Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00925H, Paper

George E. P. O'Connell, Richard F. Webster, Elise Elkington, Rose Amal, Jason Scott, Emma C. Lovell
Introducing light to thermal DRM may be an effective strategy to improve catalyst stability, but light's role in the stability mechanism is not well understood.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01029A, Paper

Haiting Ye, Takuma Sato, Taishi Nakanishi, Shigetomo Ito, Shigenobu Umemiya, Masahiro Terada
Chiral phosphoric acid catalysts were screened rationally and efficiently through the theoretical prediction model of the kinetic resolution of racemic γ-hydroxybutyrate without performing an exhaustive search for plausible lactonisation pathways.
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Catal. Sci. Technol., 2024, 14,6247-6258
DOI: 10.1039/D4CY00741G, Paper

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Clément Molinet-Chinaglia, Elizabeth Vera, Philippe Vernoux, Laurent Piccolo, Stéphane Loridant
H₂ reducing pretreatment at 500 °C promotes the activity of low-Pt-content Pt/CeO₂ catalysts by increasing the number of active Pt⁰ NPs. A 12 h oxidative post-treatment at 500 °C which forms PtO_x species easily activated also leads to improvement.
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Catal. Sci. Technol., 2024, 14,6307-6320
DOI: 10.1039/D4CY00873A, Paper

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Yasemen Kuddusi, Maarten R. Dobbelaere, Kevin M. Van Geem, Andreas Züttel
The effect of catalyst synthesis and reaction conditions on catalytic activity were accurately predicted with an interpretable data-driven strategy. The method is demonstrated for CO₂ methanation and is extendable to other catalytic processes.
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Catal. Sci. Technol., 2024, 14,6372-6379
DOI: 10.1039/D4CY00905C, Paper

Shi-Jiao Dong, Sai Huang, Ao Wang, Yan Meng, Gang Xu, Jun-Ling Song
The electrochemical reduction of nitrate to NH₃ can be a promising and sustainable alternative for the industrially used, energy-intensive Haber–Bosch process under mild conditions and also solve the issue of nitrate nitrogen pollution in water.
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Catal. Sci. Technol., 2024, 14,6420-6429
DOI: 10.1039/D4CY00906A, Paper

Shilin Li, Yunhui Tian, Guangxin Zhang
The regulations of the Bi₂MoO₆ structure, such as dopant incorporation, composite formation, and synthesis condition modification, have garnered significant attention due to their implications for enhancing photocatalytic activity.
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Catal. Sci. Technol., 2024, 14,6278-6285
DOI: 10.1039/D4CY00983E, Paper

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Meng Wang, Jingyi Wang, Yan Zhang, Yunbo Yu, Wenpo Shan
High-temperature calcination usually induces the sintering of catalysts, thus resulting in negative effects on their performance.
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Catal. Sci. Technol., 2024, 14,6380-6392
DOI: 10.1039/D4CY00923A, Paper

Mengyan Huang, Bo Liu, Junwei Wu, Junfeng Gu, Yichen Zheng, Peiyan Ma, Bei Li, Zhengyi Fu
The carboxyl groups in CC-MoC@MoS₂ play a similar role to the amino acid residues in PS II.
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Catal. Sci. Technol., 2024, 14,6176-6179
DOI: 10.1039/D4CY00955J, Communication

Zhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei Lu
Visible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00952E, Paper

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Assunta D'Amato, Maria Voccia, Filippo Bruno, Sara D'Aniello, Lucia Caporaso, Francesco De Riccardis, Irene Izzo, Giorgio Della Sala, Mina Mazzeo
New binary catalysts formed by a bis-thiourea and a series of flexible polyaza-macrocycles are revealed to be efficient catalysts for the ring opening polymerization (ROP) of L-lactide.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01018C, Paper

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Martin Gerbaulet, Anja Hemschemeier, Thomas Happe
CbA5H from Clostridium beijerinckii is an oxygen-stable [FeFe]-hydrogenase. Here we report that CbA5H is stable in high concentrations of acetone and acetonitrile and also withstands intermediate concentrations of DMSO, ethanol and methanol.
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Catal. Sci. Technol., 2024, 14,6524-6536
DOI: 10.1039/D4CY00832D, Paper

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Duygu Hacıefendioğlu, Ali Tuncel
MIL-100(V) used as a heterogeneous catalyst for tunable selective oxidation of benzyl alcohol to benzaldehyde or benzoic acid by changing only the reaction temperature.
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Catal. Sci. Technol., 2024, 14,6561-6572
DOI: 10.1039/D4CY00888J, Paper

Yan Wang, Chengkai Luo, Li Wei, Mingzhong Cai
Heterogeneous copper-catalyzed heterocyclization between 2-iodoanilines and 2-bromothiophenols has been developed for the assembly of substituted phenothiazines.
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Catal. Sci. Technol., 2024, 14,6670-6677
DOI: 10.1039/D4CY00949E, Paper

Chandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook Baeg
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO₂. The CO₂ conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
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Catal. Sci. Technol., 2024, 14,6600-6608
DOI: 10.1039/D4CY01019A, Paper

Hyunjun Choe, Minsun Cha, Ahram Kim, Jon D. Stewart
Introducing an additional mutation at position 73 dramatically increases the substrate range, allowing access to a wide variety of sphingolipid analogs.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00860J, Paper

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Bing Wang, Nicola Da Roit, Michael Zimmermann, Markus Boese, Thomas Zevaco, Silke Behrens
Pd/Zn-nanoparticles were used as precursors to study the influence of the molar Zn/Pd ratio and hierarchical HZSM-5 zeolites in the syngas-to-dimethyl ether process.
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Nanoscale, 2024, 16,20202-20215
DOI: 10.1039/D4NR02274B, Paper

Mohd Rashid, Milan Kumar Jena, Sneha Mittal, Biswarup Pathak
In this study, we explored the role of functionalized entities (C, H, N, and OH) in graphene electrodes using a machine learning (ML) framework integrated with the quantum transport method to achieve precise single DNA nucleotide identification.
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Nanoscale, 2024, 16,20155-20167
DOI: 10.1039/D4NR03113J, Paper

Rajeev Gupta, Monika Singhal
A novel eco-friendly composite electrode/current collector made from polycaprolactone and graphite filler offers bulk conductivity, is freestanding, cost-effective, and shows supercapacitive energy storage potential with electrodeposited polyaniline.
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Nanoscale, 2024, 16,20216-20227
DOI: 10.1039/D4NR02935F, Paper

Hang Liu, Lei Zhang, Sébastien Lebègue, Fabrice Bournel, Jean-Jacques Gallet, Ahmed Naitabdi
Thickness-dependent morphology and electronic properties of ZnO ultrathin films grown on Pt(111) under the CO oxidation reaction at 1 mbar.
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Nanoscale, 2024, 16,20260-20279
DOI: 10.1039/D4NR02283A, Paper

Leila Naderi, Saeed Shahrokhian
A flexible 1D micro-SC was fabricated based on a multidimensional nanoarchitecture derived from MOF on foam-like microwires and FeCoS nanoflakes on nanocellulose/graphene fibers and exhibited high energy storage capability.
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Nanoscale, 2024, 16,20288-20303
DOI: 10.1039/D4NR02541E, Paper

Zhenghui Xie, Feiran Meng, Junlong Yang, Yuhong Wang, Chul B. Park, Pengjian Gong, Guangxian Li
Hybrid 1D nanofiber/2D nanoplatelet nanocomposite foam sensor and Monte-Carlo modelling of complex 1D/2D sensing nanostructure.
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Nanoscale, 2024, 16,20331-20341
DOI: 10.1039/D4NR02691H, Paper

H. Cheng, B. Tang, H. Y. Bao, F. Shan, C. X. Lu
This method produces microcapsules that possess a high thermal rate and good UV absorption and fluorescence properties, making them suitable for use in fluorescent buildings, textiles, coatings, and other applications.
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Nanoscale, 2024, 16,20319-20330
DOI: 10.1039/D4NR02639J, Paper

Sachin Yadav, Bikash Gajar, R. P. Aloysius, Sangeeta Sahoo
The interplay between superconducting fluctuations (SFs) and weak localization (WL) has been probed by temperature dependent resistance [R(T)] and magnetoresistance (MR) measurements in two-dimensional disordered superconducting TiN thin films.
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Nanoscale, 2024, 16,20082-20088
DOI: 10.1039/D4NR03940H, Communication

Minling Zheng, Yubo Liu, Qifu Zhang, Wenjing Li, Yong Zhang, Guangxue Feng, Yating Hu, Shaoming Huang
A bimetallic CoNi-MET with fixed metal occupancy combines the strong water resistance of Co-MET with the high porosity of a Ni-MET.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03810J, Paper

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Katsuya Mutoh, Sonomi Kawakita, Teppei Yahagi, Takuya Nakashima
Single chiral ligand coordination effectively deracemizes intrinsically chiral Au₁₃ clusters with binary mixed ligands of chiral and achiral diphosphines.
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Nanoscale, 2024, 16,20354-20355
DOI: 10.1039/D4NR90194K, Correction

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Ziwei Li, Fan Yang, Di Wu, Yanhong Liu, Yang Gao, Haichen Lian, Hongxin Zhang, Zhibin Yin, Aiguo Wu, Leyong Zeng
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR04011B, Communication

Kentaro Tashiro
Homochiral selective secondary nucleation, promoted by the choice of solvent or stirring, was suggested as the key process for the emergence of macroscopic chiral symmetry breaking in the gelation of Fmoc amino acids.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03566F, Paper

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Darya Burak, Jae Hyun Han, Joon Soo Han, In Soo Kim, Md Abdur Rahman, Joel K. W. Yang, So-Hye Cho
PHPS was transformed via TiO₂ photocatalytic properties into ultrathin SiO₂ shells, passivating TiO₂ activity while retaining its whiteness and high refractive index—perfect for cosmetics, paints, and optical coatings.
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03545C, Paper

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Lauri Palmolahti, Harri Ali-Löytty, Markku Hannula, Tuomas Tinus, Kalle Lehtola, Antti Tukiainen, Jarno Reuna, Mika Valden
Amorphous TiO₂ has insufficient chemical stability that can be enhanced with annealing induced crystallization. However, the crystalline structure is already predetermined by the defect composition of the amorphous phase. In...
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02248C, Paper

Liyang Yu, Haoyong Jin, He Xia, Xiaoxiong Wang, Liang Wang, Dezheng Li, Jiangli Zhao, Yuanhua Sang, Jichuan Qiu, Ning Lu, Hong Liu, Ning Yang
Schematic showing the PLA/CS-IKVAV Janus film for promoting neuronal differentiation and SCI repair.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02941K, Paper

Laure Bsawmaii, Clément Delacou, Valerii Kotok, Sébastien Méance, Koutayba Saada, M. Amine Kribeche, Saïd Tahir, Christophe Roblin, Antonin Louiset, Hanako Okuno, Manoel Manghi, John Palmeri, François Henn, Adrien Noury, Vincent Jourdain
Nanofluidic devices incorporating an individual single-walled carbon nanotube, which achieve a 1–3 orders of magnitude noise reduction over conventional devices, were fabricated using high dielectric constant materials.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02854F, Paper

Jiamin Liang, Yuxin Song, Huan Xing, Liang Ma, Fengxia Wang, Mingfang Zhang, Hongli Zhang, Gang Zou, Guang Yang
A electrochemical sensor for the chiral recognition of Trp based on chiral polyaniline (D-PANI) and β-CD-MOF was designed. It displayed higher affinity of L-Trp, and the oxidation peak current ratio (IL/ID) of DPV could be reached at 2.26.
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03616F, Paper

Sanjiv Sonkaria, Tae Woo Lee, Aniket Kumar, Soo-Kyung Hwang, Piotr Jablonski, Versha Khare
The photocatalytic competence of brookite relative to polymorphs anatase and rutile has generally been considered structurally and energetically unfavourable for reasons that remain largely unknown and unchallenged. Here, we demonstrate...
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03370A, Paper

Yan Wang, Weiqiang Liao, Xikai Yang, Kexin Wang, Shengpeng Yuan, Dan Liu, Cheng Liu, Shiman Yang, Li Wang
A wearable acoustic vibration pressure sensor was developed based on an interfacial-enhanced iontronic dielectric and integrated with an acoustic recognition system using a deep learning classifier.
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03171G, Paper

Murat OZLEK, Merve Sehnaz Akbulut, Engin Burgaz
This study investigates the effects of graphene content and applied press on electrical and thermal conductivities of graphite/polyaniline (GP) and graphite/graphene/polyaniline (GGP) composites which were produced by using direct mixing...
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02850C, Paper

Diana Santiago, Maricela Lizcano, Sean P. McDarby, Ching-cheh Hung, Baochau N. Nguyen
Schematic of intercalation and exfoliation of submicron hBN.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03021D, Paper

Dipayan Ray, Ankush Saini, Ankit Kumar, Sumit Kumar, Monojit Bag, Prasenjit Kar
Water-assisted, growth-controlled synthesis of CsPb₂Br₅ microcrystals for fast responsive UV-detectors.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03736G, Review Article

Hammad Hasan, Md Ifzal Azhar, Santosh Kumar Behera, Md Palashuddin Sk
This review covers fundamental principles and techniques for measuring chiral properties as well as the synthesis of chiral sulfur-based nanomaterials, their optical and chiroptical properties, and possible applications.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03190C, Paper

Sakthivel Kaliyaperumal, Karthik Kiran Sarigamala, Padmini Moorthy, Balaji Ramachandran, Narendhar Chandrasekar, Tim Albrecht
In situ phase engineering of transition metal dichalcogenides (TMDs) based hybrid heterostructures with controlled sulfur vacancies offers a promising strategy for superior-performance lithium–sulfur (Li–S) batteries.
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03329A, Minireview

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Nazifa Tabassum, Brian P. Bloom, Gouranga H. Debnath, David H. Waldeck
This work discusses the imprinting of optoelectronic chirality on hybrid-organic inorganic perovskites, which are a new class of chiral nanomaterials for manipulation and control of spin polarized current and circularly polarized light.
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03942D, Communication

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Anton Senenko, Alexander Anatolievich Marchenko, Oleksandr Kurochkin, Oleksiy Kapitanchuk, Mykola Kravets, Vassili Nazarenko, Volodymyr Sashuk
We present the spontaneous isomerization of donor-acceptor Stenhouse adducts anchored onto a gold surface, visualized using scanning tunneling spectroscopy. Our investigation reveals a palette of molecular arrangements, including those with...
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03333G, Paper

Kun Hee Ye, Taeyoung Jeong, Seungjae Yoon, Dohyun Kim, Cheol Seong Hwang, Jung-Hae Choi
The in-plane tensile strain was reported to enhance the ferroelectricity of Hf1-xZrxO2 thin films by promoting the formation of the polar orthorhombic (PO-) phase. However, its origin remains yet to...
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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR04201H, Paper

Ruyi Liang, Yiyang Shen, Tanqing Long, Peilin Yang, Chuanrui Xu, Tongbo Wu, Mingxia Zhang
The toehold-mediated strand displacement reaction plays a crucial role in the functionality of DNA nanodevices. However, the reaction's velocity is heavily reliant on the length of the toehold region. A...
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Biomater. Sci., 2024, 12,1707-1715
DOI: 10.1039/D3BM01765F, Paper

Andrew C. Murphy, Heidi F. Oldenkamp, Nicholas A. Peppas
This article demonstrates an inverse emulsion scheme to polymerize a variety of ionizable and non-ionizable monomers to form stimuli-responsive nanoparticles with potential applications in biomaterials science.
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Biomater. Sci., 2024, 12,1693-1706
DOI: 10.1039/D3BM02012F, Paper

Subin Jeong, Hyeon-Min Nam, Gun Yong Sung
We report spheroids prepared by injecting LEF1 and Wnt1 into DPCs via transfection and then adding KCs and HUVECs. Through SEM, we observed a part extending outward from the TK and TKH surfaces, as indicated by white arrows.
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Biomater. Sci., 2024, 12,1662-1692
DOI: 10.1039/D3BM01451G, Review Article

Qiao Li, Yuan Lianghao, Gao Shijie, Wang Zhiyi, Tang Yuanting, Chen Cong, Zhao Chun-Qin, Fu Xianjun
In this review, we have summarized the common self-assembled mechanism of NSMs-based SANDDSs. Meanwhile, the potential applications for cancer treatment and future development prospects are also prospected.
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Biomater. Sci., 2024, 12,1871-1882
DOI: 10.1039/D3BM01922E, Paper

Meng Zhang, Hongjin Xue, Jiaxin Yang, Xin Zhao, Mei Xue, Wei Sun, Jianfeng Qiu, Zhihong Zhu
A Cu/ZIF-8/Vc-Ca/HA nanosystem synchronously releases Fenton catalytic Cu²⁺ and Vc-Ca to achieve improved chemodynamic therapy via H₂O₂ self-supply and GSH depletion.
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