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Origin of anisotropic thermal transport in CsPbBr3

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05037A, Communication
Open Access
Wilarachchige D. C. B. Gunatilleke, Oluwagbemiga P. Ojo, George S. Nolas
We reveal the specific structural and bonding features that result in anisotropic thermal transport for CsPbBr3 by directional single-crystal measurements and elucidate the bases for the low Debye temperature and speed of sound.
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Synthesis of substituent-free dioxadiaza[8]circulene to investigate intermolecular interactions and photophysical properties

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Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05539J, Communication
Aoi Nakagawa, Wataru Ota, Takumi Ehara, Yusuke Matsuo, Kiyoshi Miyata, Ken Onda, Tohru Sato, Shu Seki, Takayuki Tanaka
Substituent-free dioxadiaza[8]circulene has been synthesized and its dense packing structure and optical properties were analyzed in detail.
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Rapid identification of P–C bonds in phosphorus–carbon anode materials

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03317E, Communication
Yadong Ye, Qiang Xiao, Huanyu Xie, Hongchang Jin, Hengxing Ji
This work presents a simple, rapid, and convenient spectroscopic analysis method for characterizing the bonding state in phosphorus-carbon composites.
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Rapid and sensitive detection of vanillylmandelic acid based on a luminescent fourteen-metal Tb(III) planar nanocluster

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03667K, Communication
Yanheng Meng, Shiqing Wang, Xiaoli Lv, Xianfeng Huang, Wei-Bing Zhang, Xiaojun Wu, Desmond Schipper, Xiaoping Yang
A 14-metal Tb(III) nanocluster with four CO32- anions as templates was constructed for the quantitative and qualitative detection of vanillylmandelic acid (VMA) with high sensitivity and selectivity. The luminescence response...
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Palladium catalyzed C(sp3)-H alkylation of 8-methylquinolines with aziridines: access to functionalized γ-quinolinylpropylamines

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05275G, Communication
Anita Sahoo, Tripti Paul, Shubhajit Basak, Tharmalingam Punniyamurthy
Palladium-catalyzed directed site-selective C(sp3)-H alkylation of 8-methylquinolines has been accomplished using aziridine as an alkylating source via a sequential C-H and C-N bond activation. Site selectivity, funtional group tolerance and...
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Base-Promoted Cascade 5-exo-dig Annulation/Carboxylation of o-(1-Alkynyl)benzenesulfonamides with CO2: Divergent Synthesis of Mono- or Gem-dicarboxylic Esters

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05239K, Communication
Yang Yao, Junxue Bai, Peidong Cheng, Han Yang, Jianwei Sun, Song Sun
A base-promoted cascade 5-exo-dig cyclization/carboxylation of o-alkynylsulfamides with CO2 has been accomplished, furnishing a variety of benzosultams-containing acrylates in good yields by using CO2 as the carboxylic source. Notably, in...
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Machine Learning Directed Discovery and Optimisation of a Platinum-Catalysed Amide Reduction

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Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05273K, Communication
Open Access
Eleonora Casillo, Benon Maliszewski, Cesar Blanco, Thomas Scattolin, Catherine Cazin, Steven P Nolan
The discovery and optimisation of reaction conditions leading to the reduction of amides, a fundamental large-scale industrial reaction, is achieved using a machine learning (ML) platform and a platinum catalyst....
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Synthesis of Aryl Fluorocyclopropanes from Aryl Fluorodiazirines and Alkenes in Continuous Flow

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Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC01881H, Communication
Hoang-Minh To, Shima Mirakhorli, Thierry Ollevier
Photochemically induced generation of aryl fluorocarbene from arylfluorodiazirines and their subsequent [2 + 1] cycloaddition with alkenes was developed in continuous flow. The in situ generated electrophilic aryl fluorocarbene reacted...
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Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with axially chiral biaryl electrophiles

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Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04293J, Communication
Tiantian Yin, Shiyuan Sui, Shuqi Li, Junbiao Chang, Dachang Bai
Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with chiral biaryl electrophiles for the synthesis of axially chiral organosilanes.
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Iron-catalysed intramolecular C(sp3)–H amination of alkyl azides

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Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04169K, Feature Article
Open Access
Kai Wu, Chi-Ming Che
This review summarizes recent major advances in iron-catalysed C–H aminations of alkyl azides through iron–alkylnitrene/alkylimido intermediates to access various N-heterocycles.
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Positional effects of electron-donating and withdrawing groups on the photophysical properties of single benzene fluorophores

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04451G, Communication
Dopil Kim, Jun Yeong Kim, Haein Kim, Eunjin Jeong, Minhyuk Lee, Dongwook Kim, JunWoo Kim, Myung Hwan Park, Min Kim
We investigated how the positional arrangement of electron-donating (amino) and electron-withdrawing (ester) groups in single benzene-based fluorophores influences their emission properties. By synthesizing 26 regioisomeric fluorophores, we achieved wavelength modulation...
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Sustainable Production of Aromatic Chemicals from Lignin using Enzymes and Engineered Microbes

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05064A, Feature Article
Open Access
Timothy D.H. Bugg, Victoria Sodré
Lignin is an aromatic biopolymer found in plant cell walls, that is the must abundant source of renewable aromatic carbon in the biosphere. Hence there is considerable interest in the...
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For the love of legiyam

By www.thehindu.com
Published On :: Fri, 28 Oct 2016 16:49:22 +0530

SRINIVASA RAMANUJAM queues up to find out what goes into this Deepavali preparation at the iconic Dabba Chetty Shop in Mylapore


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Fragrance of composite culture

By www.thehindu.com
Published On :: Mon, 31 Oct 2016 15:34:20 +0530

Atiya Zaidi brings the flavours of the Doab to the city and leaves RAHUL VERMA licking his fingers


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The wonders of veganism

By www.thehindu.com
Published On :: Tue, 01 Nov 2016 15:27:50 +0530

The latest trend in the food space is going off milk and meat. Read on and find out where Bengaluru stands on this


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In the creative universe of Raghu Rai

By www.thehindu.com
Published On :: Thu, 10 Nov 2016 16:51:14 +0530

The internationally-acclaimed photographer tells us how he enjoys his work and food


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The call of kulchas

By www.thehindu.com
Published On :: Sat, 19 Nov 2016 15:42:55 +0530

Discover special Amritsari kulchas in Central Delhi


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A blend of old and new

By www.thehindu.com
Published On :: Sat, 19 Nov 2016 15:52:54 +0530

Karen Anand discusses the idea behind her Farmers’ Markets and memories of Hyderabad


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Coimbatore’s Kaapi 2.0 offers healthy snacks with strong filter coffee

By www.thehindu.com
Published On :: Sat, 27 Aug 2022 15:04:22 +0530

Kaapi 2.0, a new chain of minimalist cafes in the city, offers healthy snack options to munch on along with filter coffee


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With pop-up restaurants, chefs discover the joys of cooking flexible, seasonal menus

By www.thehindu.com
Published On :: Fri, 02 Sep 2022 19:47:26 +0530

A pandemic-prompted wave of pop-up kitchens has now become a creative way for independent chefs and edgy restaurants to travel, experiment and connect with diners


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Dawat-e-Hyderabadi with ladies of Luqma kitchen studio

By www.thehindu.com
Published On :: Sat, 24 Sep 2022 12:14:53 +0530

Traditional Hyderabadi dishes include much more than dum biryani, proves a team of women at Luqma kitchen studio


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Cloud kitchens make a mark in Thiruvananthapuram with pocket-friendly food and a wide range of cuisines

By www.thehindu.com
Published On :: Fri, 14 Oct 2022 13:12:55 +0530

Still ordering in, though lockdowns are over? You are not alone. As cloud kitchens juggle cuisines and experiment with new dishes from a single space, takeaway in Thiruvananthapuram gets more interesting every day


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Take home a piece of heritage at this Visakhapatnam sweet store

By www.thehindu.com
Published On :: Thu, 27 Oct 2022 15:10:47 +0530

Sarvani Sweets launches its series sweet boxes featuring some iconic heritage spots of Visakhapatnam


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Guardians of the galaxy, with fries

By www.thehindu.com
Published On :: Fri, 11 Nov 2022 19:12:45 +0530

Ciclo Café’s new venture, Big Burger Theory, introduces hampers of hefty space-themed burgers with unexpected frills from guacamole to Japanese curry


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Visiting Abu Dhabi this holiday season? Get a sense of the city’s growing luxury dining scene

By www.thehindu.com
Published On :: Tue, 22 Nov 2022 12:48:16 +0530

Abu Dhabi is rising as a culinary destination with an emphasis on luxury dining offering cuisine from across the globe


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Chances of infection: food safety squad continues aggressive checking in eateries

By www.thehindu.com
Published On :: Sun, 08 Jan 2023 18:14:53 +0530

Nearly 70 shops dealing with food-based business inspected; flash inspections conducted considering the crowd turnout for Kerala State School Kalolsavam


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At Kraft, a concept store in Chennai, shop for pendant lights and wall art over a meal of crispy keema dosas and Korean burgers

By www.thehindu.com
Published On :: Wed, 19 Apr 2023 17:54:36 +0530

Shop, eat, and try your hand at games at Kraft, the concept store that showcases around 60 different types of furniture and decor


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A healthy lunch bowl or gourmet food? Cloud kitchens in Coimbatore offer a diverse menu

By www.thehindu.com
Published On :: Tue, 23 May 2023 16:23:32 +0530

From gourmet food, and healthy bowls to vegetarian sushi and experimental cuisines, cloud kitchens in the city are offering intricate culinary experiences. We pick three of them and sample what they offer 


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The origins of the Bengali tradition of ‘cha-ta’ may be colonial

By www.thehindu.com
Published On :: Thu, 22 Jun 2023 20:59:07 +0530

Evenings snacks are a serious business with Bengali cha and the tradition may have something to do with the high tea of the Brits


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Two approaches to win an argument as a software engineer

By humanwhocodes.com
Published On :: Tue, 16 Mar 2021 00:00:00 +0000

If you’ve spent any time developing software professionally and then you are probably used to the spirited debates that take place between software engineers as well as between software engineers and management, design, and product. Software engineers are not known for being shy about their opinions on any particular subject, and especially when it comes...


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Enhanced glucose-responsivity of PBA–diol hydrogel networks by reducing crosslink affinity

By pubs.rsc.org
Published On ::

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00106K, Paper
Open Access
Sijie Xian, Yuanhui Xiang, Svenja Deichmann, Matthew J. Webber
New diol chemistries are explored for insulin delivery from glucose-responsive hydrogels comprised of dynamic-covalent crosslinking interactions between phenylboronic acids and diols.
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The structural, electronic and thermodynamic properties of the designed p-benzoquinone based dicationic ionic liquids: insight from DFT–GD3 and QTAIM

By pubs.rsc.org
Published On ::

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00119B, Paper
Hossein Roohi, Sajedeh Habibipour, Khatereh Ghauri
In this work, physicochemical properties of the dicationic ionic liquids [BTAD][A1–8]2 ([BTAD]2+ = [p-C6O2(N3H2)2]2+ and A1–8 = [CH3CO2]−, [CF3CO2]−, [N(CN)2]−, [CF3SO3]−, [ClO4]−, [BF4]−, [NTf2]− and [PF6]−) were theoretically investigated.
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Wireframe DNA origami nanostructure with the controlled opening of edges

By pubs.rsc.org
Published On ::

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00144C, Paper
Maryam Mogheiseh, Reza Hasanzadeh Ghasemi
Design and simulation of wireframe DNA origami nanostructures with fast and controlled opening capability using modified DAEDALUS code.
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In silico investigation of the interaction between α-synuclein aggregates and organic supramolecular assemblies

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Published On ::

Mol. Syst. Des. Eng., 2024, 9,1155-1166
DOI: 10.1039/D4ME00071D, Paper
Laura Le Bras, Yves L. Dory, Benoît Champagne
An α-synuclein aggregate with the PreNAC and NACore areas, responsible for the aggregation, highlighted.
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Computational-assisted molecular design, synthesis and application of benzobisthiadiazole-based near-infrared dye in electrowetting displays

By pubs.rsc.org
Published On ::

Mol. Syst. Des. Eng., 2024, 9,1144-1154
DOI: 10.1039/D4ME00115J, Paper
Junheng Chen, Haoteng Lin, Xintong Wang, Dinggui He, Baoyi Luo, Yuanyuan Guo, Wangqiao Chen, Guofu Zhou
Computational-assisted molecular design of benzobisthiadiazole-based donor–acceptor–donor type near-infrared dyes, their synthesis and application as colored inks in electrowetting displays.
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Construction of amide-bonded supramolecular multifunctional fillers towards boosted self-healing, thermal conductivity and dielectric properties

By pubs.rsc.org
Published On ::

Mol. Syst. Des. Eng., 2024, 9,1167-1178
DOI: 10.1039/D4ME00114A, Paper
Junlong Yao, Zongqiang Fu, Huan Yang, Lin Gao, Xueliang Jiang, Wei Nie, Zhengguang Sun, Haolan Lu, Meiyun Lin, Jinglou Xu
The two modified fillers effectively improved the self-healing efficiency, dielectric properties and thermal conductivity of the supramolecular composites by forming a synergistic effect of amide bonds.
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Dual responsive fluorescence switching of organohydrogel towards base/acid

By pubs.rsc.org
Published On ::

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00067F, Communication
Manish Kumar Dixit, Moupia Mukherjee, Bharat Kumar Sahu, Abul Kalam, Mrigendra Dubey
Herein, we report a dual acid/base responsive fluorescent and simultaneous reversible phase transformative organohydrogel (OHG).
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Unveiling the influence of oxidation state and heavy atom effects in chalcogen group on boron centered D(X)BNA core: a computational study on RTP versus TADF

By pubs.rsc.org
Published On ::

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00131A, Paper
Ramalingam Mahaan, Murugesan Panneerselvam, Luciano T. Costa, Aruljothy John Bosco
The effects of heavy atoms and oxidation states in chalcogen groups on D(X)BNA cores, combined with substitutions of weak and strong donors, led to the identification of potential TADF and RTP molecules among the 14 molecules.
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Development of xanthan gum-based solid desiccants for the extraction of water vapors from humid air

By pubs.rsc.org
Published On ::

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00134F, Paper
Hemant Mittal, Ali Al Alili, Saeed M. Alhassan, Naved I. Malek, Md. Didarul Islam
A xanthan gum-acrylamide desiccant with interconnected capillary channels was prepared and showed 1.38 g g−1 water adsorption at 90% RH and 25 °C, retaining 70% capacity over 20 cycles, proving its effectiveness as a salt-free desiccant.
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Le tout-en-un SÉSAME - 39 sujets blancs - Écrits et oraux - Tutos offerts

By www.vuibert.fr
Published On :: Wed, 23 Oct 2024 04:01:24 +0000

25,00 €

René Guimet, Jean-Dominique Picchiottino, Sophie Mattern, Marie-Laure Boursat, Benoît Thierry-Hildenbrand, Anne-Marie Bonnerot, Dominique Dumas, Loris Sirieix
8e édition
octobre 2024
352 pages
Visez l'excellence au Sésame grâce à notre équipe d'experts !
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Nouveau
978-2-311-21959-3
Concours 2025
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Le tout-en-un ACCES - 24 sujets blancs - Ecrits et oraux - Tutos offerts

By www.vuibert.fr
Published On :: Wed, 23 Oct 2024 04:01:24 +0000

25,90 €

Jean-Dominique Picchiottino, Sophie Mattern, Marie-Laure Boursat, Benoît Thierry-Hildenbrand, Anne-Marie Bonnerot, Clara Vinh
8e édition
octobre 2024
344 pages
Le Tout-en-un pour réussir les épreuves du concours ACCÈS : tout le cours et des entraînements intensifs !
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Indicative of Supremacy

By www.thehindu.com
Published On :: Sat, 16 Jul 2016 00:11:45 +0530


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Import of true renunciation

By www.thehindu.com
Published On :: Sun, 17 Jul 2016 21:45:14 +0530


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Power of Rama Bhakti

By www.thehindu.com
Published On :: Sun, 31 Jul 2016 20:49:45 +0530


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Qualities of great men

By www.thehindu.com
Published On :: Wed, 03 Aug 2016 22:30:33 +0530


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Power of atma jnana

By www.thehindu.com
Published On :: Wed, 10 Aug 2016 00:03:21 +0530


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Effect of Grace

By www.thehindu.com
Published On :: Mon, 15 Aug 2016 02:51:16 +0530


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Effect of Grace

By www.thehindu.com
Published On :: Mon, 15 Aug 2016 02:53:58 +0530


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Revelation of Cosmic form

By www.thehindu.com
Published On :: Thu, 25 Aug 2016 22:00:29 +0530


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Significance of Saranagati

By www.thehindu.com
Published On :: Tue, 30 Aug 2016 21:55:53 +0530


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