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Hydrazone-linked Covalent Organic Frameworks for Fluorescence Detection of Hg2+

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05468G, Communication
Xuefeng Wang, Zhaowei Yang, Lingsuo Meng, Xuehui Li, Hongtao Wei, Jing Ning, Shitao Wang, Dapeng Cao, Long Hao
A hydrazone-linked COF (DvDf-C3XJ-COF) with hydrogen-bond reinforcement and abundant coordination sites was synthesized, exhibiting strong fluorescence and high sensitivity/selectivity for Hg²⁺ detection, with a detection limit of 1.65 × 10⁻⁶...
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From one to two: In-site constructing C3N5-Poly (triazine imide) heterojunction for enhanced O2 activation

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05077K, Communication
Shiling Xu, Ziheng Yang, Laiqing Zhang, Xiaorui Zhang, Zikang Zeng, Wenxuan Wang, Yujun Liang, Lan Yuan, Chuang Han
A novel C3N5-Poly (triazine imide) (PTI) heterojunction was designed and constructed by thermal polymerization process, which featured with intimated S-scheme interface coupling and exhibited a predominant performance for H2O2 production....
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Interlayer spacing expansion for V2O5 towards ultra-stable zinc anode-based flexible electrochromic displays in Zn2+/Li+-PC organic electrolyte

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04974H, Communication
Zhe Li, Zhaoyang Song, Linhua Liu, William Yu, Jingwei Chen, Qianqian Zhu, Haizeng Li
To enhance the electrochemical stability and kinetics of V2O5, 3,4-ethylenedioxythiophene (EDOT) was in-situ polymerized within V2O5 interlayers, rendering PEDOT@V2O5 with enlarged layer spacing, increased stability in organic electrolyte, superior electrochemical...
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Boosting the electrochemical performance of Ni-rich LiNi0.96Co0.02Mn0.02O2 cathode by high-valence Zr/Mo dual-doping

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04275A, Communication
Hongmei Cao, Yudong Zhang, Xunzhu Zhou, Jie Yu, Xiang Chen, Lin Li
Ni-rich oxides are attractive high-energy cathodes for lithium-ion batteries but suffer from inherent instability. Herein, we employed an ectopic Zr4+/Mo6+ dual-doping strategy to reinforce the layered structure through robust M-O...
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Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05173D, Communication
Bing Zeng, Yuexin Wang, Kanghui Xiong, Keke Zhang, Siyu Zhang, Xianjun Lang
A catalytic amount of TEMPO, mobile in the reaction medium, enhances the hole transfer of NU-1003 photocatalysis for blue light-powered oxidation of organic sulfides with O2.
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Lipidic biomass as a renewable chemical building block for polymeric materials

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04993D, Feature Article
Rafael Turra Alarcon, Gabriel Iago Iago, Caroline Gaglieri, Aniele De Moura, Éder Tadeu Gomes Cavalheiro, Gilbert Bannach
Polymers are intrinsically connected to our modern society and are found and used in different technologies. Although polymers are worthwhile, concerns about synthetic polymers from non-renewable sources have arisen. Therefore,...
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Engineering biotin anchored-MWCNTs as a superb carrier for facile delivery of the potent Ru(II)-N^N scaffold in breast cancer cells

Chem. Commun., 2024, 60,13376-13379
DOI: 10.1039/D4CC04276J, Communication
Lavanya Thilak Babu, Nilmadhab Roy, Tiasha Dasgupta, Sreejani Ghosh, Ramasamy Tamizhselvi, Priyankar Paira
This article portrays the construction of biotinylated-MWCNTs for SMVT-guided delivery of a potent Ru(II)-scaffold into MCF7 cells.
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Revealing the structural influence mechanism of intrinsic potassium/calcium elements on bio-waste-derived hard carbon for sodium-ion batteries

Chem. Commun., 2024, 60,13380-13383
DOI: 10.1039/D4CC03546A, Communication
Yinghao Zhang, Chun Wu, Qinghang Chen, Chuangchuang Li, Wenjie Huang, Qianxiong Wen, Xiang-Xi He, Xingqiao Wu, Shu-Lei Chou
The evolution mechanism of hard carbon structures in terms of graphitization and pore structure caused by K/Ca has been clarified.
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Nitrogen-doped graphene quantum dot-intensified tungsten oxide nanosheets as a SERS substrate for antibiotics detection

Chem. Commun., 2024, 60,13360-13363
DOI: 10.1039/D4CC05052E, Communication
Lu Tan, Xuanzhao Lu, Shuzhen Yue, Yue Cao, Yang Zhou, Baokang Jin, Jun-Jie Zhu
Tungsten oxide nanosheets loaded with nitrogen-doped graphene oxide quantum dots (NGQDs/WO3 NSs) were fabricated as SERS substrates.
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Mn and Mo co-doped NiS nanosheets induce abundant Ni3+–O bonds for efficient electro-oxidation of biomass

Chem. Commun., 2024, 60,13392-13395
DOI: 10.1039/D4CC04818K, Communication
Pengfei Ren, Zixuan Wang, Wenchao Zhang, Fang Duan, Shuanglong Lu, Mingliang Du, Han Zhu
MnMo–NiS were synthesized for electro-oxidizing ethylene glycol (EG), glycerol (GLY), and 5-hydroxymethylfurfural (HMF), achieving faradaic efficiencies of 97.5%, 98.6%, and 99.2%, and yield rates of 615.7, 475.5, and 333.9 μmol h−1 cm−2.
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Sb nanoparticles embedded uniformly on the surface of porous carbon fibres for high-efficiency sodium storage

Chem. Commun., 2024, 60,13428-13431
DOI: 10.1039/D4CC04806G, Communication
Yafei Zhao, Kai Xue, Xinyu Liu, Zhiyuan Gao, Junhao Zhang, Yuanjun Liu, Xiangjun Zheng, ZhongYao Duan, Qianqian Fan, Xingmei Guo
Sb nanoparticles (∼5 nm) are embedded uniformly on the surface of carbon fibers to prepare Sb NPs–SCFs, which exhibit excellent sodium storage with a stable capacity of 381.9 mA h g−1 at 1.0 A g−1 after 200 cycles, due to their unique structure.
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Sulfonated hierarchical ZSM-5 zeolite monoliths as solid acid catalyst for esterification of oleic acid

Chem. Commun., 2024, 60,13356-13359
DOI: 10.1039/D4CC05044D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Binhang Zhao, Pan Yang, Nan Zhang, Donald R. Inns, Elena F. Kozhevnikova, Alexandros P. Katsoulidis, Ivan V. Kozhevnikov, Alexander Steiner, Haifei Zhang
Sulfonated hierarchical H-ZSM-5 monoliths were synthesized via ice-templating as solid acid catalysts for biodiesel production.
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Pivotal role of starch in restoring the photocatalytic performance of chitosan films for eliminating water pollutants

Chem. Commun., 2024, 60,13364-13367
DOI: 10.1039/D4CC04759A, Communication
Aman Chauhan, Archana Negi, Kirti, Moondeep Chauhan, Ajeet Kaushik, Ganga Ram Chaudhary
The enhanced adsorption properties of chitosan films after starch impregnation combined with the excellent charge-transfer traits of the CdS@CuS catalyst restore the reduced photocatalytic activity towards ciprofloxacin degradation.
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Expedient (3+3)-annulation of carbonyl ylides with azaoxyallyl cations: formal access to oxa-benzo[c]azepin-3-ones

Chem. Commun., 2024, 60,13368-13371
DOI: 10.1039/D4CC04946B, Communication
Kshitiz Verma, Hemanga Bhattacharyya, Sharajit Saha, Tharmalingam Punniyamurthy
Cascade C–C/C–N bond formation of carbonyl ylides with azaoxyallyl cations generated in situ using Rh-catalysis has been accomplished in the presence of a base at room temperature.
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Bipyridine-based conjugated microporous polymers for boosted photocatalytic U(VI) separation

Chem. Commun., 2024, 60,13348-13351
DOI: 10.1039/D4CC04456H, Communication
Yun Xie, Zifan Li, Chenchen Liu, Qiming Song, Yunhai Liu, Zhibin Zhang, Bin Han
Incorporating bipyridine (BPY) units into conjugated microporous polymers (CMPs) boosts exciton dissociation, charge separation, and oxidation capacity, thereby exhibiting an admired U(VI) separation rate under sacrificial agent-free conditions.
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Ultrafine PtCo alloy nanoparticles integrated into porous N-doped nanosheets for durable oxygen reduction reaction

Chem. Commun., 2024, 60,13432-13435
DOI: 10.1039/D4CC04661G, Communication
Baoliang Chen, Lei Zhao, Zhaozhao Zhu, Pei Xiong, Zhao Li, Jun Song Chen, Lanlan Li, Rui Wu
The PtCo–CoNC–P catalyst, featuring sub-3 nm small-size PtCo alloy nanoparticles integrated into a porous nitrogen-doped nanosheet, exhibits exceptional durability after 30 000 cycles of accelerated durability tests.
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Ultra-high Li+ transfer efficiency of in situ grown membrane for high-performance batteries

Chem. Commun., 2024, 60,13412-13415
DOI: 10.1039/D4CC04546G, Communication
Jian Wang, Kang Ma, Yanbo Zhang, Jiawei Chen, Xin Song, Jianmin Zhang
Lewis acid effect of in situ grown nano-Al2O3 promotes lithium salt dissociation to improve Li+ transport efficiency.
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Functional metal–organic frameworks derived electrode materials for electrochemical energy storage: a review

Chem. Commun., 2024, 60,13292-13313
DOI: 10.1039/D4CC04086D, Highlight
Basree, Arif Ali, Khusboo Kumari, Musheer Ahmad, Ganesh Chandra Nayak
Pristine MOFs and their derivatives have been proven for supercapacitor as well as energy storage due to their versatile features like huge specific surface area, high porosity, redox active metal centre, high thermal stability, and so on.
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Atomistic insight into the promising thermoelectric performance of the copper-based ternary phosphide CaCuP

Chem. Commun., 2024, 60,13400-13403
DOI: 10.1039/D4CC04660A, Communication
Un-Gi Jong, Chol Ryu, Ji-Min Hwang, Su-Hyang Kim, Il-Gwang Ju, Chol-Jun Yu
We provide a valuable atomistic insight into the thermoelectric properties of hexagonal CaCuP, revealing that nano-structuring can double the thermoelectric figure of merit by further reducing lattice thermal conductivity.
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Enhancing the performance of ionic conductivity for solid-state electrolytes: an effective strategy of injecting lithium ions within anionic metal–organic frameworks

Chem. Commun., 2024, 60,13416-13419
DOI: 10.1039/D4CC04515G, Communication
Lu Shi, Xin Wang, Zhiliang Liu
An ionotropic MOF (Li+[Cu-BTC]) with lithium ions in the pores of the lattice was synthesized, which displays outstanding lithium ionic conducting properties over a wide temperature range.
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Catalytically transforming legacy phthalate esters from plastic waste into benzoic acid and benzoate plasticizers

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05158K, Communication
Open Access
Simon Windels, Dirk E. De Vos
Upcycling of plastic-waste derived phthalate plasticizers into benzoic acid via a one-pot hydrolysis–decarboxylation process using Cu2O and H-beta 75 in water.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Intramolecular cyclization of N-aryl amides for the synthesis of 3-amino oxindoles

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05259E, Communication
Haitao Yang, Yu Pan, Yijing Tian, Kaili Yu, Yifeng Bai, Yonggang Jiang, Hongbin Zhang, Guogang Deng, Xiaodong Yang
A mild and efficient strategy to synthesize pharmaceutically important 3-amino oxindoles from readily available N-aryl amides has been developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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A MOF-derived CuO/TiO2 photocatalyst for methanol production from CO2 reduction in an AI-assisted continuous flow reactor

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05008H, Communication
Bhavya Jaksani, Ruchi Chauhan, Switi Dattatraya Kshirsagar, Abhilash Rana, Ujjwal Pal, Ajay K. Singh
An AI-assisted continuous flow reactor for CO2 reduction to methanol using a MOF-derived CuO/TiO2 photocatalyst.
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Polarizable AMOEBA force field predicts thin and dense hydration layer around monosaccharides.

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04415K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Luke A Newman, Mackenzie G Patton, Breyanna A Rodriguez, Ethan W Sumner, Valerie Vaissier Welborn
Polarizable force fields crucially enhance the modeling of macromolecules in polar media. Here, we present new parameters to model six common monosaccharides with the polarizable AMOEBA force field. These parameters...
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Ceria-based supported metal catalysts for the low-temperature water-gas shift reaction

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04072D, Feature Article
Xin-Pu Fu, hui zhao, Chun-Jiang Jia
Water-gas shift (WGS) reaction is a crucial step for the industrial production of hydrogen or upgrading hydrogen generated from fossil or biomass sources by removing the residual CO. However, current...
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Sandwich structured Fe3O4@C@MoSe2 architecture for efficient lithium-ion storage

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04631E, Communication
Linan Yang, Chengjie Zhang, Liuyang Cao, Rong Xu, Hongbo Li, Zhanjun Yang, Juan Li
A unique sandwich structure Fe3O4@C@MoSe2 architecture is proposed for high-performance lithium storage. Carbon shell as the connection of in/external structures can not only improve the overall conductivity, but also alleviate...
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Tuneable Sulfonated Hypercrosslinked Polymers for Selective Esterification: Insights into Performance and Stability

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05208K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paul Schweng, Dorian Guerin-Faucheur, Freddy Kleitz, Robert Thomas Woodward
We report sulfonated hypercrosslinked polymers (SHCPs) as heterogeneous catalysts for the selective esterification of hexanoic acid with benzyl alcohol. The SHCPs demonstrate tuneable catalytic activity and selectivity, outperforming conventional acid...
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Axial oxygen-bridged FeN4O/NC produced by ultrafast joule heating for efficient oxygen reduction reaction

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05604C, Communication
Feng Liu, Xinyu Guo, Yan Zhong, Shaqi Fu, Jingsha Li, Chunmei Zhang, Heng Zhang, Fenghui Ye, Shuai Yuan, Chuangang Hu, Chunxian Guo
Herein, we report an atomically dispersed Fe-N-C catalyst with axial oxygen ligands (FeN4O/NC) firstly synthesized by ultrafast joule heating. The formation of oxygen species between FeN4 and graphene, which offers...
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Copper nanoclusters: emerging photoredox catalysts for organic bond formations

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04774E, Feature Article
Open Access
Arunachalam Sagadevan, Kathiravan Murugesan, Osman M. Bakr, Magnus Rueping
In this feature article, we provide an overview of the photocatalytic capabilities of copper-based nanoclusters for organic bond-forming reactions.
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For the love of legiyam

SRINIVASA RAMANUJAM queues up to find out what goes into this Deepavali preparation at the iconic Dabba Chetty Shop in Mylapore




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Ramen for the soul

It doesn’t get better than hot ramen on a cold day in London




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Reconsider decision to distribute fortified rice through PDS in Wayanad: Shreyams Kumar

Health issues, social impact not considered, says LJD State president




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Watch | Payasam cakes and Mahabali cookies for Onam

Bakers and chefs are innovating with the traditional flavours of Onam




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Home bakers and chefs in Thiruvananthapuram have spread out a delectable platter for Christmas

Cakes, cookies, puddings and more are in the Christmas hampers sold by home cooks




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Predictions for 2023: AI, VR boom in hospitality, wellness and gaming, and Balenciaga in India

This is the time of year when that we draw up the Best Of 2022 lists, and trend forecasts for 2023. And But how do you predict the unpredictable? We start with gains from the past.



  • Life & Style

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At Kraft, a concept store in Chennai, shop for pendant lights and wall art over a meal of crispy keema dosas and Korean burgers

Shop, eat, and try your hand at games at Kraft, the concept store that showcases around 60 different types of furniture and decor




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The millet makeover: Nutrihub, ICAR-IIMR’s technology business incubator for millet start-ups is a game changer

Scientists at the Indian Institute of Millet Research are helping start-ups create products, from icecream to beer, with the grain at Nutrihub



  • Life & Style

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Design strategy and molecular level understanding: hole transport materials with suitable transition dipole orientation for OLEDs

Mol. Syst. Des. Eng., 2024, 9,1116-1129
DOI: 10.1039/D3ME00127J, Paper
Krishan Kumar, Sunil Kumar, Anirban Karmakar, Dipanshu Sharma, Feng-Rong Chen, Mangey Ram Nagar, Jwo-Huei Jou, Subrata Banik, Subrata Ghosh
A combined experimental and theoretical study on a group of phenothiazine-substituted pyridine is reported.
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Crafting porous nanoscaled architecture as a potential frontier for drug delivery

Mol. Syst. Des. Eng., 2024, 9,1085-1106
DOI: 10.1039/D4ME00098F, Review Article
Koyeli Girigoswami, Pragya Pallavi, Agnishwar Girigoswami
Porous nanostructures exhibit remarkable nanoplatforms for payload delivery to diseased cells with high loading capacity, favorable release profiles, improved hemocompatibility, biocompatibility, and safe clearance after biodegradation.
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Self-supervised graph neural networks for polymer property prediction

Mol. Syst. Des. Eng., 2024, 9,1130-1143
DOI: 10.1039/D4ME00088A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Qinghe Gao, Tammo Dukker, Artur M. Schweidtmann, Jana M. Weber
Self-supervised learning for polymer property prediction in scarce data domains.
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Development of xanthan gum-based solid desiccants for the extraction of water vapors from humid air

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00134F, Paper
Hemant Mittal, Ali Al Alili, Saeed M. Alhassan, Naved I. Malek, Md. Didarul Islam
A xanthan gum-acrylamide desiccant with interconnected capillary channels was prepared and showed 1.38 g g−1 water adsorption at 90% RH and 25 °C, retaining 70% capacity over 20 cycles, proving its effectiveness as a salt-free desiccant.
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DECESF - DC 1 à 4 - Préparation complète pour réussir sa formation - Tout-en-un 2025-2026

22,90 €15,00 €

Agnès Fostel, Gladys Bugeault, Véronique Fauconnet, Brigitte Gautier, Karl Grux, Martine Le Manach, Line Mariale, Dalila Mechaheb, Antoine Pétard, Anne Rachel Tournier, Roselyne Vuagnat
5e édition
octobre 2024
256 pages
Un livre complet pour préparer le diplôme d'État de conseiller en économie sociale familiale (DECESF) !
Ouvrage tout-en-un
Nouveau
978-2-311-21591-5
Diplôme d'État de Conseiller en économie sociale familiale
Disponible
Livre




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Ludopédagogie en santé : pour les formations en santé

22,00 €

Garry Laudren, Alexandre Niggel
1re édition
novembre 2024
136 pages
Créez des expériences ludiques pour révolutionner l'apprentissage en santé !
Livre
Nouveau
978-2-311-66545-1
Méthode pas à pas, exercices pratiques et fiches outils
Disponible
Livre




for

Reward for a bhakta




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Adoration for Siva




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Blessed and fortunate




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Revelation of Cosmic form




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Reverence for Acharyas




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Prerequisites for liberation




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Prerequisites for liberation