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Synthesis of dual emitting iodocuprates: can solvents switch the reaction outcome?

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00346H, Research Article
Alexander V. Artem'ev, Alexey S. Berezin, Ilya V. Taidakov, Irina Yu. Bagryanskaya
An unprecedented structure-directing effect of solvents in halocuprate self-assembly reactions was discovered. The compounds presented show remarkable dual luminescence, strongly changing the emission color upon varying temperature.
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Enabling high performance n-type metal oxide semiconductors at low temperatures for thin film transistors

Inorg. Chem. Front., 2020, 7,1822-1844
DOI: 10.1039/D0QI00038H, Review Article
Nidhi Tiwari, Amoolya Nirmal, Mohit Rameshchandra Kulkarni, Rohit Abraham John, Nripan Mathews
The review highlights low temperature activation processes for high performance n-type metal oxide semiconductors for TFTs.
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Constructing heterostructured FeS2/CuS nanospheres as high rate performance lithium ion battery anodes

Inorg. Chem. Front., 2020, 7,1900-1908
DOI: 10.1039/C9QI01674K, Research Article
Xiaoxia Xu, Lingjie Li, Huiqing Chen, XiaoSong Guo, Zhonghua Zhang, Jing Liu, Changming Mao, Guicun Li
Heterostructured porous FeS2/CuS nanospheres exhibit enhanced reaction kinetics, excellent rate capability and desirable long-term cycling stability performance.
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A concerted evolution of supramolecular interactions in a {cation; metal complex; π-acid; solvent} anion-π system

Inorg. Chem. Front., 2020, 7,1851-1863
DOI: 10.1039/D0QI00101E, Research Article
Emilia Kuzniak, James Hooper, Monika Srebro-Hooper, Jedrzej Kobylarczyk, Magdalena Dziurka, Bogdan Musielak, Dawid Pinkowicz, Jesus Raya, Sylvie Ferlay, Robert Podgajny
Comprehensive studies on a concerted evolution of supramolecular interactions with multicomponent synthon reproduction provide a new tool to describe the trapping of flat [M(L)4]2− complexes within π-acidic cavities.
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An In situ Raman study of intermediate adsorption engineering by high-index facet control during the hydrogen evolution reaction

Inorg. Chem. Front., 2020, 7,1892-1899
DOI: 10.1039/D0QI00124D, Research Article
Jia-sen Zhu, Hao Yang, Weihong Zhang, Yanchao Mao, Shu-shen Lyu, Jian Chen
An in situ Raman study of the mechanism of HER catalytic performance enhanced by high-index facets on Ti@TiO2 nanosheets.
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Ligand substitution induced single-crystal-to-single-crystal transformations in two Ni(II) coordination compounds displaying consequential changes in proton conductivity

Inorg. Chem. Front., 2020, 7,1880-1891
DOI: 10.1039/D0QI00088D, Research Article
Rong-Yun Li, Hou-Ting Liu, Chuan-Cong Zhou, Zhi-Tong Chu, Jing Lu, Su-Na Wang, Juan Jin, Wen-Fu Yan
Two Ni(II) coordination compounds can reversibly SC–SC transform into each other induced by ligand substitution, causing changes in their proton conductivities.
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Coral-like ZnFe2O4–ZnO mesoporous heterojunction architectures: synthesis and enhanced sensing properties for triethylamine

Inorg. Chem. Front., 2020, 7,1918-1926
DOI: 10.1039/D0QI00134A, Research Article
Tianye Yang, Xiaodong Yang, Mingming Zhu, Hongwei Zhao, Mingzhe Zhang
A unique coral-like ZnFe2O4–ZnO heterojunction architecture based sensor has been synthesized and shows excellent sensing performance for TEA with a particularly fast response time of 0.9 s.
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Single-chain magnet behavior in a 2p–3d–4f spin array with a nitronyl nitroxide biradical

Inorg. Chem. Front., 2020, 7,1949-1956
DOI: 10.1039/D0QI00098A, Research Article
Juan Sun, Jing Xie, Licun Li, Jean-Pascal Sutter
New nitronyl nitroxide biradical-bridged 3d–4f chains have been constructed in which improved SCM behavior is observed.
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Electrochemical behavior of NiCl2/Ni in acidic AlCl3-based ionic liquid electrolyte

Inorg. Chem. Front., 2020, 7,1909-1917
DOI: 10.1039/D0QI00166J, Research Article
Jiguo Tu, Mingyin Kou, Mingyong Wang, Shuqiang Jiao
The degradation mechanism of the Al-NiCl2 cell is confirmed to be mainly due to mass loss and electrode cracking caused by the dissolution of some Ni metal as the reduction product of NiCl2 during discharging in acidic AlCl3-based electrolyte.
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Restricted active space simulations of the metal L-edge X-ray absorption spectra and resonant inelastic X-ray scattering: revisiting [CoII/III(bpy)3]2+/3+ complexes

Inorg. Chem. Front., 2020, 7,1927-1938
DOI: 10.1039/D0QI00148A, Research Article
Meiyuan Guo, Xiaorui Liu, Rongxing He
The metal L-edge spectra of cobalt compounds have been interpreted through restricted active space calculations.
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Luminescent metal–organic frameworks (LMOFs) as potential probes for the recognition of cationic water pollutants

Inorg. Chem. Front., 2020, 7,1801-1821
DOI: 10.1039/D0QI00167H, Review Article
Partha Samanta, Sumanta Let, Writakshi Mandal, Subhajit Dutta, Sujit K. Ghosh
This review aims to provide an overview regarding the development of luminescent metal–organic frameworks (LMOFs) based sensory materials for the detection of cationic inorganic and organic water pollutants.
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Ir3Pb alloy nanodendrites with high performance for ethanol electrooxidation and their enhanced durability by alloying trace Au

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00233J, Research Article
Genlei Zhang, Zhenxi Zhang
Porous Ir3Pb nanodendrites exhibit excellent activity and superior CO2 selectivity for the EOR under acidic conditions, and their durability can be enhanced dramatically by alloying trace Au.
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Mitochondrial DNA targeting and impairment by a dinuclear Ir–Pt complex that overcomes cisplatin resistance

Inorg. Chem. Front., 2020, 7,1864-1871
DOI: 10.1039/D0QI00224K, Research Article
Cheng Zhang, Ruilin Guan, Xinxing Liao, Cheng Ouyang, Jiangping Liu, Liangnian Ji, Hui Chao
A dinuclear complex [(ppy)Ir(tpy)PtCl]2+ (Ir–Pt) can exhibit strong antitumor activity towards cisplatin-resistant cancer cells and induce cell necrosis via mtDNA damage and mitochondrial dysfunction.
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π-Type halogen bonding enhanced the long-lasting room temperature phosphorescence of Zn(II) coordination polymers for photoelectron response applications

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00191K, Research Article
Xiao-Gang Yang, Xiao-Min Lu, Zhi-Min Zhai, Jian-Hua Qin, Xin-Hong Chang, Min-Le Han, Fei-Fei Li, Lu-Fang Ma
Long-lasting phosphorescence emission was achieved via π-type halogen bonding in Zn(II) based coordination polymers. The delocalized H-aggregates afforded large electron channels for efficient charge transport and high photoelectron response.
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Excitation wavelength dependent emission of silver(I) complexes with a pyrimidine ligand

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00254B, Research Article
Nikita A. Shekhovtsov, Katerina A. Vinogradova, Alexei S. Berezin, Taisiya S. Sukhikh, Viktor P. Krivopalov, Elena B. Nikolaenkova, Mark B. Bushuev
Interplay of three emission mechanisms for silver(I) complexes leads to luminescence thermochromism and color tunable emission.
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Evolution of D6R units in the interzeolite transformation from FAU, MFI or *BEA into AEI: transfer or reassembly?

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00359J, Research Article
Juan Zhang, Yueying Chu, Feng Deng, Zhaochi Feng, Xiangju Meng, Feng-Shou Xiao
The formation and evolution of building units for zeolites play an important role during crystallization.
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An advanced composite with ultrafast photocatalytic performance for the degradation of antibiotics by natural sunlight without oxidizing the source over TMU-5@Ni–Ti LDH: mechanistic insight and toxicity assessment

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00050G, Research Article
Reza Abazari, Ali Morsali, Deepak P. Dubal
Pharmaceuticals are considered as emerging organic contaminants that have become a serious environmental problem, which endanger human health and environmental bio-diversity.
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Interconnected porous nanoflakes of CoMo2S4 as an efficient bifunctional electrocatalyst for overall water electrolysis

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00318B, Research Article
Shasha Tang, Xiaogang Li, Marc Courté, Jingjing Peng, Denis Fichou
Interconnected porous nanoflakes of the bimetallic CoMo2S4 are synthesized and investigated as bifunctional catalysts for highly efficient overall water electrolysis.
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Mechanism of oxygen vacancy assisted water-splitting of LaMnO3: Inorganic perovskite prediction for fast solar thermochemical H2 production

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00338G, Research Article
Mingkai Fu, Huajun Xu, Xin Li
Highly reducible and thermally-stable lanthanum-manganese perovskites represent a promising class of materials for solar thermochemical hydrogen production. However, such materials suffer from low hydrogen production rate, resulting in incomplete re-oxidation...
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Exploiting cation aggregation in new magnesium amidohaloaluminate electrolytes for magnesium batteries

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01606F, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Etienne V. Brouillet, Marco Amores, Serena A. Corr, Stuart D. Robertson
The active species in magnesium electrolytes is regularly assigned as being the thermodynamically stable dinuclear [Mg2Cl3]+ cation. By deliberately targeting other implicated aggregates, their effect on Mg-ion battery performance is easily ascertained.
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Improving Catalysis for Electrochemical Water Splitting Using Phosphosulphide Surface

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00295J, Research Article
Lisi Yin, Xinran Ding, Wenxian Wei, YiHui Wang, Zizheng Zhu, Kai Xu, Ziming Zhao, Hong Zhao, Tingting Yu, Tao Yang
As an energy carrier, hydrogen shows great promise superior to the traditional fossil fuel to meet the ever-increasing global energy demands. Electrochemical water splitting has been considered to be an...
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Cyclometalated Ir(III) Complexes Towards Blue-Emissive Dopant for Organic Light-Emitting Diodes: Fundamentals of Photophysics and Designing Strategies

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00001A, Review Article
Sunhee Lee, Won-Sik Han
The main difficulties hindering development of a deep-blue phosphorescent cyclometalated Ir(III) complex are insufficient colour purity, i.e., failure to achieve ideal Commission Internationale de L’Eclairage (CIE) coordinates of (0.14, 0.09),...
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Aerobic Oxidation Catalyzed by Polyoxometalates Associated to an Artificial Reductase at Room Temperature and in Water

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00442A, Research Article
Ahmad Naim, Yoan Chevalier, Younes Bouzidi, Priyanka Gairola, Pierre Mialane, Anne Dolbecq-Bastin, Frédéric Avenier, Jean-Pierre Mahy
Four polyoxometalates (POMs) were combined with an artificial reductase based on polyethyleneimine (PEI) and flavin mononucleotide (FMN) which is capable of delivering single electrons upon addition of nicotinamide adenine dinucleotide...
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Indian horse = Cheval Indien [videorecording] / Elevation Pictures presents ; Screen Siren Pictures, Devonshire Productions ; directed by Stephen S. Campanelli ; screenplay by Dennis Foon ; produced by Christine Haebler, Trish Dolman, Paula Devonshire ; e

1 videodisc (101 min.) : sound, color ; 4 3/4 in




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Roxanne [videorecording] / Columbia Pictures presents a Daniel Melnick Indieprod & LA Films production ; screenplay by Steve Martin ; produced by Michael Rachmil & Daniel Melnick ; directed by Fred Schepisi

1 videodisc (approximately 107 min.) : sound, color ; 4 3/4 in




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Crimson tide [videorecording] / Hollywood Pictures presents a Don Simpson/Jerry Bruckheimer production ; produced by Don Simpson, Jerry Bruckheimer ; story by Michael Schiffer and Richard P. Henrick ; screenplay by Michael Schiffer ; directed by Tony Scot

1 videodisc (116 min.) sound, color; 4 3/4 in




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Professor Marston and the Wonder Women [videorecording]/ Annapurna Pictures presents in association with Stage 6 Films ; a Topple Pictures & Boxspring Entertainment production ; produced by Terry Leonard, Amy Redford ; written and directed by Angela R

1 videodisc (approximately 108 minutes) : sound, color ; 4 3/4 in




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Wonder Woman [videorecording] / directed by Patty Jenkins ; screenplay by Allan Heinberg ; story by Zack Snyder & Allan Heinberg and Jason Fuchs ; produced by Charles Roven, Deborah Snyder, Zack Snyder, Richard Suckle ; a Warner Bros. Pictures present

2 videodiscs (141 min.) : sound, color ; 4 3/4 in




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It's no more just about Real or Barca breaking records: La Liga India head

Jose Antonio Cachaza, MD, LaLiga India, dwells on his team's digital strategy to reach fans in remote villages that even courier companies don't reach




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Will consider raising duties on fuel and liquor: Manpreet Badal, Punjab FM

Punjab would like to help the Centre in any way possible to deal with the coronavirus disease (Covid-19) pandemic, said state Finance Minister Manpreet Singh Badal




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Early lockdowns in India may flatten Covid-19 curve: Nimhans virologist

In a Q&A, V Ravi says at some later stage two-thirds of the population will have gotten Covid-19 but that stage many would have recovered without even knowing they had been infected




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Coronavirus crisis in India has not exploded yet: Bhramar Mukherjee

The biostatistician says the peak of virus may hit India by mid-May and a 42- to 56-day lockdown can help in flattening the curve




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India could use 3-5% of GDP stabilising economy: World Bank economists

The lockdown of economies around the world causes a much sharper decline in economic activity than in normal recessions, says World Bank chief economist south Asia region, Hans Timmer




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‘The Two Popes’ Pits Tradition Against Progress

What the new Netflix drama can teach us about the interdependency of orthodoxy and reform.




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The real story is not whether the four young women will marry, but whether they will become better people.




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The Good Place Finds Meaning in the End

What Christians might take away from a godless but moral imagining of the afterlife (and after-afterlife).




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The Eubank family offers food, shelter, and medicine on the frontlines in Iraq and Burma.




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Faith-driven streaming services can’t compete with the ever-growing number of entertainment giants flooding into homes. Maybe they don’t have to.




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