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[ASAP] Development of a Robust and Highly Selective Ru(II)-Catalyzed Dynamic Kinetic Resolution Used to Manufacture AMG 232

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00427




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[ASAP] Scalable Synthesis of Esp and Rhodium(II) Carboxylates from Acetylacetone and RhCl<sub>3</sub>·<italic toggle="yes">x</italic>H<sub>2</sub>O

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00164




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[ASAP] Investigating Process Variables and Additive Selection To Optimize Polymorphic Control of Carbamazepine in a CO<sub>2</sub> Antisolvent Crystallization Process

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00545




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[ASAP] Photo-oxidation of Cyclopentadiene Using Continuous Processing: Application to the Synthesis of (1<italic toggle="yes">R</italic>,4<italic toggle="yes">S</italic>)-4-Hydroxycyclopent-2-en-1-yl Acetate

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00066




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[ASAP] Efficient Kinetic Data Acquisition and Model Prediction: Continuous Flow Microreactors, Inline Fourier Transform Infrared Spectroscopy, and Self-Modeling Curve Resolution

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00037




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[ASAP] Process Development and Large-Scale Synthesis of BTK Inhibitor BIIB068

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00087




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[ASAP] A Versatile Electrochemical Batch Reactor for Synthetic Organic and Inorganic Transformations and Analytical Electrochemistry

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00091




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[ASAP] Improved Synthesis of 6-Chloro-5-methylpyridin-2-amine: A Key Intermediate for Making Lumacaftor

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00556




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[ASAP] <italic toggle="yes">N</italic>-Acyl-5,5-Dimethylhydantoins: Mild Acyl-Transfer Reagents for the Synthesis of Ketones Using Pd–PEPPSI or Pd/Phosphine Catalysts

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00054




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[ASAP] Bromine–Lithium Exchange on a <italic toggle="yes">gem</italic>-Dibromoalkene, Part 2: Comparative Performance of Flow Micromixers

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00203




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[ASAP] Scalable Synthesis of <italic toggle="yes">S</italic>-Fluoromethyl Benzenesulfonothioate

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00101




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[ASAP] Optimized Synthesis of 7-Azaindazole by a Diels–Alder Cascade and Associated Process Safety

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00184




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[ASAP] Enzymatic Preparation of the Chiral (<italic toggle="yes">S</italic>)-Sulfoxide Drug Esomeprazole at Pilot-Scale Levels

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00115




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[ASAP] Continuous Process for Preparing the Difluoromethylating Reagent [(DMPU)<sub>2</sub>Zn(CF<sub>2</sub>H)<sub>2</sub>] and Improved Synthesis of the ICHF<sub>2</sub> Precursor

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00089




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[ASAP] Development and Production of an Enantioselective Tetrahydroisoquinoline Synthesis Enabled by Continuous Cryogenic Lithium–Halogen Exchange

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00141




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[ASAP] <sc>d</sc>-Serine as a Key Building Block: Enzymatic Process Development and Smart Applications within the Cascade Enzymatic Concept

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00024




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[ASAP] Correction to “Application of Crabtree/Pfaltz-type Iridium Complexes for the Catalyzed Asymmetric Hydrogenation of an Agrochemical Building Block”

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00206




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[ASAP] Catalyst-Free Cyclization- and Curtius Rearrangement-Induced Functional Group Transformation: An Improved Synthetic Strategy of First-in-Class ATX Inhibitor Ziritaxestat (GLPG-1690)

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00511




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RSC - Mol. BioSyst. latest articles





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Properties, fabrication and applications of plasmonic semiconductor nanocrystals

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02511A, Minireview
Haibo Yin, Yasutaka Kuwahara, Kohsuke Mori, Catherine Louis, Hiromi Yamashita
We highlight three widely explored oxide-based plasmonic materials, including HxMoO3−y, HxWO3−y, and MoxW1−xO3−y, and their applications in catalysis.
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Atomic-scale engineering of metal–oxide interfaces for advanced catalysis using atomic layer deposition

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00304B, Perspective
Lina Cao, Junling Lu
Two main routes to optimization of metal–oxide interfaces: reducing metal particle size and oxide overcoating.
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The effect of crystallite size on low-temperature hydrothermal stability of Cu-SAPO-34

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00414F, Paper
Jinpeng Du, Xiaoyan Shi, Yulong Shan, Yingjie Wang, Wenshuo Zhang, Yunbo Yu, Wenpo Shan, Hong He
Two Cu-SAPO-34 catalysts with different crystallite sizes were obtained, and catalyst with smaller crystallite size had better low-temperature hydrothermal stability because of less Cu2+ species on the surface.
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Synthesis and characterization of a supported Pd complex on carbon nanofibers for the selective decarbonylation of stearic acid to 1-heptadecene: the importance of subnanometric Pd dispersion

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00322K, Paper
Open Access
Elba Ochoa, Wilson Henao, Sara Fuertes, Daniel Torres, Tomas van Haasterecht, Elinor Scott, Harry Bitter, Isabel Suelves, Jose Luis Pinilla
Evaluation of the dispersion of Pd active sites on the catalyst performance during fatty acids decarbonylation to α-olefins was explored in this work. Pd subnanometric particles, clusters and aggregates were found to modulate the catalyst activity.
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Enhancing aqueous pollutants photodegradation via Fermi level matched Z-scheme BiOI/Pt/g-C3N4 photocatalyst: unobstructed photogenerated charge behavior and degradation pathway exploration

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00429D, Paper
Jingjing Jiang, Yueyu Song, Xingyue Wang, Tianren Li, Mingyu Li, Yanhong Lin, Tengfeng Xie, Shuangshi Dong
Z-scheme photocatalytic system was widely requisited to solve water pollution problem. However, the degradation mechanism for pollutants with Z-scheme photocatalyst has been ambiguous. In this work, an efficient all solid-state...
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Domino lignin depolymerization and reconnection to complex molecules mediated by boryl radicals

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00558D, Paper
Longcheng Hong, Astrid Spielmeyer, Janin Pfeiffer, Hermann A. Wegner
Lignin has been demonstrated as a source of complex molecules via a boryl-mediated domino degradation/reconnection process.
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Computational investigation of the ligand effect on the chemo/regioselectivity and reactivity of cobalt-catalysed hydroformylation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02562F, Paper
Pan Li, Chaoren Shen, Jie Min, Jing-Yuan Mei, Huan Zheng, Lin He, Xinxin Tian
The ligand effect on the chemo/regioselectivity and reactivity of cobalt-catalysed hydroformylation has been discussed.
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Synergetic effect of Lewis acid and base in modified Sn-β on the direct conversion of levoglucosan to lactic acid

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00089B, Paper
Wenda Hu, Zixin Chi, Yan Wan, Shuai Wang, Jingdong Lin, Shaolong Wan, Yong Wang
The synergetic effect of Lewis acid and base in modified Sn-β boosts the yield of lactic acid produced from levoglucosan.
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Superior adsorption capability and excellent photocatalytic activity derived from the ferroelectric external screening effect in Bi3TiNbO9 single-crystal nanosheets

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02513H, Paper
Xiaofeng Yin, Yingjie Sun, Xiaojun Wu, Xiaoning Li, Huan Liu, Wen Gu, Wei Zou, Liuyang Zhu, Zhengping Fu, Yalin Lu
A new strategy based on the ferroelectric external screening effect was used to enhance dye adsorption and degradation activity.
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Oxidation of lignocellulosic platform molecules to value-added chemicals using heterogeneous catalytic technologies

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00240B, Minireview
Pedro L. Arias, Juan A. Cecilia, Iñaki Gandarias, José Iglesias, Manuel López Granados, Rafael Mariscal, Gabriel Morales, Ramón Moreno-Tost, Pedro Maireles-Torres
This minireview gives an overview about heterogeneous catalytic technologies for the oxidation of key platform molecules (glucose, 5-hydroxymethylfurfural, furfural and levulinic acid) into valuable chemicals.
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Hydrodeoxygenation of anisole to benzene over an Fe2P catalyst by a direct deoxygenation pathway

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00046A, Paper
Shuyuan Wang, Dan Xu, Yunlei Chen, Song Zhou, Di Zhu, Xiaodong Wen, Yong Yang, Yongwang Li
Fe2P catalyst was highly selective for the cleavage of C–O bond of anisole via direct deoxygenation pathway.
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Metal free alkene hydrogenation by B-doped graphitic carbon nitride

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00488J, Paper
Ashima Dogra, Ilaria Barlocco, Amritpal Singh, Ferenc Somodi, Alberto Villa, Neeraj Gupta
Metal free hydrogenation of styrene under mild conditions employing boron-doped carbon nitride catalysts is reported.
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Integrated design for electrocatalytic carbon dioxide reduction

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00453G, Minireview
Xin Zhao, Lijie Du, Bo You, Yujie Sun
We have summarized three novel strategies for electrocatalytic carbon dioxide reduction, including concurrent CO2 electroreduction, tandem CO2 electroreduction and hybrid CO2 electroreduction.
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Water-soluble NHC-stabilized platinum nanoparticles as recoverable catalysts for hydrogenation in water

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00481B, Paper
Andrea M. Ruiz-Varilla, Edwin A. Baquero, Bruno Chaudret, Ernesto de Jesús, Camino Gonzalez-Arellano, Juan C. Flores
Aromatic compounds have been hydrogenated in water using recoverable catalysts based on water-soluble platinum nanoparticles capped with NHC ligands.
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Recent advances and prospects of inkjet printing in heterogeneous catalysis

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00040J, Minireview
Open Access
Hesam Maleki, Volfango Bertola
This review provides an insight into inkjet printing technology in the context of heterogeneous catalysis.
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Enhancing the methane low-temperature conversion on the Zn/ZSM-5 in the presence of methanol by regulating methanol-to-aromatics reaction pathway

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00449A, Paper
Zhixiang Xi, Bingjie Zhou, Yue Yu, Binbo Jiang, Zhengliang Huang, Zuwei Liao, Jingdai Wang, Yao Yang, Jingyuan Sun, Yongrong Yang
Co-reaction method provides efficient strategy for methane conversion in mild condition, which is of urgent importance of direct valorization of natural gas to liquid hydrocarbons. However, vague mechanism and neglect...
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Molybdenum carbide supported metal catalysts (Mn/MoxC; M = Co, Ni, Cu, Pd, Pt) – metal and surface dependent structure and stability

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00504E, Paper
Fan Wang, Teng Li, Yun Shi, Haijun Jiao
The surface and metal-dependent morphologies and energies of molybdenum carbide supported metal catalysts (Mn/MoxC; M = Co, Ni, Cu, Pd, Pt) have been systematically investigated on the basis of periodic density functional theory computations.
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Deactivation and regeneration of carbon supported Pt and Ru catalysts in aqueous phase hydrogenation of 2-pentanone

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00163E, Paper
Jiajie Huo, Hien N. Pham, Yan Cheng, Hsi-Hsin Lin, Luke T. Roling, Abhaya K. Datye, Brent H. Shanks
Aqueous phase conversion of biomass-derived molecules requires development of catalysts and operating strategies that create viable operation for extended performance as necessitated for industrial applications.
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Seaweed bio-inspired ZnO piezoelectric cilia array applied in microreactors for enhanced photocatalytic performance

Catal. Sci. Technol., 2020, 10,2337-2342
DOI: 10.1039/C9CY02509J, Paper
Yukai Chen, Jiaojiao Fang, Baoying Dai, Huimin Wei, Jiahui Kou, Chunhua Lu
A piezoelectric built-in electric field is believed to be an effective way to separate photoinduced carriers and enhance photocatalytic performance.
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Development of an engineered thermostable amine dehydrogenase for the synthesis of structurally diverse chiral amines

Catal. Sci. Technol., 2020, 10,2353-2358
DOI: 10.1039/D0CY00071J, Paper
Lei Liu, Dong-Hao Wang, Fei-Fei Chen, Zhi-Jun Zhang, Qi Chen, Jian-He Xu, Zhi-Long Wang, Gao-Wei Zheng
Structurally diverse chiral amines and amino alcohols were synthesized using an engineered thermostable amine dehydrogenase, demonstrating its extensive synthesis potential.
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Fine-tuning of the substrate binding mode to enhance the catalytic efficiency of an ortho-haloacetophenone-specific carbonyl reductase

Catal. Sci. Technol., 2020, 10,2462-2472
DOI: 10.1039/C9CY02335F, Paper
Aipeng Li, Xue Li, Wei Pang, Qing Tian, Ting Wang, Lianbing Zhang
Fine-tuning of the substrate binding mode was successfully applied for enhancing the catalytic efficiency of an ortho-haloacetophenone-specific carbonyl reductase.
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Synergistic photocatalysis–Fenton reaction for selective conversion of methane to methanol at room temperature

Catal. Sci. Technol., 2020, 10,2329-2332
DOI: 10.1039/D0CY00028K, Communication
Yi Zeng, Hang Chen Liu, Jing Sheng Wang, Xing Yang Wu, Song Ling Wang
Combining the photocatalysis and Fenton reaction highly promote the yield and selectivity of CH3OH from CH4 with solar light at room temperature, up to 471 μmol g−1 h−1 and 83%, respectively.
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Effect of ceria morphology on the performance of MnOx/CeO2 catalysts in catalytic combustion of N,N-dimethylformamide

Catal. Sci. Technol., 2020, 10,2473-2483
DOI: 10.1039/C9CY02384D, Paper
Fengying Huang, Dongsheng Ye, Xiaohan Guo, Wangcheng Zhan, Yun Guo, Li Wang, Yunsong Wang, Yanglong Guo
MnOx/CeO2 catalysts were prepared by a deposition–precipitation method, through loading MnOx into ceria supports with different morphologies (nanorods (NRs), nanocubes (NCs) and nano-octahedrons (NOs)).
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Microemulsion solventing-out co-precipitation strategy for fabricating highly active Cu–ZnO/Al2O3 dual site catalysts for reverse water gas shift

Catal. Sci. Technol., 2020, 10,2343-2352
DOI: 10.1039/C9CY02608H, Paper
Ziheng Zhen, Wenxiang Tang, Wei (Willy) Chu, Tao Zhang, Li Lv, Shengwei Tang
A new strategy for the preparation of dual site catalysts is introduced, which combines microemulsion technology and anti-solvent extraction technology.
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Pd–Au bimetallic catalysts supported on ZnO for selective 1,3-butadiene hydrogenation

Catal. Sci. Technol., 2020, 10,2503-2512
DOI: 10.1039/C9CY02395J, Paper
Open Access
Belén Bachiller-Baeza, Ana Iglesias-Juez, Giovanni Agostini, Eva Castillejos-López
The effect of the ZnO morphology on the properties of Pd–Au bimetallic catalysts has been discussed.
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Antimony-doped tin oxide as an efficient electrocatalyst toward the VO2+/VO2+ redox couple of the vanadium redox flow battery

Catal. Sci. Technol., 2020, 10,2484-2490
DOI: 10.1039/C9CY01793C, Paper
Yang Lv, Chunmei Yang, Haining Wang, Jin Zhang, Yan Xiang, Shanfu Lu
Enhanced electrocatalytic activity of ATO toward the VO2+/VO2+ redox reaction by adjusting electronic conductivity.
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Path of electron transfer created in S-doped NH2-UiO-66 bridged ZnIn2S4/MoS2 nanosheet heterostructure for boosting photocatalytic hydrogen evolution

Catal. Sci. Technol., 2020, 10,2531-2539
DOI: 10.1039/D0CY00127A, Paper
Qi Ran, Zebin Yu, Ronghua Jiang, Lun Qian, Yanping Hou, Fei Yang, Fengyuan Li, Mingjie Li, Qianqian Sun, Heqing Zhang
This work introduces the synthesis of ZnIn2S4/NH2-UiO-66/MoS2 sheet heterostructure photocatalysts and their application to photocatalytic hydrogen evolution.
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Hourglass-type polyoxometalate-based crystalline materials as efficient cooperating photocatalysts for the reduction of Cr(VI) and oxidation of dyes

Catal. Sci. Technol., 2020, 10,2593-2601
DOI: 10.1039/D0CY00208A, Paper
Xuerui Tian, Yaqi Zhang, Yuanyuan Ma, Qing Zhao, Zhangang Han
Hourglass-type polyoxometalate-based crystalline materials exhibit efficient photocatalytic activities towards simultaneous photocatalytic Cr(VI) reduction and organic MB oxidation.
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Hydroxyl groups attached to Co2+ on the surface of Co3O4: a promising structure for propane catalytic oxidation

Catal. Sci. Technol., 2020, 10,2573-2582
DOI: 10.1039/D0CY00265H, Paper
Kun Chen, Wenzhi Li, Zean Zhou, Qifu Huang, Yang Liu, Qiuyan Duan
Co3O4 catalysts with three specific morphologies (nanocubes, nanosheets, and nanooctahedra) were prepared using simple preparation methods and tested for catalytic combustion of propane under the same reaction conditions.
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The direct decomposition of NO into N2 and O2 over copper doped Ba3Y4O9

Catal. Sci. Technol., 2020, 10,2513-2522
DOI: 10.1039/D0CY00194E, Paper
Siman Fang, Atsushi Takagaki, Motonori Watanabe, Tatsumi Ishihara
Both NO decomposition activity and long-term stability increase significantly after the introduction of Cu into Ba3Y4O9.
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