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A Framework for Educational Equity and Culturally Responsive Pedagogy

This webinar defined educational inequity and discussed its implications. It included a brief introduction to culturally responsive pedagogy and what broader systemic changes may be necessary to implement equity and culturally responsive pedagogy.




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Seeing Is Believing: Visualizing Data for Evidence-Based Policymaking

While many industries have increasingly turned to data science to make informed business decisions, social service organizations and government agencies have been slower to fully embrace the potential of current and emerging data science methods. The challenges are real.




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Join Us and Partners for a Grantmakers for Education Webinar—Making the Case: Establishing Evidence to Support Practitioners, Strategy, and Outcomes

Interested in learning how to build more evidence into philanthropic practice? Join Mathematica, The Wallace Foundation, and the Afterschool Alliance for a Grantmakers for Education webinar.




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Sign Up for a Free Webinar on Improving Attendance in Pre-Kindergarten and Kindergarten

Chronic absenteeism is particularly high in the early grades, compared with elementary and middle school. For a young child to succeed and develop a strong foundation for learning, he or she must attend school regularly.




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SSI Youth Solutions Project: Informational Webinar for Applicants on the Call for Policy Proposals

Mathematica is seeking innovative ideas on how to help youth who receive Supplemental Security Income (SSI) improve their employment outcomes as they transition to adulthood.




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Evidence for Educators by Educators: New Approaches to Building Evidence for Continuous Improvement

Join us for a webinar for a discussion about the role of evidence in a continuous improvement process and how a free, online platform—the Evidence to Insights Coach—can help educators generate the evidence they need when they need it.




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Health Affairs Briefing on the Affordable Care Act Turns 10

The March 2020 issue of Health Affairs, “The Affordable Care Act Turns 10,” offers must-read analyses of the ACA.




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Q-CCIIT: Measuring the Quality of Caregiver–Child Interactions: Free Webinar for Early Childhood Professionals

Mathematica will launch a groundbreaking new quality measurement observation tool, now available to the early childhood community (including program administrators, professional development providers, researchers, and others) during a webinar.




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Free Webinar: How States, Districts, and REL Mid-Atlantic Partner to Create New Diagnostic Measures Using Existing Data

This webinar highlights three research-to-practice partnerships between state and local policymakers and the Regional Educational Laboratory Mid-Atlantic to address this challenge, connecting educators and policymakers with researchers who provide analytic support and help education agencies build capacity to conduct their own analyses.




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Learning Remotely in the Age of COVID-19: Lessons from Evidence and Concerns for Equity

The spread of COVID-19 has caused schools and districts across the country to shutter their doors. States, districts, and schools must suddenly and unexpectedly grapple with the new reality of providing a quality education to every student remotely.




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Refining Your Remote Learning Strategies Using a Data-Driven Approach: The Evidence to Insights Coach

With school buildings closed by COVID-19, schools and districts across the country are rapidly (and sometimes frantically) transitioning to remote learning.




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Macrocyclization of 3-Triflyloxybenzynes with Tetrahydrofuran via Anionic Thia-Fries Rearrangement

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00135J, Communication
Chaorong Qi, Ruixiang Cheng, Wenfang Xiong, Lu Wang, Yanwei Ren, Huanfeng Jiang
A novel and uncommon macrocyclization reaction between 3-triflyloxybenzynes and tetrahydrofuran has been developed for the first time, providing a direct method for the synthesis of a range of functionalized 19-membered...
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Correction: Preparation of carbon dots by non-focusing pulsed laser irradiation in toluene

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC90181D, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huiwu Yu, Xiangyou Li, Xiaoyan Zeng, Yongfeng Lu
To cite this article before page numbers are assigned, use the DOI form of citation above.
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A fentanyl vaccine constructed upon opsonizing antibodies specific for the Galα1-3Gal epitope

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02107E, Communication
Jiaxing Wang, Beverly A Ellis, Bin Zhou, Lisa M. Eubanks, Steven Blake, Kim D Janda
A double conjugation strategy was implemented to produce an anti-fentanyl vaccine, which was predicated upon preformed-antibody-assisted antigen presentation. The new vaccine was found to reduce the psychoactive effects of fentanyl...
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Simultaneous co-assembly of fenofibrate and ketoprofen peptide for the dual-targeted treatment of nonalcoholic fatty liver disease (NAFLD)

Chem. Commun., 2020, 56,4922-4925
DOI: 10.1039/D0CC00513D, Communication
Zhongyan Wang, Chuanrui Ma, Yuna Shang, Lijun Yang, Jing Zhang, Cuihong Yang, Chunhua Ren, Jinjian Liu, Guanwei Fan, Jianfeng Liu
An ingenious co-assembled nanosystem based on fenofibrate and ketoprofen peptide for the dual-targeted treatment of NAFLD by reducing hepatic lipid accumulation and inflammatory responses.
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Photochemical α-carboxyalkylation of tryptophols and tryptamines via C–H functionalization

Chem. Commun., 2020, 56,4930-4933
DOI: 10.1039/D0CC00847H, Communication
Zhiqiang Pan, Yuchang Liu, Fengchi Hu, Qinglong Liu, Wenbin Shang, Chengfeng Xia
A process for the α-carboxyalkylation of tryptophols and tryptamines by the functionalization of C–H bonds under visible light irradiation has been developed.
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On-surface synthesis of planar acenes via regioselective aryl–aryl coupling

Chem. Commun., 2020, 56,4890-4893
DOI: 10.1039/D0CC01043J, Communication
Lin Feng, Tao Wang, Hongxing Jia, Jianmin Huang, Dong Han, Wenzhao Zhang, Honghe Ding, Qian Xu, Pingwu Du, Junfa Zhu
The reaction of 2,2'-dibromo-biphenyl (DBBP) on a Ag(111) surface leads to the generation of planar dibenzo[e,l]pyrene, in contrast to the nonplanar saddle-shaped tetraphenylene formed in solution.
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Noncovalent structural locking of thermoresponsive polyion complex micelles, nanowires, and vesicles via polymerization-induced electrostatic self-assembly using an arginine-like monomer

Chem. Commun., 2020, 56,4954-4957
DOI: 10.1039/D0CC00427H, Communication
Qingqing Zhao, Qizhou Liu, Chao Li, Lei Cao, Lei Ma, Xiyu Wang, Yuanli Cai
The noncovalent locking of nanostructured thermoresponsive polyion complexes can be achieved via polymerization-induced electrostatic self-assembly (PIESA) using an arginine-like cationic monomer.
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Graphene-modulated assembly of zinc phthalocyanine on BiVO4 nanosheets for efficient visible-light catalytic conversion of CO2

Chem. Commun., 2020, 56,4926-4929
DOI: 10.1039/D0CC01518K, Communication
Ji Bian, Jiannan Feng, Ziqing Zhang, Jiawen Sun, Mingna Chu, Ling Sun, Xin Li, Dongyan Tang, Liqiang Jing
Graphene-modulated ZnPc/BiVO4 Z-scheme heterojunctions for efficient visible-light catalytic CO2 conversion are achieved by increasing the optimized amount of highly dispersed ZnPc.
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Synthesis of chiral α-substituted α-amino acid and amine derivatives through Ni-catalyzed asymmetric hydrogenation

Chem. Commun., 2020, 56,4934-4937
DOI: 10.1039/D0CC01220C, Communication
Gongyi Liu, Xianghe Zhang, Heng Wang, Hengjiang Cong, Xumu Zhang, Xiu-Qin Dong
Efficient Ni-catalyzed asymmetric hydrogenation of cyclic N-sulfonyl ketimino esters and ketimines was successfully developed to prepare a series of chiral α-monosubstituted α-amino acid derivatives and amine derivatives with excellent results.
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Structural elucidation of the degradation mechanism of nickel-rich layered cathodes during high-voltage cycling

Chem. Commun., 2020, 56,4886-4889
DOI: 10.1039/D0CC00327A, Communication
Open Access
Jing Lai, Jun Zhang, Zuowei Li, Yao Xiao, Weibo Hua, Zhenguo Wu, Yanxiao Chen, Yanjun Zhong, Wei Xiang, Xiaodong Guo
A splitting of two O3 phases, rather than the often observed O1 phases in the conventional LiCoO2 electrode, was discovered in the LiNi0.85Co0.10Mn0.05O2 at high-voltage region (>4.6 V) by in situ high-resolution synchrotron radiation diffraction.
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Fe3Pt intermetallic nanoparticles anchored on N-doped mesoporous carbon for the highly efficient oxygen reduction reaction

Chem. Commun., 2020, 56,4898-4901
DOI: 10.1039/D0CC00895H, Communication
Danke Chen, Zhuoyi Li, Yu Zhou, Xu Ma, Hanqing Lin, Wen Ying, Xinsheng Peng
N-Doped mesoporous carbon catalysts dispersed with Fe3Pt intermetallic nanoparticles, exhibiting excellent ORR performance, were synthesised by direct pyrolysis of Pt–Fe co-functionalized ZIF-8.
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Unexpected persistence of cis-bridged chains in compressed AuF3

Chem. Commun., 2020, 56,4902-4905
DOI: 10.1039/D0CC01374A, Communication
Dominik Kurzydłowski, Serhiy Kobyakov, Zoran Mazej, Sharad Babu Pillai, Brahmananda Chakraborty, Prafulla K. Jha
Raman scattering measurements and DFT calculations indicate that solid AuF3 adopts a metastable cis-bridge structure upon room-temperature compression.
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Stepwise assembly of nanoclusters guided by DNA origami frames with high-throughput

Chem. Commun., 2020, 56,4918-4921
DOI: 10.1039/D0CC00274G, Communication
Xiaodong Xin, Lihui Wang, Kaiwei Wang, Lizhi Dai, Hai Cao, Zheng Li, Ye Tian
We propose two strategies to construct nanoclusters efficiently with explicit positions of nanoparticles by the surface-encoded method.
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CRISPR/Cas-directed programmable assembly of multi-enzyme complexes

Chem. Commun., 2020, 56,4950-4953
DOI: 10.1039/D0CC01174F, Communication
Samuel Lim, Jiwoo Kim, Yujin Kim, Dawei Xu, Douglas S. Clark
We describe a versatile CRISPR/Cas-based strategy to construct precisely organized, scaffolded multi-enzyme systems with improved productivity.
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A dual-round signal amplification strategy for colorimetric/photoacoustic/fluorescence triple read-out detection of prostate specific antigen

Chem. Commun., 2020, 56,4942-4945
DOI: 10.1039/D0CC01086C, Communication
Chao Jiang, Yan Huang, Ting He, Peng Huang, Jing Lin
A colorimetric/fluorescence/photoacoustic triple read-out detection of prostate specific antigen (PSA) was developed by using a silica coated Au@Ag core–shell nanorod (denoted Au@Ag@SiO2) based enzyme-linked immunosorbent assay (ELISA) system.
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The design of hypercrosslinked polymers from benzyl ether self-condensing compounds and external crosslinkers

Chem. Commun., 2020, 56,4938-4941
DOI: 10.1039/D0CC01002B, Communication
Robert T. Woodward
Hypercrosslinked polymers were produced via the self-condensation of benzyl ether compounds, providing a one-component route to highly porous networks and significant reductions in catalyst waste compared to conventional routes.
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A highly active Rh1/CeO2 single-atom catalyst for low-temperature CO oxidation

Chem. Commun., 2020, 56,4870-4873
DOI: 10.1039/D0CC00230E, Communication
Bing Han, Tianbo Li, Junying Zhang, Chaobin Zeng, Hiroaki Matsumoto, Yang Su, Botao Qiao, Tao Zhang
Rh1/CeO2 SAC is highly active for CO oxidation, which exhibits a high TOF of 0.41 s−1via the Mars–van Krevelen mechanism.
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New insight derived from a two-compartment cell: electrochemical behavior of FeF3 positive electrode

Chem. Commun., 2020, 56,4878-4881
DOI: 10.1039/D0CC01162B, Communication
Kazuki Yoshii, Noboru Taguchi, Takeshi Miyazaki, Masahiro Shikano, Hikari Sakaebe
A designed two-compartment cell revealed the degradation mechanism and an essentially effective additive for the FeF3 composite electrode.
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Conformational control of N-methyl-N,N'-diacylhydrazines by noncovalent carbon bonding in solution

Chem. Commun., 2020, 56,4874-4877
DOI: 10.1039/D0CC00943A, Communication
Jugal Kishore Rai Deka, Biswajit Sahariah, Kalpita Baruah, Arun Kumar Bar, Bani Kanta Sarma
Unusual N(amide)⋯C–X noncovalent carbon bonding interactions stabilize the transcis (tc) amide bond rotamers of N-methyl-N,N'-diacylhydrazines over the expected transtrans (tt) rotamers in solution.
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Beyond temperature: controlling collagen fibrillogenesis under physiological conditions via interaction with cucurbit[7]uril

Chem. Commun., 2020, 56,4946-4949
DOI: 10.1039/D0CC01444C, Communication
Qiuping Xie, Delong Hou, Jinming Chang, Zhou Xu, Qi Zeng, Zhonghui Wang, Yi Chen
A supramolecular strategy as efficient as temperature that enabled facile control over collagen fibrillogenesis under physiological conditions was reported.
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Pd-Promoted cross coupling of iodobenzene with vinylgold via an unprecedented phenyl transmetalation from Pd to Au

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02645J, Communication
Jiwei Wang, Licheng Zhan, Gendi Wang, Yin Wei, Min Shi, Jun Zhang
Oxidative addition of Pd/Au vinylene species with iodobenzene reveals the effect of a strong metallophilic Pd⋯Au interaction on phenyl transmetalation from PdIV to AuI, which allows subsequent reductive elimination of LAuI at Pd and Au.
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A convenient reagent for the conversion of aldoximes into nitriles and isonitriles

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00188K, Communication
Wei Zhang, Jin-Hong Lin, Pengfei Zhang, Ji-Chang Xiao
Described herein is the convenient transformation of aldoximes into nitriles or isonitriles by slightly modifying reaction conditions.
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Construction of Nanocage-Structured Heterogeneous Binary Metal Sulfides via Step-by-Step Confined Growth for Boosted Lithium Storage Properties

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00962H, Communication
Rongfang Zhao, Yue Han, Wenlong Li, Jinhua Li, Ming Chen, Lingxin Chen
Nanocage-structured materials-heterogeneous binary metal sulfides (MoS2 and Co9S8) in carbon nanocages (Co9S8/MoS2@CNCs) via step-by-step confined growth display superior Li-storage performance, profiting from the synergistic effect of bimetallic sulfides, high filling...
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Ultrasensitive DNA Electrochemical Biosensor Based on MnTBAP Biomimetic Catalyzed AGET ATRP Signal Amplification Reaction

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02176H, Communication
Haobo Sun, Yunliang Qiu, Yajie Lu, Jinming Kong, Xueji Zhang
In this paper, an ultrasensitive, highly selective and green electrochemical biosensor for quantifying DNA sequences (aM DNA) based on MnTBAP catalyst for AGET ATRP reaction is proposed. For the first...
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Surfactant-free synthesis of ultralong silver nanowires for endurable transparent conducting electrodes

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01915A, Communication
Sian-Hong Tseng, Lian-Ming Lyu, Kai-Yuan Hsiao, Wan-Hua Ho, Ming-Yen Lu
The present study employed the surfactant-free growth of ultralong (~50 μm) silver nanowires (AgNWs) with high aspect ratio (up to 500) by galvanic replacement. AgNW conducting film were fabricated as...
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Bimolecular Vinylation of Arenes by Vinyl Cations

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02300K, Communication
ZHILONG LI, Vincent Gandon, Christophe Bour
Styrene derivatives can be easily synthesized from vinyl triflates and arenes under mild reaction conditions, using [Li][Al(OC(CF3)3)4] as a catalyst and LiHMDS as a base. This transformation is likely to...
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Fluorescent Molecular Logic Gates based on Photoinduced Electron Transfer (PET) Driven by a Combination of Atomic and Biomolecular Inputs

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00478B, Communication
Open Access
Glenn Wright, Chaoyi Yao, Tom Moody, A. P. De Silva
Molecular AND logic gates 1, 3, 5 and 7, which are designed according to principles of photoinduced electron transfer (PET) switching, respond to co-existing Candida antarctica lipase B and H+...
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A DNA logic gate with dual-anchored proximity aptamers for accurate identification of circulating tumor cells

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00564A, Communication
Tianshu Chen, Xin Fu, Qianqian Zhang, Dongsheng Mao, Yuchen Song, Chang Feng, Xiaoli Zhu
We have designed a DNA logic gate that can integrate multiple biomarkers recognition with signal amplification to perform accurate and and sensitive analysis of circulating tumor cells (CTCs). It also...
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Intra-mitochondrial self-assembly to overcome the intracellular enzymatic degradation of L-peptides

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02029J, Communication
M. T. Jeena, Seokyoung Lee, Ayan Kumar Barui, Seongeon Jin, Yuri Cho, Suk-Won Hwang, Sehoon Kim, Ja-Hyoung Ryu
The design of peptide-based therapeutics is generally based on the replacement of L-amino acids with D-isomers to obtain improved therapeutic efficiency.
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A three-dimensional BODIPY–iron(III) compound with improved H2O2-response for NIR-II photoacoustic imaging guided chemodynamic/photothermal therapy

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01164A, Communication
Changjin Ou, Yewei Zhang, Wei Ge, Liping Zhong, Yong Huang, Weili Si, Wenjun Wang, Yongxiang Zhao, Xiaochen Dong
3D boron dipyrromethene (BODIPY)–Fe(III) coordination polymer nanoparticles with NIR-II absorption were developed as photothermal and chemodynamic agent to effectively kill cancer cells.
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A difluoroboron β-diketonate based thermometer with temperature-dependent emission wavelength

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01505A, Communication
Jian-Xin Wang, Yi-Shuai Yu, Li-Ya Niu, Bo Zou, Kai Wang, Qing-Zheng Yang
Difluoroboron β-diketonate complexes that manifested temperature-dependent emission wavelength are reported.
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Deep imaging for visualizing nitric oxide in lipid droplets: discovering the relationship between nitric oxide and resistance to cancer chemotherapy drugs

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01856B, Communication
Miantai Ye, Wei Hu, Meng He, Chenchen Li, Shuyang Zhai, Zhihong Liu, Yanying Wang, Huijuan Zhang, Chunya Li
A near-infrared two-photon fluorescent probe for selective detection and deep-depth imaging of NO helps to discover the relationship between NO and resistance to antitumor drugs.
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Harnessing chemical exchange: 19F magnetic resonance OFF/ON zinc sensing with a Tm(III) complex

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01876G, Communication
Meng Yu, Da Xie, Rahul T. Kadakia, Weiran Wang, Emily L. Que
A Tm(III) complex displays an “off–on” 19F NMR/MRI response to Zn(II) upon tuning the chemical exchange rate.
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An ultrasensitive electrochemical biosensor for Pseudomonas aeruginosa assay based on a rolling circle amplification-assisted multipedal DNA walker

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01619E, Communication
Huang Zhou, Shaoyun Duan, Ji Huang, Fengjiao He
An ultrasensitive electrochemical biosensor was developed based on RCA and multipedal DNA walking strategy for the assay of 16S rRNA gene, and it has great application potential in food safety, environmental monitoring, and disease diagnosis.
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Smart azobenzene-containing tubular polymersomes: fabrication and multiple morphological tuning

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01934H, Communication
Lishan Li, Songbo Cui, An Hu, Wei Zhang, Yiwen Li, Nianchen Zhou, Zhengbiao Zhang, Xiulin Zhu
Several kinds of novel azobenzene-containing tubular polymersomes were fabricated via self-assembly, and their shape could be tuned precisely by changing the chemical structure, self-assembly condition and external stimuli.
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A highly active and robust iron quinquepyridine complex for photocatalytic CO2 reduction in aqueous acetonitrile solution

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01930E, Communication
Yanfei Qin, Lingjing Chen, Gui Chen, Zhenguo Guo, Lei Wang, Hongbo Fan, Marc Robert, Tai-Chu Lau
[Fe(qnpy)(H2O)2]2+ is a highly efficient and robust catalyst for visible-light-driven reduction of CO2 to CO, with a TON for CO of up to 14 095 and selectivity of 98% using Ru(phen)3Cl2 as photosensitizer and BIH as sacrificial reductant.
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3D spongy nanofiber structure Fe–NC catalysts built by a graphene regulated electrospinning method

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01517B, Communication
Weiyuan Ding, Hongquan Yu, Yu Tang, Zhuxin Li, Bijiao Liu, Dechong Liu, Yuyu Wang, Shu hong Liu, Hong Zhao, Daniel Mandler
A Fe–NC catalyst containing carbon nanotubes, mesopores and macropores with a measurable 3D framework structure was prepared by electrospinning.
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A radical-mediated 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite: facile access to sulfonyl isoxazoles

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01659D, Communication
Xin Yue, Ming Hu, Xingyi He, Shuang Wu, Jin-Heng Li
An unprecedented indium-promoted three-component 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite for producing 5-sulfonylisoxazoles via [3+2] annulation is reported.
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Enhancing the catalytic properties of well-defined electrophilic platinum complexes

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01438A, Feature Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Pablo Ríos, Amor Rodríguez, Salvador Conejero
Well-defined electrophilic or low-electron count platinum complexes are very versatile catalysts for a variety of chemical transformations.
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