tianyuan Zhang, Guangchang Shu, Leiyu Fan, Zhouxiang Wu, Lei Yan, Liyuan Zhang, Haoxiang Yu, Ting-Feng Yi, Jie Shu
A high-performance aqueous Zn2+/Cl dual-ion battery is built by using nanocarbon armor reinforced Ag particles as the cathode, metallic Zn as the anode and ZnCl2 as the electrolyte.
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Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt(IV) prodrugs for cancer treatment

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00386A, Research Article
Peng Sun, Jia-Qian Wang, Qiang Xie, Xuan-Lin Ren, Xin Qiao, Jing-Yuan Xu
Two multifunctional fibrate-Pt(IV) prodrugs, 1 and 3, bearing lipid-modulating agents, exhibited impressive anticancer activity by triggering ferroptosis and apoptosis.
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An unprecedented {Y2 ⊂ Y10} type disk-like Y12 nanocluster featuring electroluminescence property in OLED device

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00635F, Research Article
Lin-Ping Shi, Wen-Liang Li, Pu-Yue Wang, Xiaoming Wu, Zhao-Quan Yao, Jiong-Peng Zhao, Fuchen Liu
Although great efforts have been made in exploring the exquisite rare-earth (RE) clusters, the design and construction of planar RE-clusters with disk-like geometrical features are still scarce. Herein, a novel...
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Unleashing the power of directed electron transfer: unraveling the potential of {PV4}2 in heterogeneous photocatalysis

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00606B, Research Article
Xin Su, Yuzan He, Kunhong Li, Miao Wang, Wei Tang, Shihao Zhang, Pengtao Ma, Jingyang Niu, Jingping Wang
{PV4}2 unleash the power of directed electron transfer in heterogeneous photocatalysis reduction.
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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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Trifluoroacetic acid molecules confined into/onto metal–organic frameworks using H2btzip for efficiently improving proton conductivity using a synergistic effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00605D, Research Article
Xiaoxue Ma, Xin Li, Xueke Han, Lu Zhang, Ronghua Liu, Hongguo Hao, Hui Yan, Xin Zhao, Xiangjin Kong, Huawei Zhou, Xia Li, Hongjie Zhu, Suna Wang, Yunwu Li, Dichang Zhong, Fangna Dai
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
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Govt directs major steel players to use iron ore fines also for steel making

The country is heavily dependent on imports for coking coal.




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Indian rice exports get delayed at ports as Customs officials hold up consignments

Exporters say they incur $70/tonne additional costs; Customs officials playing safe to verify if shipments are white or parboiled rice




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Crude oil futures rise amid declining US inventories

December Brent oil futures rose to $74.37, while November WTI futures climbed to $70.59.




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Kandla Customs Commissioner orders release of ship detained in organic rice export irregularities

Tells Kandla traffic manager to allow another ship to set sail after getting release order from Gujarat HC




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Crude oil futures rise as US inventories decline 

Market players are also assessing the supply risks from West Asia following the tensions in the region




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Nickel prices likely to be under pressure on market surplus

Analysts peg its average price for 2024 at around $17,000/tonne




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Crude oil futures slip as industry data shows increase in US inventory 

US crude oil inventories rose by 1.64 million barrels for the week ended October 18. Market estimates had earlier pegged increase at 0.7 million barrels




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Crude oil posts marginal gains following US SPR refill plans

November crude oil futures were trading at ₹5,686 on MCX during the initial hour of trading on Tuesday




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Crude oil trades higher as industry data shows decrease in US inventories 

Official data on crude oil inventory level in the US is expected later on Wednesday




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Crude oil trades higher ahead of US Presidential poll

Market also focussed on outcome of US Federal Reserve meeting later in the week




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Crude oil futures fall as industry data shows inventory gain in US 

Market eyes results of the US presidential election




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Crude oil gains as market analyses Trump’s victory in US Presidential election

The Trump administration could stimulate economic growth in the US, which could help boost consumption demand in that country, say analysts




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Morning run, nutritious meals and unwinding

Prioritise mornings with running, balanced diet, revitalizing workouts and meditation for mental health, says Nishant Pitti, CEO and Co-Founder, EaseMyTrip




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Walks, conscious nutrition and switching off with Buzo

Akshay Chaturvedi, Founder CEO of Leverage.biz, shares tips on health, fitness and his beloved German shepherd




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More than just a number: A call to improve adverse event reporting

Heal the hurt: Redressal and support are critical to keep the faith in the system from breaking down




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Data integrity alarm sounded for CROs, the backbone to pharma industry

USFDA cautions CROs; says such incidents “undermine the reputation of generic industry”




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Trust instincts, avoid quick fixes

Amit Saneja, CEO, Educate Online, on his exercise routine, mindful eating and ways to sustainable health.




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Golf, gluten-free diet, and music

Personal fitness diary




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Maharashtra’s sugar mills warn of potential halt to cane crushing season over MSP and ethanol price stalemate

Despite annual hikes in the Fair and Remunerative Price (FRP) for sugarcane, the MSP of sugar has remained unchanged since 2019




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Arya.ag bags $19.8 million from US International Development Finance Corporation

These funds will be utilised to connect farmers and FPOs with buyers across the country




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Helping lift economic status of rural women — the Kissandhan way!

The SLCM subsidiary offers short-term loans, plans new products with longer term




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US imposes 5.7% CVD on India’s frozen shrimp exports

Washington’s hefty levy may jeopardise exports; Ecuador in comparison will face 3.75% duty, Indonesia and Vietnam 2.84%




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6 weather models point to La Nina not emerging during Nov-Feb, says Australia’s BoM

IOD negative conditions likely by November, but may turn neutral by December




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Syngenta signs MoUs with CSSRI and HAU on crop productivity, sustainable agriculture

MoUs aim to implement projects related to capacity building of rural youth in agriculture and allied sciences, safe use of crop protection chemicals and adoption of new technologies, among other things




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Mustard sown in 18.76 lakh ha in Rajasthan till Oct-end

Over 46 per cent of the targetted area of 40.50 lakh ha has been covered in the largest producing state




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Can solar energy transform farms for sustainable agriculture and environmental conservation?

Time to follow ancient belief of sun and farm produce to help improve economics of agriculture




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WISMA warns of losses to sugar mills if crushing season is delayed further

“We had requested the government to allow mills to begin crushing as early as November 5. However, the ministerial committee has decided to start the season on November 15”: WISMA President




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Haresh Vyas is Chairman of World Castor Sustainability Forum

“Vyas brings a wealth of experience and an unfaltering commitment to sustainable agricultural practices, setting the stage for transformative growth and enhanced sustainability within the castor industry”




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Seafood exporters differ on US market over Trump’s win 

The drop in shrimp production in the South American country would help Indian products to make further inroads to the US market




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India-US farm trade to get a boost with Trump’s comeback

Experts predict an increase in India’s exports, including tea, coffee, and spices, while imports of American farm products like tree nuts and fresh fruits are also likely to rise




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Call for joint efforts to reduce greenhouse gas emissions at 31st Swadeshi Science Congress

31st Swadeshi Science Congress inaugurated at Kochi’s ICAR-CIFT 




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Chana prices crash as imports from Australia begin and sowing starts

Huge imports of yellow peas also weigh on prices




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Sowing seeds of trust: How blockchain is cultivating a new era of digital farming

Realising its full potential in digital farming requires addressing certain critical challenges




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Two-day NAARM meet on sustainable agri start-ups from November 12

A-Idea is a technology business incubator promoted by the NAARM




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CCL Products says more customers prefer short-term coffee contracts as market stays volatile

See some softening in Vietnam prices as new arrivals are set to begin next month




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Nitin Gadkari: India’s road infrastructure set to outshine the US

Gadkari highlighted the significance of efficient highways, waterways, and railways in reducing logistics costs and stimulating economic growth.




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Air India steps up technology focus, eyes higher direct channel sales




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Acquisition proposals worth ₹2,200 cr issued to industry, says Vice Navy Chief




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Escorts Kubota to divest railway equipment business to Sona Comstar for ₹1,600 crore

The transaction, structured as a slump sale, is expected to close by September 30, 2025.