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Hyundai IONIQ 9 SUV Showcases Spacious Lounge-like Interior Ahead Of Premiere

Discover the Hyundai IONIQ 9's spacious lounge-like interior designed for comfort and versatility, set to premiere in Los Angeles this November.




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Advanced Tips For Protecting Your Car's Exterior During India's Monsoon Season

The monsoon season in India brings relief from the scorching heat, but it also poses challenges for car owners. Protecting your car’s exterior during this wet season is crucial to maintain its appearance and value. This guide offers advanced tips for




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FTII JET admit card 2023 out; Check Details Here

FTII JET 2023: The Film and Television Institute of India has activated the FTII JET admit card 2023 download link today on March 11, 2023. Candidates will have to log on to the FTII official website, applyadmission.net, to download the hall




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JEE Mains 2023 Application Form Correction Window Open; Check Details Here

JEE Mains 2023: The National Testing Agency, NTA has opened the facility to edit and make corrections on the Joint Entrance Examination (JEE) 2023 application form for session 2 exam. BTech, BE and B.Arch candidates who have filled the JEE Mains




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KC Mahindra Education Trust released the scholarship for Indian students in PG Programmes

KC Mahindra Education Trust Scholarship: The KC Mahindra Education Trust has announced its scholarship programme for postgraduate studies abroad. The KC Mahindra Scholarship programme aims to enable Indian students to pursue their higher education dreams. Candidates can register themselves by visiting




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Andhra Pradesh AP inter Admit Card Out; Check Details Here

The Board of intermediate examinations Andhra Pradesh (BIEAP) has issued the AP inter admit card 2023 for class 11 and Class 12 theory exams. The BIE AP admit card is available at the official website at bieap.apcfss.in. Students can also take




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AFCAT 1 Result announced; Check Details Here

AFCAT 1 Result: The Indian Air Force (IAF) has released the Air Force Common Admission Test (AFCAT) 2023 results. The AFCAT 2023 result will be available on the official website at afcat.cdac.in. Candidates can check their AFCAT results through their individual




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LIC AAO 2023 Mains Admit Card Declared; Check Exam Preparation Tips Here

The Life Insurance Corporation of India (LIC) has released the Assistant Administrative Officers (AAO) Mains admit card for the phase 2 exam.Candidates who are going to appear for the LIC AAO examination can download the LIC AAO 2023 Mains admit card




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University of Hull invited applications for MBA Programmes; Check Details Here

The University of Hull, opened the online applications for online master of business administration. The two year MBA global course is available in both online as well as part time and aims to equip the students with expertise and tools required.




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Kannur University Admission 2023: Applications are Invited for UG and PG Courses

Applications are invited to get admission in Kannur University. Registration forms for various programmes across several departments are accessible on Kannur University's official admission webpage. The deadline for applications is 30 May 2023. Students can pursue undergraduate, graduate, and certificate programmes




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Kerala University M.Ed 2024: Application Process, Eligibility and more

The University of Kerala, one of India's founding 16 universities, offers undergraduate and postgraduate degrees in a variety of subjects and is associated with 150 government/private aided and private unaided colleges. M.Ed is a two-year professional course aimed to improve applicants'




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The electrochemical modulation of single molecule fluorescence

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00111G, Paper
Ying Yang, Yuanqing Ma, J. Justin Gooding
We demonstrate how to effectively modulate the fluorescence intensity of organic dye-labelled cell samples on an indium tin oxide surface using electrochemistry with redox-active mediators present in an oxygen scavenger buffer.
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Molecular sandwich-based DNAzyme catalytic reaction towards transducing efficient nanopore electrical detection of antigen proteins

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00146J, Paper
Lebing Wang, Shuo Zhou, Yunjiao Wang, Yan Wang, Jing Li, Xiaohan Chen, Daming Zhou, Liyuan Liang, Bohua Yin, Youwen Zhang, Liang Wang
A molecular sandwich-based DNAzyme catalytic reaction is capable of transducing detectable nucleic acids as a substitute for difficult to yield protein detection in complicated biological matrices, in a nanopore.
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Integrated scanning electrochemical cell microscopy platform with local electrochemical impedance spectroscopy using a preamplifier

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00122B, Paper
Ancheng Wang, Rong Jin, Dechen Jiang
An integrated SECCM with LEIS is established by combining the preamplifier based EIS measurement with scanning electrochemical cell microscopy.
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Single-molecule electrochemical imaging of ‘split waves’ in the electrocatalytic (EC') mechanism

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00126E, Paper
Wandong Zhao, Jin Lu
Imaging the single molecule electrocatalytic (EC') process and correlating it with the conventional ensemble EC' mechanism.
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Ion concentration polarization causes a nearly pore-length-independent conductance of nanopores

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00148F, Paper
DaVante Cain, Ethan Cao, Ivan Vlassiouk, Tilman E. Schäffer, Zuzanna S. Siwy
The conductance and selectivity of low-aspect-ratio nanopores are almost independent of the length due to polarization effects controlled by the geometric and electrochemical properties of the whole (pore + reservoir) system.
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Revealing the diverse electrochemistry of nanoparticles with scanning electrochemical cell microscopy

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00115J, Paper
Lachlan F. Gaudin, Cameron L. Bentley
Through presenting and discussing these findings, this article seeks to highlight complications in single-NP SECCM experiments, particularly those arising from issues with sample preparation.
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Seeing nanoscale electrocatalytic reactions at individual MoS2 particles under an optical microscope: probing sub-mM oxygen reduction reaction

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00132J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nikan Afsahi, Zhu Zhang, Sanli Faez, Jean-Marc Noël, Manas Ranjan Panda, Mainak Majumder, Naimeh Naseri, Jean-François Lemineur, Frédéric Kanoufi
Interferometric scattering microscopy (iSCAT) allows visualizing individual petal-like MoS2 sub-microparticles and monitoring operando their activity towards oxygen reduction reaction.
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Scanning electrochemical probe microscopy: towards the characterization of micro- and nanostructured photocatalytic materials

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00136B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Giada Caniglia, Sarah Horn, Christine Kranz
The feasibility of fabricating micro- and sub-micro-sized AFM probes based on Pt-B electrodeposition for the electrochemical detection of H2 evolution is demonstrated.
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Controlling the droplet cell environment in scanning electrochemical cell microscopy (SECCM) via migration and electroosmotic flow

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00080C, Paper
Open Access
Samuel F. Wenzel, Heekwon Lee, Hang Ren
The contributions of migration and electroosmotic flow induced by electrochemical redox molecules in dual-barrel SECCM were characterised.
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Delivery of carbon dioxide to an electrode surface using a nanopipette

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00124A, Paper
Jaimy Monteiro, Harry Dunne, Kim McKelvey
A new scanning probe approach for the delivery of a gas-phase reactant to the surface of an electrocatalyst through a self-replenishing bubble located at the end of a scanning probe has been developed.
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Nanoscale visualization of the anti-tumor effect of a plasma-activated Ringer's lactate solution

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00116H, Paper
Open Access
Junichi Usuda, Kenshin Yagyu, Hiromasa Tanaka, Masaru Hori, Kenji Ishikawa, Yasufumi Takahashi
To characterize the anti-tumor effect of plasma-activated Ringer's lactate solutions, we used scanning ion conductance microscopy, using glass nanopipettes as probes, to visualize the structural changes of the cell surface.
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Charge-induced deformation of scanning electrolyte before contact

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00147H, Paper
Liang Liu
Deformation of liquid and gel electrolytes before touching the sample in SECCM and SGECM: equilibrium does not always exist.
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Unraveling Aqueous Alcohol Freezing : new theoretical tools from graph theory to extract molecular processes in MD simulations

Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00165F, Paper
Rawan AbouHaidar, Sana Bougueroua, Denis DUFLOT, Marie-Pierre Gaigeot, Barbara E Wyslouzil, Celine Toubin
Ice clouds in the upper troposphere are crucial for regulating Earth’s climate by affecting stratospheric humidity and the global radiative balance. A key aspect of cloud formation is heterogeneous ice...
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Observation of cavitation dynamics in viscous deep eutectic solvents during power ultrasound sonication

Faraday Discuss., 2024, 253,458-477
DOI: 10.1039/D4FD00031E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ben Jacobson, Shida Li, Paul Daly, Christopher E. Elgar, Andrew P. Abbott, Andrew Feeney, Paul Prentice
We characterise the development of cavitation structure in three deep eutectic solvents of increasing viscosity, and water, via high-speed imaging and parallel acoustic detection..
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Cationic micelles in deep eutectic solvents: effects of solvent composition

Faraday Discuss., 2024, 253,26-41
DOI: 10.1039/D4FD00045E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Iva Manasi, Stephen M. King, Karen J. Edler
The size of cationic micelles in a pTSA based deep eutectic solvent can be tuned by changing the solvent composition, which alters the surfactant–solvent interactions.
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Tailored carbon dioxide capacity in carboxylate-based ionic liquids

Faraday Discuss., 2024, 253,233-250
DOI: 10.1039/D4FD00052H, Paper
Nicolas Scaglione, Jocasta Avila, Agilio Padua, Margarida Costa Gomes
Tetraalkylphosphonium carboxylate ionic liquids absorb large quantities of carbon dioxide and are easily regenerated.
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Ion transport in polymerized ionic liquids: a comparison of polycation and polyanion systems

Faraday Discuss., 2024, 253,426-440
DOI: 10.1039/D4FD00070F, Paper
Open Access
Javad Jeddi, Jukka Niskanen, Benoît H. Lessard, Joshua Sangoro
Four model 1,2,3-triazole-based polyILs with polycation or polyanion backbones, are investigated to understand the impact of mobile ion types and backbone chemical structure.
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Chemical models for dense solutions

Faraday Discuss., 2024, 253,79-99
DOI: 10.1039/D4FD00084F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
J.-F. Dufrêche, B. Siboulet, M. Duvail
Here we examine the question of the chemical models widely used to describe dense solutions, particularly ionic solutions.
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Concluding remarks: Dense ionic fluids: because sometimes, more is more

Faraday Discuss., 2024, 253,510-523
DOI: 10.1039/D4FD00150H, Paper
Rob Atkin
A DIF is a electrolyte where the ion–ion distance is smaller than the Bjerrum length, causing strong electrostatic coupling in correlated domains. Ionic domains may be interspersed with non-polar or immiscible regions.
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Nafion coated nanopore electrode for improving electrochemical aptamer-based biosensing

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00144C, Paper
Open Access
Grayson F. Huldin, Junming Huang, Julius Reitemeier, Kaiyu X. Fu
Nafion blocks the aptamer's active sites from planar gold, while the aptamer retains its redox activity from nanoporous gold.
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Adsorption and vibrational spectroscopy of CO on the surface of MgO from periodic local coupled-cluster theory

Faraday Discuss., 2024, 254,628-640
DOI: 10.1039/D4FD00041B, Paper
Open Access
Hong-Zhou Ye, Timothy C. Berkelbach
Local correlation allows accurate periodic CCSD(T) calculations to be efficiently performed for molecules on realistic surfaces with large basis sets, yielding accurate adsorption energies and vibrational frequencies.
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Challenges with relativistic GW calculations in solids and molecules

Faraday Discuss., 2024, 254,216-238
DOI: 10.1039/D4FD00043A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gaurav Harsha, Vibin Abraham, Dominika Zgid
Accurate electronic-structure calculations for molecules and solids with heavy elements require an interplay of electronic correlations and relativistic effects. However, this tedious task poses problems for the existing quantum chemistry machinery.
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Classification and quantitative characterisation of the excited states of π-conjugated diradicals

Faraday Discuss., 2024, 254,107-129
DOI: 10.1039/D4FD00055B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lujo Matasović, Hugo Bronstein, Richard H. Friend, Felix Plasser
A detailed classification scheme for the excited states of diradicals is presented highlighting the connections between the states of closed-shell and open-shell molecules.
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Rapidly convergent quantum Monte Carlo using a Chebyshev projector

Faraday Discuss., 2024, 254,429-450
DOI: 10.1039/D4FD00035H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zijun Zhao, Maria-Andreea Filip, Alex J. W. Thom
We present a series of algorithmic changes that can be used to accelerate the MR-CCMC algorithm in particular and QMC algorithms in general.
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Spiers Memorial Lecture: Quantum chemistry, classical heuristics, and quantum advantage

Faraday Discuss., 2024, 254,11-52
DOI: 10.1039/D4FD00141A, Paper
Open Access
Garnet Kin-Lic Chan
We describe the problems of quantum chemistry, the intuition behind classical heuristic methods used to solve them, a conjectured form of the classical complexity of quantum chemistry problems, and the subsequent opportunities for quantum advantage.
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Restoring translational symmetry in periodic all-orbital dynamical mean-field theory simulations

Faraday Discuss., 2024, 254,641-652
DOI: 10.1039/D4FD00068D, Paper
Open Access
Jiachen Li, Tianyu Zhu
The use of overlapping atom-centered impurity fragments in recently-developed ab initio all-orbital DMFT, where all local orbitals within the impurity are treated with high-level quantum chemistry impurity solvers, is investigated.
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Introducing electron correlation in solid-state calculations for superconducting states

Faraday Discuss., 2024, 254,598-611
DOI: 10.1039/D4FD00073K, Paper
Wilver A. Muriel, Trinidad Novoa, Carlos Cárdenas, Julia Contreras-García
The superconducting electron localization can be obtained from a common solid-state calculation, where correlation is introduced as a redistribution of electrons around the Fermi level. This is applied to two typical superconductors, H3S and LaH10.
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Stochastic and low-scaling techniques/extended systems: general discussion

Faraday Discuss., 2024, 254,570-585
DOI: 10.1039/D4FD90043J, Discussion
Ali Alavi, Kemal Atalar, Timothy C. Berkelbach, George H. Booth, Ji Chen, Don Danilov, Werner Dobrautz, Francesco A. Evangelista, Gaurav Harsha, Venkat Kapil, Ke Liao, Pierre-François Loos, Krishna Reddy Nandipati, Felix Plasser, Andrew W. Prentice, Markus Reiher, Brenda Rubenstein, Benjamin Xu Shi, Alex J. W. Thom, Zikuan Wang, Carlos Mejuto-Zaera, Dominika Zgid, Martijn A. Zwijnenburg
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Stochastic and low-scaling techniques: general discussion

Faraday Discuss., 2024, 254,451-499
DOI: 10.1039/D4FD90042A, Discussion
Ali Alavi, Marcus Allen, Kemal Atalar, Timothy C. Berkelbach, George H. Booth, Hugh G. A. Burton, Garnet Kin-Lic Chan, Luca Craciunescu, Don Danilov, Werner Dobrautz, Francesco A. Evangelista, Maria-Andreea Filip, Emmanuel Giner, Gabriel Greene-Diniz, Andreas Grüneis, Yang Guo, Gaurav Harsha, Basil Ibrahim, Venkat Kapil, Daniel Kats, Peter J. Knowles, Marie-Bernadette Lepetit, Ke Liao, Giovanni Li Manni, Pierre-François Loos, Erika Magnusson, Antoine Marie, Carlos Mejuto-Zaera, Frank Neese, Arman Nejad, Verena A. Neufeld, Katarzyna Pernal, Felix Plasser, Andrew W. Prentice, Visagan Ravindran, Umatur Rehman, Markus Reiher, Christian Schilling, Gustavo Scuseria, James Shee, Benjamin X. Shi, Kalman Szenes, David P. Tew, Alex J. W. Thom, Zikuan Wang, Dominika Zgid, Andrew Zhu, Martijn A. Zwijnenburg
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DNA TV Show: Baba Bageshwar calls for Hindu unity on Social Media

Baba Bageshwar's message asks for a similar expression in the digital world by adding "Hindu" to social media names.




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DNA TV Show: Public calls out celebrities' hypocrisy on Diwali pollution

Many well-known figures have taken to their platforms to condemn fireworks, emphasizing the harmful effects on air quality and the anxiety caused to pets and wildlife.




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Nelson of all Nelsons in Cricket: Remembering South Africa 11/11, when they needed 111 runs at 11:11 am on 11/11/11

Umpire Ian Gould humorously suggested that players and fans stand on one leg for a minute to honour what has been dubbed "the Nelson of all Nelsons"




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IND vs AUS: Gautam Gambhir confirms Jasprit Bumrah as India captain if Rohit Sharma misses Perth Test

The opening match is scheduled to begin on November 22 in Perth.




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Rashid Khan narrowly escapes serious head injury during AFG vs BAN, WATCH viral video

The incident involving Rashid Khan and Rahmanullah Gurbaz occurred during the third ODI between Afghanistan and Bangladesh at Sharjah Cricket Stadium on Monday, November 11.




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Maharashtra polls: Congress suspends seven more rebel candidates

The newly suspended leaders include -- Shamkant Saner, Rajendra Thakur, Aba Bagul, Manish Anand, Suresh Kumar Jethliya, Kalyan Borade, and Chandrapaul Chauksey.




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Big blow to former JD(S) MP Prajwal Revanna as SC denies bail in rape case

On May 31, he was arrested from Bengaluru airport by CID's SIT on his return from Germany where he remained for 35 days after hundreds of explicit videos surfaced allegedly featuring him with multiple women. He lost the Lok Sabha election by over 40,000 votes.




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Delhi air pollution: No relief for Delhi-NCR as air quality remains in 'very poor' category; AQI breaches 400-mark in...

Some of the areas worst affected by air pollution included Wazirpur (AQI at 421), Jahangirpuri (419) and Anand Vihar (403), where the air quality dropped to 'severe' levels.




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Delhi reports record high chikungunya, malaria cases in 5 years

The number of chikungunya cases in 2020 stood at 111, in 2021, there were 89 cases, in 2022, 48 cases, and in 2023, 65 cases.