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Polymer electrolytes with high cation transport number for rechargeable Li–metal batteries: current status and future direction

Energy Environ. Sci., 2024, 17,8457-8481
DOI: 10.1039/D4EE03097D, Review Article
Xinyuan Shan, Zhaowei Song, Hang Ding, Lengwan Li, Yuhang Tian, Alexei P. Sokolov, Ming Tian, Kang Xu, Peng-Fei Cao
The high-cation transport number polymer electrolytes (HTPEs) with simultaneously high cation transport number and high ionic conductivity could provide a solution to enable high-performance solid-state batteries.
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Weakened hydrogen bond connectivity promotes interfacial mass transfer for industrial level scalable biomass electrooxidation

Energy Environ. Sci., 2024, 17,8801-8809
DOI: 10.1039/D4EE03482A, Paper
Zhaohui Yang, Lan Chen, Yijun Yin, Chenyang Wei, Zhimin Xue, Tiancheng Mu
The inhomogeneous valence distribution due to in the intrinsic electric field of a material can weaken the interfacial H-bonding connectivity under the bias potential, which promotes the mass transfer of HMF during the HMF electrooxidation reaction.
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Microenvironment engineering of covalent organic framework based single/dual-atom catalysts toward sustainable energy conversion and storage

Energy Environ. Sci., 2024, 17,8482-8528
DOI: 10.1039/D4EE03704A, Review Article
Ligang Wang, Jialu Li, Shufang Ji, Yuli Xiong, Dingsheng Wang
The recent advances in design principles, synthetic strategies, advanced characterization techniques and promising applications of state-of-the-art COF-based SACs/DACs were comprehensively discussed and explored.
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Achieving high performance triboelectric nanogenerators simultaneously with high-voltage and high-charge energy cycle

Energy Environ. Sci., 2024, 17,8734-8744
DOI: 10.1039/D4EE02447H, Paper
Open Access
Yikui Gao, Jiaqi Liu, Linglin Zhou, Lixia He, Di Liu, Peiyuan Yang, Bingzhe Jin, Zhong Lin Wang, Jie Wang
This work achieves a high-voltage and high-charge energy cycle for TENGs, as well as lossless energy transmission between TENGs and PMCs.
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Deep ion mass transfer addressing the capacity shrink challenge of aqueous Zn‖MnO2 batteries during the cathode scaleup

Energy Environ. Sci., 2024, 17,8904-8914
DOI: 10.1039/D4EE02871F, Paper
Na Jiang, You Zeng, Qi Yang, Puda Lu, Keqi Qu, Lihang Ye, Xuejun Lu, Ziqiang Liu, Xixian Li, Yongchao Tang, Jinchao Cao, Shimou Chen, Chunyi Zhi, Jieshan Qiu
This work shows that the introduction of interstitial carbon into the MnO2 lattice could reduce the affinity toward SO42− and OH, thus suppressing the surface coverage of ZHS and improving the Zn||MnO2 battery performance under large loading mass.
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Circular battery design: investing in sustainability and profitability

Energy Environ. Sci., 2024, 17,8529-8544
DOI: 10.1039/D4EE03418J, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Andreas Wolf, Felix Nagler, Philip Daubinger, Christoph Neef, Karl Mandel, Andreas Flegler, Guinevere A. Giffin
The market share of low-cost battery chemistries, which offer little to no recycling profitability with current methods, is growing. Design for circularity could be the key to reducing costs and enhancing sustainability for these batteries.
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Bicontinuous-phase electrolyte for a highly reversible Zn metal anode working at ultralow temperature

Energy Environ. Sci., 2024, 17,8966-8977
DOI: 10.1039/D4EE02815E, Paper
Mi Xu, Beinuo Zhang, Yudong Sang, Dan Luo, Rui Gao, Qianyi Ma, Haozhen Dou, Zhongwei Chen
A bicontinuous-phase electrolyte with a well-balanced solvation sheath is proposed, which delivers fast desolvation kinetics and generates a uniform in situ solid electrolyte interface, thus achieving a long-lasting Zn anode at low temperatures.
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Self-assembled porous salt crystals for solar-powered crystallization

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04741A, Paper
Jie Yu, Lenan Zhang, Jintong Gao, Wenyu Han, Ruzhu Wang, Zhenyuan Xu
Thermally localized solar evaporation has been recognized as an efficient and suitable pathway for desalination and brine treatment. However, the annoying salt crystallization inside the porous evaporator brings challenges for...
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Cousin, elder son arrested for murdering woman




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Coir cluster to be operational in Coimbatore in 2025




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Doctors decry suspension of obstetrician-gynaecologist after infant’s death in Mayiladuthurai

They want the the Joint Director of Health Services, who placed the doctor under suspension following protest by the family members and relatives alleging medical negligence, to withdraw the order




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Mayor inspects Chathiram bus stand in Tiruchi




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Nutritious meal employees observe fast in three districts




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KTR’s Delhi visit is just diversion politics: Komatireddy Venkat Reddy




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Violation of rules causes traffic bottleneck on VOC Road




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The morning ‘hush’ hour

The arrival of the newspaper meant a long silence for its reading




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​Revenue repercussions: on GST revenue trends

Festive season GST receipts hold a critical signal for growth




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India’s cities, expanding hubs of precarious employment

There have been fundamental shifts in India’s urban workforce and city development, affecting informal workers in particular




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Caste census data will be made public barring personal info of individuals, says Revanth Reddy

The data from the ongoing caste survey will not only be a road map for welfare and development, but also help the government in taking steps to increase the OBC quota; without accurate data, our goal of increasing reservations for BCs will not be achieved




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India, Pakistan and modifying the Indus Waters Treaty

Given the lack of trust between the two countries, renegotiating the IWT to review and make changes might prove difficult




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The Musi’s clean-up: On Hyderabad’s river plan




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Crowd of confusion: On the Maharashtra political scene, polls  

The polls may settle the churn in Maharashtra politics 




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‘I don’t want to lose trust of my people’: Maratha quota activist Manoj Jarange Patil on withdrawal from poll fray 

In a conversation with Manoj Jarange Patil, in his village ‘Antrawali Sarati’, which became the epicentre of Maratha agitation, he again blamed the home minister as a mastermind behind not giving reservation. “No matter who makes the government, we will keep fighting till reservation is granted”, he said. 




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The rebellious maths teacher

P.K. Srinivasan took his ideals across the world, from Indian village classrooms to American lecture halls and African colleges, embodying a lifelong rebellion against a system that suppressed creativity




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The Ramayana within us

The core characteristics of the main characters of the epic manifest within everyone, depending on the situation




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Maharashtra Assembly polls: A litmus test for Marathas

The Marathas may find it difficult to retain their socio-political domination




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TiO2 nanopowder and nanofilm catalysts in the disinfection and mineralization of S. aureus with solar-simulated radiation

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00540B, Paper
Raed Shqier, Ahed Zyoud, Muath H. S. Helal, Heba Nassar, Raed Alkowni, Mohyeddin Assali, Shaher Zyoud, Naser Qamhieh, Abdul Razack Hajamohideen, Shadi Sawalha, Samer H. Zyoud, Hikmat S. Hilal
TiO2 films photo-catalyze S. aureus rupture and mineralization of resulting organic materials.
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Mediated electron transfer in a photo-bioreactor: continuous flow hydroxylation using cytochrome P450 BM3 in NADPH-free conditions

React. Chem. Eng., 2024, 9,803-815
DOI: 10.1039/D3RE00569K, Paper
Ali Fendri, Donya Valikhani, Joelle N. Pelletier
We designed a proof-of-concept photo-bioreactor enabling continuous flow NADPH-free activation of cytochrome P450 BM3 via mediated electron transfer.
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Dominant role of zeolite in coordination between metal and acid sites on an industrial catalyst for tetralin hydrocracking

React. Chem. Eng., 2024, 9,940-949
DOI: 10.1039/D3RE00605K, Paper
Jiayao Qi, Hanqiong Jia, Fei Wang, Hang Gao, Bo Qin, Xinwei Zhang, Jinghong Ma, Yanze Du, Ruifeng Li
An effective approach for upgrading light cycle oil (LCO) is the targeted conversion of poly-aromatic hydrocarbons to valuable monoaromatic hydrocarbons.
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A robust data analytical method to investigate sequence dependence in flow-based peptide synthesis

React. Chem. Eng., 2024, 9,825-832
DOI: 10.1039/D3RE00494E, Paper
Open Access
Bálint Tamás, Pietro Luigi Willi, Héloïse Bürgisser, Nina Hartrampf
A new data analytical method for flow-based peptide synthesis enables robust and quantitative analysis of sequence-dependent difficult couplings.
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General synthesis of secondary imines via reductive coupling of carbonyl and nitro compounds employing a reusable cobalt catalyst

React. Chem. Eng., 2024, 9,925-929
DOI: 10.1039/D3RE00509G, Paper
Chaochong Zhang, Yurong He, Peng Zhou, Yuandie Ma, Ziliang Yuan, Guoqiang She, Zhe Zheng, Juncheng Hu, Qingqing Jiang, Jason Chun-Ho Lam, Bo Han, Zehui Zhang, Bing Liu
Reusable nitrogen-doped carbon-encapsulated Co nanoparticle catalysts are found robust for the synthesis of secondary imines via the reductive amination of carbonyl compounds with NH3 or directly with nitro compounds.
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A safe and new strategy for N-arylation of 2,4-thiazolidinediones via microwave irradiation using base catalyst K2CO3 in DMF

React. Chem. Eng., 2024, 9,842-848
DOI: 10.1039/D3RE00641G, Paper
Ragini C. Patil, Nita M. Khiratkar, Sumeer Ahmed, Joazaizulfazli Jamalis, Aso Hameed Hasan, Malika Berredjem, Sarkar M. A. Kawsar, Ajmal R. Bhat
Green efforts as an alternative to existing conventional methods for providing new tools, knowledge and design of organic synthesis, will contribute to the economy and protecting the environment and health.
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Machine-learning assisted optimisation during heterogeneous photocatalytic degradation utilising a static mixer under continuous flow

React. Chem. Eng., 2024, 9,872-882
DOI: 10.1039/D3RE00570D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas M. Kohl, Yan Zuo, Benjamin W. Muir, Christian H. Hornung, Anastasios Polyzos, Yutong Zhu, Xingdong Wang, David L. J. Alexander
Machine-learning assisted optimisation of a continuous photodegradation reaction, using a TiO2 coated catalytic static mixer successfully accounting for catalyst degradation.
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Green synthesis of surfactant-free mesoporous silica with strong hydrophilicity via metal salt modifications for moisture adsorption

React. Chem. Eng., 2024, 9,816-824
DOI: 10.1039/D3RE00513E, Paper
Pariyawalee Sangteantong, Kunpirom Chainarong, Waleeporn Donphai, Metta Chareonpanich
In this work, the green synthesis of mesoporous silica (MPS) was carried out using low-cost sodium silicate as a precursor.
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Continuous flow synthesis of the ionizable lipid ALC-0315

React. Chem. Eng., 2024, 9,959-966
DOI: 10.1039/D3RE00630A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakob B. Wolf, Ju Weon Lee, Matthew B. Plutschack, Dario Cambié, Andreas Seidel-Morgenstern, Peter H. Seeberger
The ionizable lipid ALC-0315 is the major component of the lipid nanoparticles used to encapsulate the mRNA in the Biontech–Pfizer COVID-19 vaccine.
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Selective aerobic oxidative C–C bond cleavage using a high-entropy oxide-derived multimetallic catalyst

React. Chem. Eng., 2024, 9,967-973
DOI: 10.1039/D3RE00525A, Paper
Shaoyuan Guo, Xinli Tong, Jipeng Wang, Hang Tang
A stable and efficient high entropy catalyst is developed for the selective oxidative C–C bond cleavage in the presence of O2.
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At-line monitoring of hydrogen peroxide released from its photocatalytic and continuous synthesis

React. Chem. Eng., 2024, 9,777-781
DOI: 10.1039/D3RE00659J, Communication
Open Access
Anders Ø. Tjell, Lars-Erik Meyer, Barbara Jud, Selin Kara, Torsten Mayr
Photocatalytic synthesis of H2O2 in a continuous operation set-up using nitrogen-doped carbon nanodots (N-CNDs) and simultaneous determination of generated H2O2.
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Digital Pareto-front mapping of homogeneous catalytic reactions

React. Chem. Eng., 2024, 9,787-794
DOI: 10.1039/D3RE00673E, Communication
Open Access
Negin Orouji, Jeffrey A. Bennett, Sina Sadeghi, Milad Abolhasani
We present a digital framework for rapid multi-objective reaction space exploration and optimization of homogeneous catalytic reactions through autonomous experimentation and Bayesian optimization.
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Catalytic degradation of pine sawdust over heterotopic Ca–Fe and HZSM-5 to produce aromatic hydrocarbons

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00572K, Paper
Huifen Kang, Xintong Guo, Mei An, Conghua Ma, Guozhang Chang, Qingjie Guo, Jingjing Ma
Up to 90.47% aromatic proportion and a 31.02 mg g−1 BTEX yield were obtained by heterogeneous catalysis of Ca–Fe and HZSM-5.
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Efficient aqueous-phase hydrogenation of m-xylylenediamine to 1,3-cyclohexandimethylamine over a highly active and stable ruthenium catalyst

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00712J, Paper
Jing Guo, Heng Shao, Le Gao, Wancheng Ma, Wei Zhang, Long Huang, Haibin Chu
The strong interaction between Ru and –NH2 in Ru/NH2–Al2O3 led to the formation of highly dispersed Ru and modification of its electronic properties, and consequently greatly enhanced its performance and stability.
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Automated kinetic model identification via cloud services using model-based design of experiments

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00047A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Emmanuel Agunloye, Panagiotis Petsagkourakis, Muhammad Yusuf, Ricardo Labes, Thomas Chamberlain, Frans L. Muller, Richard A. Bourne, Federico Galvanin
Industry 4.0 has birthed a new era for the chemical manufacturing sector, transforming reactor design and integrating digital twin into process control.
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Photochemical organocatalytic heteroarylation of anilines and secondary alicyclic amines in continuous-flow

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00130C, Paper
Egor N. Boronin, Milena M. Svetlakova, Ilya I. Vorobyov, Yulia B. Malysheva, Yuri V. Polushtaytsev, Sergey N. Mensov, Andrey V. Vorotyntsev, Alexey Yu. Fedorov, Timothy Noël, Alexander V. Nyuchev
Photoorganocatalytic arylation of amines in continuous-flow enables scaling up including decreasing of both reaction time and catalyst loading.
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On a seamlessly replicable circular photoreactor for lab-scale continuous flow applications

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00109E, Paper
Yi-Hsuan Tsai, Martin Cattoen, Guillaume Masson, Gabrielle Christen, Lisa Traber, Morgan Donnard, Frederic R. Leroux, Guillaume Bentzinger, Sylvain Guizzetti, Jean-Christophe M. Monbaliu
A cost effective and replicable continuous flow circular photoreactor system is introduced. All body parts of the reactor are 3D-printed and the electronics are purchased from various mainstream suppliers. The...
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Scaling-up continuous production of mesoporous silica particles at kg scale: design & operational strategies

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00707C, Paper
Rajashri B. Jundale, Jayesh R. Sonawane, Anil V. Palghadmal, Hemant Kumar Jaiswal, Hital S. Deore, Amol A. Kulkarni
This paper demonstrates a continuous flow pilot-scale production of highly porous mesoporous silica particles (MSPs) via a soft template based technique.
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Efficient removal of dibutyl phthalate from aqueous solutions: recent advances in adsorption and oxidation approaches

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00055B, Review Article
Yaqi Wang, Jiawei Wu, Wenju Zhang, Linyun Zhong, Dan Zhang, Siqi Yan, Junyou Shi
Dibutyl phthalate (DBP), a recognized endocrine-disrupting contaminant, poses substantial environmental challenges due to its persistence, resistance to degradation, and potential for bioaccumulation.
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Enphase Energy to cut workforce by 17%; to focus manufacturing in the US, India and China

500 employees and contractors to be affected by the lay-offs




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Tesla market value hits $1 trillion as Trump win fans optimism for Elon Musk’s companies

Musk’s companies are expected to get favourable treatment in the Trump regime, for the support he extended to the Trump campaign




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Ashok Leyland sees a positive shift in the e-bus procurement market with reasonable bidding rates

Dheeraj Hinduja expressed confidence that these initiatives are helping establish a more stable and predictable framework for procuring electric vehicles, which will benefit the sector’s long-term growth




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Leela Palaces Hotels’ parent Schloss Bangalore plans multi-use asset management

India has an existing stock of 858 branded residences associated with hotel brands, with a pipeline of another 2,040 units across New Delhi, Gurgaon and Mumbai, as per industry report




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WPP scales up investments in India, opens up new campus in Chennai

India is the fifth largest market for WPP and one of its fastest growing markets too. It also plans to add new campuses at Bangalore and Coimbatore in the coming years