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From generation to collection – impact of deposition temperature on charge carrier dynamics of high-performance vacuum-processed organic solar cells

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03623A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Richard Adam Pacalaj, Yifan Dong, Ivan Ramirez, Roderick C. I. MacKenzie, Seyed Mehrdad Hosseini, Eva Bittrich, Julian Eliah Heger, Pascal Kaienburg, Subhrangsu Mukherjee, Jiaying Wu, Moritz Riede, Harald Ade, Peter Müller-Buschbaum, Martin Pfeiffer, James Robert Durrant
Substrate heating during co-evaporation of bulk heterojunction organic solar cells aids phase separation and improves performance. While recombination remains unaffected, hole transport improves due to more crystalline donor domains.
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Stress regulation via surface micro-etching and reconstruction for enhancing triple-cation perovskite solar cells with an efficiency of 25.54%

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04248D, Paper
Yang Ding, Erming Feng, Siyuan Lu, Jianhui Chang, Caoyu Long, Sichao Tong, Hengyue Li, Junliang Yang
A surface micro-etching and reconstruction strategy is developed to regulate the stresses in a perovskite film, achieving a benign transition from tensile stress to compressive stress.
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The construction of multifunctional solid electrolyte interlayers for stabilizing Li6PS5Cl-based all-solid-state lithium metal batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03289F, Paper
Ya Chen, Xin Gao, Zheng Zhen, Xiao Chen, Ling Huang, Deli Zhou, Tengfei Hu, Bozhen Ren, Runjing Xu, Jiayi Chen, Xiaodong Chen, Lifeng Cui, Guoxiu Wang
The established multifunctional interlayers effectively eliminate both anode-initiated and GB-initiated dendrites and guarantee satisfactory battery performance for ASSLMBs.
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Quantitatively detecting and characterizing metallic lithium in lithium-based batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03468F, Review Article
Zhi Zheng, Xue Fang, Wei Deng, Peng Li, Xiaobo Zheng, Hang Zhang, Lin Li, Shulei Chou, Yuan Chen, Yongbing Tang, Jiazhao Wang
Quantitative detection and characterization methods for analysis of metallic Li and related inactive components of Li batteries and their related characteristics are discussed.
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High-Entropy Materials for Aqueous Zinc Metal Batteries

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04442H, Review Article
Xiaomin Han, Ran Zhao, Jingjing Yang, Yahui Wang, Anqi Zhang, Zhifan Hu, Mengge Lv, Chuan Wu, Ying Bai
To meet the challenges raised by the utilization of intermittent clean energies, rechargeable aqueous zinc ion battery (AZIB) stands at the forefront due to its competitive capacity, low cost, and...
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Oxygen redox activities governing high-voltage charging reversibility of Ni-rich layered cathodes

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03832K, Paper
Gi-Hyeok Lee, Suwon Lee, Jiliang Zhang, Bernardine L. D. Rinkel, Matthew J. Crafton, Zengqing Zhuo, Youngju Choi, Jialu Li, Junghoon Yang, Jongwook W. Heo, Byungchun Park, Bryan D. McCloskey, Maxim Avdeev, Wanli Yang, Yong-Mook Kang
A schematic illustration indicative of the improved structural reversibility through stabilizing oxidized oxygen by Al doping.
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A donor:hole-transport layer alloy for high-efficiency and stable binary organic solar cells with promoted hole collection and suppressed recombination

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04072D, Paper
Xianghui Zeng, Ting Xu, Hansheng Chen, Baoshen Deng, Qing Yan, Xuanlin Wen, Zijian Li, Haoxuan Zeng, Chuanlin Gao, Yaodong Xiao, Jiwei Liao, Hui Liu, Bin He, Peigang Han, Guangye Zhang, Shunpu Li, Yiwang Chen, Chen Xie
A donor-based nanoparticle (NPs)-incorporated hole-transport layer was synthesized for fine-tuning the energy level of anodes in organic solar cells. The conventional and inverted devices achieved record efficiencies of 19.9% and 17.2%, respectively.
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Removal of Residual Contaminants by Minute-level Washing Facilitates the Direct Regeneration of Spent Cathode from Retired EV Li-ion Batteries

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03021D, Paper
Yi Guo, Yang Li, Kai Qiu, Yan Li, Wei Jing Yuan, Chenxi Li, Xinyu Rui, Lewei Shi, Hou Yukun, Saiyue Liu, Dongsheng Ren, Tan Tiening, Gaolong Zhu, Languang Lu, Shengming Xu, Biao Deng, Xiang LIU, Minggao Ouyang
The direct regeneration of spent cathodes stands out as an environmentally and economically benign strategy within the battery ecosystem, eclipsing the cumbersome metallurgical approaches. Before addressing the lithium loss and...
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A monolithic Co-FeCo8S8 electrode for stable anion exchange membrane water electrolyzer driven by fluctuating power supply

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04993D, Communication
Jahangir Khan, Heming Liu, Tianhao Zhang, Xin Kang, Zhiyuan Zhang, Yuxiao Dong, Shanlin Li, Jiarong Liu, Qiangmin Yu, Bilu Liu
Integrating water electrolysis and green electricity offers a promising approach towards sustainable and clean energy. However, such a system demands electrodes that can swiftly and stably adapt to fluctuating power...
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Reduction of bulk and interface defects via photo-annealing treatment for high-efficiency antimony selenide solar cells

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02877E, Paper
Xiaoyang Liang, Xinhua Wang, Qiwei Chang, Bingxin Yang, Wei Dang, Zheng Zhang, Yingnan Guo, Lin Yang, Zhiqiang Li
A novel interface engineering strategy with a photo-annealing treatment is proposed for regulating the interface of the Sb2Se3/CdS heterojunction.
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XRDMatch: a semi-supervised learning framework to efficiently discover room temperature lithium superionic conductors

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02970D, Paper
Zheng Wan, Zhenying Chen, Hao Chen, Yizhi Jiang, Jinhuan Zhang, Yidong Wang, Jindong Wang, Hao Sun, Zhongjie Zhu, Jinhui Zhu, Linyi Yang, Wei Ye, Shikun Zhang, Xing Xie, Yue Zhang, Xiaodong Zhuang, Xiao He, Jinrong Yang
We propose XRDMatch, a semi-supervised learning framework that integrates consistency regularization and pseudo-labeling. Using X-ray diffraction patterns as descriptors, it effectively addresses data scarcity by leveraging abundant unlabeled data.
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Ordered grain boundary reconstruction induces high-efficiency thermoelectric power generation in SnTe

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04639K, Paper
Qian Deng, Fujie Zhang, Xiaoyu Yang, Ruiheng Li, Chengliang Xia, Pengfei Nan, Yue Chen, Binghui Ge, Ran Ang, Jiaqing He
The “ordered grain boundary reconstruction” significantly improved the thermoelectric performance of SnTe, achieving a record conversion efficiency of ∼10.5%.
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A novel high-performance all-liquid formic acid redox fuel cell: simultaneously generating electricity and restoring the capacity of flow batteries

Energy Environ. Sci., 2024, 17,8545-8556
DOI: 10.1039/D4EE02450H, Paper
Dongbo Wei, Lyuming Pan, Jing Sun, Meisheng Han, Manrong Song, Jincong Guo, Qing Zhang, Cailin Xiao, Zheng Li, Shuaibin Wan, Yubai Li, Lin Zeng, Lei Wei, Tianshou Zhao
This work presents an all-liquid formic acid redox fuel cell using degraded redox flow battery electrolyte as the cathode fuel. This approach efficiently generates power while regenerating the electrolyte, advancing energy conversion and storage.
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Trimming defective perovskite layer surfaces for high-performance solar cells

Energy Environ. Sci., 2024, 17,8582-8592
DOI: 10.1039/D4EE03585B, Paper
Chanhyeok Kim, Kihoon Kim, Youngmin Kim, Nikolai Tsvetkov, Nam Joong Jeon, Bong Joo Kang, Hanul Min
The defect density on the top surface of the perovskite thin film was significantly higher than that in the bulk. A trimming solvent treatment removed the defective top surface, substantially reducing the defect concentration and strain.
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Hydrogel electrolytes with an electron/ion dual regulation mechanism for highly reversible flexible zinc batteries

Energy Environ. Sci., 2024, 17,8570-8581
DOI: 10.1039/D4EE03067B, Paper
Fusheng Luo, Song Yang, Qing Wu, Yue Li, Jinlong Zhang, Yanhui Zhang, Jun Huang, Haibo Xie, Yiwang Chen
The unique electron/ion dual regulation mechanism is established in the well-designed hydrogel electrolyte by integrating polyacrylamide network and carboxylated multi-walled carbon nanotubes for high performance flexible ZIBs.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Naphtho[1,2-c:5,6-c']bis([1,2,3]thiadiazole) enables the design of efficient halogen-free polymer donors and fabrication of organic solar cells with >19% efficiency

Energy Environ. Sci., 2024, 17,8593-8608
DOI: 10.1039/D4EE02414A, Paper
Tao Jia, Yongmin Luo, Yulong Hai, Tao Lin, Xudong Qin, Ruijie Ma, Kezhou Fan, Aleksandr A. Sergeev, Top Archie Dela Peña, Yao Li, Mingjie Li, Kam Sing Wong, Gang Li, Jiaying Wu, Shengjian Liu, Fei Huang
Fusion and isomerization strategies are used to develop an electron-withdrawing motif naphtho[1,2-d:5,6-d']bis([1,2,3]thiadiazole) (iNT) and a halogen-free polymer donor achieving an efficiency of 19.1%.
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Unraveling the relationship between the phenethylammonium-induced 2D phase on the perovskite surface and inverted wide bandgap perovskite solar cell performance

Energy Environ. Sci., 2024, 17,8658-8669
DOI: 10.1039/D4EE02133A, Paper
Xiaomin Huo, Silvia Mariotti, Yaoyao Li, Ting Guo, Chenfeng Ding, Penghui Ji, Shuai Yuan, Tongtong Li, Ning Meng, Xiaomin Liu, Jiahao Zhang, Ilhem Nadia Rabehi, Yu Zhang, Suling Zhao, Hengyuan Wang, Dandan Song, Luis K. Ono, Zheng Xu, Yabing Qi
We studied the impact of phenethylammonium chloride on PIN-structured wide bandgap perovskite solar cells. Elimination of the 2D phase results in a champion efficiency of 20.61% and a VOC loss of only 410 mV with hysteresis-free J–V curves.
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Interplay of intercalation dynamics and lithium plating in monolithic and architectured graphite anodes during fast charging

Energy Environ. Sci., 2024, 17,8702-8721
DOI: 10.1039/D4EE02211D, Paper
Open Access
Aleksandar S. Mijailovic, Seth Waag-Swift, Guanyi Wang, Bingyao Zhou, Mei Luo, Wenquan Lu, Qingliu Wu, Brian W. Sheldon
Fast charging of high-capacity anodes is challenging due to lithium plating reactions, which lead to poor cycling performance and safety concerns.
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Laser-induced high-entropy alloys as long-duration bifunctional electrocatalysts for seawater splitting

Energy Environ. Sci., 2024, 17,8670-8682
DOI: 10.1039/D4EE01093K, Paper
Open Access
Yunchao Xie, Shichen Xu, Andrew C. Meng, Bujingda Zheng, Zhenru Chen, James M. Tour, Jian Lin
This work presents a rapid in situ synthesis of FeNiCoCrRu high entropy alloy with porous structures via CO2 laser induction under ambient conditions. FeNiCoCrRu exhibits excellent seawater electrolysis and a superior long duration of >3000 hours.
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Polymer electrolytes with high cation transport number for rechargeable Li–metal batteries: current status and future direction

Energy Environ. Sci., 2024, 17,8457-8481
DOI: 10.1039/D4EE03097D, Review Article
Xinyuan Shan, Zhaowei Song, Hang Ding, Lengwan Li, Yuhang Tian, Alexei P. Sokolov, Ming Tian, Kang Xu, Peng-Fei Cao
The high-cation transport number polymer electrolytes (HTPEs) with simultaneously high cation transport number and high ionic conductivity could provide a solution to enable high-performance solid-state batteries.
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Post-deposition in situ passivation of AgBiS2 nanocrystal inks for high-efficiency ultra-thin solar cells

Energy Environ. Sci., 2024, 17,8885-8892
DOI: 10.1039/D4EE03266G, Paper
Jae Taek Oh, Yongjie Wang, Carmelita Rodà, Debranjan Mandal, Gaurav Kumar, Guy Luke Whitworth, Gerasimos Konstantatos
A post-deposition in situ passivation strategy using a multi-functional molecular agent is reported with enhanced colloidal dispersibility of an environmentally-friendly AgBiS2 nanocrystal ink, achieving a PCE over 10% in a solar cell.
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Achieving high performance triboelectric nanogenerators simultaneously with high-voltage and high-charge energy cycle

Energy Environ. Sci., 2024, 17,8734-8744
DOI: 10.1039/D4EE02447H, Paper
Open Access
Yikui Gao, Jiaqi Liu, Linglin Zhou, Lixia He, Di Liu, Peiyuan Yang, Bingzhe Jin, Zhong Lin Wang, Jie Wang
This work achieves a high-voltage and high-charge energy cycle for TENGs, as well as lossless energy transmission between TENGs and PMCs.
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An octave box inspired energy regularization triboelectric nanogenerator for highly efficient wave energy harvesting

Energy Environ. Sci., 2024, 17,8829-8837
DOI: 10.1039/D4EE02969K, Paper
Yuanchao Ren, Zizhuo Wang, Jie Chen, Fei Wu, Hengyu Guo
Inspired by the mechanical transmission structure of octave boxes, this work proposes a novel energy regularization triboelectric nanogenerator to effectively convert chaotic wave energy into stable electric output.
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Self-healing polymer dielectric exhibiting ultrahigh capacitive energy storage performance at 250 °C

Energy Environ. Sci., 2024, 17,8866-8873
DOI: 10.1039/D4EE03705G, Paper
Open Access
Wenhan Xu, Fei Yang, Guodong Zhao, Shixian Zhang, Guanchun Rui, Muchen Zhao, Lingling Liu, Long-Qing Chen, Qing Wang
The Anderson localization effect has been exploited in the design of high-temperature dielectric polymers, resulting in reduced conduction loss and outstanding capacitive energy storage performance over a wide temperature range up to 250 °C.
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Harnessing enhanced lithium-ion storage in self-assembled organic nanowires for batteries and metal-ion supercapacitors

Energy Environ. Sci., 2024, 17,8874-8884
DOI: 10.1039/D4EE02777A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ievgen Obraztsov, Rostislav Langer, Jean G. A. Ruthes, Volker Presser, Michal Otyepka, Radek Zbořil, Aristides Bakandritsos
Mesoscale engineering of small organic molecules towards a 3D nanowire network offers a potent toolkit for improved energy storage performance.
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Advancing high-efficiency, stretchable organic solar cells: novel liquid metal electrode architecture

Energy Environ. Sci., 2024, 17,8915-8925
DOI: 10.1039/D4EE03406F, Paper
Seungbok Lee, Sungjun Oh, Seungseok Han, Dongchan Lee, Jihyung Lee, Yonghwi Kim, Hoe-Yeon Jeong, Jin-Woo Lee, Min-Ho Lee, Wu Bin Ying, Seonju Jeong, Seungjae Lee, Junho Kim, Yun Hoo Kim, Bumjoon J. Kim, Eun-chae Jeon, Taek-Soo Kim, Shinuk Cho, Jung-Yong Lee
Highly efficient and stretchable organic solar cells were developed with a novel liquid metal top electrode. Metallic interlayers enabled its fabrication via thermal evaporation, achieving 14.6% PCE and 70% PCE retention under 63% strain.
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Global softening to manipulate sound velocity for reliable high-performance MgAgSb thermoelectrics

Energy Environ. Sci., 2024, 17,8810-8819
DOI: 10.1039/D4EE03521F, Paper
Open Access
Airan Li, Longquan Wang, Jiankang Li, Takao Mori
A global softening strategy using stearic acid in MgAgSb to reduce sound velocity has been shown to enhance its thermoelectric performance, achieving high zT values and demonstrating strong potential for low-grade heat harvesting.
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Towards efficient and stable organic solar cells: fixing the morphology problem in block copolymer active layers with synergistic strategies supported by interpretable machine learning

Energy Environ. Sci., 2024, 17,8954-8965
DOI: 10.1039/D4EE03168G, Paper
Yu Cui, Qunping Fan, Hao Feng, Tao Li, Dmitry Yu. Paraschuk, Wei Ma, Han Yan
Interpretable machine learning identifies the causal structure–property relationships and key control factors in block copolymer organic solar cells with excellent power conversion efficiency and thermal stability.
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Bicontinuous-phase electrolyte for a highly reversible Zn metal anode working at ultralow temperature

Energy Environ. Sci., 2024, 17,8966-8977
DOI: 10.1039/D4EE02815E, Paper
Mi Xu, Beinuo Zhang, Yudong Sang, Dan Luo, Rui Gao, Qianyi Ma, Haozhen Dou, Zhongwei Chen
A bicontinuous-phase electrolyte with a well-balanced solvation sheath is proposed, which delivers fast desolvation kinetics and generates a uniform in situ solid electrolyte interface, thus achieving a long-lasting Zn anode at low temperatures.
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Advancing high-temperature electrostatic energy storage via linker engineering of metal–organic frameworks in polymer nanocomposites

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04085F, Paper
Zongliang Xie, Zhiyuan Huang, He Li, Tianlei Xu, Haoyu Zhao, Yunfei Wang, Pang Xi, Zhiqiang Cao, Virginia Altoe, Liana M Klivansky, Zaiyu Wang, Steven Shelton, Shiqi Lai, Peng Liu, Chenhui Zhu, Michael D. Connolly, Corie Y. Ralston, Xiaodan Gu, Zongren Peng, Jian Zhang, Yi Liu
High-performance, thermally resilient polymer dielectrics are essential for film capacitors used in advanced electronic devices and renewable energy systems, particularly at elevated temperatures where conventional polymers fail to perform. Compositing...
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High-entropy doping for high-performance zero-cobalt high-nickel layered cathode materials

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE05020G, Paper
Jiahui Zhou, Jiehui Hu, Xia Zhou, Zhen Shang, Yue Yang, Shengming Xu
Considering the high price and scarcity of cobalt resource, zero-cobalt, high-nickel layered cathode material (LNM) have been considered as the most promising material for next-generation high-energy-density lithium-ion batteries (LIBs). However,...
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Salt Dissociation and Localized High-concentration Solvation by Interface of Fluorinated Gel and Polymer Solid Electrolyte

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04078C, Paper
Dechao Zhang, Yuxuan Liu, Dedi Li, Shimei Li, Qi Xiong, Zhaodong Huang, Shixun Wang, Hu Hong, Jiaxiong Zhu, Haiming Lyu, Chunyi Zhi
Low salt dissociation and unstable [Li(N, N-dimethylformamide (DMF))x]+ solvent structure in poly(vinylidene fluoride) (PVDF)-based solid polymer electrolyte (SPE) remarkably restricts the high throughput ion transport and interfacial stability. Here, we...
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Anti-Freezing Hydrogel Electrolyte with Regulated Hydrogen Bond Network Enables High-Rate and Long Cycling Zinc Batteries

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02772H, Paper
Shaojie Guo, Mengyu Yan, DongMing Xu, Pan He, Kaijian Yan, Jiexin Zhu, Yongkun Yu, Zeya Peng, Yanzhu Luo, Feifei Cao
Zinc-based batteries, utilizing hydrogel electrolytes, present significant promise as power sources for next-generation flexible devices due to their stretchable nature and enhanced safety features. Nonetheless, the current hydrogel electrolytes require...
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Surface-deprotonated ultra-small SnO2 quantum dots for high-performance perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03193H, Paper
Wuchen Xiang, Yiheng Gao, Bobo Yuan, Shuping Xiao, Rui Wu, Yiran Wan, Zhiqiang Liu, Liang Ma, Xiang-Bai Chen, Weijun Ke, Guojia Fang, Pingli Qin
SnO2 electron transport layers (ETLs) have improved perovskite solar cell (PSC) efficiencies but face issues with surface protonation, leading to energy loss and instability. We developed ultra-small (2.5 nm) SnO2...
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T.N. govt. circular declares November 14-20 as Children’s Week

As November 14 is celebrated as National Children’s Day and November 20 as World Children’s Day across the world, the Social Welfare Department requests all Anganwadis in Tamil Nadu to organise events to celebrate the week




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Hospital in Coimbatore introduces machine for advanced radiation therapy




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Tiruchi Engagements for November 13, 2024




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Additional Chief Secretary holds review meeting at Bharathidasan University




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Help desk launched at Bharathidasan University




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Fee for OP consultation: meeting at Kozhikode MCH on November 21




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Ministerial staff urge Chief Secretary to ensure compliance with transfer policy norms

The staff body accuses Department of Personnel and Administrative Reforms of failing to follow the norms for its own department, and of violating transfer policy norms prevailing in the government for more than 15 years in the matters of transfer, promotion, recruitment rules, regularisation of services, of an estimated 3,000 ministerial employees




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Mayor inspects Chathiram bus stand in Tiruchi




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Rahim meets family after 18 years in Saudi jail




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NHAI begins repair work on Tiruchi-Padalur section




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Karnataka High Court stays criminal case against 29-year-old who had printed that ‘voting for Modi would be his marriage gift’ on his wedding card




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KTR’s Delhi visit is just diversion politics: Komatireddy Venkat Reddy




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Govt. has started acquisition of private land for flood mitigation projects in the city: Udhayanidhi

Civic agencies have been directed to prepare for rain over the next four days. A total of 1,194 pumps and 524 jet-rodding and 158 super-sucker machines have been readied for use in the city, he says




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Stray dog menace puts Railways, Kozhikode Corporation in a spot

A tourist from Germany was bitten by a stray dog at the Kozhikode railway station recently




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More coaching centres for competitive exams to be opened in State, says Higher Education Minister




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Kochi International Marina gets a facelift

Stakeholders seek dredging, renovation of adjacent Bolgatty Palace Hotel