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980 nm NIR light driven overall water splitting over a combined CdS–RGO–NaYF4–Yb3+/Er3+ photocatalyst

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Catal. Sci. Technol., 2020, 10,2389-2397
DOI: 10.1039/D0CY00256A, Paper
Wei Gao, Yuqi Wu, Gongxuan Lu
Infrared light (NIR) accounts for more than 50% of the energy donated by the Sun to the Earth, but most of this type of energy is not utilized in photocatalytic reactions.
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Single-step benzene hydroxylation by cobalt(II) catalysts via a cobalt(III)-hydroperoxo intermediate

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Catal. Sci. Technol., 2020, 10,2540-2548
DOI: 10.1039/C9CY02601K, Paper
Karunanithi Anandababu, Sethuraman Muthuramalingam, Marappan Velusamy, Ramasamy Mayilmurugan
Cobalt(II) complexes reported as efficient and selective catalysts for single-step phenol formation from benzene using H2O2. The catalysis proceeds likely via cobalt(III)-hydroperoxo species.
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New findings and current controversies in the reaction of ruthenium red and ammonium cerium(IV) nitrate: focus on the precipitated compound

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Catal. Sci. Technol., 2020, 10,2491-2502
DOI: 10.1039/C9CY02499A, Paper
Bahram Sarvi, Seyedeh Maedeh Hosseini, Bahareh Deljoo, Abdelhamid El-Sawy, Alireza Shirazi Amin, Mark Aindow, Steven L. Suib, Mohammad Mahdi Najafpour
During water-oxidation reaction in the presence of RuR and CAN, a heterogeneous nano-sized Ru-Ce compound is detected, which is formed by the interaction of [(NH3)5RuORu(NH3)4ORu(NH3)5],6+/7+ nitrate ions, and the products of the reduction of CAN.
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Direct synthesis of hydrogen peroxide without the use of acids or halide promoters in dissolution

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Catal. Sci. Technol., 2020, 10,2333-2336
DOI: 10.1039/D0CY00416B, Communication
Open Access
G. Blanco-Brieva, F. Desmedt, P. Miquel, J. M. Campos-Martin, J. L. G. Fierro
We show the first catalyst family able to produce hydrogen peroxide at concentrations higher than 5 wt% in the absence of any promoter or stabilizing agent in dissolution.
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Effects of Ni loading on the physicochemical properties of NiOx/CeO2 catalysts and catalytic activity for NO reduction by CO

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Catal. Sci. Technol., 2020, 10,2359-2368
DOI: 10.1039/C9CY02619C, Paper
Shuhao Zhang, Jaeha Lee, Do Heui Kim, Taejin Kim
The NO reduction by CO reaction was investigated using NiOx/CeO2 catalysts with different Ni loadings. Surface NiOx controls the catalytic activity which was related to the molecular structure and reducibility of the catalysts.
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Alumina grafted SBA-15 sustainable bifunctional catalysts for direct cross-coupling of benzylic alcohols to diarylmethanes

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Catal. Sci. Technol., 2020, 10,2583-2592
DOI: 10.1039/D0CY00471E, Paper
Chandran Rajendran, Govindaswamy Satishkumar, Charlotte Lang, Eric M. Gaigneaux
AlSBA-15 catalysts possessing Brønsted acid and Lewis acid–base bifunctionalities catalyze the direct arylation of benzyl alcohols to diarylmethanes with an 85% product yield through C–O bond activation.
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Facile sulfolane-modified resins for enhanced dimethoxymethane carbonylation

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Catal. Sci. Technol., 2020, 10,2561-2572
DOI: 10.1039/D0CY00201A, Paper
Jie Yao, Lei Shi, Wenjie Deng, Jiaqi Fan, Yan Wang, Weizhe Gao, Dongxi Zhang, Wenliang Zhu, Zhongmin Liu
A simple resin modification method for 50 h DMM carbonylation with a high STY of 3.15 mmolMMAc (gcat h)−1 and 100% MMAc selectivity.
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Kinetic study of the methane dry (CO2) reforming reaction over the Ce0.70La0.20Ni0.10O2−δ catalyst

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Catal. Sci. Technol., 2020, 10,2652-2662
DOI: 10.1039/C9CY02192B, Paper
Lidia Pino, Cristina Italiano, Massimo Laganà, Antonio Vita, Vincenzo Recupero
The kinetic behaviour of the Ce0.70La0.20Ni0.10O2−δ catalyst during the methane dry reforming reaction was investigated in a fixed bed reactor in the temperature range of 923–1023 K with the partial pressure of CH4 and CO2 ranging between 5 and 50 kPa.
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Construction of heterostructure based on hierarchical Bi2MoO6 and g-C3N4 with ease for impressive performance in photoelectrocatalytic water splitting and supercapacitor

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Catal. Sci. Technol., 2020, 10,2427-2442
DOI: 10.1039/D0CY00211A, Paper
C. Murugan, M. Karnan, M. Sathish, A. Pandikumar
This work demonstrates the formation of g-C3N4/Bi2MoO6 heterostructure for water splitting and supercapacitor; which shows highest PEC efficiency and symmetric device delivered a energy density and power density of 47 W h kg−1 and 4.5 kW kg−1.
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Carbon deposits during catalytic combustion of toluene on Pd–Pt-based catalysts

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Catal. Sci. Technol., 2020, 10,2452-2461
DOI: 10.1039/D0CY00101E, Paper
Yu Yang, Gang Wang, Peng Zheng, Falu Dang, Jiannian Han
Carbon is easily deposited on a catalyst during the catalytic combustion of toluene, resulting in catalyst deactivation.
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Gold-catalyzed domino cyclization enabling construction of diverse fused azaspiro tetracyclic scaffolds: a cascade catalysis mechanism due to a substrate and counterion

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Catal. Sci. Technol., 2020, 10,2415-2426
DOI: 10.1039/D0CY00120A, Paper
Yunhe Li, Xiang Zhao
The detailed mechanism and origins of gold-catalyzed domino cyclization to diverse fused azaspiro tetracyclic scaffolds by cooperative dual catalysis and cascade catalysis are systematically studied.
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Integrated adsorption and photocatalytic degradation of VOCs using a TiO2/diatomite composite: effects of relative humidity and reaction atmosphere

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Catal. Sci. Technol., 2020, 10,2378-2388
DOI: 10.1039/D0CY00168F, Paper
Guangxin Zhang, Arman Peyravi, Zaher Hashisho, Zhiming Sun, Yangyu Liu, Shuilin Zheng, Lexuan Zhong
The optimal relative humidity condition for VOC degradation is related to the length of the carbon chain of VOCs.
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Enhanced and selective photocatalytic reduction of CO2 by H2O over strategically doped Fe and Cr into porous boron carbon nitride

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Catal. Sci. Technol., 2020, 10,2663-2680
DOI: 10.1039/D0CY00343C, Paper
Niwesh Ojha, Abhinav Bajpai, Sushant Kumar
Strategic doping of metals and non-metals into a photocatalyst can help in tuning the band gap and alignment of band structure.
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Loop engineering of aryl sulfotransferase B for improving catalytic performance in regioselective sulfation

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Catal. Sci. Technol., 2020, 10,2369-2377
DOI: 10.1039/D0CY00063A, Paper
Yu Ji, Shohana Islam, Haiyang Cui, Gaurao V. Dhoke, Mehdi D. Davari, Alan M. Mertens, Ulrich Schwaneberg
Loop engineering of aryl sulfotransferase B improves catalytic performance in regioselective sulfation.
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Adjustable anchoring of Ni/Co cations by oxygen-containing functional groups on functionalized graphite paper and accelerated mass/electron transfer for overall water splitting

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Catal. Sci. Technol., 2020, 10,2627-2643
DOI: 10.1039/D0CY00181C, Paper
Yiyi Huang, Lei Sun, Zebin Yu, Ronghua Jiang, Jun Huang, Yanping Hou, Fei Yang, Boge Zhang, Runzhi Zhang, Yalan Zhang
NCS–NCO/FGP0.44 with a cellular network of porous nanosheets and close-contact heterointerface reveals accelerated interfacial mass/electron transportation for overall water splitting.
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Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2

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Catal. Sci. Technol., 2020, 10,2549-2560
DOI: 10.1039/D0CY00330A, Paper
Open Access
Nicola Weder, Benjamin Probst, Laurent Sévery, Ricardo J. Fernández-Terán, Jan Beckord, Olivier Blacque, S. David Tilley, Peter Hamm, Jürg Osterwalder, Roger Alberto
Molecular and heterogeneous water reduction combined: Over 2 days of electrocatalysis of a cobalt polypyridyl catalyst immobilized on TiO2.
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Enhanced oxygen evolution catalysis by aluminium-doped cobalt phosphide through in situ surface area increase

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Catal. Sci. Technol., 2020, 10,2398-2406
DOI: 10.1039/D0CY00123F, Paper
Timothy E. Rosser, Juliana P. S. Sousa, Yasmine Ziouani, Oleksandr Bondarchuk, Dmitri Y. Petrovykh, Xian-Kui Wei, Jo J. L. Humphrey, Marc Heggen, Yury V. Kolen'ko, Andrew J. Wain
Al-doping of cobalt phosphide oxygen evolution catalysts results in enhanced performance which, based on in situ and operando analysis, is shown to result from a surface area increase associated with modified oxidation behaviour.
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Synthesis and molecular structure of model silica-supported tungsten oxide catalysts for oxidative coupling of methane (OCM)

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00289E, Paper
Daniyal Kiani, Sagar Sourav, Israel E. Wachs, Jonas Baltrusaitis
Catalysts with only dispersed phase Na–WO4 sites where Na/W < 2 are slightly less active but significantly more C2 selective than the traditional Na2WO4/SiO2 catalysts that contain a crystalline phase where Na/W = 2.
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Enhancing hydrogen evolution reaction through modulating electronic structure of self-supported NiFe LDH

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00315H, Paper
Xiao-Peng Li, Wen-Kai Han, Kang Xiao, Ting Ouyang, Nan Li, Feng Peng, Zhao-Qing Liu
NiFe-layered double hydroxide (NiFe LDH), as an efficient oxygen evolution reaction (OER) electrocatalyst, has emerged as a promising electrocatalyst for catalyzing overall water splitting in alkaline electrolyte.
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Outstanding Reviewers for Catalysis Science & Technology in 2019

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Catal. Sci. Technol., 2020, 10,2328-2328
DOI: 10.1039/D0CY90032J, Editorial

We would like to take this opportunity to highlight the Outstanding Reviewers for Catalysis Science & Technology in 2019, as selected by the editorial team for their significant contribution to the journal.
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Optimized preparation and regeneration of MFI type base catalysts for D-glucose isomerization in water

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00188K, Paper
Margarida M. Antunes, Auguste Fernandes, Diogo Falcão, Martyn Pillinger, Filipa Ribeiro, Anabela A. Valente
Eco-friendly solid bases possessing hierarchical MFI structure for D-glucose isomerization to D-fructose. Optimizing catalyst synthesis and composition for enhanced stability.
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Mechanistic insights into the oxidation of copper(I) species during NH3–SCR over Cu-CHA zeolites: A DFT study

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00379D, Paper
Chong Liu, Hiroe Kubota, Takashi Toyao, Zen Maeno, Ken-ichi Shimizu
Selective catalytic reduction of nitrogen oxides using ammonia (NH3–SCR) over Cu-exchanged zeolites proceeds via reduction of Cu(II) to Cu(I) and subsequent reoxidation of Cu(I) to Cu(II). Although the mechanism of...
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Selenium-catalyzed oxidation of alkenes: insight into the mechanisms and developing trend

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00400F, Perspective
Hongen Cao, Rongrong Qian, Lei Yu
Recent progresses of the selenium-catalyzed oxidation of alkenes are summarized at the mechanism level. It may be beneficial for designing novel selenium-containing catalysts and alkene oxidation protocols for the next phase of studies.
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An in situ grown lanthanum sulfide/molybdenum sulfide hybrid catalyst for electrochemical hydrogen evolution

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00425A, Paper
Xinran Ding, Tao Yang, Wenxian Wei, Yihui Wang, Kai Xu, Zizheng Zhu, Hong Zhao, Tingting Yu, Dongen Zhang
An La2S3–MoS2 catalyst with expanded interlayer spacing and engineered nano-interfaces was facilely synthesized, demonstrating enhanced catalytic activity for electrochemical hydrogen evolution.
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Carbon nanotube/PTFE as a hybrid platform for lipase B from Candida antarctica in transformation of α-angelica lactone into alkyl levulinates

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00545B, Paper
Anna Szelwicka, Anna Kolanowska, Piotr Latos, Sebastian Jurczyk, Slawomir Boncel, Anna Chrobok
A highly active biocatalyst based on a hybrid platform was designed for the conversion of α-angelica lactone to alkyl levulinates.
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Origin of CO2 as the main carbon source in syngas-to-methanol process over Cu: theoretical evidence from a combined DFT and microkinetic modeling study

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00602E, Paper
Dongyang Xu, Panpan Wu, Bo Yang
A theoretical study combining DFT and microkinetic modeling provides evidence that CO2 is the main carbon source in methanol synthesis from syngas (CO, CO2 and H2) over Cu.
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Heterogeneous iron-containing nanocatalysts – promising systems for selective hydrogenation and hydrogenolysis

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00086H, Minireview
Anastasiya A. Shesterkina, Leonid M. Kustov, Anna A. Strekalova, Vladimir B. Kazansky
Bimetallic catalytic systems Fe–Me (Pt, Pd, Cu) demonstrate synergy in the activity/selectivity pattern in reactions involving hydrogen: selective hydrogenation of CC bonds, NO2 and carbonyl groups and hydrogenolysis of C–O bonds.
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MOFs based on 1D structural sub-domains with Brønsted acid and redox active sites as effective bi-functional catalysts

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00235F, Paper
José María Moreno, Alexandra Velty, Urbano Díaz
Low-dimensional MOF-type catalysts containing Brønsted acid and redox active sites, based on assembled 1D organic–inorganic nanoribbons, for one-pot two-step reactions.
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Bimetallic scorpionate-based helical organoaluminum complexes for efficient carbon dioxide fixation into a variety of cyclic carbonates

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00593B, Paper
Marta Navarro, Luis F. Sánchez-Barba, Andrés Garcés, Juan Fernández-Baeza, Israel Fernández, Agustín Lara-Sánchez, Ana M. Rodríguez
The binuclear aluminum complexes [AlR2(κ2-NN';κ2-NN')AlR2] with TBAB/PPNCl behave as excellent systems for cyclic carbonate formation from CO2 with challenging epoxides.
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Insights into isothiourea-catalyzed asymmetric [3 + 3] annulation of α,β-unsaturated aryl esters with 2-acylbenzazoles：Mechani-sm, origin of stereoselectivity and switchable chemoselectivity

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00295J, Paper
Congcong Wang, Shi-Jun Li, Qiao-Chu Zhang, Donghui Wei, Lina Ding
Recently, isothiourea-catalyzed asymmetric [3 + 3] annulation reactions of α,β-unsaturated aryl esters with 2-acylbenzothiazole (or 2-acylbenzoxazole) were reported with switchable chemoselectivity to form either dihydropyridone or dihydropyrone, but predicting the...
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Regulation of rutile/anatase TiO2 heterophase interface by Ni12P5 to improve photocatalytic hydrogen evolution

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00634C, Paper
Qiu Chengwei, Jinjin Lin, Jinni Shen, Dan Liu, Zizhong Zhang, Huaxiang Lin, Xuxu wang
Anatase/rutile TiO2 heterophase junction composite has been documented to have much higher photocatalytic activity than single phase TiO2 (nude anatase or nude rutile) for various chemical reactions including the hydrogen...
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Two-way desorption coupling to enhance the conversion of syngas into aromatics by MnO/H-ZSM-5

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00275E, Paper
Syed Zulfiqar Ali Gilani, Le Lu, Muhammad Tahir Arslan, Babar Ali, Qi Wang, Fei Wei
We herein report a composite catalyst containing partially reducible and highly active manganese oxide and nano-size H-ZSM-5 with short b-axis, prepared for the direct conversion of syngas into aromatics.
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Pt-Ligand single-atom catalysts: tuning activity by oxide support defect density

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02594D, Paper
Xuemei Zhou, Linxiao Chen, George E. Sterbinsky, Debangshu Mukherjee, Raymond R. Unocic, Steven L. Tait
Metal–ligand coordination stabilizes single atom Pt on pristine and defective TiO2 supports to impact local coordination and catalytic hydrosilylation activity.
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Surface reconstruction and effect of Ni-modification in the selective hydrogenation of 1,3-butadiene over Mo2C-based catalysts

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00402B, Paper
Qiuchen Yang, Rui Qiu, Xixi Ma, Ruijun Hou, Kening Sun
In the current study, Mo2C, NiMo2C, H-Mo2C and H-NiMo2C were synthesized to understand the effects of Ni modification and synthesis route. The catalysts were characterized by XRD, N2-physisorption, SEM, TEM,...
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Facile synthesis of oxygen-deficient nano-TiO2 coordinated by acetate ligands for enhanced visible-light photocatalytic performance

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00592D, Paper
Shaohua Pang, Yunfei Lu, Lin Cheng, Juming Liu, Huiyan Ma, Jucai Yang, Qiancheng Zhang
To date, various methods have been adopted to enhance the visible-light photocatalytic activity of nano-TiO2. However, a more facile and moderate method is still highly desirable. In this work, a...
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Importance of the decoration in shaped cobalt nanoparticles in the acceptor-less secondary alcohol dehydrogenation

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00390E, Paper
Kamila Kaźmierczak, Raj Kumar Ramamoorthy, Arthur Moisset, Guillaume Viau, Arnaud Viola, Marion Giraud, Jennifer Peron, Lorette Sicard, Jean-Yves Piquemal, Michèle Besson, Noémie Perret, Carine Michel
Ligands matter for shaped decorated Co nanoparticles, at the frontier between homogeneous and heterogeneous catalysis.
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Semi-rational hinge engineering: modulating the conformational transformation of glutamate dehydrogenase for enhanced reductive amination activity towards non-natural substrates

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02576F, Paper
Xinjian Yin, Yayun Liu, Lijun Meng, Haisheng Zhou, Jianping Wu, Lirong Yang
The hinge region was identified to be a promising hotspot for activity engineering of GluDHs, providing a potent alternative for developing high-performance biocatalysts toward valuable optically pure L-amino acid production.
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Effective N-methylation of nitroarenes with methanol catalyzed by a functionalized NHC-based iridium catalyst: a green approach to N-methyl amines

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00707B, Paper
Miguel González-Lainez, M. Victoria Jiménez, Vincenzo Passarelli, Jesús J. Pérez-Torrente
Compound [IrBr(CO)2(κC-tBuImCH2PyCH2OMe)] featuring a flexible pyridine/OMe functionalized NHC ligand κ1C coordinated efficiently catalyzes the selective N-monomethylation of nitroarenes using methanol as both the reducing agent and the C1 source. A...
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Phosphorus-Doped Inverse Opal g-C3N4 for Efficient and Selective CO Generation from Photocatalytic Reduction of CO2

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00457J, Paper
xiaoyue huang, Wenyi Gu, Songchang Hu, Yan Hu, Liang Zhou, Juying Lei, Lingzhi Wang, Yongdi Liu, Jinlong Zhang
In this work, inverse opal (IO) structure construction and phosphorus doping were combined to modify carbon nitride (g-C3N4) for photocatalytic reduction of CO2. The inverse opal structure was fabricated by...
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Bifunctional rhenium-copper nanostructures for intensified and stable ethanol synthesis via hydrogenation of dimethyl oxalate

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00579G, Communication
Zhongnan Du, Meng Chen, Xuepeng Wang, Xingkun Chen, Xiaolin Mou, Yuan Tan, Wenshao Yang, Chuanqi Huang, Hejun Zhu, Ronghe Lin, Yunjie Ding
Decorating small copper nanoparticles with isolated and/or clusted oxophilic rhenium species enables the first low-copper catalytic technology for intensified and stable ethanol production under mild conditions in dimethyl oxalate hydrogenation....
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Synthesis of vinyl chloride monomer by acetylene hydrochlorination with a ruthenium-based N-heterocyclic carbene complex catalyst

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00512F, Paper
Ming Cai, Haiyang Zhang, Baochang Man, Jian Li, Linfeng Li, Yanqin Li, Dongyang Xie, Renpan Deng, Jinli Zhang
With the implementation of Minamata Convention and the urgent demand for green, and efficient mercury-free catalysts, the carbon-supported IPr-(Ru)/AC catalyst was synthesized and assessed for its successful application in acetylene...
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Ligand photodissociation in Ru(II)–1,4,7-triazacyclononane complexes enhances water oxidation and enables electrochemical generation of surface active species

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02575H, Paper
Hussein A. Younus, Nazir Ahmad, Ibrahim Yildiz, Serge Zhuiykov, Shiguo Zhang, Francis Verpoort
Ligand transformations involved in metal complexes during water oxidation (WO), such as ligand decomposition, partial oxidation, or complete dissociation have been reported, however, ligand photodissociation has not been reported yet.
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Impact of edge structures on interfacial interactions and efficient visible-light photocatalytic activity of metal–semiconductor hybrid 2D materials

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00420K, Paper
Open Access
Deobrat Singh, Pritam Kumar Panda, Nabil Khossossi, Yogendra Kumar Mishra, Abdelmajid Ainane, Rajeev Ahuja
The present work systematically investigates the structural, electronic, and optical properties of MoS2/Si2BN heterostructures based on first-principles calculations.
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Homogeneous vs. Heterogeneous: Mechanistic Insights into Iron Group Metal-Catalyzed Reductions from Poisoning Experiments

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00644K, Minireview
Axel Jacobi von Wangelin, Sebastian Sandl, Dominik Gärtner
Iron group metal catalysts constitute a promising alternative to well-established noble metal catalysts in reduction reactions. However, the development of effective 3d metal catalysts has largely been hampered by their...
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Heterogenization for polyoxometalates as solid catalysts in aerobic oxidation of glycerol

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00403K, Paper
Meilin Tao, yue li, Yiming Li, Xueyan Zhang, Yurii Geletii, Xiaohong Wang, Craig L Hill
A series of heterogeneous catalysts based on phosphomolybdic salts with different Lewis metals in counter or substituent places LnPMo12O40 (L = Al3+, Fe3+, Cr3+, Ti4+, Zr4+ and Zn2+, abbreviated as...
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Stability of the ketyl radical as a descriptor in the electrochemical coupling of benzaldehyde

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00282H, Paper
Jacob Anibal, Arnav Malkani, Bingjun Xu
Electroreductive coupling is an emerging pathway for the renewable upgrading of biomass derived oxygenates. This work investigates electrochemical benzaldehyde reduction on Au, Cu, Pt and Pd using reactivity testing and in situ spectroscopy.
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Site-specific catalytic activities to facilitate solvent-free aerobic oxidation of cyclohexylamine to cyclohexanone oxime over highly efficient Nb-modified SBA-15 catalysts

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00479K, Paper
Wei Ding, Haoyu Peng, Wenzhou Zhong, Liqiu Mao, Dulin Yin
The development of highly active and selective heterogeneous catalysts for efficient oxidation of cyclohexylamine to cyclohexanone oxime is a challenge associated with the highly sensitive nitrogen center of cyclohexylamine.
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Photocatalytic asymmetric epoxidation of trans-stilbene with manganese–porphyrin/graphene-oxide nanocomposite and molecular oxygen: axial ligand effect

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00441C, Paper
Elahe Ahadi, Hassan Hosseini-Monfared, Alex Spieß, Christoph Janiak
An efficient, visible light-driven manganese–porphyrin photocatalyst was developed for the asymmetric epoxidation of trans-stilbene by molecular oxygen under mild conditions.
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Does the structure of CuZn hydroxycarbonate precursors affect the intrinsic hydrogenolysis activity of CuZn catalysts?

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00143K, Paper
Violetta Pospelova, Jaroslav Aubrecht, Kateřina Pacultová, Miloslav Lhotka, Oleg Kikhtyanin, David Kubička
A comparative study of the properties and activity of catalysts derived from single-phase CuZn precursors to elucidate the effect of the precursor structure on the catalyst activity in DMA hydrogenolysis and to examine replacement of CuCr catalysts.
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Phosphine-catalyzed [3 + 2] annulation of 2-aminoacrylates with allenoates and mechanistic studies

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00092B, Paper
Xiao-Yun Wu, Hou-Ze Gui, Harish Jangra, Yin Wei, Min Shi, Hendrik Zipse
A convenient and efficient strategy for the synthesis of 3-pyrrolines containing an amino quaternary stereogenic center via phosphine-catalyzed formal [3 + 2] annulation of allenoates with 2-aminoacrylates is disclosed. A...
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