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β-Cyclodextrin and cucurbit[7]uril as protective encapsulation agents of the CO-releasing molecule [CpMo(CO)3Me]

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT01863J, Paper
Rodrigo P. Monteiro, Isabel B. Calhau, Ana C. Gomes, André D. Lopes, José P. Da Silva, Isabel S. Gonçalves, Martyn Pillinger
For inclusion compounds between the complex [CpMo(CO)3Me] (1) and β-cyclodextrin or cucurbit[7]uril, the macrocyclic hosts modulate to different degrees the UV light-mediated CO release from encapsulated 1.
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Co-doping regulation on Ni-based electrocatalysts to adjust the selectivity of oxygen reduction reaction for Zn–air batteries and H2O2 production

Dalton Trans., 2024, 53,17819-17828
DOI: 10.1039/D4DT01625D, Paper
Songhan Hu, Kai Wang, Xinxin Xu, Qiang Wang
Two Ni-based electrocatalysts with different ORR selectivity were synthesized from a NiMOF, which show promising prospects in Zn–air batteries and H2O2 production.
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Effect of mono- and dinuclear thiosemicarbazone platinacycles in the proliferation of a colorectal carcinoma cell line

Dalton Trans., 2024, 53,17803-17818
DOI: 10.1039/D4DT01490A, Paper
Open Access
Francisco Reigosa-Chamorro, Sandra Cordeiro, M. Teresa Pereira, Beatriz Filipe, Pedro V. Baptista, Alexandra R. Fernandes, José M. Vila
The study of the antiproliferative activity of thiosemicarbazone platinacycles puts forward their high selectivity and low IC50 values.
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Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents

Dalton Trans., 2024, 53,18003-18012
DOI: 10.1039/D4DT02285H, Paper
Anupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti Ghoshal
An ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.
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Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance

Dalton Trans., 2024, 53,17948-17962
DOI: 10.1039/D4DT02118E, Paper
Anandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel Elumalai
We disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.
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An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection

Dalton Trans., 2024, 53,17893-17901
DOI: 10.1039/D4DT02111H, Paper
Yunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo Lu
An acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.
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Unprecedented C–F bond cleavage in perfluoronaphthalene during cobaltocene reduction

Dalton Trans., 2024, 53,17789-17793
DOI: 10.1039/D4DT02791D, Communication
Gargi Kundu, Debjit Pramanik, Soumya Ranjan Dash, Ravi Kumar, Mayur Sangole, Srinu Tothadi, Aryya Ghosh, Kumar Vanka, Kirandeep Singh, Sakya S. Sen
The reduction of octafluoronapthalene by cobaltocene in preence of NHC led to a distinct Co(I) species with the cleavage of the C–F bond and the formation of Co–C bond.
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Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02655A, Paper
Z. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun Xu
Four BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...
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Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02621G, Paper
Open Access
Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro Marrone
Paddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...
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Are Coal Producers doing an OPEC?



  • Siddhartha P Saikia

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Price pooling mantra: Wake up to expensive electricity



  • Siddhartha P Saikia

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Cooked unapproved layouts




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Why do we succumb to pressure?




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It's all in the interpretation




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Confessions of an impractical person

How one ignored the imperfection of life by finding solace in the perfection of art




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Apparel oft proclaims the times

Sartorial preferences change from one era to another




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NanoRaman: correlated tip-enhanced optical spectroscopy and scanning-probe microscopy

Register now: 8 March 2018
A webinar sponsored by HORIBA Scientific




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Tracking proton therapy with acoustic waves

Katia Parodi describes an innovative technique for improving ion-beam therapy




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Karnataka byelection: It is a proxy war between Lad and Reddy in mineral-rich Sandur

Though Sandur has been the hotbed of mining activities, often hitting the headlines for illegal mining, this issue is barely resonating in the campaign




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Karnataka makes online applications mandatory for private aided school teacher recruitment

DSEL has developed a separate app to conduct aided schools teachers’ recruitment transparently




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Tobacco crop hit by rain; farmers complain of poor prices

Usually, low grade tobacco accounts for about 25 to 30% of the total yield. This year, low grade tobacco is about 10% more than normal




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Medical malpractice destroys profession’s nobility, says BLDE Vice-Chancellor




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Karnataka Ministers seek action against Union Minister Pralhad Joshi for ‘agent’ comment on retired high court judge Michael D’Cunha

The two Ministers told the Governor that Mr. Joshi made a deliberate attempt to politicise and taint a constitutionally sanctioned inquiry, betraying public trust in the process




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Man gets life imprisonment for murdering wife




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Siddaramaiah to launch projects in Mysuru on November 12 and 13




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Ragi, paddy procurement under MSP to start soon in Mysuru

MSP for ragi has been fixed at ₹4,290 a quintal while for paddy, the MSP is ₹2,300 a quintal; farmers must register on the FRUITS portal to use the facility




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Karnataka High Court directs Chief Secretary to form panel to examine plea for declaring Allama Prabhu Swamy temple as ancient monument  

The temple is submerged in the backwaters of Hidkal dam in Belagavi district for nearly six months in a year




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Chief Minister Siddaramaiah has no moral right to seek resignation of Prime Minister Narendra Modi, says Union Minister

Pralhad Joshi was responding to a challenge by Mr. Siddaramaiah to the PM to prove charges of corruption in Karnataka or resign.




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Department of Pre-University Education to train PU students for K-CET and NEET in Shivamogga

Training programme to be inaugurated formally in Shivamogga tomorrow




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Kalaburagi: Man sentenced to 20 years of imprisonment for sexually assaulting minor girl




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Preparations complete for bypolls in Shiggaon Assembly segment




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D’Cunha report revealed ₹918 crore misappropriated in COVID equipment procurement: Sharan Prakash Patil




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Effective development of human resources facilitates growth: Pralhad Joshi




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Ronaldo panned for promoting supplement

The most scathing criticism came from Dr. Cyriac Abby Phillips, a Indian hepatologist and social media influencer known as 'The Liver Doc' on X.




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Music resistance from 1900 to the present / edited by Igor Contreras Zubillaga, Helena Martín-Nieva.

Turnhout : Brepols, 2022.




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Integrated motivational interviewing and cognitive behavioral therapy (ICBT) [electronic resource] : a practitioners guide / Joseph Hyde, Maria Torres, Win Turner, R. Lyle Cooper.

Hoboken, New Jersey : John Wiley & Sons, Inc., [2024]




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Schema-focused working methods for arts and body-based therapies [electronic resource] : a practical guide / edited by Suzanne Haeyen.

New York, NY : Routledge , 2024.




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Why people smoke [electronic resource] : an innovative approach to treating tobacco dependence / Frank T. Leone and Sarah Evers-Casey ; with illustrations by Joey Leone.

Philadelphia : University of Pennsylvania Press, [2023]




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Maha CM asks officials to provide compensation for farm losses due to unseasonal rains




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Prioritise celebrating Diwali with lights to avoid noise and air pollution: BMC issues new guidelines for firecracker use during festivities




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High-tech snooping: Maha hoteliers say privacy of customers, celebs at risk




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Harmanpreet, Sreejesh bag top honours at FIH Star Awards

Indian captain Harmanpreet Singh led the scoring charts at the Paris Olympics with 10 goals; Sreejesh brought the curtains down on his career at the highest level, putting together an incredible Olympic campaign




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Czech legend Jan Zelezny comes on board as Neeraj Chopra’s coach ahead of 2025 season

Jan Zelezny, 58, is widely considered the greatest javelin thrower of the modern era and is a world and Olympic champion. He also holds the record in the event.




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Is the new BYD eMAX 7 a practical EV for the big Indian family?

The BYD eMAX 7 is among the newest electric MPVs targeting family users in the Indian market. Combining advanced technology with an emphasis on practicality, this EV which provides options for both 6- and 7-seater configurations, aiming to meet the needs of families seeking a spacious yet sustainable ride. 




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Manipur beats Bengal; Uttar Pradesh qualifies for quarterfinals




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Morne Morkel, the consummate professional, faces a baptism of fire

India’s bowling coach will have to manage his spearhead Bumrah, who is also likely to lead the side in Perth, along with inexperienced seamers, guiding them to hit the right lengths; Prasidh’s performance for India-A will delight him as he looks to fill the Shami void




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Sprint ace Mark Cavendish ends cycling career in style with Singapore win

Mark Cavendish, one of the best road sprinters in cycling history, retired in style by winning the Tour de France Criterium in Singapore




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Jiri Privratsky beats Smit Moradiya by 0.1 point for air rifle gold

Well-known shooters Umamahesh Maddineni and Aishwary Pratap Singh Tomar were pushed out of the medals table, the little-known Smit shot brilliantly in the climax




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Aravindh stuns Aronian to claim the top prize




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Premier League referee David Coote suspended over derogatory remarks against Liverpool

Two videos circulating on social media appear to show David Coote giving his personal opinion on Jurgen Klopp and Liverpool when asked by another unidentified man.