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Accurate determination of ultra-trace rare earth elements by LA-ICP-MS/MS and its application to cassiterite for effective elimination of Gd and Tb false positive anomalies

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00271G, Paper
Ming Yang, Wu Wei, Yue-Heng Yang, Rolf L. Romer, Shi-Tou Wu, Tao Wu, Li-Feng Zhong
This study reports a new method for in situ determination of ultra-low REE contents in cassiterite by LA-ICP-MS/MS with an O2 and mass-shift detection strategy to avoid Gd and Tb anomalies.
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Improvements in low-level radionuclide measurement capability through use of the Apex Q sample introduction system combined with ICP-MS/MS

J. Anal. At. Spectrom., 2024, 39,2929-2936
DOI: 10.1039/D4JA00216D, Paper
Ben Russell, Frankie Falksohn, Alexandre Tribolet, Hibaaq Mohamud, Olivia Pearson, Emma Braysher, Saskia Burke, Anu Bhaisare
Improvement in sensitivity and interface removal capability for radionuclide measurement using desolvating sample introduction combined with ICP-MS/MS.
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High-precision, mass dependent Si isotope measurements via the critical mixture double-spiking technique

J. Anal. At. Spectrom., 2024, 39,2799-2808
DOI: 10.1039/D4JA00152D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiao-Ning Liu, Martijn Klaver, Remco C. Hin, Christopher D. Coath, Hong Chin Ng, Tim Elliott
We developed critical mixture double-spiking Si isotope measurement, achieving an enhanced long-term reproducibility of ±0.03‰ (δ30Si, 2 s.d.), which is ∼4 times better than the current methods' long-term reproducibility over ±0.1‰ (δ30Si, 2 s.d.).
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Bimodal data fusion of LIBS spectroscopy and plasma acoustic emission signals: improving the accuracy of machining process identification for low roughness samples

J. Anal. At. Spectrom., 2024, 39,2737-2747
DOI: 10.1039/D4JA00225C, Paper
Shilei Xiong, Minchao Cui, Nan Yang, Guangyuan Shi, Yuxin Pi, Yuyang Mu, Yuntao Zhang, Yue Zhao
The fusion of LIBS spectral data with PAES data improves machining process classification identification accuracy.
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Development and application of reference and routine analytical methods providing SI-traceable results for the determination of technology-critical elements in PCB from WEEE

J. Anal. At. Spectrom., 2024, 39,2809-2823
DOI: 10.1039/D4JA00235K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Giancarlo D'Agostino, Marcus Oelze, Jochen Vogl, Jean-Philippe Ghestem, Nicolas Lafaurie, Ole Klein, Daniel Pröfrock, Marco Di Luzio, Luigi Bergamaschi, Radojko Jaćimović, Caroline Oster, Johanna Irrgeher, Shaun T. Lancaster, Anna Walch, Anita Röthke, Lena Michaliszyn, Axel Pramann, Olaf Rienitz, Timo Sara-Aho, Oktay Cankur, Derya Kutan, Johanna Noireaux
Development and test of five reference analytical methods and six routine analytical methods providing SI-traceable results of twenty technology-critical elements in end-of-life PCB materials.
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Optimization of informative variables selection for quantitative analysis of heavy metal (Cu) contaminated Tegillarca granosa using laser-induced breakdown spectroscopy

J. Anal. At. Spectrom., 2024, 39,2824-2831
DOI: 10.1039/D4JA00084F, Paper
Xudong Huang, Xiaojing Chen, Guangzao Huang, Zhonghao Xie, Wen Shi, Shujat Ali, Leiming Yuan, Xi Chen
The KMRCD algorithm successfully selected 50 informative variables from the 1520 variables in the LIBS spectra.
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Evaluation and calibration of matrix effects during SIMS silicon isotope analysis in silicate glasses

J. Anal. At. Spectrom., 2024, 39,2832-2840
DOI: 10.1039/D4JA00253A, Paper
Liu-Yang Chen, Yu Liu, Di Zhang, Guo-Qiang Tang, Qiu-Li Li
A matrix effect calibration model during SIMS silicon isotope analysis based on the contents of Si, Ca, Al and Mg (SCAM model) in silicate glasses.
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Trace element determination by femtosecond LA-ICP-MS in 10 mg extraterrestrial geological samples prepared as lithium borate glasses

J. Anal. At. Spectrom., 2024, 39,2728-2736
DOI: 10.1039/D4JA00275J, Paper
Yan-Hong Liu, Ding-Shuai Xue, Wen-Jun Li, Zhong-Qiang Wang, Yan Liang, Shun Guo, Bo Wan
This method involves precise trace element determination in X-ray fluorescence (XRF) lithium borate glass prepared from 10 mg extraterrestrial geological samples using femtosecond LA-ICP-MS.
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Sodium nanoferrite-based solid phase extraction: a green method for the simultaneous determination of cadmium, copper, and lead

J. Anal. At. Spectrom., 2024, 39,2884-2892
DOI: 10.1039/D4JA00210E, Paper
Saima Perveen, Aysen Hol, Jameel Ahmed Baig, Syed Tufail Hussain Sherazi, Khalil Akhtar, Sajjad Hussain, Fahad Abbasi
A solid phase extraction (SPE) methodology utilizing sodium ferrite nanoparticles (Na2Fe4O7-NPs; SF-NPs) is presented for the simultaneous determination of heavy metals (HMs) via flame atomic absorption spectrometry (FAAS).
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Quantification of technetium-99 in wastewater by means of automated on-line extraction chromatography – anion-exchange chromatography – inductively coupled plasma-mass spectrometry

J. Anal. At. Spectrom., 2024, 39,2774-2782
DOI: 10.1039/D4JA00270A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Maximilian Horstmann, C. Derrick Quarles, Steffen Happel, Michael Sperling, Andreas Faust, David Clases, Uwe Karst
Ultratrace concentrations of pertechnetate are determined by preconcentration on a dedicated resin and anion exchange chromatography with ICP-MS detection.
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Efficient preconcentration of ultra-trace rhenium from geological materials via induced adsorption for accurate isotope analysis

J. Anal. At. Spectrom., 2024, 39,2748-2755
DOI: 10.1039/D4JA00295D, Paper
Yumeng Liu, Tianyu Chen, Tao Li, Weiqiang Li, Qingquan Hong, Jiubin Chen
Preconcentration via induced adsorption achieves the quantitative recovery of Re and facilitates Re isotope analysis.
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Data fusion of spectral and acoustic signals in LIBS to improve the measurement accuracy of carbon emissions at varying gas temperatures

J. Anal. At. Spectrom., 2024, 39,2756-2766
DOI: 10.1039/D4JA00287C, Paper
Shu Chai, Jie Ren, Suming Jiang, Aochen Li, Ziqing Zhao, Haimeng Peng, Qiwen Zhang, Wendong Wu
A novel mid-level data fusion method integrating spectral and acoustic signals of laser-induced plasmas was proposed to improve the measurement accuracy of carbon concentrations in flue gas at varying gas temperatures.
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Mg separation from samples with very high Ca/Mg ratios for Mg isotope analysis

J. Anal. At. Spectrom., 2024, 39,2767-2773
DOI: 10.1039/D4JA00266K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Niklas Keller, Michael Tatzel
We present an efficient method to separate Mg from samples with high Ca/Mg matrices for the analysis of Mg isotope ratios. By utilising the automated sample purification system prepFAST, the labour is substantially minimised.
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A single-column and efficient procedure for separating Fe and Mg from geological materials for isotopic analyses using MC-ICP-MS

J. Anal. At. Spectrom., 2024, 39,2783-2790
DOI: 10.1039/D4JA00272E, Paper
Guanhong Zhu, Zhenmin Ge, Le Zhang, Gangjian Wei, Jinlong Ma
We developed a single-column and efficient procedure for separating Fe and Mg from geological materials for isotope measurements.
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Assessing the performance of handheld LIBS for predicting soil organic carbon and texture in European soils

J. Anal. At. Spectrom., 2024, 39,2903-2916
DOI: 10.1039/D4JA00292J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alex Wangeci, Maria Knadel, Olga De Pascale, Mogens H. Greve, Giorgio S. Senesi
Evaluating the performance of handheld LIBS for determination of soil properties across a continental scale.
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Atomic spectrometry update: review of advances in the analysis of metals, chemicals and materials

J. Anal. At. Spectrom., 2024, 39,2617-2693
DOI: 10.1039/D4JA90052A, Atomic Spectrometry Update
Eduardo Bolea-Fernandez, Robert Clough, Andy Fisher, Bridget Gibson, Ben Russell
This review covers advances in the analysis of advanced materials, metals, fuels and lubricants, nanostructures, ceramics, refractories, chemicals, catalysts and nuclear materials by a range of techniques including ICP-MS, non-destructive surface ablation and X-ray.
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A new concept for correction of instrumental isotopic fractionation in MC-ICP-MS using a pair of monoisotopic elements: a critical evaluation

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00117F, Paper
Open Access
Andrii Tupys, Klaudia Tetfejer, Ludwik Halicz, Ewa Bulska, Jakub Karasiński
In this research work, we investigated the possibility of using mixtures of monoisotopic elements (93Nb/89Y, 165Ho/159Tb and 209Bi/197Au) as calibrators for accurate determination of isotope ratios by multicollector mass spectrometry (MC-ICP-MS).
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INSIGHTS INTO THE ROLE OF TRANSITION AND NOBLE METALS MEDIATING PHOTOCHEMICAL VAPOR GENERATION

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00261J, Tutorial Review
Open Access
Ralph E Sturgeon, Enea Pagliano, Gisele Simone Lopes, Renato Neto, Jane Kelly Sousa Brito
Abstract The recent expansion of the suite of elements amenable to photochemical vapor generation (PVG) is primarily linked to the addition of mg/L concentrations of selected transition metals (TMs) to...
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Chemical analysis of Chang’e-5 lunar soil using LA–ICP–MS in highly diluted fused glass discs

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00329B, Technical Note
Shi-Tou Wu, Ding-Shuai Xue, Yue-Heng Yang, Hao Wang, Chunlai Li, Fu-Yuan Wu
The bulk chemical compositions of extraterrestrial material can provide critical information on the evolution and magmatism of planetary bodies. However, accurate measurements are challenging, because these samples, particularly returned samples,...
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A single-stage purification method for the precise determination of zirconium isotopic composition in geological samples by double spike MC-ICP-MS

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00332B, Paper
Lanping Feng, Chen Wang, Yan Han, Wen Zhang, Jing-Liang Guo, Lian Zhou, Zhaochu Hu
A simple, fast and efficient column separation method for extracting Zr from geological sample matrices using DGA resin.
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A miniaturized microplasma excitation source coupled with photochemically induced volatile species generation as a cost-effective tool for in situ mercury pollution analyses

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00306C, Technical Note
Open Access
Tymoteusz Klis, Pawel Pohl, Anna Dzimitrowicz, Piotr Jamroz
A portable, miniaturized atmospheric microplasma discharge system coupled with the photochemical vapour generation was developed for the sensitive Hg determination in water samples using OES.
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Magneto-electrical fusion enhancement of LIBS signal: A case of Al and Fe emission lines’ characteristic analysis in soil

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00223G, Paper
Zihan Yang, Mengyu Pang, Jincheng Ma, Yanru Zhao, Keqiang Yu, Y. He
Soil is a vital resource for human survival. In particular, aluminum (Al) and iron (Fe) metal elements in soil play significant roles in stabilizing soil organic matter. Therefore, the rapid...
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Sensitive and Rapid Determination of Iodine/Calcium Ratio in Carbonate Rock Samples by ICP-MS Based on Solution Cathode Glow Discharge Sampling

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00264D, Paper
Xuan Wang, Xing Liu, Lanlan Jin, Zhenli Zhu, Junhang Dong, Pengju Xing, Linjie Chen, Yuanhui Geng, Jingwen Zhang, Hao Tong, Hongtao Zheng, Min Zhang, Shenghong Hu
The iodine-to-calcium ratio (I/Ca) in carbonate rocks has been extensively used to indicate marine oxidation states. However, the low-iodine and high-calcium characteristics of carbonate samples pose challenges in achieving rapid...
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Laser-Induced Breakdown Spectroscopy (LIBS): calibration challenges, combination with other techniques, and spectral analysis using data science

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00250D, Critical Review
Dennis Ferreira, Diego Victor De Babos, Mauro Henrique Lima-Filho, Heloisa Froehlick Castello, Alejandro C. Olivieri, Fabiola Manhas Verbi Pereira, Edenir Rodrigues Pereira-Filho
Laser-Induced Breakdown Spectroscopy (LIBS) is a versatile and powerful analytical technique widely used for rapid, in-situ elemental analysis across various fields, from industrial quality control to planetary exploration. This review...
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Fundamental studies of laser ablation ICPMS using a nitrogen plasma source and helium, argon and nitrogen as carrier gas

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00327F, Paper
Open Access
Dylan Käser, Ralf Kägi, Bodo Hattendorf, Detlef Günther
Nitrogen as alternative carrier gas for LA-ICPMS showed similar sensitivities and quantification capabilities as using helium in combination with a N2 plasma. The role of the gas and of the ablation cell design on the aerosol structure was studied.
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SPCal - An open source, easy-to-use processing platform for ICP-TOFMS based single event data

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00241E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas Edward Lockwood, Lukas Schlatt, David Clases
Single particle inductively coupled plasma – mass spectrometry (SP ICP-MS) has evolved into one of the most powerful techniques for the bottom-up characterisation of nanoparticle suspensions. The latest generations of...
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Calculating common maintenance charges

Your property-related legal queries answered by S.C. RAGHURAM, Partner, RANK Associates, a Chennai-based law firm




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For the cause of realty

The two-day NAR-India Convention in Bengaluru beginning today will bring in 1,200 delegates from 44 countries where real estate professionals and industry experts will interact to see India adopt the best practices.




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Calculating maintenance costs

Your property-related legal queries answered by S.C. RAGHURAM, Partner, RANK Associates, a Chennai-based law firm



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