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Small-sized starch nanoparticles for efficient penetration of plant cells

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05493H, Communication
Yongxian Chen, Simin Jiang, Yang Wang, Fuxue Zhang, Liu Wang, Li Zhao, Siyu Liu, Junjun Tan, Staffan Persson, Bo Sun, Junsheng Chen, Andreas Blennow
Fluorescent starch nanoparticles used in live cell imaging in plants suggest that small-sized starch nanoparticles can efficiently penetrate plant cells, indicating great potential for applications in plant science and agriculture.
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Visible light-activated polyphenol–Al3+ coordination for ambient and quantitative xylose-to-furfural conversion

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04899G, Communication
Jinshu Huang, Qizhi Luo, Tengyu Liu, Song Yang, Hu Li
Visible light-enhanced coordination of polyphenol–Al3+ is uncovered to switch Lewis/Brønsted acid sites for room-temperature cascade upgrading of xylose to furfural in ultrahigh yields.
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Pyrazolate-supported Cr3(μ3-O) cores; homovalent CrIII3 and mixed-valent CrIII2CrIV

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05161K, Communication
Jessica M. López-Plá, Mohammed Obies, Georgia Zahariou, Michael Pissas, Yiannis Sanakis, John E. McGrady, Raphael G. Raptis
The thermally assisted reaction of Cr(NO3)3·9H2O, 4-Cl-pzH, and Et3N yielded electrochemically active trinuclear CrIII–oxo–pyrazolate complexes with formula (Ph4P)2[Cr3(μ3-O)(μ-4-Cl-pz)6X3], X = Cl (1) and Br (2).
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Directed nucleophilic aromatic substitution reaction

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04912H, Communication
Yasuyuki Nitta, Takashi Nishikata, Michinori Sumimoto, Yusei Nakashima
In this study, we discovered a directed nucleophilic aromatic substitution reaction, "directed SNAr (dSNAr)", in the reaction of ortho-iodobezamides and amine in the presence of pyridine. The reaction proceeded ortho-specifically...
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Fabrication of gelatin hydrogels using pre-coordinated lanthanide complexes via imine crosslinking

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03886J, Communication
Chen-Cheng Yu, Yu Yun Hsu, Yu-Chia Su, Yi-Chen Yang, Tzu-Ying Wang, Yi-Cheun Yeh
Precoordinated lanthanide-containing complexes are used to crosslink polyethyleneimine-modified gelatin to form gelatin hydrogel through imine bond formation.
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Hydrazone-linked Covalent Organic Frameworks for Fluorescence Detection of Hg2+

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05468G, Communication
Xuefeng Wang, Zhaowei Yang, Lingsuo Meng, Xuehui Li, Hongtao Wei, Jing Ning, Shitao Wang, Dapeng Cao, Long Hao
A hydrazone-linked COF (DvDf-C3XJ-COF) with hydrogen-bond reinforcement and abundant coordination sites was synthesized, exhibiting strong fluorescence and high sensitivity/selectivity for Hg²⁺ detection, with a detection limit of 1.65 × 10⁻⁶...
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From one to two: In-site constructing C3N5-Poly (triazine imide) heterojunction for enhanced O2 activation

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05077K, Communication
Shiling Xu, Ziheng Yang, Laiqing Zhang, Xiaorui Zhang, Zikang Zeng, Wenxuan Wang, Yujun Liang, Lan Yuan, Chuang Han
A novel C3N5-Poly (triazine imide) (PTI) heterojunction was designed and constructed by thermal polymerization process, which featured with intimated S-scheme interface coupling and exhibited a predominant performance for H2O2 production....
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Interlayer spacing expansion for V2O5 towards ultra-stable zinc anode-based flexible electrochromic displays in Zn2+/Li+-PC organic electrolyte

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04974H, Communication
Zhe Li, Zhaoyang Song, Linhua Liu, William Yu, Jingwei Chen, Qianqian Zhu, Haizeng Li
To enhance the electrochemical stability and kinetics of V2O5, 3,4-ethylenedioxythiophene (EDOT) was in-situ polymerized within V2O5 interlayers, rendering PEDOT@V2O5 with enlarged layer spacing, increased stability in organic electrolyte, superior electrochemical...
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Electrocatalytic reduction of N2 to NH3 by MIL-88 derived pod-like Fe7Se8/C nanomaterials under ambient conditions

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04683H, Communication
Gongyao Nie, Huanhuan Zhang, Lanhua Yi, Xiao Ma, Wei Yi, Jiawei Wan, Yebo Lu, Xingzhu Wang
In this paper, pod-like Fe7Se8/C nanocomposite catalyst materials were prepared by MIL-88 selenide annealing and the as-prepared Fe7Se8/C nanocatalyst exhibited excellent electrocatalytic performance in neutral electrolyte for electrocatalytic nitrogen reduction...
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Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05173D, Communication
Bing Zeng, Yuexin Wang, Kanghui Xiong, Keke Zhang, Siyu Zhang, Xianjun Lang
A catalytic amount of TEMPO, mobile in the reaction medium, enhances the hole transfer of NU-1003 photocatalysis for blue light-powered oxidation of organic sulfides with O2.
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Crystal-Facet Modulated Pathway of CO2 Photoreduction on Bi4NbO8Cl Nanosheets Boosting Production of Value-Added Solar Fuels

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05581K, Communication
Yong Zhou, Haoqiang Chi, Zhengdao Li, Yong Cai Zhang, Zhigang Zou, Yong Yang, Xinxin Lu, Peiting Hao
Two ultrathin nanosheets of Bi4NbO8Cl were successfully synthesized for photocatalytic conversion of CO2 into solar fuel. featuring differently exposed (001) and (201) facets. In contrast to bulk Bi4NbO8Cl, which produced...
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Engineering biotin anchored-MWCNTs as a superb carrier for facile delivery of the potent Ru(II)-N^N scaffold in breast cancer cells

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Chem. Commun., 2024, 60,13376-13379
DOI: 10.1039/D4CC04276J, Communication
Lavanya Thilak Babu, Nilmadhab Roy, Tiasha Dasgupta, Sreejani Ghosh, Ramasamy Tamizhselvi, Priyankar Paira
This article portrays the construction of biotinylated-MWCNTs for SMVT-guided delivery of a potent Ru(II)-scaffold into MCF7 cells.
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Revealing the structural influence mechanism of intrinsic potassium/calcium elements on bio-waste-derived hard carbon for sodium-ion batteries

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Chem. Commun., 2024, 60,13380-13383
DOI: 10.1039/D4CC03546A, Communication
Yinghao Zhang, Chun Wu, Qinghang Chen, Chuangchuang Li, Wenjie Huang, Qianxiong Wen, Xiang-Xi He, Xingqiao Wu, Shu-Lei Chou
The evolution mechanism of hard carbon structures in terms of graphitization and pore structure caused by K/Ca has been clarified.
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Nitrogen-doped graphene quantum dot-intensified tungsten oxide nanosheets as a SERS substrate for antibiotics detection

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Chem. Commun., 2024, 60,13360-13363
DOI: 10.1039/D4CC05052E, Communication
Lu Tan, Xuanzhao Lu, Shuzhen Yue, Yue Cao, Yang Zhou, Baokang Jin, Jun-Jie Zhu
Tungsten oxide nanosheets loaded with nitrogen-doped graphene oxide quantum dots (NGQDs/WO3 NSs) were fabricated as SERS substrates.
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Catalytic asymmetric Michael and Nef-type sequential reaction of nitroolefin with azlactone to construct oxazole-fused succinimide

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Chem. Commun., 2024, 60,13384-13387
DOI: 10.1039/D4CC04858J, Communication
Rui Weng, Yuqiao Zhou, Yaqin Zhang, Xiaoming Feng, Xiaohua Liu
A series of oxazole-fused succinimides bearing vicinal quaternary carbon centers were synthesized via catalytic asymmetric Michael addition and Nef-type sequential reactions of nitroolefins with azlactones.
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Employing a PhI(OAc)2-mediated domino reaction to assemble nitrogen-containing heterocyclic derivatives and assessing their anti-inflammatory activity

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Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication
Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)2 at 23 °C.
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Mn and Mo co-doped NiS nanosheets induce abundant Ni3+–O bonds for efficient electro-oxidation of biomass

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Chem. Commun., 2024, 60,13392-13395
DOI: 10.1039/D4CC04818K, Communication
Pengfei Ren, Zixuan Wang, Wenchao Zhang, Fang Duan, Shuanglong Lu, Mingliang Du, Han Zhu
MnMo–NiS were synthesized for electro-oxidizing ethylene glycol (EG), glycerol (GLY), and 5-hydroxymethylfurfural (HMF), achieving faradaic efficiencies of 97.5%, 98.6%, and 99.2%, and yield rates of 615.7, 475.5, and 333.9 μmol h−1 cm−2.
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A polychloride-enabled synthesis of [NEt3Me][PCl6] serving as a potential PCl3-storage and PCl5-reagent

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Chem. Commun., 2024, 60,13372-13375
DOI: 10.1039/D4CC04319G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Moritz J. Ernst, Merlin Kleoff, Patrick Voßnacker, Günther Thiele, Christian Müller, Sebastian Riedel
The reaction of the ionic liquid [NEt3Me][Cl3] with white phosphorus (P4) gives, quantitatively, hexachlorophosphate [NEt3Me][PCl6], which shows similar reactivity as PCl5 and can be used as a potential PCl3-storage material.
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PVDF nanocomposites with aligned boron nitride nanosheets and dispersed BaTiO3@PEG nanoparticles by a superspreading strategy towards high energy density

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Chem. Commun., 2024, 60,13344-13347
DOI: 10.1039/D4CC04430D, Communication
Dajun Hou, Jingjing Zhou, Wen Chen, Jing Zhou, Pengchao Zhang
The limited improvement in discharge energy density (Ue) of polyvinylidene fluoride (PVDF) nanocomposites filled with low-dielectric-constant (εr) nanosheets has been addressed by using a superspreading layering strategy.
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Ion induced ultra-tough single-network ionogel

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Chem. Commun., 2024, 60,13388-13391
DOI: 10.1039/D4CC04732J, Communication
Zhenchuan Yu, Biaolong Ma, Jiqiang Wang
A strategy to fabricate ultra-tough ionogels by ionic induction is proposed, which provides a simple and general method for tuning ionogel properties.
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Efficient electrocoupling of CO2 and N2 to urea by a gas-penetrable Bi nanosheet-wrapped Cu hollow fiber

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Chem. Commun., 2024, 60,13420-13423
DOI: 10.1039/D4CC04595E, Communication
Jinning Wang, Yuyu Wang, Fang Wang, Jinfu Ma, Zhengguo Zhang, Shixiong Min
A gas-penetrable electrode of Bi nanosheet-wrapped Cu hollow fiber (Bi NSAs@Cu HF) exhibits high activity and stability for urea production from the electrocoupling of CO2 and N2.
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Sb nanoparticles embedded uniformly on the surface of porous carbon fibres for high-efficiency sodium storage

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Chem. Commun., 2024, 60,13428-13431
DOI: 10.1039/D4CC04806G, Communication
Yafei Zhao, Kai Xue, Xinyu Liu, Zhiyuan Gao, Junhao Zhang, Yuanjun Liu, Xiangjun Zheng, ZhongYao Duan, Qianqian Fan, Xingmei Guo
Sb nanoparticles (∼5 nm) are embedded uniformly on the surface of carbon fibers to prepare Sb NPs–SCFs, which exhibit excellent sodium storage with a stable capacity of 381.9 mA h g−1 at 1.0 A g−1 after 200 cycles, due to their unique structure.
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Sulfonated hierarchical ZSM-5 zeolite monoliths as solid acid catalyst for esterification of oleic acid

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Chem. Commun., 2024, 60,13356-13359
DOI: 10.1039/D4CC05044D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Binhang Zhao, Pan Yang, Nan Zhang, Donald R. Inns, Elena F. Kozhevnikova, Alexandros P. Katsoulidis, Ivan V. Kozhevnikov, Alexander Steiner, Haifei Zhang
Sulfonated hierarchical H-ZSM-5 monoliths were synthesized via ice-templating as solid acid catalysts for biodiesel production.
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Expedient (3+3)-annulation of carbonyl ylides with azaoxyallyl cations: formal access to oxa-benzo[c]azepin-3-ones

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Chem. Commun., 2024, 60,13368-13371
DOI: 10.1039/D4CC04946B, Communication
Kshitiz Verma, Hemanga Bhattacharyya, Sharajit Saha, Tharmalingam Punniyamurthy
Cascade C–C/C–N bond formation of carbonyl ylides with azaoxyallyl cations generated in situ using Rh-catalysis has been accomplished in the presence of a base at room temperature.
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Polymeric membrane ion-selective electrode based on potential-modulated ion transfer: ultrasensitive measurement of oceanic pH

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Chem. Commun., 2024, 60,13404-13407
DOI: 10.1039/D4CC04807E, Communication
Lu Liu, Yuanxin Liu, Tianjia Jiang, Rongning Liang, Wei Qin
A simple approach to improve the precision of potentiometric sensors is proposed based on potential-modulated ion transfer without memory effects.
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Bipyridine-based conjugated microporous polymers for boosted photocatalytic U(VI) separation

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Chem. Commun., 2024, 60,13348-13351
DOI: 10.1039/D4CC04456H, Communication
Yun Xie, Zifan Li, Chenchen Liu, Qiming Song, Yunhai Liu, Zhibin Zhang, Bin Han
Incorporating bipyridine (BPY) units into conjugated microporous polymers (CMPs) boosts exciton dissociation, charge separation, and oxidation capacity, thereby exhibiting an admired U(VI) separation rate under sacrificial agent-free conditions.
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Universal synthesis of pure-phase IB-group Sn-based alloys with modulable electrocatalytic CO2 reduction products

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Chem. Commun., 2024, 60,13436-13439
DOI: 10.1039/D4CC05317F, Communication
Luyao Yang, Wenqing Zhang, Ximei Lv, Qianqian Zhao, Xiaojing Liu, Shulin Zhao, Yuhui Chen
A universal method for synthesizing a range of pure-phase IB-group Sn-based alloy catalysts (Cu3Sn, Ag4Sn, and AuSn) for electrochemical reduction of CO2.
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Constructing efficient organic solar cells by highly volatile solid additives with controlled phase morphology

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Chem. Commun., 2024, 60,13424-13427
DOI: 10.1039/D4CC04675G, Communication
Yueheng Liu, Yetai Cheng, Shenbo Zhu, Zhengdong Wei, Chenyi Zhang, Shuyue Song, Xinyue Cui, Ya-Nan Chen, Andong Zhang, Yahui Liu, Hao Lu, Huawei Hu, Zhishan Bo
We synthesized two highly volatile and low-cost solid additives, PT and TFT.
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Ultrafine PtCo alloy nanoparticles integrated into porous N-doped nanosheets for durable oxygen reduction reaction

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Chem. Commun., 2024, 60,13432-13435
DOI: 10.1039/D4CC04661G, Communication
Baoliang Chen, Lei Zhao, Zhaozhao Zhu, Pei Xiong, Zhao Li, Jun Song Chen, Lanlan Li, Rui Wu
The PtCo–CoNC–P catalyst, featuring sub-3 nm small-size PtCo alloy nanoparticles integrated into a porous nitrogen-doped nanosheet, exhibits exceptional durability after 30 000 cycles of accelerated durability tests.
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Functional metal–organic frameworks derived electrode materials for electrochemical energy storage: a review

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Chem. Commun., 2024, 60,13292-13313
DOI: 10.1039/D4CC04086D, Highlight
Basree, Arif Ali, Khusboo Kumari, Musheer Ahmad, Ganesh Chandra Nayak
Pristine MOFs and their derivatives have been proven for supercapacitor as well as energy storage due to their versatile features like huge specific surface area, high porosity, redox active metal centre, high thermal stability, and so on.
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Solid-state synthesis of ligand-assisted lead halide nanoclusters

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Chem. Commun., 2024, 60,13396-13399
DOI: 10.1039/D4CC04623D, Communication
David C. Zeitz, Kai-Chun Chou, Jin Z. Zhang
A solid-state synthesis of blue-emitting lead halide nanoclusters has been demonstrated for the first time.
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Atomistic insight into the promising thermoelectric performance of the copper-based ternary phosphide CaCuP

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Chem. Commun., 2024, 60,13400-13403
DOI: 10.1039/D4CC04660A, Communication
Un-Gi Jong, Chol Ryu, Ji-Min Hwang, Su-Hyang Kim, Il-Gwang Ju, Chol-Jun Yu
We provide a valuable atomistic insight into the thermoelectric properties of hexagonal CaCuP, revealing that nano-structuring can double the thermoelectric figure of merit by further reducing lattice thermal conductivity.
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Bioinspired hydrogels: polymeric designs towards artificial photosynthesis

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Chem. Commun., 2024, 60,13314-13324
DOI: 10.1039/D4CC04033C, Feature Article
Open Access
Reina Hagiwara, Ryo Yoshida, Kosuke Okeyoshi
This Feature Article outlines the design of polymer networks for water splitting induced by visible light to develop artificial chloroplasts. The network serves as a mediator for photoinduced electron transfer among precisely organised molecules.
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An effective orange-red solution-processed circularly polarized organic light-emitting diode

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04938A, Communication
Junqing Wang, Xiaoyi Lai, Yongzhi Zhou, Lei Hua, Weiguo Zhu, Pengfei Duan, Yafei Wang
Two orange-red emission circularly polarized thermally activated delayed fluorescence emitters (R)-ad-PXZ/(S)-ad-PXZ were synthesized. The solution processable device exhibits the maximum external quantum efficiency of 9.0% and gEL value of 10−3.
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A MOF-derived CuO/TiO2 photocatalyst for methanol production from CO2 reduction in an AI-assisted continuous flow reactor

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05008H, Communication
Bhavya Jaksani, Ruchi Chauhan, Switi Dattatraya Kshirsagar, Abhilash Rana, Ujjwal Pal, Ajay K. Singh
An AI-assisted continuous flow reactor for CO2 reduction to methanol using a MOF-derived CuO/TiO2 photocatalyst.
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Polarizable AMOEBA force field predicts thin and dense hydration layer around monosaccharides.

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04415K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Luke A Newman, Mackenzie G Patton, Breyanna A Rodriguez, Ethan W Sumner, Valerie Vaissier Welborn
Polarizable force fields crucially enhance the modeling of macromolecules in polar media. Here, we present new parameters to model six common monosaccharides with the polarizable AMOEBA force field. These parameters...
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Rapid and sensitive detection of vanillylmandelic acid based on a luminescent fourteen-metal Tb(III) planar nanocluster

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03667K, Communication
Yanheng Meng, Shiqing Wang, Xiaoli Lv, Xianfeng Huang, Wei-Bing Zhang, Xiaojun Wu, Desmond Schipper, Xiaoping Yang
A 14-metal Tb(III) nanocluster with four CO32- anions as templates was constructed for the quantitative and qualitative detection of vanillylmandelic acid (VMA) with high sensitivity and selectivity. The luminescence response...
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Palladium catalyzed C(sp3)-H alkylation of 8-methylquinolines with aziridines: access to functionalized γ-quinolinylpropylamines

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05275G, Communication
Anita Sahoo, Tripti Paul, Shubhajit Basak, Tharmalingam Punniyamurthy
Palladium-catalyzed directed site-selective C(sp3)-H alkylation of 8-methylquinolines has been accomplished using aziridine as an alkylating source via a sequential C-H and C-N bond activation. Site selectivity, funtional group tolerance and...
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Metal-free photocatalysts with charge-transfer excited states enable visible light-driven atom transfer radical polymerization

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04470C, Communication
Yuchen Huang, Yangxin Liu, Yingde Yan, Yanjun Gong, Yifan Zhang, Yanke Che, Jincai Zhao
Photoredox-catalyzed atom transfer radical polymerization (O-ATRP) offers powerful tools for the precise control of polymer synthesis. Metal-free photocatalysts are particularly desirable due to their high level of control in O-ATRP...
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Ceria-based supported metal catalysts for the low-temperature water-gas shift reaction

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04072D, Feature Article
Xin-Pu Fu, hui zhao, Chun-Jiang Jia
Water-gas shift (WGS) reaction is a crucial step for the industrial production of hydrogen or upgrading hydrogen generated from fossil or biomass sources by removing the residual CO. However, current...
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Base-Promoted Cascade 5-exo-dig Annulation/Carboxylation of o-(1-Alkynyl)benzenesulfonamides with CO2: Divergent Synthesis of Mono- or Gem-dicarboxylic Esters

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05239K, Communication
Yang Yao, Junxue Bai, Peidong Cheng, Han Yang, Jianwei Sun, Song Sun
A base-promoted cascade 5-exo-dig cyclization/carboxylation of o-alkynylsulfamides with CO2 has been accomplished, furnishing a variety of benzosultams-containing acrylates in good yields by using CO2 as the carboxylic source. Notably, in...
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Machine Learning Directed Discovery and Optimisation of a Platinum-Catalysed Amide Reduction

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05273K, Communication
Open Access
Eleonora Casillo, Benon Maliszewski, Cesar Blanco, Thomas Scattolin, Catherine Cazin, Steven P Nolan
The discovery and optimisation of reaction conditions leading to the reduction of amides, a fundamental large-scale industrial reaction, is achieved using a machine learning (ML) platform and a platinum catalyst....
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Sandwich structured Fe3O4@C@MoSe2 architecture for efficient lithium-ion storage

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04631E, Communication
Linan Yang, Chengjie Zhang, Liuyang Cao, Rong Xu, Hongbo Li, Zhanjun Yang, Juan Li
A unique sandwich structure Fe3O4@C@MoSe2 architecture is proposed for high-performance lithium storage. Carbon shell as the connection of in/external structures can not only improve the overall conductivity, but also alleviate...
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Tuneable Sulfonated Hypercrosslinked Polymers for Selective Esterification: Insights into Performance and Stability

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05208K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paul Schweng, Dorian Guerin-Faucheur, Freddy Kleitz, Robert Thomas Woodward
We report sulfonated hypercrosslinked polymers (SHCPs) as heterogeneous catalysts for the selective esterification of hexanoic acid with benzyl alcohol. The SHCPs demonstrate tuneable catalytic activity and selectivity, outperforming conventional acid...
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Axial oxygen-bridged FeN4O/NC produced by ultrafast joule heating for efficient oxygen reduction reaction

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05604C, Communication
Feng Liu, Xinyu Guo, Yan Zhong, Shaqi Fu, Jingsha Li, Chunmei Zhang, Heng Zhang, Fenghui Ye, Shuai Yuan, Chuangang Hu, Chunxian Guo
Herein, we report an atomically dispersed Fe-N-C catalyst with axial oxygen ligands (FeN4O/NC) firstly synthesized by ultrafast joule heating. The formation of oxygen species between FeN4 and graphene, which offers...
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Copper nanoclusters: emerging photoredox catalysts for organic bond formations

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04774E, Feature Article
Open Access
Arunachalam Sagadevan, Kathiravan Murugesan, Osman M. Bakr, Magnus Rueping
In this feature article, we provide an overview of the photocatalytic capabilities of copper-based nanoclusters for organic bond-forming reactions.
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A liquid-infiltrated Al2O3 framework electrolyte enables aqueous zinc batteries

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04928D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rongyu Deng, Yi Yuan, Zixuan Li, Feixiang Wu, Alex W Robertson
Aqueous zinc-ion battery anodes face the twin challenges of dendrite growth and severe side reactions. Here a liquid-infiltrated Al2O3 framework electrolyte (LIAFE) is developed to address these issues and enables...
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Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with axially chiral biaryl electrophiles

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04293J, Communication
Tiantian Yin, Shiyuan Sui, Shuqi Li, Junbiao Chang, Dachang Bai
Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with chiral biaryl electrophiles for the synthesis of axially chiral organosilanes.
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Laccase-catalyzed tyrosine click reaction with 1-methyl-4-arylurazole: rapid labeling on protein surfaces

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03802A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Keita Nakane, Chizu Fujimura, Shogo Miyano, Zhengyi Liu, Tatsuya Niwa, Hafumi Nishi, Tetsuya Kadonosono, Hideki Taguchi, Shusuke Tomoshige, Minoru Ishikawa, Shinichi Sato
Our study shows efficient tyrosine labeling using 1-methyl-4-arylurazole (MAUra) with laccase under mild conditions. This method achieves a high efficiency (kcat/Km = 7.88 × 104 M−1 s−1), selectively targeting exposed tyrosine sites on proteins.
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Iron-catalysed intramolecular C(sp3)–H amination of alkyl azides

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04169K, Feature Article
Open Access
Kai Wu, Chi-Ming Che
This review summarizes recent major advances in iron-catalysed C–H aminations of alkyl azides through iron–alkylnitrene/alkylimido intermediates to access various N-heterocycles.
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