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Calcium L-aspartate nanoparticles modify root ultrastructure and improve plant yield in Brassica napus L.

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Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00989K, Paper
kesong lu, jiayu hou, Riaz Muhammad, Babar Saba, Abd-Elkader Ali M., El-Desouki Zeinab, Cun-cang Jiang
Calcium (Ca) is an indispensable nutrient in plant development. Nanoparticles (NPs) are widely used in agricultural production, among which calcium L-aspartate nanoparticles (Ca(L-asp)-NPs), as a new type of Ca fertilizer,...
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High-efficiency removal of Cd(II) and As(III) from irrigation water using a S–Fe–C composite: performance and mechanisms

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00863K, Paper
Zihao Liang, Yanpeng Liang, Hua Lin, Yuxi Lu, Huawei Li, Jie Zhang, Honghu Zeng, Gongning Chen
SFC showcased exceptional Cd(II) and As(III) removal capacities of 405 mg g−1 and 349 mg g−1, respectively, while preserving magnetic recovery properties after repeated adsorption cycles, making it an environmentally sustainable functional material.
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Mycogenic silver nanoparticles from Penicillium citrinum IB-CLP11 – their antimicrobial activity and potential toxicity effects on freshwater organisms

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00002A, Paper
Arthur Pérez Aguiar, Cristiane Angélica Ottoni, Claudia de Lima Ramos Aquaroli, Evelyn Caroline Vicente Mendes, Ana Lúzia de Souza Araújo, Marta Filipa Simões, Edison Barbieri
Silver nanoparticles (AgNPs) are some of the most attractive nanomaterials for commercial applications, but they can also be a very challenging issue from the point of view of cytotoxicity and phytotoxicity as agents that damage genetic information.
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Characterization of black carbon and silica nanoparticle interactions with human plasma proteins

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00773A, Communication
Si-si Chen, Hong-juan Chen, Xue-wen Guo, Wei-juan Zheng, Hong-zhen Lian
Black carbon and silica nanoparticles, modeling different sources of PM, differ in protein corona composition and effects on protein structure.
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Classification, uptake, translocation, and detection methods of nanoparticles in crop plants: a review

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00059E, Critical Review
He-Yi Zhang, Wen-Hao Su
Nanotechnology offers a viable solution to enhancing agricultural sustainability by supporting seed germination and crop growth.
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A multi-technique analysis of gelatin biodegradation on the surface of core–shell nanoparticles by Alteromonas macleodii extracellular proteases

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Environ. Sci.: Nano, 2024, 11,1429-1441
DOI: 10.1039/D3EN00523B, Paper
Sergio Fernández-Castillo Suárez, Cécile Courrèges, Javier Jiménez-Lamana, Simon Godin, Sophie Nolivos, Régis Grimaud, Luisa Ronga, Joanna Szpunar, Joachim Allouche
Multi-technique characterization at the nanoscale of gelatin biodegradation on the surface of core–shell nanoparticles by extracellular proteases.
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Quantitatively differentiating foliar adhesion and absorption of different lead-based particles on Solanum melongena L.

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Environ. Sci.: Nano, 2024, 11,1417-1428
DOI: 10.1039/D3EN00640A, Paper
Bing Zhao, Siyu Zhang, Xuejiao Zhang, Qing Zhao, Jason C. White, Fengchang Wu, Baoshan Xing
This study quantitatively distinguished foliar adhesion and absorption between Pb nano- and submicron particles of different chemical forms.
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High-performance TiO2 catalyst composited with In–1,1,2,2-tetra(4-carboxylbiphenyl)ethylene for the efficient degradation of organic pollutants

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Environ. Sci.: Nano, 2024, 11,1533-1542
DOI: 10.1039/D3EN00820G, Paper
Xinyu Liu, Chenchen Li, Jian Nan, Ruike Liang, Huabin Wang, Rui Xu, Yong Zhang
A combination of metal–organic frameworks (MOFs) with TiO2 can improve the performance of TiO2 in the photocatalytic degradation of organic pollutants.
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Fractionation and preconcentration of silver nanoparticles at environmentally relevant concentrations through induced eco-corona formation and spICP-MS characterization

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Environ. Sci.: Nano, 2024, 11,1559-1570
DOI: 10.1039/D3EN00933E, Paper
Aline Martins de Andrade, Anerise de Barros, Italo Odone Mazali, Marco Aurélio Zezzi Arruda
The release of nanoparticles (NPs) into environmental matrices has raised concerns regarding the contamination of environmental matrices. An induced eco-corona method was used to preconcentrate silver NPs in environmental waters analysed by spICP-MS.
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Preparation of UV-responsive hydrogels based on nanocellulose and their utilization in fungicide delivery

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Environ. Sci.: Nano, 2024, 11,1442-1451
DOI: 10.1039/D3EN00910F, Paper
Chaoqun You, Xinyue Ji, Hanchen Lin, Ning Ma, Wei Wei, Lingfeng Long, Like Ning, Fei Wang
A stimuli-responsive hydrogel for fungicide delivery based on UV-sensitive molecular (AZO)-conjunct CNCs is successfully prepared.
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Toward environmentally favorable nano-sensing by production of reusable gold nanoparticles from gold nano-waste: life cycle and nanocircular economy implications

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Environ. Sci.: Nano, 2024, 11,1499-1507
DOI: 10.1039/D3EN00505D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Seju Kang, Asifur Rahman, Sean McGinnis, Peter Vikesland
This study aids in the identification of environmentally friendly and sustainable applications of gold nanoparticles.
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Silver nanoparticle doped laser-induced graphene fabrication methodology affects silver nanoparticle size, distribution, biological and electrochemical properties

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Environ. Sci.: Nano, 2024, 11,1582-1596
DOI: 10.1039/D3EN00371J, Paper
Chetan Prakash Sharma, Abhishek Gupta, Meghna Khadka, Hadar Ben-Yoav, Avner Ronen, Christopher J. Arnusch
Three fabrication methods for metal-doped laser-induced graphene (LIG) are compared resulting in stable nanoparticles embedded within LIG. Variable nanoparticle size, distribution, antibacterial and electrochemical properties were observed.
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Biomass@MOF nanohybrid materials for competitive drug adsorption: analysis by conventional macroscopic models and statistical physical models

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Environ. Sci.: Nano, 2024, 11,1543-1558
DOI: 10.1039/D3EN00843F, Paper
Bryan Fernando Rivadeneira-Mendoza, Luis Santiago Quiroz-Fernández, Fausthon Fred da Silva, Rafael Luque, Alina M. Balu, Joan Manuel Rodríguez-Díaz
This study discloses the design of nanohybrid Biomass@MOF resulting from the functionalization of a hydrochar (HC) through hydrothermal treatment (HT) of corn cob residues and MIL-53(Al).
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Biogenic synthesis of dual-emission chlorophyll-rich carbon quantum dots for detection of toxic heavy metal ions – Hg(II) and As(III) in water and mouse fibroblast cell line NIH-3T3

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Environ. Sci.: Nano, 2024, 11,1636-1653
DOI: 10.1039/D3EN00789H, Paper
Ravi Pratap, Nurul Hassan, Monika Yadav, Saurabh Kumar Srivastava, Shilpi Chaudhary, Anita Kamra Verma, Jayeeta Lahiri, Avanish S. Parmar
Due to the excessive residues and serious adverse effects, it is urgent to develop an efficient method to detect Hg2+ and As3+ in drinking water to protect human health.
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Understanding the active sites and associated reaction pathways of metal-free carbocatalysts in persulfate activation and pollutant degradation

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Environ. Sci.: Nano, 2024, 11,1368-1393
DOI: 10.1039/D3EN00988B, Critical Review
Huawen Hu, Dongchu Chen, Yaoheng Liang, Wenyi Wang, Yinlei Lin, Xuejun Xu, Xiaowen Wang, Kun Wang, Yuyuan Zhang, Jian Zhen Ou
Environmental remediation based on peroxomonosulfate- and peroxydisulfate-activation-enabled radical/non-radical oxidation has gained growing interest due to the strong oxidation power, long life of reactive oxygen species, and wide pH adaptability.
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Molecular mechanisms of dimethylarsinic acid adsorption onto aluminum substituted ferrihydrite surfaces

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Environ. Sci.: Nano, 2024, 11,1713-1723
DOI: 10.1039/D3EN00664F, Paper
Yiting Ge, Jiaqi Wang, Fayang Guo, Meng Yuan, Wentao Wang, Jiangshan Li, Jing Zhang, Xionghan Feng, Wenfeng Tan, Yupeng Wu, Hui Yin
Aluminum substitution in ferrihydrite promotes the formation of monodentate mononuclear and outer-sphere complexes of dimethylarsinic acid on the mineral surfaces at the expense of bidentate binuclear complexes at pH 6.
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Doped carbon dots affect heavy metal speciation in mining soil: changes of dissimilated iron reduction processes and microbial communities

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Environ. Sci.: Nano, 2024, 11,1724-1739
DOI: 10.1039/D3EN00823A, Paper
Xinyi Huang, Shaobo Liu, Xuanming Liu, Xiaofei Tan, Shuai Guo, Mingyang Dai, Qiang Chen, Gaobin Chen, Chenzhi Feng
Carbon dots (CDs) inevitably accumulate in soils due to their widespread use, affecting soil enzyme activities and microbial community structure.
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Composite materials based on halloysite clay nanotubes and cellulose from Posidonia oceanica sea balls: from films to geopolymers

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Environ. Sci.: Nano, 2024, 11,1508-1520
DOI: 10.1039/D3EN00879G, Paper
Martina Maria Calvino, Giuseppe Cavallaro, Stefana Milioto, Giuseppe Lazzara
The combination of natural halloysite nanotubes and cellulose recovered from egagropili is effective to fabricate composite films and geopolymers promising for packaging and building applications, respectively.
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Nanoscale control over water-film thickness using temperature modulation: tuning mineral carbonation reactivity

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Environ. Sci.: Nano, 2024, 11,1412-1416
DOI: 10.1039/D3EN00884C, Communication
Open Access
Christopher J. Thompson, Sebastian T. Mergelsberg, Bavan P. Rajan, Paul F. Martin, Sebastien N. Kerisit, John S. Loring
Temperature modulation was demonstrated as a novel way to control water partitioning during the reaction of silicate minerals with water-saturated supercritical carbon dioxide.
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Recycling and repurposing of waste carbon nanofiber polymers: a critical review

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Environ. Sci.: Nano, 2024, 11,1394-1411
DOI: 10.1039/D3EN00784G, Critical Review
Zhihao Liu, Zhijie Chen, Zimin Wang, Daijun Zhang, Bing-Jie Ni
Carbon nanofibers are a class of lightweight, high-performance composite materials.
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Mining, refining, and QSAR analysing the nanoinformatics in EPA NaKnowBase

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00619K, Paper
Paul Harten, Henry Helgen, Wilson Melendez, Bradley Beach, William K. Boyes, Iason Sotiropoulos, Pantelis Karatzas, Haralambos Sarimveis, Holly M. Mortensen
The EPA nanoQSAR model predicts the impacts of in vitro cell viability following exposure to certain nanomaterials.
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Functional silver-based nanomaterials affecting zebrafish development: the adverse outcomes in relation to the nanoparticle physical and chemical structure

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Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00813D, Paper
Open Access
Patrizia Bonfanti, Anita Colombo, Rossella Daniela Bengalli, Maurizio Gualtieri, Ilaria Zanoni, Magda Blosi, Anna Costa, Paride Mantecca
The growing demand for effective antimicrobials determined a significant increase of new nanoformulated materials to fight against bacteria and viruses, to be used in many industrial sectors including textiles, cosmetics,...
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Sulfur-doped porous carbon sheets embedded with rich iron sites for 1O2 dominated peroxymonosulfate activation

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00971H, Paper
Yadan Song, Yalong Liu, Yangju Li, Haipeng Hu, Kexin Huang, Zhe Zhang, Zhongxian Li, Wanning Cao, Kai Jiang, Dapeng Wu
Porous carbon films co-doped with iron, nitrogen, and sulfur were synthesized via a one-step pyrolysis process, which have multiple active sites and can produce bulk 1O2 through PMS activation, which is effective in phenol degradation.
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Adsorption of nucleotides and nucleic acids on goethite nanoparticle: mode, sites and relationship with phosphate and non-phosphate structure

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Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00891F, Paper
Huajun Feng, Shanshan Ma, Zaiming Chen, Yungui Li, Meizhen Wang, Yangcheng Ding
The impact of iron (hydr)oxide adsorption on nucleotides and nucleic acids (NNA) in the environment varies. However, there is a lack of quantitative reports on how iron (hydr)oxide adsorption changes...
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Crystallinity regulation induced organics degradation on Ultra-thin 2D Co3O4/SiO2 Nanosheets: the critical trigger of oxygen vacancy

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Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D4EN00134F, Paper
Wenhui Bai, Hongze Lu, Yang Liu, Xue Yuan, Yuejie Ai, Lidong Wang, Zhe Chen
As an antibiotic drug, sulfamethoxazole (SMX) is a nitrogen-containing and sulfur-containing heterocyclic compound, which is an endocrine disruptor and difficult to be biodegraded. Not only can it exist stably in...
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Anatase TiO2 nanomaterials are much more effective in enhancing hydrolysis of organophosphorus compounds than their rutile counterparts

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00138A, Paper
Tong Li, Yiting Ju, Tingting Du, Chuanjia Jiang, Tong Zhang, Wei Chen
The crystalline phase significantly affects the efficiency of TiO2 nanomaterials in catalyzing hydrolysis reactions of organophosphates, primarily by modulating the surface Lewis acidity of TiO2.
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Correction: Nano-pelargonidin modulates p53/PARP/HSP 90/XRCC1 signaling axis to combat cypermethrin-induced genotoxicity and metabolic dysfunction in fish: a molecular docking predicted in vivo approach

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN90017K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Priyanka Sow, Sudatta Dey, Rishita Dey, Asmita Samadder, Sisir Nandi, Debojyoti Tarafdar, Anisur Rahman Khuda-Bukhsh
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Constructing a novel super-crosslinked triazine COF through molecular expansion for enhanced photocatalytic performance under visible light

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00176A, Paper
Yuxuan Shao, Dan You, Yuqi Wan, Zhiquan Pan, Qingrong Cheng
A novel hypercrosslinked triazine COF photocatalyst (HCTF-2) with excellent photocatalytic performance was constructed by molecular expansion. HCTF-2 has a larger specific surface area and exhibits excellent molecular oxygen activation ability.
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A zwitterionic salt–cocrystal: in vitro insights from niraparib tosylate, an anti-cancer drug

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00114A, Paper
Ramesh Reddy Mudda, Ramesh Devarapalli, Arijit Das, Pulla Reddy Lakkireddy, C. Malla Reddy, Ramanaiah Chennuru
Schematic representation showing nomenclature of different cocrystals.
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Incisive analysis of hydrogen-bonded supramolecular architectures in designer polycyclitols: observation of some interesting self-assembly patterns

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CrystEngComm, 2024, 26,1952-1961
DOI: 10.1039/D4CE00010B, Paper
Showkat Rashid, Ahmad Husain, Bilal A. Bhat, Goverdhan Mehta
This article examines C–H⋯O and O–H⋯O hydrogen-bonded patterns in polyoxygenated decalins, showcasing varied supramolecular architectures influenced by oxyfunctionalisation and surrogate carbonate groups.
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A facile synthesis of a Ce-based MOF at room temperature for effective adsorption of methylene blue

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CrystEngComm, 2024, 26,2009-2017
DOI: 10.1039/D4CE00096J, Paper
Yang Zhou, Dan Wang, Qiuxiang Feng, Qi Wu, Feng Cao, Li Jiang, Qianli Zhang, Jie Liu
Ce-UiO-66-NH2 was synthesized in water and ethanol at room temperature for effective removal of MB in aqueous solution.
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Macro- and micro-structural manifestation and engineering of large-size polycrystalline ZnSe

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CrystEngComm, 2024, 26,1986-1993
DOI: 10.1039/D3CE01243C, Paper
Xiaobo Zhao, Cong Zhang, Zhengping Wang, Dazhi Lu, Haohai Yu, Huaijin Zhang
Polycrystalline ZnSe materials with sizes of 100 mm were grown by the CVD method, and their constitution structures and defects were investigated to analyze the influence of the preparation conditions on the optical transmission properties of the materials.
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Study on growth technology and optical properties of large size and high quality methylamine lead bromide single crystals

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CrystEngComm, 2024, 26,2003-2008
DOI: 10.1039/D4CE00028E, Paper
Yuanlong Sun, Yundong Ma, Xiangting Li, Ziyu Hu, Guozong Zheng
As a new generation of photoelectric materials, organic–inorganic halide perovskites have been widely used in photodetectors, solar cells and other fields, but most of the current mainstream applications are thin film materials.
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Rock-salt Ti1−xO → rutile TiO2−x transformation twinning via pulsed laser deposition – implications for the dense (hkl)-specific phase change and optoelectronic properties

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CrystEngComm, 2024, 26,1926-1939
DOI: 10.1039/D3CE01091K, Paper
Chang-Ning Huang, Jian-Yu Chen, Yu-Xuan Lin, Pouyan Shen
The R + r intimate intergrowth was found to form a butterfly twin following the optimum crystallographic orientation relationship [101]R//[11̄]r by the close-packed (̄11)R and (011)r planes as the twin boundary and phase interface, respectively.
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Effects of nucleating agents on the II–I transition of iPB-1

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CrystEngComm, 2024, 26,1940-1951
DOI: 10.1039/D3CE01303K, Paper
Zhiqi Li, Jingqing Li, Shichun Jiang
For iPB-1, II–I transition is of industrial importance; whereas, the traditional solid–solid II–I transition mechanism encountered challenges. It is form I formation in amorphous phase that triggers II-I transition with crystal reorganizations.
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“Feather-duster” like ZnIn2S4/TiO2 heterostructured nanocomposites with enhanced visible-light photocatalytic performance

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CrystEngComm, 2024, 26,2025-2032
DOI: 10.1039/D3CE01239E, Paper
Wenjie Liu, Lei Li, Jingru Li, Fang Wang, Chun-Shuai Cao, Jianzhou Gui, Alex T. Kuvarega, Bhekie B. Mamba, Dan Liu
The ZnIn2S4/TiO2 heterostructures show an increased surface area and strengthened interface contacts, facilitating efficient photogenerated carrier separation and leading to high photocatalytic performance under visible light irradiation.
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Synthesis, structure, and properties of helical bis-Zn(II) complexes of hexapyrrolic ligands

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00019F, Paper
Pinky Chauhan, Poornenth Pushpanandan, Mangalampalli Ravikanth
Bis(3-pyrrolyl BODIPY)s were used to prepare rare examples of hexapyrrolic ligands by demasking BF2 units. The hexapyrrolic ligands, without isolating, were used to prepare novel examples of double-stranded bis-Zn(II) helicate complexes.
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Pure organic TPB single crystal for direct X-ray detection

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00200H, Paper
Kai Jiang, Lingyan Xu, Rongjin Shang, Lu Liang, Yingming Wang, Zhentao Qin, Wanqi Jie
High-quality TPB single crystals were obtained without obvious step-like growth morphology. The TPB devices could present α-particle and γ-ray spectral responses with high energy resolution, showing potential for direct radiation detection.
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Modulating the active phase in perovskite LaCoO3 with B-site doping of Cu for efficient methanol reforming to produce hydrogen

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01268A, Paper
Weiling Zhang, Peiwei Han, Juan Li, Zizhen Niu, Guowei Wang, Nan Wang, Xiangnan Li, Lyumeng Ye, Xinjun Li
The structure transformation of Cu+–Ov–Co2+ and Cu2+–O–Co3+ on the efficient MSR reaction.
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Thermal fluctuation-induced selective CO2 uptake of seemingly nonporous N,C-protected dipeptide crystals as elucidated by in situ X-ray crystallographic analysis

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01018J, Paper
Kazuaki Yamanaka, Ryusei Oketani, Yuya Mori, Takashi Sato, Seiji Tsuzuki, Hiroki Takahashi, Hirohito Tsue
A novel N,C-protected dipeptide deposited nonporous but yet CO2-sorbing molecular crystals, of which the CO2 sorption state was disclosed.
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Synthesis and luminescent properties of three excellent yellow emissive Cu(I) complexes based on the diphosphine ligand and the diimine ligand

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00206G, Paper
Wen-Long Mou, Cheng-Jie Gao, Zi-Xi Li, Si-Jie Fan, Chuan-Bin Hou, Jing-Tong Zhao, Shuai Zhang, Zhong-Feng Li, Hong-Liang Han, Chun-Bo Duan, Guo Wang, Qiong-Hua Jin
High quantum yield (72–88%) yellow-emitting Cu(I) complexes obtained by tuning the nitrogen ligands and anions.
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Assessing aspects of solution-based chemical synthesis to convert waste Si solar cells into nanostructured aluminosilicate crystals

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00038B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Edita Garskaite, Math Bollen, Enock Mulenga, Mathis Warlo, Glenn Bark, Espen Olsen, Dalia Brazinskiene, Denis Sokol, Dietrich Buck, Dick Sandberg
An affordable, scalable, and easily adoptable solution-based processing route provides a potential way of converting waste Si solar cells into aluminosilicate minerals to contribute to sustainability in the solar energy value chain.
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New 8-hydroxy quinoline-polycyclic aromatic hydrocarbon (PAH) conjugates and their sulfonated derivatives: effects of sulfonation and PAH size on their structural, supramolecular and cytotoxic properties

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00105B, Paper
Suman Sehlangia, Surbhi Dogra, Prosenjit Mondal, Chullikkattil P. Pradeep
The ring size of polycyclic aromatic hydrocarbons (PAHs) and sulfonation affect the supramolecular interactions and cytotoxic properties of a new series of 8-hydroxy quinoline-PAH conjugates.
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Advanced MnOx/MnWO4 hetero-nanoflakes with abundant oxygen vacancies for high-performance flexible asymmetric supercapacitors with high energy density

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CrystEngComm, 2024, 26,2087-2095
DOI: 10.1039/D4CE00052H, Paper
Yanli Yin, Jingli Wang, Sihao Chen, Nengneng Han, Zhiliang Chen, Yuezhou Jing, Yahui Zhang, Juan Xu, Zhongyang Li
High-performance flexible supercapacitors assembled with MnOx/MnWO4@C-3 hetero-nanoflake anodes, exhibiting a maximum areal energy density of 48.49 mW h cm−2.
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Enhanced photocatalytic activity of single-atom Au1/TiO2 catalysts prepared using cold plasma

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CrystEngComm, 2024, 26,2103-2111
DOI: 10.1039/D4CE00171K, Paper
Zikun Yang, Jingxuan Zheng, Mengge Shi, Zhao Wang
Single-atom Au1/TiO2-DBD catalysts were synthesised using DBD plasma and glow plasma, and the synergistic effect of single-atom Au and oxygen vacancies improved the degradation performance.
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Gefitinib salts/cocrystals with phenolic acids as a promising solid-state approach to improve solubility

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CrystEngComm, 2024, 26,2112-2122
DOI: 10.1039/D4CE00039K, Paper
Yao Zou, Xin Meng, Baoxi Zhang, Hongmei Yu, Guorong He, Ningbo Gong, Yang Lu, Guanhua Du
In this study, we designed and synthesized a series of gefitinib (GEF) salts and cocrystals with phenolic acids, comprising two salts, one cocrystal, and two salt cocrystals. All these forms exhibited significant improvements in solubility compared to pure GEF.
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Fabrication of BiVO4 submicron rods photoanodes through phase transition assisted by Mo doping

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CrystEngComm, 2024, 26,2078-2086
DOI: 10.1039/D4CE00074A, Paper
Shuang Zhao, Haipeng Zhang, Zhaoqi Wang, Deifei Xiao, Xianbin Xu, Peng Wang, Zhaoke Zheng, Yuanyuan Liu, Ying Dai, Hefeng Cheng, Zeyan Wang, Baibiao Huang
Herein, Mo doping has been found to effectively lower the phase transition temperature from tetragonal zircon BiVO4 to monoclinic scheelite BiVO4. Our research introduces a novel method for the production of submicron rods BiVO4 photoanodes.
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Using the nature of the achiral solvent to orient chiral resolution

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CrystEngComm, 2024, 26,2056-2059
DOI: 10.1039/D4CE00124A, Communication
Joséphine de Meester, Oleksii Shemchuk, Laurent Collard, Johan Wouters, Simon Baillieux, Koen Robeyns, Tom Leyssens
Both (R)- and (S)-Binol can be resolved from a racemic mixture using the same (R,R)-diamine resolving agent, merely adapting the nature of the solvent. This peculiarity is explained by the existence of both a diastereomeric as well as enantiospecific solvate cocrystal system.
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The structural evolution of CL-20-based energetic host–guest solvates at decomposition temperature according to the perceptions of THz spectroscopy

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01310C, Paper
Lu Shi, XiaoHui Duan, Hongzhen Li
This work employed variable-temperature THz spectroscopy to analyze the structural evolution of host–guest energetic CL-20/H2O2 and CL-20/H2O solvates, as well as the mechanism of intermolecular interactions using DFT calculation and MD simulation.
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Chemical solution deposition of a (GaAl)2O3 single layer with high thickness and silver-enhanced crystal quality

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00086B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiao Tang, Wesam A. AlQanbar, Mohamed Ben Hassine, Yi Lu, Haicheng Cao, Chuanju Wang, Zixian Jiang, Tingang Liu, Na Xiao, Mingtao Nong, Vishal Khandelwal, Xiaohang Li
A new study presents a revolutionary CSD method to create thick (180 nm) single-layer (GaAl)2O3 films with enhanced crystal quality through silver doping.
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