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[ASAP] Update to Our Reader, Reviewer, and Author Communities—April 2020

Organometallics
DOI: 10.1021/acs.organomet.0c00266




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[ASAP] Synthesis, Characterization, and Catalytic Reactivity of {CoNO}<sup>8</sup> PCP Pincer Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00167




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[ASAP] Revisiting the Palladium-Catalyzed Carbonylation of Allyl Alcohol: Mechanistic Insight and Improved Catalytic Efficiency

Organometallics
DOI: 10.1021/acs.organomet.0c00117




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[ASAP] Transformation of a Norbornadiene Unit to Ethylenylcyclopentene Requiring Cooperation between Boron and Rhodium Centers

Organometallics
DOI: 10.1021/acs.organomet.0c00155




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[ASAP] Spatial Recognition Within Terpenes: Redox and H-bond Promoted Linkage Isomerizations and the Selective Binding of Complex Alkenes

Organometallics
DOI: 10.1021/acs.organomet.0c00151




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[ASAP] Linkage Isomerism in Dinuclear Al and Ga Organometallic Complexes: Structural and Reactivity Consequences

Organometallics
DOI: 10.1021/acs.organomet.0c00096




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[ASAP] Self-Assembled Redox-Active Tetraruthenium Macrocycles with Large Intracyclic Cavities

Organometallics
DOI: 10.1021/acs.organomet.0c00116




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[ASAP] Effect of the Lead(II) Bond Angle on the Reactivity of Diaminoplumbylenes toward Ammonia: From Inertness to Immediate Ammonolysis

Organometallics
DOI: 10.1021/acs.organomet.0c00196




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[ASAP] Sila-Peterson Reaction of Cyclic Silanides

Organometallics
DOI: 10.1021/acs.organomet.0c00106




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[ASAP] Improving Redox Reversibility and Intermetallic Coupling of Co(III) Alkynyls through Tuning of Frontier Orbitals

Organometallics
DOI: 10.1021/acs.organomet.0c00183




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[ASAP] Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00049




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[ASAP] Synthesis and Characterization of an Oxo-Centered Homotrimetallic Uranium(IV)–Cyclobutadienyl Dianion Complex

Organometallics
DOI: 10.1021/acs.organomet.0c00104




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[ASAP] Ga(N,P) Growth on Si and Decomposition Studies of the N–P Precursor Di-<italic toggle="yes">tert</italic>-butylaminophosphane (DTBAP)

Organometallics
DOI: 10.1021/acs.organomet.0c00078




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[ASAP] Reactivity of [Ce(NR<sub>2</sub>)<sub>3</sub>] (R = SiMe<sub>3</sub>) with Prospective Carbon Atom Transfer Reagents

Organometallics
DOI: 10.1021/acs.organomet.0c00186




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[ASAP] Radical Capture at Nickel(II) Complexes: C–C, C–N, and C–O Bond Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00021




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[ASAP] Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe<sub>2</sub>(?<sup>4</sup>-cod)]: <italic toggle="yes">cis</italic>- versus <italic toggle="yes">trans</italic>-[

Organometallics
DOI: 10.1021/acs.organomet.0c00188




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[ASAP] <italic toggle="yes">O</italic>-Carboranylene versus Phenylene Backbones in Cyclization Reactions of 1,2 Diketones with Hydrosilanes

Organometallics
DOI: 10.1021/acs.organomet.0c00208




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[ASAP] Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00122




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[ASAP] Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold

Organometallics
DOI: 10.1021/acs.organomet.0c00066




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WordPress 3.6

Schedules, who needs schedules! In this episode we chat about a few interesting stories and sites we have stumbled across and discuss some of the upcoming features destined to appear in WordPress 3.6. Now with added music!




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He Who Dares Pays

Episode #004 is kindly supported by Handheld – a conference focusing on “big ideas for small devices” taking place in Cardiff, UK on November 27th – 28th. Early bird tickets are a snip at £99 + VAT (regular price £139 + VAT). Read Craig’s post announcing the conference for more details. And yes, there’s a band!

Thanks again to Handheld Conf for supporting this episode




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Remote No More!

Thanks again to Handheld Conference for supporting this week’s episode. It’s a conference focusing on “big ideas for small devices” taking place in Cardiff, UK on November 27th – 28th. Grab your ticket today.

This week we focus on Yahoo!’s decision to ban remote working, executing ideas, deep dish pizza and automagical open source cocktails.




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How to Work Remotely

We are back after a what can only be termed a travel enforced sabbatical. This week we chat about two new books focusing on remote working, Kieran regales us with more eco-living tales and we discuss why our industry seems obsessed on building businesses to flip.




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Getty goes Free

Six links and just under one hour of chat, what are we playing at? Variety is the name of the game this week. We discuss Kieran’s new event, Getty Images big news, magazine web sites, Netflix, coding standards, text editors and round off with the Mark Cuban’s best ever investment.





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The Joys &#038; Perils of Remote Working

In a change to the announced billing, an impromptu early morning phone call made us think a chat about remote working might be in order. As many of us fight the January blues, and inevitable bout of illness that the new year often brings, it felt a timely opportunity to discuss the good, and the bad, aspects of working from a distance.

Topics we discuss include:

  • How does working remotely affect us?
  • What we both like and dislike about it
  • How much real work you achieve per day
  • The importance of “banter”
  • Is the reality like the dream?
  • A typical day for remote working?
  • Do we put extra pressure on ourselves to output more as we are not in the office?
  • How to feel part of the company you work for

And finally for those Nabaztag doubters out there you can read the full history of the internet enabled rabbit on Wikipedia!

Five Simple Steps Giveaway

To be in with a chance of winning one of the two sets of Five Simple Step’s Pocket Guide Collection 3 all you have to do it answer one of the following two questions correctly. Kieran’s decision will be final (he’s a harsh judge):

  1. Q: What was Matthew Lillard’s handle in the cult-classic 1995 film Hackers?
  2. Q: In the same year Sandra Bullock played a Systems Analyst in the film The Net. During the course of the film her identity is changed by cyber criminals but what is the name they gave her?

To enter just send a tweet to @backtofrontshow with your answer. We’ll announce winners on the next episode.




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Free Content Forever?

In this week’s episode, we turn our gaze to the topic of ad-blockers and paid content. We discuss Vitaly from Smashing Magazine’s recent post looking at how they are funding their content strategy and discuss our own views on paying for digital content.

As always we book end the show with some “bants” including heartfelt thanks to some of our favourite supporters and a nod to a Cornish brewing companies new site.




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The Future of Medium?

Happy New Year to you all! Rather unsurprisingly we missed our end of year review but the outline was probably one of our best. Maybe we’ll do it next year!

This episode we catch up on Kieran’s move behind the camera, argue over what exactly constitutes a pair of Daps and delve into the future of Medium in light of Ev Williams recent announcement.

If you like the show don’t forget you can support our astronomical S3 costs by becoming an exclusive member of the Back to Front Show Club!




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Kieran&#8217;s Big Red Button

It’s hard to believe it’s only been one week, no really, since our last confession. Where does the time go?

In this episode we catch up on what’s happened in our lives in the last seven days, discuss the latest goings on at Medium, ponder why the Guardian doesn’t write listicles and end on probably the best API in the world!




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Kieran's Tiny House Dream

Tap tap, is this thing on? After eight months or working out how to plug in our USB microphones, we finally figured it out and are back with 45 glorious minutes of chat!

In this episode, we learn all about “New Kieran” — new job, new house, and a new laptop. We also discuss a great post on lessons learned running a subscription-based newsletter, discuss Hanno’s great online playbooks for remote working and end on a new Maus that neither of us wants.

Next up is our 50th episode — let us know what we should discuss via Twitter.




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Gujarat clears ordinance for labour reforms

In the wake of exodus of thousands of migrant workers who are leaving the state, the Gujarat cabinet has approved a new ordinance where existing stringent labour laws will be liberalised to ensure smooth functioning of industries in the post lockdown period.




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At frontline, junior docs are soldiers, generals

In the ward of Covid-19 patients, one could expect the medicine, anaesthesia or pulmonology experts at work. But if one visits Civil Hospital, the treating doctor could well be on his/ her way to become ophthalmologist, gynaecologist or general surgeon! In SVP hospital, he or she may be specialising in psychiatry too!




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Gujarat HC restores land to civic body from royals

The Gujarat high court rebuked the erstwhile royal family of the princely state of Bhavnagar for its "dishonest intention" to claim a land parcel in an unauthorized manner from the Bhavnagar Municipal Corporation.




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Ahd: Patient’s death discovered 7 hours later

In an incident that raises serious questions about Covid-19 care centres run by the city civic body, a 27-year-old coronavirus positive man died in his bed after suffering seizure at room 808-Block G3, at Samras Covid-19 care centre in Navrangpura. Only asymptomatic patients are isolated here so that they can be monitored and sent to hospital if they develop symptoms, or discharged when they turn negative.




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Palghar workers stuck in Guj wait to return home

Hundreds of brick kiln workers and their families from Dahanu and Talasari talukas stranded in Gujarat since the lockdown began, are waiting to return to their homes.




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Parents away, cops celebrate kid's birthday

(This story originally appeared in AhmedabadMirror on May 9, 2020)




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Resource Showcase: JSTOR

JSTOR provides access to more than 12 million academic journal articles, books, and primary sources in 75 disciplines. During the Covid-19 crisis, JSTOR are providing expanded access to more than 35,000 additional eBook titles. Learn how to do research using JSTOR Learn how to teach remotely with JSTOR See what other resources the library has for your subject




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Resource Showcase: National Emergency Library

Internet Archive has launched a National Emergency Library, containing over 1.4 million ebooks that are usually restricted by institutional passwords and paywalls. These are freely available during the Covid-19 crisis until 30 June 2020. Read more about additional e-resources currently available See what e-resources we currently have on trial See what other resources the library has for your subject




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Resource Showcase: The New York Times

Did you know that you can access The New York Times via Durham University Library and Collections? As well as access to current articles, via TimesMachine you can access The New York Times archive as far back as 1851. Access The New York Times Access the archive via TimesMachine See what other newspapers and news services are available via Durham University Library and Collections




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Resource Showcase: Trial e-resources

British Online Archives: Providing access to over 80 collections of primary resources, the website hosts over 3 million records drawn from both private and public archives. These records are organised thematically, covering 1,000 years of world history, from politics and warfare to slavery and medicine. This is one of many e-resources we currently have on trial. You can see the complete list and gain access via our trial e-resources page. Please remember to leave feedback – your opinions help shape our collections.




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Resource Showcase: Trial e-resources

IBISWorld: A leading global provider of industry research and analysis. With over 6000 granular reports across 5 geographies, IBISWorld supports curriculum and course development, student assignments and projects, careers counselling/employability, entrepreneurship and new business start-up preparation. This is one of many e-resources we currently have on trial. You can see the complete list and gain access via our trial e-resources page. Please remember to leave feedback – your opinions help shape our collections.




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Resource Showcase: Daily Mirror Historical Archive

The archive features more than 800,000 pages of brand-new, full text searchable, scans of the complete run of the Mirror from 1903-2000, including the Sunday Mirror. This is one of many e-resources we currently have on trial. You can see the complete list and gain access via our trial e-resources page. Please remember to leave feedback – your opinions help shape our collections. See what other newspapers and news services are available via Durham University Library and Collections




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Synthesis of lignin-functionalized phenolic nanosphere supported Ag nanoparticles with excellent dispersion stability and catalytic performance

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04311J, Paper
Shilin Chen, Guanhua Wang, Wenjie Sui, Ashak Mahmud Parvez, Chuanling Si
This work presents a novel and green lignin-based nanocomposite and highlights the synergism of lignin's multiple functions (surfactant, sacrificial template, and reducing agent) in the material preparation process.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Humin based resin for wood modification and property improvement

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03620B, Paper
Open Access
Anna Sangregorio, Anitha Muralidhara, Nathanael Guigo, Lisbeth G. Thygesen, Guy Marlair, Carlo Angelici, Ed de Jong, Nicolas Sbirrazzuoli
Focus on humins, a co-product from sugar conversion, to highlight their capacity to impregnate wood cell walls for making durable wood products.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Methylation-triggered fractionation of lignocellulosic biomass to afford cellulose-, hemicellulose-, and lignin-based functional polymers via click chemistry

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00451K, Paper
Kentaro Miki, Hiroshi Kamitakahara, Arata Yoshinaga, Yuki Tobimatsu, Toshiyuki Takano
This paper reports a new concept for the biorefinery of lignocellulosic biomass where the derivatisation and fractionation of lignocellulose are accomplished at the same time.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ni-Based Heterogeneous Catalysts for the Transformation of Fatty Acids into Higher Yields of O-Free Hydrocarbons

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00853B, Paper
Diego Valencia, Citlalli Zenteno, Diana Gomora-Herrera, María Teresa Gómez-Pérez, Jorge Aburto
A series of novel catalytic materials were synthesized by changing the chemical compounds in the impregnation solutions. A rigid, aromatic and bidentate molecule 1,10-phenanthroline (PhN) was used as a ligand...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photocatalyst-free visible light promoted E → Z isomerization of alkenes

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04303A, Communication
Jianbin Xu, Na Liu, Haiping Lv, Chixian He, Zining Liu, Xianfu Shen, Feixiang Cheng, Baomin Fan
A photocatalyst-free, simple and green method of visible light driven photocatalytic E to Z isomerization of alkenes has been developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Aqueous miscible organic layered double hydroxides as catalyst precursors for biodiesel synthesis

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00571A, Paper
Chunping Chen, Maxwell Greenwood, Jean-Charles Buffet, Dermot O'Hare
Surface area and basicity density dependence of base-catalysed transesterification of sunflower oil by potassium salt prepared AMO-layered double hydroxides.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Eco-friendly and sustainable synthesis of biocompatible nanomaterials for diagnostic imaging: current challenges and future perspectives

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00734J, Critical Review
Ghazaleh Jamalipour Soufi, Siavash Iravani
Current advancements, important challenges and future perspectives of biocompatible nanomaterials for diagnostic imaging are discussed as well as their greener synthesis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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New biobased-zwitterionic ionic liquids: efficiency and biocompatibility for the development of sustainable biorefinery processes

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01002B, Paper
Gaël Huet, Monica Araya-Farias, Ranim Alayoubi, Sylvain Laclef, Benjamin Bouvier, Isabelle Gosselin, Christine Cézard, Romain Roulard, Matthieu Courty, Caroline Hadad, Eric Husson, Catherine Sarazin, Albert Nguyen Van Nhien
A combination of experiments and modeling reveals the influence of alkyl chain lengths in biobased ZILs on the biocompatibility towards various microorganisms.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry