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New 8-hydroxy quinoline-polycyclic aromatic hydrocarbon (PAH) conjugates and their sulfonated derivatives: effects of sulfonation and PAH size on their structural, supramolecular and cytotoxic properties

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00105B, Paper
Suman Sehlangia, Surbhi Dogra, Prosenjit Mondal, Chullikkattil P. Pradeep
The ring size of polycyclic aromatic hydrocarbons (PAHs) and sulfonation affect the supramolecular interactions and cytotoxic properties of a new series of 8-hydroxy quinoline-PAH conjugates.
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Enantioselective enrichment of chiral 1-phenylethanol in the camphor-based chiral metal–organic framework CFA-22

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CrystEngComm, 2024, 26,2051-2055
DOI: 10.1039/D4CE00181H, Communication
Richard Röβ-Ohlenroth, Katharina Knippen, Maryana Kraft, Dirk Volkmer
The novel enantioselective CFA-22 metal–organic frameworks were successfully developed and investigated for chiral adsorption separation of e.g. racemic 1-phenylethanol.
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Advanced MnOx/MnWO4 hetero-nanoflakes with abundant oxygen vacancies for high-performance flexible asymmetric supercapacitors with high energy density

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CrystEngComm, 2024, 26,2087-2095
DOI: 10.1039/D4CE00052H, Paper
Yanli Yin, Jingli Wang, Sihao Chen, Nengneng Han, Zhiliang Chen, Yuezhou Jing, Yahui Zhang, Juan Xu, Zhongyang Li
High-performance flexible supercapacitors assembled with MnOx/MnWO4@C-3 hetero-nanoflake anodes, exhibiting a maximum areal energy density of 48.49 mW h cm−2.
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Enhanced photocatalytic activity of single-atom Au1/TiO2 catalysts prepared using cold plasma

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CrystEngComm, 2024, 26,2103-2111
DOI: 10.1039/D4CE00171K, Paper
Zikun Yang, Jingxuan Zheng, Mengge Shi, Zhao Wang
Single-atom Au1/TiO2-DBD catalysts were synthesised using DBD plasma and glow plasma, and the synergistic effect of single-atom Au and oxygen vacancies improved the degradation performance.
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Color-resolved mechanoluminescence of Eu and Mn co-doped SrMg2(PO4)2

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CrystEngComm, 2024, 26,2096-2102
DOI: 10.1039/D4CE00070F, Paper
Qingshan He, Yajing Yan, Ting Wang, Longchao Guo, Yang Yue, Nannan Zhu, Weifang Bu, Xin An, Bosong Duan, Xuanyu Zhu, Xue Yu
The linear relationship between the ML intensity ratio (MLIR) and stress of this phosphor leads to a change in ML color, resulting in visualization of ML performance of knee motion via the artificial skin based on SMP:Eu,Mn phosphor.
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Fabrication of BiVO4 submicron rods photoanodes through phase transition assisted by Mo doping

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CrystEngComm, 2024, 26,2078-2086
DOI: 10.1039/D4CE00074A, Paper
Shuang Zhao, Haipeng Zhang, Zhaoqi Wang, Deifei Xiao, Xianbin Xu, Peng Wang, Zhaoke Zheng, Yuanyuan Liu, Ying Dai, Hefeng Cheng, Zeyan Wang, Baibiao Huang
Herein, Mo doping has been found to effectively lower the phase transition temperature from tetragonal zircon BiVO4 to monoclinic scheelite BiVO4. Our research introduces a novel method for the production of submicron rods BiVO4 photoanodes.
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Using the nature of the achiral solvent to orient chiral resolution

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CrystEngComm, 2024, 26,2056-2059
DOI: 10.1039/D4CE00124A, Communication
Joséphine de Meester, Oleksii Shemchuk, Laurent Collard, Johan Wouters, Simon Baillieux, Koen Robeyns, Tom Leyssens
Both (R)- and (S)-Binol can be resolved from a racemic mixture using the same (R,R)-diamine resolving agent, merely adapting the nature of the solvent. This peculiarity is explained by the existence of both a diastereomeric as well as enantiospecific solvate cocrystal system.
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Coral-mimetic production of aragonite films from CO2 captured by biogenic polyamines

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CrystEngComm, 2024, 26,2065-2071
DOI: 10.1039/D4CE00126E, Paper
Open Access
Kohei Takashina, Hiroto Watanabe, Yuya Oaki, Yoshikazu Ohno, Ko Yasumoto, Hiroaki Imai
We designed CaCO3 films comprised of aragonite nanorods by mimicking the microstructure and the formation process of the calcareous skeleton of a stony coral in the sea.
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Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn3B7O13Cl

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CrystEngComm, 2024, 26,2060-2064
DOI: 10.1039/D4CE00060A, Communication
Haodong Li, Duo Zhang, Jiesen Guo, Qiangqiang Wang, Yuxin Ma, Munan Hao, Yuetong Wu, Fanshu Meng, Tianming Liu, Yibo Xu, Xu Chen, Changchun Zhao, Dezhong Meng, Zhiyuan Zheng, Ruijin Sun
High-quality single crystals of Mn3B7O13Cl have been successfully synthesized, to unravel the elusive mechanism behind its spontaneous polarization.
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The structural evolution of CL-20-based energetic host–guest solvates at decomposition temperature according to the perceptions of THz spectroscopy

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Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01310C, Paper
Lu Shi, XiaoHui Duan, Hongzhen Li
This work employed variable-temperature THz spectroscopy to analyze the structural evolution of host–guest energetic CL-20/H2O2 and CL-20/H2O solvates, as well as the mechanism of intermolecular interactions using DFT calculation and MD simulation.
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Chemical solution deposition of a (GaAl)2O3 single layer with high thickness and silver-enhanced crystal quality

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Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00086B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiao Tang, Wesam A. AlQanbar, Mohamed Ben Hassine, Yi Lu, Haicheng Cao, Chuanju Wang, Zixian Jiang, Tingang Liu, Na Xiao, Mingtao Nong, Vishal Khandelwal, Xiaohang Li
A new study presents a revolutionary CSD method to create thick (180 nm) single-layer (GaAl)2O3 films with enhanced crystal quality through silver doping.
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Degradation of tetracycline by visible light using Ca2Nb2O7 composite oxides with perovskite and pyrochlore sub-crystalline phases

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Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00044G, Paper
Junwei Xu, Chengxin Lu, Xianfeng Zhang, Rumeng Ouyang, Xiuzhong Fang, Xianglan Xu, Xiang Wang
We synthesized two paramorphs of Ca2Nb2O7 for visible light degradation of tetracycline, and found that pyrochlore phase has better reactivity compared to perovskite phase, which is attributed to the intrinsic oxygen vacancies and lattice disorder of pyrochlore phase.
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First-principles prediction of a direct Z-scheme WSe2/HfS2 van der Waals heterostructure for overall photocatalytic water decomposition

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Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00267A, Paper
Yan Zhang, Zhi-Bo Qiang, Jian-Xin Ding, Kang-Xin Xie, Li Duan, Lei Ni
The direct Z-scheme heterostructures photocatalyst has been validated as an efficacious approach for addressing the energy source issues and environmental challenges. This manuscript employs the first-principles to scrutinize singular-layer WSe2...
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Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic(V)-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper
Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
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Evolution of fractal patterns in lead-free, zero-dimensional perovskite Cs2InBr5(H2O)

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Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00204K, Paper
Wanyin Ge, Yang Maohao, Masaki Saruyama, Kenshi Matsumoto, Ryota Sato, Haruka Takekuma , Ryo Takahata, Toshiharu Teranishi
The crystallization behavior of halide perovskites is of great significance. Fractal structures, featured by self-similarity between local morphology and global structures, have consistently captivated scientists’ interest across diverse disciplines. In...
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AlN interlayer-induced reduction of dislocation density in the AlGaN epilayer

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Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00191E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David Maria Tobaldi, Luc Lajaunie, Arianna Cretì, Massimo Cuscunà, Iolena Tarantini, Marco Esposito, Gianluca Balestra, Mauro Lomascolo, Adriana Passaseo, Vittorianna Tasco
The emerging ultrawide-bandgap AlGaN alloy system holds promise for the development of advanced materials in the next generation of power semiconductor and UV optoelectronic devices. Within this context, heterostructures based...
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Local concentration controls the hydrate phase of calcium oxalate

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01286G, Paper
Zhaodong Wang, Lala Du, Qihang Wang, Jingjing Xie, Zhengyi Fu, Zhaoyong Zou
The calcium oxalate phase selection in supersaturated solution is determined by a combination of thermodynamic and kinetic factors.
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Enhanced Zn ion storage performance of polypyrrole coated Mn3O4 composites electrode

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Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00252K, Paper
Shilong Li, Ming Zhao, Weichao Zhang, Xiang Wu
Aqueous zinc ion batteries (AZIBs) possess significant application potential in energy storage field due to their large capacity, low redox potential and high safety. Among various materials, Mn3O4 electrode has...
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Highly enhanced cationic dye adsorption from water by nitro-functionalized Zn-MOF nano/microparticles and a biomolecular binder for improving the reusability

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Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00131A, Paper
Gunasekaran Arunkumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Savarimuthu Philip Anthony
Zn-MOF with a nitro-functionalized ligand exhibited enhanced cationic dye adsorption, and binder coating improved the reusability.
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Structural chemistry of decalins and perfluorodecalins

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01117H, Paper
Bartłomiej Paska, Grzegorz Cichowicz, Patryk Rzepiński, Michał Ksawery Cyrański, Łukasz Dobrzycki, Roland Boese
Crystaline phases of decalins and perfluorodecalins.
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Orthogonal stimulation of structural transformations in photo-responsive MOF films through linker functionalization

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00221K, Communication
Open Access
Sumea Klokic, Benedetta Marmiroli, Denys Naumenko, Giovanni Birarda, Simone Dal Zilio, Miriam de J. Velásquez-Hernández, Paolo Falcaro, Lisa Vaccari, Heinz Amenitsch
Controlling the magnitude of structural dynamics in flexible MOF films by an applied stimulus is largely desired for specific applications such as energy storage.
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3-(3,5-Dinitrophenyl)-5-amino-1,2,4-oxadiazole: synthesis, structure and properties of a novel insensitive energetic material

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Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00201F, Paper
Binshan Zhao, Baolong Kuang, Mou Sun, Tingwei Wang, Chao Zhang, Meiqi Xu, Cong Li, Zujia Lu, Jian-guo Zhang
A novel heat-resistant energetic compound 3-(3,5-dinitrophenyl)-5-amino-1,2,4-oxadiazole with low mechanical sensitivity on the basis of combining dinitrobenzene and aminooxadiazole was synthesized through a simple method in this work.
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Nitro group and K+-based secondary building units for the self-assembly of 3D coordination polymers built on dinuclear dianionic helicate connectors

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00255E, Paper
Open Access
Raúl Mendoza-Báez, Alan Molina-Renteria, Juan Olguín
Two dinuclear dianionic helicates, K2[MII2(L)3] M = MnII (1) and NiII (2), based on 2-hydroxy-5-nitrobenzaldehyde, self-assemble into novel 3D coordination polymers due to nitro groups acting as secondary assembly instruction.
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Synthesis and structural trends in a series of simple tetraalkylphosphonium salts

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Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00210E, Paper
Jakub Gawraczynski, Piotr J Leszczynski, Michal Ksawery Cyranski, Łukasz Dobrzycki, Wiktor Koźmiński, Karol J. Fijalkowski, Wojciech Grochala, Tomasz Jaroń
A series of sulfates (S) and hydrogen sulfates (HS) containing tetramethylphosphonium (TMP), tetraethylphosphonium (TEP) and tetrabutylphosphonium (TBP) cations have been prepared from the respective bromides using ion metathesis reactions. The...
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Flux growth and characterization of gallium-rare earth borates

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CrystEngComm, 2024, 26,2180-2189
DOI: 10.1039/D3CE01269G, Paper
Victor V. Maltsev, Elizaveta V. Koporulina, Elena A. Volkova, Diana D. Mitina, Anna I. Jiliaeva, Vladimir L. Kosorukov, Alexey E. Afanasev, Daniil A. Naprasnikov
YGa3(BO3)4 single crystals were grown from a K2Mo3O10-based flux, and also RGa3(BO3)4 (R = Y, Pr–Yb) spontaneous crystals (RGB) were obtained by a high-temperature flux growth technique from a complex R2O3–Bi2O3–B2O3–Ga2O3 solvent.
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Synthesis and photophysical properties of charge transfer cocrystals based on TCNB and fluorene and its derivatives

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Published On ::

CrystEngComm, 2024, 26,2155-2165
DOI: 10.1039/D3CE01208E, Paper
Wenxiu Yao, Pengfei Wu, Yidan Xie, Xinyu Shen, Shuwei Xia, Liangmin Yu
A series of charge transfer cocrystals with fluorescence properties involving 1,2,4,5-tetracyanobenzene as acceptor, fluorene, 2-bromofluorene, carbazole and 2-bromocarbazole as donor were synthesized via cocrystal design strategies.
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Facile syntheses, structures and photocatalytic properties of 3D iodoargentate frameworks derived from TM-flexible-amino-ligand templates

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Published On ::

CrystEngComm, 2024, 26,2172-2179
DOI: 10.1039/D4CE00247D, Paper
Yan Gao, Xiao Yang, Taohong Ren, Dingxian Jia
3D iodoargentates [Co(en)3(Ag2I4)]n (1), [Fe(en)3(Ag2I4)]n (2) and [Co(dien)2(Ag2I4)]n·nH2O (3) were prepared by solvothermal methods. Compounds 1–3 were catalytic activity for photodegradation of crystal violet under visible light irradiation.
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The development of an approach for the precision determination of thermal strain tensor elements for single crystals using the example of t-Ag0.8Li0.2InSe2

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Published On ::

CrystEngComm, 2024, 26,2207-2218
DOI: 10.1039/D3CE01186K, Paper
Polina S. Serebrennikova, Sergey I. Lobanov, Alexander S. Sukhikh, Lyudmila I. Isaenko, Sergey A. Gromilov
A new approach to the precision determination of single-crystal unit cell parameters is proposed and demonstrated using tetragonal Ag0.8Li0.2InSe2.
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Distribution of basal plane dislocations in 4-degree off-axis 4H-SiC single crystals

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Published On ::

CrystEngComm, 2024, 26,2143-2154
DOI: 10.1039/D4CE00055B, Paper
Sheng'ou Lu, Binjie Xu, Yazhe Wang, Hongyu Chen, Wei Hang, Rong Wang, Julong Yuan, Xiaodong Pi, Deren Yang, Xuefeng Han
The basal plane slip model in 4H-SiC was developed to investigate the effects of off-axis angles on total resolved shear stress. The results showed that the TRSS changed from 6-fold to 4-fold symmetry with the increasing off-axis angles.
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Effects of B2S3 additive on diamond crystallization at HPHT conditions

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Published On ::

CrystEngComm, 2024, 26,2190-2196
DOI: 10.1039/D4CE00147H, Paper
Yong Li, Shuai Wang, Hongyu Xiao, Qiang Wang, Zhengguo Xiao, Yanchao She, Ying Wang
The color of the diamond obtained with the B2S3 additive changes from yellow to light blue and the resistivity of the synthesized diamond drops from 3.89 × 10 Ω cm to 2.51 × 10−1 Ω cm with the introduction of Ti/Cu into the synthetic cavity.
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Study on Raman scattering spectroscopy of Mn-doped GaN grown by the ammonothermal method

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Published On ::

CrystEngComm, 2024, 26,2166-2171
DOI: 10.1039/D4CE00093E, Paper
Wenhao Lu, Tengkun Li, Guoqiang Ren, Zhenghui Xia, Kaihe Xie, Shaozhe Li, Liangkun Shen, Ke Xu
Mn-doped GaN crystals of a-plane and (11−22) plane were grown by the ammonothermal method.
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In situ P-doping induced Se vacancies enhance the supercapacitor performance of NiCo2Se4

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Published On ::

CrystEngComm, 2024, 26,2197-2206
DOI: 10.1039/D4CE00048J, Paper
Miaomiao Wang, Weizhe Liu, Li Zhang, Huanli Liu, Xiao Yang
In this paper, we report the synthesis of P-doped NiCo2Sex nanomaterials with rich Se vacancies induced by P doping, which greatly improves the supercapacitor performance of electrode materials.
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WhatsApp to offer new Channels feature

By www.thehindubusinessline.com
Published On :: Thu, 08 Jun 2023 15:09:24 +0530

Channels will be first available in select organisations in Colombia and Singapore.


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Twitter under Jack Dorsey and team were in repeated, continuous violations of Indian law: Rajeev Chandrasekhar

By www.thehindubusinessline.com
Published On :: Tue, 13 Jun 2023 10:17:06 +0530

The former Twitter Chief Executive Officer and Co-founder has alleged that the Indian government threatened to shut down Twitter during farmers protest


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Reddit protest: Why are thousands of subreddits going dark?

By www.thehindubusinessline.com
Published On :: Tue, 13 Jun 2023 11:21:47 +0530

Starting next month, third-party app developers using Reddit's vast troves of data will have to pay a price and the changes could affect players across the spectrum


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The ever-growing influence of Influencers

By www.thehindubusinessline.com
Published On :: Tue, 27 Jun 2023 20:15:56 +0530

From politicians to brands, everyone wants to partner content creator sensations


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Meta takes aim at Twitter with the launch of Threads

By www.thehindubusinessline.com
Published On :: Thu, 06 Jul 2023 09:27:45 +0530

Threads passes 5 million sign ups in four hours: CEO Zuckerberg


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Twitter’s blue bird flies off, Musk brings in the X factor

By www.thehindubusinessline.com
Published On :: Mon, 24 Jul 2023 07:51:13 +0530

Twitter sees dramatic new updates that might change its entire character


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New York City bans use of TikTok on city-owned phones

By www.thehindubusinessline.com
Published On :: Fri, 18 Aug 2023 10:17:00 +0530

Joins US federal government, majority of states in banning the social media app on security concerns


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X to offer video, audio calls, as Musk aims for super-app

By www.thehindubusinessline.com
Published On :: Thu, 31 Aug 2023 15:16:42 +0530

X users can make video, audio calls without sharing phone number


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Majority of Indian parents say their kids addicted to social media, OTT: Survey

By www.thehindubusinessline.com
Published On :: Fri, 22 Sep 2023 11:51:49 +0530

It further revealed that 73 per cent of urban Indian parents surveyed want the data protection law to ensure mandatory parental consent is sought for children under 18


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India-Pakistan match garnered peak concurrency viewership of 3.5 crore on Disney+Hotstar

By www.thehindubusinessline.com
Published On :: Sat, 14 Oct 2023 22:41:53 +0530

India vs Pakistan match during the Asia Cup 2023 garnered 2.8 crore viewers on the platform.


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YouTube rewinds to top trending content, creators of 2023

By www.thehindubusinessline.com
Published On :: Wed, 13 Dec 2023 16:45:40 +0530

Short-form videos, Chandrayaan-3 live telecast among Youtube’s top draws of 2023


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I&B Ministry issues advisory to media and social media platforms ahead of Ram temple consecration ceremony

By www.thehindubusinessline.com
Published On :: Sat, 20 Jan 2024 18:53:31 +0530

This comes after the Ministry observed that certain fake and unverified messages are being spread, especially on social media.


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TikTok, ByteDance sue to block US law seeking sale or ban of app

By www.thehindubusinessline.com
Published On :: Wed, 08 May 2024 09:37:44 +0530

A law, signed by Joe Biden on April 24, gives ByteDance until January 19 to sell TikTok or face a ban


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Centre extends deadline for Telangana millers for supply of rice to FCI

By www.thehindubusinessline.com
Published On :: Thu, 28 Jul 2022 20:18:11 +0530

Asks State government to adhere to quality norms


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Two-quarters of no disruptions will help revive entry-level bike and cars segments: FADA chief  

By www.thehindubusinessline.com
Published On :: Fri, 12 Aug 2022 16:53:35 +0530

The EV segment needs to deliver good quality products, said Vinkesh Gulati


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FinMin releases Revenue Deficit Grant of ₹7,183 crore to 14 States

By www.thehindubusinessline.com
Published On :: Tue, 06 Sep 2022 16:53:35 +0530

West Bengal received the highest amount of ₹1,132.25 crore


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Margins of most MSMEs to remain below pre-Covid levels this fiscal

By www.thehindubusinessline.com
Published On :: Wed, 16 Nov 2022 19:04:14 +0530

Except for a few in select sectors, many will reach the pre-Covid revenue mark: Crisil report


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Windfall profit tax on crude oil hiked, levy on export of diesel cut

By www.thehindubusinessline.com
Published On :: Thu, 17 Nov 2022 09:48:25 +0530

The export tax on jet fuel or ATF, which was set at ₹5 a litre in the last review on November 1, has not been altered


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