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Lewis acid sites and flexible active centers synergistically boost efficient electrochemical ammonia synthesis

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J. Mater. Chem. A, 2024, 12,30476-30485
DOI: 10.1039/D4TA04884A, Paper
Li-Bo Chen, Tong-Hui Wang, Xing-You Lang, Qing Jiang
The Lewis acid sites enhance N2 adsorption and activation, while the flexible active center facilitates hydrogenation and NH4+ formation, regenerating the catalyst.
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Sulfur-doped g-C3N4/V2C MXene Schottky junctions for superior photocatalytic H2 evolution

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J. Mater. Chem. A, 2024, 12,30429-30441
DOI: 10.1039/D4TA05929H, Paper
Haitao Wang, Jipeng Fan, Jing Zou, Yujie Zheng, Dingsheng Wang, Jizhou Jiang
An advanced sulfur-doped g-C3N4/V2C MXene (SCN/V2C) Schottky junction HER photocatalyst was prepared via vacuum ball milling and subsequent annealing.
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Microphase-separation-induced polyzwitterionic ionogel with tough, highly conductive, self-healing and shape–memory properties for wearable electrical devices

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J. Mater. Chem. A, 2024, 12,30618-30628
DOI: 10.1039/D4TA04228J, Paper
Guang Zeng, Wenshuo Gao, Weicheng Qiu, Guanling Li, Shousen Chen, Xin He, Guoxing Sun, Weijia Yang, Yue Xin
A polyzwitterionic ionogel with a phase separation structure was designed to achieve a balance between mechanical robustness and ionic conductivity. This design holds immense potential for applications in wearable sensors.
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Multifunctional additive enables lead-adsorbing carbon electrodes for perovskite solar cells

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J. Mater. Chem. A, 2024, 12,30611-30617
DOI: 10.1039/D4TA05429F, Paper
Yuanzhu Jiang, Aodong Zhu, Teng Liao, Wang Zhao, Mengmeng Cheng, Xinxin Zhang, Yi-Bing Cheng, Junyan Xiao
Phosphate, being a single-component multifunctional additive, serves as a viable material for the carbon electrode in perovskite solar cells. This utilization ensures the device's performance and mitigates the risk of potential lead pollution.
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Exploring reaction mechanisms for CO2 reduction on carbides

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J. Mater. Chem. A, 2024, 12,30340-30350
DOI: 10.1039/D4TA05592F, Paper
Naveed Ashraf, Atef Iqbal, Younes Abghoui
The electrocatalytic conversion of carbon dioxide (CO2) into valuable fuels offers immense promise in pursuing sustainable energy solutions.
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Electrochemical synthesis of wormcast-like Pd-based polycrystalline high entropy aggregates for methanol water co-electrocatalysis

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J. Mater. Chem. A, 2024, 12,30757-30767
DOI: 10.1039/D4TA06304J, Paper
Yaxing Liu, Wenhao Ding, Jiaxin Liu, Guizhe Zhao, Weiyin Li, Yaqing Liu
A wormcast-like nanostructure of PdFeCoNiCu-pHENs with enriched grain boundary defects was synthesized via electrodeposition. This work opens new possibilities for designing advanced nanomaterials aimed at efficient electrochemical energy conversion.
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Rational engineering and synthesis of pyrene and thiazolo[5,4-d]thiazole-functionalized conjugated microporous polymers for efficient supercapacitor energy storage

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Published On ::

J. Mater. Chem. A, 2024, 12,30508-30521
DOI: 10.1039/D4TA05908E, Paper
Abdul Basit, Yang-Chin Kao, Yasser A. El-Ossaily, Shiao-Wei Kuo, Mohamed Gamal Mohamed
The Py-Th-TzTz CMP was synthesized through a Schiff base reaction and exhibited a decomposition temperature (Td10) of 352 °C. In a three-electrode system, it demonstrated a specific capacitance of 652 F g−1.
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Tracking the active phase and reaction pathway of the OER mediated by an MnMoO4 microrod electro(pre)-catalyst

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J. Mater. Chem. A, 2024, 12,30810-30820
DOI: 10.1039/D4TA05985A, Paper
Anubha Rajput, Ankita Kumari, Hirak Kumar Basak, Dibyajyoti Ghosh, Biswarup Chakraborty
MnMoO4 is a barely explored material for the electrocatalytic oxygen evolution reaction (OER) and in situ tracking of the reactive intermediates and final active species during the OER in an alkaline pH lacks a sequential study.
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Probing the key roles of the back interface in the performance of carbon-based hole-transport-layer free perovskite solar cells

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J. Mater. Chem. A, 2024, 12,30388-30397
DOI: 10.1039/D4TA06143H, Paper
Xinwei Li, Nianqing Fu, Xiaocao Peng, Hehui Lin, Jiaang Cheng, Ziming Chen, Peng Lin, Jun Du
The key roles of perovskite films in the photovoltaic performance of carbon-based PSCs employing various absorbers were comprehensively studied and elucidated.
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One-pot spatial engineering of multi-enzymes in metal–organic frameworks for enhanced cascade activity

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J. Mater. Chem. A, 2024, 12,30318-30328
DOI: 10.1039/D4TA06211F, Paper
Wenqing Fan, Kang Liang, Jieying Liang
A one-pot strategy was developed for the first time to achieve the precise spatial arrangement of multiple enzymes in MOFs, improving multi-enzyme cascade efficiency.
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Dual solar-driven hydrogen evolution and alcohol oxidation with CdS quantum dot-sensitized photocatalysts prepared by the SILAR methodology

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Published On ::

J. Mater. Chem. A, 2024, 12,30885-30891
DOI: 10.1039/D4TA03559C, Paper
Vasilis Nikolaou, Deborah Romito, Clément Maheu, Jonathan Hamon, Eric Gautron, Florian Massuyeau, Pierre-Emmanuel Petit, Stéphane Jobic, Fabrice Odobel
The first use of the successive ionic layer adsorption and reaction (SILAR) method to grow CdS quantum dots on TiO2 nanoparticles, achieving efficient photocatalytic alcohol oxidation and H2 evolution without catalysts or sacrificial donors.
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Achieving dynamic stability of single-crystal low-Co Ni-rich cathode material for high performance lithium batteries

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J. Mater. Chem. A, 2024, 12,30831-30841
DOI: 10.1039/D4TA04698F, Paper
Adil Saleem, Leon L. Shaw, Mehwish Khalid Butt, Javed Rehman, Arshad Hussain, Zawar Hussain, Rashid Iqbal, Muhammad Kashif Majeed
The demand for high-energy-density lithium-ion batteries (LIBs) has driven intensive research into cathode materials that exhibit both superior performance and stability over multiple charge–discharge cycles.
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Design and construction of porphyrin box-based metal–organic frameworks with hierarchical superstructures for efficient energy transfer and photooxidation

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J. Mater. Chem. A, 2024, 12,30685-30691
DOI: 10.1039/D4TA05576D, Paper
Qian Xu, Peng Zhang, Yuanyuan Sun, Jishi Chen, Chuantao Hou, Zonghua Wang
A porphyrin box-based MOF with hierarchical superstructures was synthesized, exhibiting enhanced performance in singlet oxygen-mediated photooxidation.
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Tailoring the electrocatalytic properties of novel microwave synthesized CuNd(2−x)GdxO4 nanoparticles for efficient total water splitting in alkaline media

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, 12,30850-30861
DOI: 10.1039/D4TA05919K, Paper
Anto Priyanka E, Sreenivasan Nagappan, J. Judith Vijaya, Angappan Sankaramahalingam, Subrata Kundu
CuNd(2−x)GdxO4 nanoparticles synthesized via microwave method as efficient OER and HER catalysts require low overpotentials exhibiting remarkable stability. Gd doping enhances charge transfer leading to optimized electrocatalysis.
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Interfacial charge transfer modulation in laser-synthesized catalysts for efficient oxygen evolution

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, 12,30269-30278
DOI: 10.1039/D4TA06794K, Paper
Dong Hyeon Lee, Rahul Kerkar, Deepak Arumugam, Jayaraman Theerthagiri, Shankar Ramasamy, Soorathep Kheawhom, Myong Yong Choi
This study introduces a NiFe LDH-based catalyst via pulsed laser irradiation in liquids and microwave methods, achieving superior oxygen evolution performance. In situ electrode casting optimizes the catalyst for water-splitting applications.
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Metal–organic framework derived low-crystallinity cobalt–nitrogen–carbon electrocatalysts for nitrate reduction to ammonia

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, 12,30409-30419
DOI: 10.1039/D4TA05443A, Paper
Yue Cao, Shengbo Yuan, Wenbo Zhou, Yan Hai, Xiaoman Li, Min Luo
NO3− and H2O molecules adsorbed on the surface of Co–N–C-500 are activated and dissociated. The generated active hydrogen species (*H) can promote the hydrogenation of the intermediates and thus increase the NH3 yield.
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Room-temperature thermochemical water splitting: efficient mechanocatalytic hydrogen production

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, 12,30906-30918
DOI: 10.1039/D4TA04650A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Takuya Yamamoto, Sho Ashida, Nanami Inubuse, Shintaro Shimizu, Yui Miura, Tomoya Mizutani, Ken-ichi Saitow
We report the accidental discovery and subsequent investigation of room-temperature thermochemical water splitting in a ball mill. High-purity H2 (>99%) was produced using water and/or seawater feedstocks in a compact (∼50 cm) low-power reactor.
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Development and application of Few-shot learning methods in materials science under data scarcity

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, 12,30249-30268
DOI: 10.1039/D4TA06452F, Review Article
Yongxing Chen, Peng Long, Bin Liu, Yi Wang, Junlong Wang, Tian Ma, Huilin Wei, Yue Kang, Haining Ji
Machine learning, as a significant branch of artificial intelligence, shortens the cycle of material discovery and synthesis by exploring the characteristics of data.
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Review of electro-spun carbon nanofiber electrode materials for electrochemical capacitors

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06221C, Review Article
Yutian Peng, Xingyu Zhang, Ruiling Sun, Xunlong Zhang, Can Ge, Yuqing Liu
Schematic illustration demonstrating various approaches to enhance the electrochemical performance of carbon nanofiber electrode materials.
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Computational prediction of solvation structures in calcium battery electrolytes

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06675H, Paper
Heonjae Jeong, Haimeng Wang, Lei Cheng
This study demonstrates comprehensive approaches for predicting solvation structures in Ca-ion battery electrolytes by integrating ab initio calculations and machine learning force fields.
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Achieving the selectivity of the oxygen reduction reaction by regulating electron spin states and active centers on Fe–Mn–N6–C dual-atom catalysts

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06650B, Paper
Shiyao Li, Honghao Chen, Yue Qiu, Chengxing Cui, Wenhui Zhong, Jun Jiang
As the first attempt to reveal the intrinsic relationship between electron spins and catalytic selectivity, this work offers new insights into the rational design of efficient transition metal atom-dispersed catalysts through spin regulation.
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Dually encapsulated LiMn0.6Fe0.4PO4 architecture with MXenes and amorphous carbon to achieve high-performance and ultra-stable lithium batteries

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06323F, Paper
Yang Song, Haidong Zhong, Tingting Hu, Qizhi Chen, Lei Shi, Jun Du, Changyuan Tao, Qian Zhang
An LMFP@MXene@C cathode material was fabricated by electrostatic adsorption and in situ graphitization, providing optimized Li+ transmission and a stable structure featuring ultrahigh average capacity and cycle stability.
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Ir nanoparticles decorated NiFe metal–organic framework as a highly efficient and stable heterostructure electrocatalyst for overall seawater splitting

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06515H, Communication
Hefeng Wang, Zixiao Li, Zhengwei Cai, Chaoxin Yang, Shengjun Sun, Xiaoyan Wang, Min Zhang, Meng Yue, Dongdong Zheng, Asmaa Farouk, Mohamed S. Hamdy, Xuping Sun, Bo Tang
Ir nanoparticle decorated NiFe metal–organic framework on Ni foam (Ir@NiFe-MOF/NF) acts as a bifunctional catalyst for the oxygen evolution reaction and the hydrogen evolution reaction in alkaline seawater with excellent performance and stability.
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Oxygen-defective ruthenium oxide as an efficient and durable electrocatalyst for acidic oxygen evolution reaction

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06592A, Paper
Jingwei Wang, Lejuan Cai, Zhipeng Yu, Hao Tan, Xinyi Xiang, Kaiyang Xu, Yang Chao, Sitaramanjaneya Mouli Thalluri, Fei Lin, Haoliang Huang, Chenyue Zhang, Yang Zhao, Wenlong Wang, Lifeng Liu
Proton exchange membrane water electrolysis (PEMWE) is considered a promising technology for green hydrogen production in combination with renewable energy. However, the high cost and particularly the scarcity of iridium...
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Recent Advances on Non-noble Metal Catalysts toward N-ethylcarbazole Hydrogen Storage

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06468B, Review Article
Hansai Wu, junming Zhang, Zicong Wang, Xianglong Kong, Gaofu Li, Ying Zhao, Piaoping Yang, Zhiliang Liu
N-ethylcarbazole (NEC) hydrogen storage has garnered significant attention owing to its large-scale safe storage of hydrogen superiority. However, the sluggish hydrogenation kinetics in NEC are extremely dependent on catalysts with...
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Enhanced oxygen exchange kinetics and long-term stability of Ruddlesden-Popper phase Pr4Ni3O10+δ cathode for solid oxide fuel cells

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01845A, Paper
Saim Saher, Affaq Qamar, Chou Yong Tan, Singh Ramesh, Walied Alfraidi
This research explores the intricacies of oxygen exchange kinetics in Pr4Ni3O10+δ (PNO), aiming to assess its potential as a viable cathode material for solid oxide fuel cell applications. Utilizing a...
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PEO/cysteine composite nanofiber-based triboelectric nanogenerator for tiny mechanical energy harvesting

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06845A, Paper
Yijun Hao, Jia Yang, Xiaopeng Zhu, Keke Hong, Jiayu Su, Yong Qin, Wei Su, Hongke Zhang, Chuguo Zhang, Xiuhan Li
Triboelectric nanogenerator (TENG) has acted as a promising method for capturing mechanical energy. However, traditional polymer triboelectric materials result burden to environment, the natural/biodegradable tribo-materials have the disadvantages of poor...
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Scalable Synthesis of N–Doped Graphene–Oxide–Supported FeCo(OH)x Nanosheets for Efficient Co–Doped Fe3O4 Nanoparticle-Based Oxygen Reduction Reaction Electrocatalysis

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06684G, Paper
Open Access
Sunglun Kwon, Jong Hyeon Lee
Developing efficient and cost-effective materials is crucial for advancing electrochemical oxygen reduction reaction (ORR). This study presents a synthesis route for high-performance spinel Fe and Co oxide nanoparticles on N-doped...
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A π–d conjugated metal–organic framework decorated on a MXene-carbon nanofiber as a self-standing electrode for flexible supercapacitors

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06232A, Paper
Zahir Abbas, Shaikh M. Mobin
A c-MOF is grown on MX-CNF, which was prepared via electrospining method. Furthermore, it utilized for flexible supercapcitors with different flexibility angles.
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Machine learning aided design of high performance copper-based sulfide photocathodes

By pubs.rsc.org
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06128D, Paper
Yuxi Cao, Kaijie Shen, Yuanfei Li, Fumei Lan, Zeyu Guo, Kelu Zhang, Kang Wang, Feng Jiang
With the help of machine learning algorithms, we developed software that can predict the performance of copper-based sulfide photocathodes and this system shows excellent accuracy of up to 96%.
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Retraction: Thermally reduced graphene oxide/polymelamine formaldehyde nanocomposite as a high specific capacitance electrochemical supercapacitor electrode

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA90211D, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ali A. Ensafi, Hossein A. Alinajafi, B. Rezaei
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Efficient hydrogen isotope separation utilizing photocatalytic capability

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA07355J, Paper
Linzhen Wu, Sifan Zeng, Weiwei Wang, Shengtai Zhang, Hongbo Li, Xiaosong Zhou
An N–O–C3N4 catalyst for catalytic hydrogen isotope separation.
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Vertical Macroporous Chitosan Aerogel Adsorbents for Simple and Efficient Enhancement of Atmospheric Water Harvesting and Air Dehumidification

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA07005D, Paper
Zhiguang Guo, Changhui Fu, Yuxuan He, Anhui Yu, Guangyi Tian, Danyan Zhan, Huimin Zhang
Adsorption-based atmospheric water harvesting (SAWH) has become one of the effective methods to extract water from the air in arid regions due to its high efficiency and low energy consumption....
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Pre-lithiation carbon anodes mitigating potassium loss toward for high-performance potassium-ion energy storage devices

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06451H, Paper
Danni Du, Qingyuan Liu, Jing Gao, Yuying Qin, Xiaobo Jiang, Yuanchang Shi, Minghao Hua, Xiaohang Lin, Zhiwei Zhang, Chengxiang Wang, Long-Wei Yin, Rutao Wang
Pre-potassiation technologies with the functions of providing additional potassium sources and/or mitigating potassium loss during cycling, make them capable of enhancing the energy density and cycling life of potassium-ion capacitors...
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Electrochemical PET recycling to formate through ethylene glycol oxidation on Ni-Co-S nanosheet arrays

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA07156E, Paper
Yi Ma, Luming Li, Jialing Tang, Zongkun Hu, Yong Zhang, Ning Jian, Huan Ge, Jun Zhao, Andreu Cabot, Junshan Li
Plastics have become an integral part of modern society due to their excellent mechanical properties, lightweight, chemical stability and low cost. However, their continuous production and use worldwide have resulted...
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Synergetic Effects from a High-Entropy NASICON-type Cathode for Advanced Sodium-Ion Batteries

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06950A, Paper
Shouyue Wang, Taiding Xu, Huitao Leng, Shengyu Liang, Wei Zhang, Yuheng Jin, Jingxia Qiu, Sheng Li
Na3V2(PO4)3 (NVP) is recognized as one of the most promising NASICON-type cathodes for sodium-ion storage. Enhancing electronic conductivity and further ensuring long-term structural stability when activating the high-voltage V⁴⁺/V⁵⁺ redox...
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Monte Carlo simulations on temperature-dependent microstructure evolution of relaxor ferroelectric polymers

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06242F, Paper
Tong Guan, Quan-Ao He, Shuang Chen
Poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] relaxor ferroelectrics have drawn a lot of attention nowadays due to their excellent multifunctionality and extensive applications. However, the microstructures behind their relaxor behaviors have not been...
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High-throughput Screening of Mechanically Interlocked Catenane Metal Complexes for Enhanced Electrocatalytic Activity

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06497F, Paper
Mohsen Tamtaji, William A. Goddard III, Guanhua Chen
Metal complexes have been thoroughly investigated for a wide range of electrochemical reactions. However, mechanically interlocked molecular machines (MIM) have not been investigated for electrochemistry through a systematic high throughput...
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Ternary NiFeCo-Glycerolate Catalysts: Rational Design for Improved Oxygen Evolution Reaction Efficiency

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Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06455K, Paper
Irlan Santos Lima, Josué M. Gonçalves, Lúcio Angnes
Catalysts capable of overcoming the bottleneck of water splitting, known as the oxygen evolution reaction (OER), are indispensable to the expansion of renewable energy systems. Thus, we report the synthesis...
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Mike Tomlin on run of AFC North games: I don't care when we play teams

By sports.yahoo.com
Published On :: Tue, 12 Nov 2024 19:41:23 GMT

The Steelers will make a little NFL history this weekend.


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Bears pivot to another potential location for Chicago stadium

By sports.yahoo.com
Published On :: Tue, 12 Nov 2024 20:58:57 GMT

The Bears can't get their effort to muster political support — and taxpayer money — for a new stadium off the ground.


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Can Russell Wilson keep performing at a high level against the Ravens?

By sports.yahoo.com
Published On :: Tue, 12 Nov 2024 21:38:00 GMT

Yahoo fantasy analyst Andy Behrens explains why fantasy managers should roll with the Pittsburgh QB in Week 11 vs. Baltimore.


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Kellen Moore: In Dallas, you have to call plays according to the sun

By sports.yahoo.com
Published On :: Tue, 12 Nov 2024 22:05:13 GMT

Cowboys owner and G.M.


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How PFF graded Purdy, 49ers in Week 10 win vs. Buccaneers

By sports.yahoo.com
Published On :: Tue, 12 Nov 2024 23:09:28 GMT

Jennifer Lee Chan highlights the San Francisco 49ers' PFF grades from the Week 10 win over the Tampa Bay Buccaneers.


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Berlin launches official bid campaign to host an NFL game the next five seasons

By sports.yahoo.com
Published On :: Wed, 13 Nov 2024 01:36:15 GMT

NFL Commissioner Roger Goodell all but said this week that the league will play a game in Berlin next season.


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Clic Casino – Revue de presse

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Published On :: Sun, 31 May 2020 13:10:00 +0000

Blogs Cette fois-ci, nous nous penchons sur le nouveau venu le plus charismatique sur la scène des casinos sans enregistrement, Clic Casino. Ce casino instantané au nom amusant est apparu sur le marché en mars 2020 et a immédiatement frappé la mâchoire des joueurs et des concurrents. Clic Casino est un casino Mozebra Ltd. fonctionnant […]


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Best Online Casino in Australia – Joo Casino Aussie

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Ripper casino Review – Get up to AU$7500 for code ‘RIPPER150’

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Woo Casino – Jurisdictions for Online Casino Gaming

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Published On :: Thu, 05 Aug 2021 10:27:00 +0000

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How to play blackjack online casino at Wager Beat Casino?

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Published On :: Fri, 17 Sep 2021 14:19:00 +0000

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