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Sip Or Skip : Meet The Boss Who Swears By The Coffee Cup Test In Interviews!

Can a coffee cup determine your success at an interview? Well, we've all been there; nervously sitting in a job interview, knowing that our future hangs in the balance. Some interviews are tough, while others might feel surprisingly straightforward. Here an




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How To Set Boundaries Like A Pro : Master The Art Of Saying No

"Good Morning Priya", wished Suzanne, her colleague who had just entered the office. She was late to the office as she always was most of the days. "Good Morning Suzanne", she wished back with a smile. Priya was under a lot




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Old Flames, New Friends : Can Friendship Rise From The Ashes Of Romance Years Later

"Congratulations and celebrations!" Justin's friends shouted in unison, raising their glasses in a toast as they gathered in a cosy corner of the reception hall. It was Justin's intimate wedding reception, and his closest friends from school, college, and work were




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Google Winter Internship 2025: Once-in-a-Lifetime Opportunity for Future Software Engineers

Dream of Working at Google? If you're a final-year student with a passion for software engineering, Google's Software Engineering Winter Internship for 2025 could be your gateway to a remarkable career! Aimed at students in their last year of




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IIT Dhanbad Offers Scholorship for Students 2024

IIT Dhanbad has designed a wide-ranging scholarship program to support students from all walks of life, enabling them to focus on their studies and achieve their academic dreams. These scholarships are available across various programs like BTech, Dual Degree,




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KU Law Students Protest for Postponement of Exams

Law students from the University of Kashmir are calling out what they consider an "unjust" and "premature" exam schedule, sparking a plea for academic fairness. These BA.LL.B 10th semester and LL.B 6th semester students argue that exams set to begin




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Royal Enfield Himalayan 450 Rally Spotted Ahead Of EICMA Debut

The Royal Enfield Himalayan 450 Rally has been spotted in all its glory ahead of its debut at EICMA 2024 tomorrow in Milan. The 450 Rally was spied at the Royal Enfield booth at the EICMA 2024 show by Instagram user




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Hero Xtreme 250 R Teased Before EICMA Unveil: Follows Design Of Xtunt 2.5R

Hero is set to showcase another motorcycle at EICMA which is based on the 2.5R Xtunt bike. This is another 250cc motorcycle that they will include in their lineup. The teaser of this has also been revealed on their social media




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LFAT 2016: University of Allahabad Releases Exam Dates

The examination dates for LFAT 2016 has been released by the University Of Allahabad (AU), Allahabad. LFAT 2016 is scheduled to be held from May 25, 2016. LFAT 2016 is held for admissions into 5 year integrated Bachelor of Arts Bachelor




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Discover The Benefits Of Vehicle Tracking Systems For Enhanced Security & Management

In today's fast-paced world, vehicle security is paramount. Automobile enthusiasts in India are increasingly turning to vehicle tracking systems. These systems offer a range of benefits that enhance both safety and convenience. By understanding these advantages, car owners can make informed




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Nissan Formula E Team Completes Successful Pre-Season Testing Ahead Of Season 11

Nissan Formula E Team completes pre-season testing in Madrid, focusing on new GEN3 Evo cars and strategies for the upcoming championship.




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Volkswagen Unveils Enhanced Offer Structure For 2025 Golf GTI And Golf R Models

Discover the refreshed offer structure for the 2025 Volkswagen Golf GTI and Golf R, featuring enhanced performance and modern designs.




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Hyundai And Children’s Of Alabama Strengthen Commitment To Child Passenger Safety Through Community Events

Hyundai and Children’s of Alabama continue their partnership to promote child passenger safety, providing resources and inspections for families.




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Hyundai IONIQ 9 SUV Showcases Spacious Lounge-like Interior Ahead Of Premiere

Discover the Hyundai IONIQ 9's spacious lounge-like interior designed for comfort and versatility, set to premiere in Los Angeles this November.




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University of Hull invited applications for MBA Programmes; Check Details Here

The University of Hull, opened the online applications for online master of business administration. The two year MBA global course is available in both online as well as part time and aims to equip the students with expertise and tools required.




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The electrochemical modulation of single molecule fluorescence

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00111G, Paper
Ying Yang, Yuanqing Ma, J. Justin Gooding
We demonstrate how to effectively modulate the fluorescence intensity of organic dye-labelled cell samples on an indium tin oxide surface using electrochemistry with redox-active mediators present in an oxygen scavenger buffer.
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Ion current oscillation of polyelectrolyte modified micropipettes

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00135D, Paper
Tianyi Xiong, Wenjie Ma, Ping Yu
Ion current oscillation of polyelectrolyte modified micropipettes in pH gradients was discovered and regulated. The periodic switch between the protonated/deprotonated state of modified micropipettes contributed to the spontaneous ICO observation.
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Molecular sandwich-based DNAzyme catalytic reaction towards transducing efficient nanopore electrical detection of antigen proteins

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00146J, Paper
Lebing Wang, Shuo Zhou, Yunjiao Wang, Yan Wang, Jing Li, Xiaohan Chen, Daming Zhou, Liyuan Liang, Bohua Yin, Youwen Zhang, Liang Wang
A molecular sandwich-based DNAzyme catalytic reaction is capable of transducing detectable nucleic acids as a substitute for difficult to yield protein detection in complicated biological matrices, in a nanopore.
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Single-molecule electrochemical imaging of ‘split waves’ in the electrocatalytic (EC') mechanism

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00126E, Paper
Wandong Zhao, Jin Lu
Imaging the single molecule electrocatalytic (EC') process and correlating it with the conventional ensemble EC' mechanism.
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Electrochemiluminescence microscopy for the investigation of peptide interactions within planar lipid membranes

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00137K, Paper
Kaoru Hiramoto, Kosuke Ino, Ibuki Takahashi, Ayumi Hirano-Iwata, Hitoshi Shiku
We propose the use of electrochemiluminescence microscopy in a solution of [Ru(bpy)3]2+ and tri-n-propylamine to monitor alterations in lipid membranes due to peptide action.
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Ion concentration polarization causes a nearly pore-length-independent conductance of nanopores

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00148F, Paper
DaVante Cain, Ethan Cao, Ivan Vlassiouk, Tilman E. Schäffer, Zuzanna S. Siwy
The conductance and selectivity of low-aspect-ratio nanopores are almost independent of the length due to polarization effects controlled by the geometric and electrochemical properties of the whole (pore + reservoir) system.
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Revealing the diverse electrochemistry of nanoparticles with scanning electrochemical cell microscopy

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00115J, Paper
Lachlan F. Gaudin, Cameron L. Bentley
Through presenting and discussing these findings, this article seeks to highlight complications in single-NP SECCM experiments, particularly those arising from issues with sample preparation.
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Scanning electrochemical probe microscopy: towards the characterization of micro- and nanostructured photocatalytic materials

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00136B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Giada Caniglia, Sarah Horn, Christine Kranz
The feasibility of fabricating micro- and sub-micro-sized AFM probes based on Pt-B electrodeposition for the electrochemical detection of H2 evolution is demonstrated.
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Regulation of transmembrane current through modulation of biomimetic lipid membrane composition

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00149D, Paper
Zhiwei Shang, Jing Zhao, Mengyu Yang, Yuling Xiao, Wenjing Chu, Yilin Cai, Xiaoqing Yi, Meihua Lin, Fan Xia
A biomimetic lipid membrane was developed by integrating DNA nanowires with a two-dimensional nanofluid membrane. By manipulating the DNA content, the composition of the membrane can be controlled, thereby adjusting ion transport.
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Advanced algorithm for step detection in single-entity electrochemistry: a comparative study of wavelet transforms and convolutional neural networks

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00130C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ziwen Zhao, Arunava Naha, Nikolaos Kostopoulos, Alina Sekretareva
In this study, two approaches for step detection in single-entity electrochemistry data are developed and compared: discrete wavelet transforms and convolutional neural networks.
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Delivery of carbon dioxide to an electrode surface using a nanopipette

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00124A, Paper
Jaimy Monteiro, Harry Dunne, Kim McKelvey
A new scanning probe approach for the delivery of a gas-phase reactant to the surface of an electrocatalyst through a self-replenishing bubble located at the end of a scanning probe has been developed.
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Nanoscale visualization of the anti-tumor effect of a plasma-activated Ringer's lactate solution

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00116H, Paper
Open Access
Junichi Usuda, Kenshin Yagyu, Hiromasa Tanaka, Masaru Hori, Kenji Ishikawa, Yasufumi Takahashi
To characterize the anti-tumor effect of plasma-activated Ringer's lactate solutions, we used scanning ion conductance microscopy, using glass nanopipettes as probes, to visualize the structural changes of the cell surface.
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Charge-induced deformation of scanning electrolyte before contact

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00147H, Paper
Liang Liu
Deformation of liquid and gel electrolytes before touching the sample in SECCM and SGECM: equilibrium does not always exist.
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Observation of cavitation dynamics in viscous deep eutectic solvents during power ultrasound sonication

Faraday Discuss., 2024, 253,458-477
DOI: 10.1039/D4FD00031E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ben Jacobson, Shida Li, Paul Daly, Christopher E. Elgar, Andrew P. Abbott, Andrew Feeney, Paul Prentice
We characterise the development of cavitation structure in three deep eutectic solvents of increasing viscosity, and water, via high-speed imaging and parallel acoustic detection..
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Speciation of the proton in water-in-salt electrolytes

Faraday Discuss., 2024, 253,478-492
DOI: 10.1039/D4FD00027G, Paper
Kateryna Goloviznina, Alessandra Serva, Mathieu Salanne
In 21 m LiTFSI water-in-salt electrolyte, the proton forms species existing in bulk water (H3O+, H5O2+, etc.) as well as the HTFSI acid, known to be a superacid in water.
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Deep eutectic solvents on a tightrope: balancing the entropy and enthalpy of mixing

Faraday Discuss., 2024, 253,273-288
DOI: 10.1039/D4FD00048J, Paper
Adriaan van den Bruinhorst, Chiara Corsini, Guillaume Depraetère, Nithavong Cam, Agílio Pádua, Margarida Costa Gomes
We quantified the balance between excess enthalpy (interactions) and excess entropy (structure/disorder) of mixing that determines large melting point depressions in deep eutectic solvents (DESs), reformulating the role of hydrogen bonding in DESs.
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Cationic micelles in deep eutectic solvents: effects of solvent composition

Faraday Discuss., 2024, 253,26-41
DOI: 10.1039/D4FD00045E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Iva Manasi, Stephen M. King, Karen J. Edler
The size of cationic micelles in a pTSA based deep eutectic solvent can be tuned by changing the solvent composition, which alters the surfactant–solvent interactions.
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Machine learning-driven investigation of the structure and dynamics of the BMIM-BF4 room temperature ionic liquid

Faraday Discuss., 2024, 253,129-145
DOI: 10.1039/D4FD00025K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fabian Zills, Moritz René Schäfer, Samuel Tovey, Johannes Kästner, Christian Holm
We demonstrate a learning-on-the-fly procedure to train machine-learned potentials from single-point density functional theory calculations before performing production molecular dynamics simulations.
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Electric field induced associations in the double layer of salt-in-ionic-liquid electrolytes

Faraday Discuss., 2024, 253,365-384
DOI: 10.1039/D4FD00021H, Paper
Open Access
Daniel M. Markiewitz, Zachary A. H. Goodwin, Michael McEldrew, J. Pedro de Souza, Xuhui Zhang, Rosa M. Espinosa-Marzal, Martin Z. Bazant
We have developed a theory for the electrical double layer of salt-in-ionic liquids accounting for the thermoreversible association of ions into Cayley tree aggregates. We find that the solution becomes more aggregated at moderate positive voltages.
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Ion transport in polymerized ionic liquids: a comparison of polycation and polyanion systems

Faraday Discuss., 2024, 253,426-440
DOI: 10.1039/D4FD00070F, Paper
Open Access
Javad Jeddi, Jukka Niskanen, Benoît H. Lessard, Joshua Sangoro
Four model 1,2,3-triazole-based polyILs with polycation or polyanion backbones, are investigated to understand the impact of mobile ion types and backbone chemical structure.
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Exploring the structure of type V deep eutectic solvents by xenon NMR spectroscopy

Faraday Discuss., 2024, 253,118-128
DOI: 10.1039/D4FD00083H, Paper
Open Access
Matteo Boventi, Michele Mauri, Franca Castiglione, Roberto Simonutti
Type V deep eutectic solvents thymol : camphor, menthol : thymol and eutectic mixtures based on menthol : carboxylic acids with variable chain length, are investigated to clarify the peculiar nanostructure of these materials..
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Spiers Memorial Lecture: From cold to hot, the structure and structural dynamics of dense ionic fluids

Faraday Discuss., 2024, 253,11-25
DOI: 10.1039/D4FD00086B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Matthew S. Emerson, Raphael Ogbodo, Claudio J. Margulis
This article presents a perspective on what we think are key topics related to the structure and structural dynamics of ILs and to some extent high-temperature molten salts.
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Speciation and dipole reorientation dynamics of glass-forming liquid electrolytes: Li[N(SO2CF3)2] mixtures of 1,3-propane sultone or tetrahydrothiophene-1,1-dioxide

Faraday Discuss., 2024, 253,42-54
DOI: 10.1039/D4FD00050A, Paper
Yasuhiro Umebayashi, Erika Otani, Hikari Watanabe, Jihae Han
Li[(CF3SO2)2N] mixtures with propane sultone or sulfolane, newly termed as glass-forming liquid electrolytes, exhibited large-size aggregate (AGG) formation via speciation and dipole reorientation. The AGGs may be crucial for the unique Li+ conduction.
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Ionic fluids out of equilibrium: electrodeposition, dissolution, electron transfer, driving forces: general discussion

Faraday Discuss., 2024, 253,407-425
DOI: 10.1039/D4FD90036G, Discussion
Andrew P. Abbott, Rob Atkin, Margarida Costa Gomes, Jean-François Dufrêche, Christopher E. Elgar, Y. K. Catherine Fung, Kateryna Goloviznina, Alexis Grimaud, Benworth Hansen, Jennifer M. Hartley, Christian Holm, Alexei Kornyshev, Kevin R. J. Lovelock, Daniel M. Markiewitz, Joshua Maurer, Shurui Miao, Susan Perkin, Frederik Philippi, Bernhard Roling, Nicolas Schaeffer, Monika Schönhoff, David J. Sconyers, Neave Taylor, Kazuhide Ueno, Adriaan van den Bruinhorst, Masayoshi Watanabe, Yuki Yamada
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Adsorption and vibrational spectroscopy of CO on the surface of MgO from periodic local coupled-cluster theory

Faraday Discuss., 2024, 254,628-640
DOI: 10.1039/D4FD00041B, Paper
Open Access
Hong-Zhou Ye, Timothy C. Berkelbach
Local correlation allows accurate periodic CCSD(T) calculations to be efficiently performed for molecules on realistic surfaces with large basis sets, yielding accurate adsorption energies and vibrational frequencies.
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Gaussian processes for finite size extrapolation of many-body simulations

Faraday Discuss., 2024, 254,500-528
DOI: 10.1039/D4FD00051J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Edgar Josué Landinez Borda, Kenneth O. Berard, Annette Lopez, Brenda Rubenstein
We employ Gaussian processes to more accurately and efficiently extrapolate many-body simulations to their thermodynamic limit.
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Accelerated basis-set convergence of coupled-cluster excitation energies using the density-based basis-set correction method

Faraday Discuss., 2024, 254,315-331
DOI: 10.1039/D4FD00033A, Paper
Diata Traore, Julien Toulouse, Emmanuel Giner
We present the first application to real molecular systems of the recently proposed linear-response theory for the density-based basis-set correction method [J. Chem. Phys., 158, 234107 (2023)].
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Classification and quantitative characterisation of the excited states of π-conjugated diradicals

Faraday Discuss., 2024, 254,107-129
DOI: 10.1039/D4FD00055B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lujo Matasović, Hugo Bronstein, Richard H. Friend, Felix Plasser
A detailed classification scheme for the excited states of diradicals is presented highlighting the connections between the states of closed-shell and open-shell molecules.
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Fast and accurate nonadiabatic molecular dynamics enabled through variational interpolation of correlated electron wavefunctions

Faraday Discuss., 2024, 254,542-569
DOI: 10.1039/D4FD00062E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kemal Atalar, Yannic Rath, Rachel Crespo-Otero, George H. Booth
Efficient multi-state interpolation of many-body wavefunctions enables rigorous nonadiabatic molecular dynamics with analytical forces and nonadiabatic coupling vectors.
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Striking the right balance of encoding electron correlation in the Hamiltonian and the wavefunction ansatz

Faraday Discuss., 2024, 254,359-381
DOI: 10.1039/D4FD00060A, Paper
Open Access
Kalman Szenes, Maximilian Mörchen, Paul Fischill, Markus Reiher
We present a discussion of explicit correlation approaches which address the nagging problem of dealing with static and dynamic electron correlation in multi-configurational active-space approaches.
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DNA TV Show: Terror threat in Delhi after Rohini blast? Police tighten security ahead of Diwali

Many revelations are being made in the investigation of this bomb blast. The connection of the blasts is also being linked to Khalistan.




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DNA TV Show: Why RBI increasing gold reserves amid record high price of yellow metal

By the end of September, the RBI had a total of 855 tonnes of gold, of which 510.5 tonnes were kept safe within India.




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DNA TV Show: Why thousands of aspirants protested against UPPSC in Prayagraj

For the first time, the UPPSC has scheduled UP PCS and RO/ARO examinations in two days.




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Nelson of all Nelsons in Cricket: Remembering South Africa 11/11, when they needed 111 runs at 11:11 am on 11/11/11

Umpire Ian Gould humorously suggested that players and fans stand on one leg for a minute to honour what has been dubbed "the Nelson of all Nelsons"




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Meet Ayush Mhatre, 17-year-old Mumbai batter who impressed MS Dhoni, CSK ahead of IPL 2025 mega auction

Ayush has reportedly been called for CSK trials after the 5th round of the Ranji Trophy.