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N-heterocyclic carbene-stabilized Cu9 clusters with combined thermally activated delayed fluorescence and phosphorescence

Inorg. Chem. Front., 2024, 11,2498-2507
DOI: 10.1039/D4QI00160E, Research Article
Lin-Mei Zhang, Mo Xie, Hui-Zhi Wei, Shang-Fu Yuan, Dong-Sheng Li, Tao Wu
Two NHC-stabilized Cu9 clusters showcase both TADF and direct phosphorescence in thermal equilibrium. The combined harvesting mechanism arises from the simultaneous presence of a small ΔE(S1 − T1) gap and relatively strong spin–orbit coupling.
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Durable dielectric switching and photo-responsivity in a Dion–Jacobson hybrid perovskite semiconductor

Inorg. Chem. Front., 2024, 11,2436-2441
DOI: 10.1039/D3QI02685J, Research Article
Peng Wang, Xinling Li, Huang Ye, Qianwen Guan, Yifei Wang, Yaru Geng, Chengshu Zhang, Hang Li, Junhua Luo
D–J phase perovskite (BDA)MA2Pb3Br10 reveals excellent photo-responsivity antifatigue merits and remarkable switching stability.
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Competition mechanism of self-trapped excitons and Te4+ ions emission in the Te4+ doped vacancy-ordered double perovskite Rb2HfCl6 and its excellent properties

Inorg. Chem. Front., 2024, 11,2457-2470
DOI: 10.1039/D4QI00109E, Research Article
Ruxin Liu, Kaishun Zou, Guanglu Zhang, Min Feng, Mingxuan Li, Juncheng Liu
The luminescence mechanism of Te4+-doped VODPs is reported. Te4+-doped Hf-based VODPs exhibit luminescence characteristics that are more in line with those of Te4+ ions, while Te4+-doped Sn- and Zr-based VODPs have STEs emission characteristics.
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Electrodeposited Superaerophobic Nickel Catalyst on Pencil-Drawn Paper: A Novel Approach for Highly Efficient and Stable Hydrogen Evolution

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00101J, Research Article
Qian Sun, Xiaoyu Hao, Tianyi Zhang, Zelin Ma, Kui Hu, Ming Yang, Xiaolei Huang, Xuqing Liu
Electrocatalytic water splitting stands at the forefront of advancing renewable energy technologies. A critical challenge in this realm is the detrimental effect of gas bubble adhesion on electrode surfaces, which...
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Efficient photocatalytic hydrogen evolution of g-C3N4/Vs-SnS2/CdS through a sulfur vacancy-rich SnS2 induced charge storage effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00602J, Research Article
Fangyuan Xing, Junyan Li, Chengzhi Wang, Shaohua Jin, Haibo Jin, Jingbo Li
Photocatalytic hydrogen production using semiconductors is one of the most promising routes for sustainable energy production.
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Post-synthetic modification of a covalent organic framework via a thiol–ene reaction for improving fluorescence detection and removal of cationic crystal violet carcinogenic dye

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00419A, Research Article
Ke Li, Bing Yan
Based on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.
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Enhanced photocatalytic CO2 reduction by controlled oxygen vacancy generation and co-constructed heterojunction strategy for Pd/CeO2

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00581C, Research Article
Fanlin Kong, Xiaoyan Lu, Jing Xie, Zhenjiang Lu, Jindou Hu, Yali Cao
Rational control of Vo concentration and the construction of a heterojunction strategy enable Pd/CeO2-Vo(r) to exhibit excellent photocatalytic CO2RR activity. The presence of COOHcreates favorable conditions for CO formation and desorption.
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Insights into the modulation mechanisms of multiple active sites in a conjugated small molecule towards organic cathode capacity from first-principles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00547C, Research Article
Zhaopeng Sun, Hao Tian, Meng Zhang, Yi Zhang, Zhiping Li, Weiwei Huang
The modulation mechanisms of Na+ within the redox-active sites of the two-dimensional conjugated organic small-molecule 3BQ, and their impact on the initial capacity of a 3BQ cathode for Na-ion batteries, were investigated using first-principles calculations.
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Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
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Application of changing the valence state of metals through the reaction time for efficient oxygen evolution reaction

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00522H, Research Article
Ming Chen, Sha Luo, Zongyan Ma, Fei Yuan, Jing Chen, Linkun Dong, Weiwen Mao, Jiantai Ma
In this study, a novel FeNi sulfide catalyst loaded on carbon nanotubes (CNTs) (FeNiS/CNTs) shows excellent OER electrocatalytic performance in alkaline solutions.
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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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Trifluoroacetic acid molecules confined into/onto metal–organic frameworks using H2btzip for efficiently improving proton conductivity using a synergistic effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00605D, Research Article
Xiaoxue Ma, Xin Li, Xueke Han, Lu Zhang, Ronghua Liu, Hongguo Hao, Hui Yan, Xin Zhao, Xiangjin Kong, Huawei Zhou, Xia Li, Hongjie Zhu, Suna Wang, Yunwu Li, Dichang Zhong, Fangna Dai
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
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AgCare Tech launches digital marketplace for agri inputs

‘Golden Farms’ is designed to digitise the agricultural input supply chain




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India dominates global natural gas contracts in 2024, cornering 30% of share

The Middle East, led by Qatar, was the primary exporter, while Asian countries, notably India and China, were key importers




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MCX launches cottonseed wash oil futures contract

It will offer a robust price risk management solutions for the cottonseed oil industry




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MCX to launch monthly gold option contract

MCX reduces gold option expiry to monthly, improving liquidity and attracting more participants, benefiting jewellers and increasing revenue




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Easing West Asia tensions bring back overseas tea buyers to Kochi 

Sales percentage increases as Russian buyers turn active




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Crude oil futures dip after Israeli attack avoids Iranian oil facilities 

November natural gas futures were trading at ₹254.50 on MCX during the initial hour of trading on Monday against the previous close of ₹258.20, down by 1.43 per cent




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Manufacturing method of lab grown diamonds should be declared before export and import: CBIC

The new norms, which will help in quick processing and inspection of consignments, are to be effective from December 1




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Why drugmakers are dialing C for current good manufacturing practices

For the industry under scrutiny over quality concerns, cGMP requires immediate attention




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Time for action

On UHC Day (December 12), focussed on “Health For All: Time for action”, WHO urges governments to invest in resilient health systems — as climate and conflict threaten humanity’s existence




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Balancing innovation and access to healthcare

The draft Patent (Amendment) Rules, 2023, have prompted extensive discussion and debate, drawing attention to India’s pivotal role in providing affordable medicines, especially to those in need




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No turning back on the biotech super highway

Industry experts call for support to firms pursuing cutting-edge technologies as they forge ahead 




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A pitch to walk the fine line between innovation and access

 Ahead of USTR’s Special 301 report, India campaigns for flexibilities in international trade laws




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PLI, plugging chinks in the country’s manufacturing armour for drugs and devices

 Call for simplification of licencing regimes gets louder even as benefits become tangible 




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Pharmacies journey through litigations and another election

Chemists’ manifesto: Call for fair play gets louder amidst deep discounts from online pharmacies




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Tobacco exposed

May 31 is World No Tobacco Day




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Redefining the regulatory pathway for nutraceutical and pharmaceutical products

As the nutraceutical landscape grows, experts call for clarity in the manufacturing debate




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Data integrity alarm sounded for CROs, the backbone to pharma industry

USFDA cautions CROs; says such incidents “undermine the reputation of generic industry”




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Act on hepatitis infections

Deaths from viral hepatitis-related causes are increasing, with around one hepatitis death every 30 seconds, says the WHO, ahead of World Hepatitis Day (July 28).




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Act of giving

World Organ Donation Day (August 13) seeks to raise awareness on this act of giving and to inspire others to become organ donors




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Clinical trial waiver, a step to improve patient access, in need of guardrails

Experts call for ensuring patient safety while expanding access to new drugs




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Code grey: Hospitals as safe zones for medical practitioners, patients

Amid rising violence, medicos call for a stringent Central Act to ensure safe workspaces and speedy action




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HML succeeds in bringing back workers to Wayanad tea plantations 

This is evident from the number of workers in the tea estates of the hill district rose by five per cent to 40 per cent during the past two months




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Centre asks sugar mills to pack 20% of production in jute bags

Warns of action against units not heeding to mandatory order




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Ninjacart pares losses to ₹259 cr for fiscal 2024

Operating revenues up 74 per cent % at Rs ₹2002 cr on volume growth




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CMFRI develops eco-friendly fish feed from black soldier fly larvae 

CMFRI transferred the technology to Amala Ecoclean, a start-up focusing on sustainable waste management and environmental solutions, for large-scale commercial production




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Big boost to rice procurement in second fortnight of October, Central purchase reaches 84 lakh tonnes

The purchases were 48 per cent lower at 20.7 lt in until October 15, whereas in the second fortnight over 63 lt rice was procured by the Centre




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Climate issues, disease seen impacting arecanut production this year

Factors such as continuous heavy rainfall with intermittent sunshine, low temperatures and high humidity help in the spreading of this disease in arecanut plantations




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Crystal Crop Protection acquires I&B Seeds

Diversifies into flower and vegetable seeds with the latest buyout




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India-US farm trade to get a boost with Trump’s comeback

Experts predict an increase in India’s exports, including tea, coffee, and spices, while imports of American farm products like tree nuts and fresh fruits are also likely to rise




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Indian Tea Association calls for creating rating system based on quality of retail packets

Consumers should know the quality of blends used in the packets, says itsIndian Tea Association chief Hemant Bangur




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The economic impact of cashew farming: How nut agriculture fuels local economies

With proper investments and policy support, this sector could deliver even greater benefits




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Key challenges faced by farmer producer companies in the agricultural ecosystem

Building genuine connections and understanding the intrinsic motivations of farmers can create a vibrant ecosystem




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UPL’s Q2 net losses widen to ₹443 crore on pricing impact

The company reported a net loss of Rs ₹443 crore for the September quarter against a loss of Rs ₹189 crore in the same period last year




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CCL Products says more customers prefer short-term coffee contracts as market stays volatile

See some softening in Vietnam prices as new arrivals are set to begin next month




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Acquisition proposals worth ₹2,200 cr issued to industry, says Vice Navy Chief




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Boeing strike to impact Indian carriers growth: CAPA India

Airbus deliveries lower than expected, says CAPA India outlook for FY 2025




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Gujarat HC orders release of SW South Wind I after pact with exporting firm

Two more arrest orders are pending against the vessel




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Indian Railways renegotiates Vande Bharat order to 80 high-capacity trainsets; JV Kinet on-board

New order consists of 80 trainsets with a 24-coach configuration, instead of originally planned 16