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U.S. Open: Taylor Fritz beats Frances Tiafoe to become first American man to reach final since 2006

Taylor Fritz has defeated a fading Frances Tiafoe 4-6, 7-5, 4-6, 6-4, 6-1 in an all-American matchup at the U.S. Open to reach his first Grand Slam final




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Aryna Sabalenka beats Jessica Pegula to win U.S. Open women’s title

Sabalenka claimed her third Grand Slam title after winning the Australian Open twice.




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Does Taylor Fritz have what it takes to realise the American dream?

The 26-year-old from California believes his run to the US Open final is repeatable. Is his assessment of his ability and his chances in a new era of men’s tennis reasonable? And can he end a two-decade-long wait for a male singles Grand Slam champion from the USA?




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Frech defeats Gadecki to capture her first career title in the Guadalajara Open

Frech made her first WTA singles final last July in Prague but this was her maiden WTA 500 final and first on hard courts




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Britain fails to reach Davis Cup Finals last eight after losing to Canada

Four groups have been playing in four cities to qualify for the eight-team Finals in Malaga, Spain, in November




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Laver Cup is 2-2 after Fritz and Shelton win doubles from Alcaraz and Zverev

American pair Taylor Fritz and Ben Shelton have edged Carlos Alcaraz and Alexander Zverev in doubles to tie the Laver Cup after the first day in Berlin




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Carlos Alcaraz hopes Davis Cup finals won't be Rafael Nadal's 'last dance'

Carlos Alcaraz said he had "missed" his compatriot at the recent Laver Cup, which Rafael Nadal skipped because of injury.




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WADA appeals to CAS against Jannik Sinner doping verdict, seeks suspension

WADA said it would seek "a period of ineligibility of between one and two years" for Italy's Jannik Sinner




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Jannik Sinner ‘disappointed and surprised’ by WADA appeal over doping case

WADA made the appeal announcement as Sinner was on court at the China Open, where the defending champion fought back to beat 69th-ranked Russian Roman Safiullin 3-6, 6-2, 6-3 in Beijing




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Coco Gauff wins China Open final in straight sets, Sinner and Alcaraz advance in Shanghai

Coco Gauff is also the second American champion in Beijing, following Serena Williams’ title runs in 2004 and 2013




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Wimbledon to replace line judges with electronic line calling after 147 years

While popular with players, the decision will sadden traditionalists and likely mean the end of the arguments over line calls that are part of Wimbledon folklore




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Djokovic tops Nadal before Sinner beats Alcaraz for the title at the Six Kings Slam exhibition

The last dance was an epic one...Tennis will miss you, wrote Novak Djokovic as he topped Rafael Nadal




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Plurality and identity: on the educational relations between chemistry and physics

Chem. Educ. Res. Pract., 2025, Advance Article
DOI: 10.1039/D4RP00288A, Perspective
Pedro J. Sánchez Gómez, Mauricio Suárez
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Contribution of an instructional module, incorporating PhET simulations, to Rwanda students’ knowledge of chemical reactions and acids and bases through Social Interaction.

Chem. Educ. Res. Pract., 2025, Accepted Manuscript
DOI: 10.1039/D4RP00105B, Paper
Jean-Baptiste Ndagijimana, Jeannette Musengimana, Henriette Mushimiyimana, Evode MUKAMA, Olivier Habimana, Paulin Manirakiza , Jean Claude Dushimimana , Jean Pierre Alpha Munyaruhengeri , Samia Khan, Elizabeth Lakin
The current study ascertained the influence an instructional module had on enhancing students’ understanding of chemical reactions and acid-base topics. The sample size for this study consisted of 197 students,...
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Design, development, and evaluation of the organic chemistry representational competence assessment (ORCA)

Chem. Educ. Res. Pract., 2025, Advance Article
DOI: 10.1039/D3RP00188A, Paper
Lyniesha Ward, Fridah Rotich, Jeffrey R. Raker, Regis Komperda, Sachin Nedungadi, Maia Popova
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A systematic review of green and sustainable chemistry training research with pedagogical content knowledge framework: current trends and future directions

Chem. Educ. Res. Pract., 2025, Advance Article
DOI: 10.1039/D4RP00166D, Review Article
Sevgi Aydin Gunbatar, Betul Ekiz Kiran, Yezdan Boz, Elif Selcan Oztay
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Chemical bonding in Swedish upper secondary school education: a force-based teaching model for enhanced understanding

Chem. Educ. Res. Pract., 2025, Accepted Manuscript
DOI: 10.1039/D4RP00258J, Paper
Catalin Koro Arvidsson
This study investigates if a force-based teaching approach, based on quantum mechanical principles and developed in a lesson study, would enhance the understanding of chemical bonding among upper secondary school...
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Superior energy storage properties in SrTiO3-based dielectric ceramics through all-scale hierarchical architecture

Mater. Horiz., 2024, 11,1732-1740
DOI: 10.1039/D3MH01965A, Communication
Chengyang Zuo, Jialing Xu, Shilin Yang, Zhiqin Cao, Hongtao Yu, Jingsong Liu, Xianhua Wei
Improving the energy storage performance of SrTiO3-based ceramics through all-scale architectures combining the effects of atomic-level doping, nanoscale domain engineering, submicroscale grain size regulation, and sample thinning.
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Hybridized local and charge transfer dendrimers with near-unity exciton utilization for enabling high-efficiency solution-processed hyperfluorescent OLEDs

Mater. Horiz., 2024, 11,1741-1751
DOI: 10.1039/D3MH01860A, Communication
Yixiao Yin, Songkun Zeng, Chen Xiao, Peng Fan, Dong Jin Shin, Ki Ju Kim, Hyewon Nam, Qian Ma, Huili Ma, Weiguo Zhu, Taekyung Kim, Jun Yeob Lee, Yafei Wang
Two dendrimers, called D-TTT-H and D-TTT-tBu, were prepared, which exhibits both hot exciton process and TADF characteristic simultaneously in solid state. The solution processable OLED showed an EQEmax of 30.88% employing D-TTT-H as a sensitizer.
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Enhanced photocatalysis of metal/covalent organic frameworks by plasmonic nanoparticles and homo/hetero-junctions

Mater. Horiz., 2024, 11,1611-1637
DOI: 10.1039/D3MH01645E, Review Article
Yannan Liu, Shengyun Huang, Xing Huang, Dongling Ma
Metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) photocatalysts face challenge in poor photocatalytic efficiency, which was promoted by the introduction of plasmonic nanoparticles (NPs) and junctions.
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A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation

Mater. Horiz., 2024, 11,1704-1709
DOI: 10.1039/D3MH01790G, Communication
Peng-Fei Li, Chun-Li Hu, Jiang-Gao Mao, Fang Kong
NCS NaLu(SeO3)2 was designed by framework-optimized structural transformation from CS NaGa(SeO3)2. NaLu(SeO3)2 exhibits large SHG responses, a wide band gap, a short UV cut-off edge, high LIDT, sufficient birefringence and high thermal stability.
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A high-performance and self-powered polarization-sensitive photoelectrochemical-type Bi2O2Te photodetector based on a quasi-solid-state gel electrolyte

Mater. Horiz., 2024, 11,1710-1718
DOI: 10.1039/D3MH01882B, Communication
Song Yang, Shujie Jiao, Yiyin Nie, Yue Zhao, Shiyong Gao, Dongbo Wang, Jinzhong Wang
A quasi-solid-state photoelectrochemical-type Bi2O2Te photodetector exhibits excellent linear polarized light detection capability.
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Elucidating the impact of oxygen functional groups on the catalytic activity of M–N4–C catalysts for the oxygen reduction reaction: a density functional theory and machine learning approach

Mater. Horiz., 2024, 11,1719-1731
DOI: 10.1039/D3MH02115G, Communication
Liang Xie, Wei Zhou, Yuming Huang, Zhibin Qu, Longhao Li, Chaowei Yang, Yani Ding, Junfeng Li, Xiaoxiao Meng, Fei Sun, Jihui Gao, Guangbo Zhao, Yukun Qin
While current experimental and computational studies often concentrate on introducing external structures or idealized MN4 models, we emphasize the often-overlooked impact of inherent OGs within the carbon structure of MN4 materials, presenting a new perspective on their catalytic activity origin.
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Novel magneto-electrocatalyst Cr2CO2-MXene for boosting nitrogen reduction to ammonia

Mater. Horiz., 2024, 11,1769-1778
DOI: 10.1039/D3MH01945D, Communication
Neng Li, Zhongyong Zhang, Zheng Wang, Bin Liu, Deyong Zhou, Xing Zhou, Peng Zhang, Xiujian Zhao
Gibbs free energy for electrocatalytic nitrogen reduction on Cr2CO2 with four magnetic states: NM, FM, Inter-AFM, and In-AFM.
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Distinguishing thermoelectric and photoelectric modes enables intelligent real-time detection of indoor electrical safety hazards

Mater. Horiz., 2024, 11,1679-1688
DOI: 10.1039/D3MH02187D, Communication
Gang Li, Chengzhi Chen, Zijian Liu, Qi Sun, Lirong Liang, Chunyu Du, Guangming Chen
Accurate identification and monitoring of indoor safety hazards can be achieved by integrating a photo-/thermoelectric material that exhibits different nominal Seebeck coefficients in the sensor.
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Hierarchical porous dual-mode thermal management fabrics achieved by regulating solar and body radiations

Mater. Horiz., 2024, 11,1760-1768
DOI: 10.1039/D3MH01938A, Communication
Chuntao Lan, Jia Meng, Chongxiang Pan, Luyao Jia, Xiong Pu
A PTM fabric with cooling and heating abilities is achieved by simultaneously regulating solar and body radiations. The hierarchical porous fabric is suitable for various scenarios (e.g., indoors/outdoors, summer/winter, low/high latitude areas).
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Magnetically driven Janus conical vertical array for all-weather freshwater collection

Mater. Horiz., 2024, 11,1779-1786
DOI: 10.1039/D3MH02083E, Communication
Xiangyi Zhang, Mengyao Zhu, Junhao Chen, Zongwei Wang, Sanchuan Li, Huiyu Yang, Hongman Xu, Guang He, Ziwei Deng, Shaojin Gu, Xin Liu, Bin Shang
The strategy for fabricating a Janus conical vertical array is novel in the integration of solar vapor generation and fog collection, which has great significance for all-weather freshwater production.
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In situ self-reconstructed hierarchical bimetallic oxyhydroxide nanosheets of metallic sulfides for high-efficiency electrochemical water splitting

Mater. Horiz., 2024, 11,1797-1807
DOI: 10.1039/D3MH02090H, Communication
Yaning Fan, Junjun Zhang, Jie Han, Mengyuan Zhang, Weiwei Bao, Hui Su, Nailiang Wang, Pengfei Zhang, Zhenghong Luo
The obtained bimetallic sulfide catalyst can be reconstituted as FeCoOOH, which has high efficacy for water splitting. The activation energy barrier of key reaction steps can be effectively reduced by dual-metal cooperation.
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Advances and challenges in the modification of photoelectrode materials for photoelectrocatalytic water splitting

Mater. Horiz., 2024, 11,1638-1657
DOI: 10.1039/D4MH00020J, Review Article
Longyue Yang, Fang Li, Quanjun Xiang
With the increasing consumption of fossil fuels, the development of clean and renewable alternative fuels has become a top priority.
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Heterostructured grafting of NiFe-layered double hydroxide@TiO2 for boosting photoelectrochemical cathodic protection

Mater. Horiz., 2024, 11,1808-1816
DOI: 10.1039/D3MH02134C, Communication
Zhi-Jun Wang, Hui Xie, Seong Chan Jun, Jiang Li, Li Cheng Wei, Yu Chen Fang, Shude Liu, Ming Ma, Zheng Xing
Grafting NiFe-LDH nanosheets onto TiO2 nanorod arrays largely improves the photoexcited charge separation and accelerates the surface oxidation reaction, leading to stable & self-enhancing photoelectrochemical cathodic protection performance.
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A dual-responsive microemulsion with macroscale superlubricity and largely switchable friction

Mater. Horiz., 2024, 11,1668-1678
DOI: 10.1039/D3MH01978K, Communication
Siwei Chen, Hong Sun, Jian Liu, Jinyu Wang, Hongsheng Lu, Jingcheng Hao, Lu Xu, Weimin Liu
A dual-responsive microemulsion capable of providing macroscale superlubrication in a broad temperature range and switching its coefficient of friction by ∼25 fold is reported. It also shows ultrahigh colloidal stability and anti-freezing properties.
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A reflection on ‘A shape-memory scaffold for macroscale assembly of functional nanoscale building blocks’

Mater. Horiz., 2024, 11,1608-1610
DOI: 10.1039/D4MH90010C, Commentary
Xiang-Sen Meng, Li-Bo Mao, Shu-Hong Yu
Yu et al. reflect on their first Materials Horizons paper (Mater. Horiz., 2014, https://doi.org/10.1039/c3mh00040k) published in the inaugural issue of the journal, and discuss how their work may have influenced the research field over the past decade.
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Aluminothermic reduction of CeO2: mechanism of an economical route to aluminum–cerium alloys

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00087K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alfred Amon, Emily E. Moore, Hunter B. Henderson, Jibril Shittu, Martin Kunz, Shane Kastamo, Nikolai Huotari, Adam Loukus, Ryan Ott, David Weiss, Scott K. McCall
Time-resolved X-ray diffraction enabled mechanistic insight into the aluminothermic reduction of CeO2. The environmentally friendly process enables a direct route to Al–Ce alloy production and a high-value use for excess Ce from rare earth mining.
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Fabrication of polymeric microspheres for biomedical applications

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH01641B, Review Article
Xuebing Li, Luohuizi Li, Dehui Wang, Jun Zhang, Kangfeng Yi, Yucai Su, Jing Luo, Xu Deng, Fei Deng
A systematic summary of fabrication technologies, a variety of structures and biomedical applications of polymeric microspheres.
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Exploring negative thermal expansion materials with bulk framework structures and their relevant scaling relationships through multi-step machine learning

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH01509B, Communication
Yu Cai, Chunyan Wang, Huanli Yuan, Yuan Guo, Jun-Hyung Cho, Xianran Xing, Yu Jia
We uses the multi-step ML method to mine 1000 potential NTE materials from ICSD, MPD and COD databases, and the presented phase diagram can serve as a preliminary criterion for judging and designing new NTE materials.
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Improved photovoltaic performance and stability of perovskite solar cells by adoption of an n-type zwitterionic cathode interlayer

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00253A, Communication
Young Wook Noh, Jung Min Ha, Jung Geon Son, Jongmin Han, Heunjeong Lee, Dae Woo Kim, Min Hun Jee, Woo Gyeong Shin, Shinuk Cho, Jin Young Kim, Myoung Hoon Song, Han Young Woo
Integration of NDI-ZI as a cathode interlayer in perovskite solar cells improves both device efficiency and stability, mitigating halide and Ag ion migration by chemically capturing ions via electrostatic Coulombic interactions.
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N-Type polymeric mixed conductors for all-in-one aqueous electrolyte gated photoelectrochemical transistors

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00267A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Latifah Almulla, Victor Druet, Christopher E. Petoukhoff, Wentao Shan, Nisreen Alshehri, Sophie Griggs, Yazhou Wang, Maryam Alsufyani, Wan Yue, Iain McCulloch, Frédéric Laquai, Sahika Inal
An n-type organic photoelectrochemical transistor produces large and reversible current changes in response to light-intensity variations in aqueous electrolytes. A long exciton lifetime of the n-type gate ensures a high photovoltage response.
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A mechanochemical process to capture and separate carbon dioxide from natural gas using boron nitride nanosheets

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00188E, Communication
Srikanth Mateti, Ying (Ian) Chen, Gautham Sathikumar, Qi Han, Shiva Prasad, Reza Ghandehari Ferdowsi, Amrito Battacharjee
A mechanochemical process to store and separate CO2 gas using boron nitride nanosheets.
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Better nanoscience through open, collaborative, and critical discussions

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH01781H, Opinion
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nathanne Cristina Vilela Rost, Maha Said, Mustafa Gharib, Raphaël Lévy, Federico Boem
Material science publications are the outcome of research, but they can contain errors. We advocate for post publication peer review as a way to collectively improve self-correction of science.
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A bioactive calcium silicate nanowire-containing hydrogel for organoid formation and functionalization

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00228H, Communication
Wenping Ma, Yi Zheng, Guangzhen Yang, Hongjian Zhang, Mingxia Lu, Hongshi Ma, Chengtie Wu, Hongxu Lu
An optimized CS/GelMA composite hydrogel is designed for organoid development, which can be used as a substrate for supporting intestinal and liver organoid formation and functionalization.
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Heterointerface regulation of covalent organic framework-anchored graphene via a solvent-free strategy for high-performance supercapacitor and hybrid capacitive deionization electrodes

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00161C, Communication
Liming Xu, Yong Liu, Xiaoyang Xuan, Xingtao Xu, Yuquan Li, Ting Lu, Likun Pan
A 2D redox-active pyrazine-based COF was solvent-free anchored on graphene for heterointerface regulation, displaying exciting energy storage and desalination performances.
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Construction of hierarchical porous and polydopamine/salicylaldoxime functional zeolite imidazolate framework-8 via controlled etching for uranium adsorption

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02108D, Communication
Kai Tuo, Jin Li, Yi Li, Chuyao Liang, Cuicui Shao, Weifeng Hou, Zhijian Li, Shouzhi Pu, Chunhui Deng
Efficient uranium extraction from seawater is critical for developing the nuclear industry. Herein, a polydopamine/salicylaldoxime decorated hierarchical zeolite imidazolate framework-8 (H-PDA/SA-ZIF-8) is constructed by using a controlled etching process. Benefiting...
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Differential-targeting core-shell microneedle patch with coordinated and prolonged releases of mangiferin and MSC-derived exosomes for scarless skin regeneration

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH01910A, Communication
Shang LYU, Qi Liu, Ho-Yin Yuen, Huizhi Xie, Yuhe Yang, Kelvin Yeung, Chak-Yin Tang, Shuqi Wang, Yaxiong Liu, Bin Li, Yong He, Xin Zhao
Microneedles for skin regeneration are conventionally restricted by uncontrollable multi-drug release, limited types of drugs, and poor wound adhesion. Here, a novel core-shell microneedle patch is developed for scarless skin...
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Polarization double-enhancement strategy to achieve super low energy consumption with ultra-high energy storage capacity in BCZT-based relaxor ferroelectrics

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00322E, Communication
Zixiong Sun, Yuhan Bai, Hongmei Jing, Tian-Yi Hu, Kang Du, Qing Guo, Pan Gao, Ye Tian, Chunrui Ma, Ming Liu, Yongping Pu
Due to dielectric capacitors’ already-obtained fast charge-discharge speed, research has been focused on improving their Wrec. Increasing the polarization and enhancing the voltage endurance are efficient ways to reach higher...
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Time-averaged atomic volume spectrum: locating and identifying vacancies

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00140K, Communication
YongQuan Wu, Hao Wang, JiaHao Fu, BoYang Zhang, Xu Zhao, Kai Zhang
We developed the TAVS method to accurately locate and fully identify vacancies based on a new concept of the atomic cage enwrapping vacancies. This flexible method is believed to be applicable to any type of vacancy in any type of material.
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Biphenyl Tetracarboxylic Acid based Metal-Organic Frameworks: A Case of Topology-Dependent Thermal Expansion

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02185H, Communication
Zhanning Liu, Chengyong Xing, Shaowen Wu, Min Ma, Jian Tian
The large inherent flexibility and highly modular nature of metal-organic frameworks (MOFs) made them ideal candidates for the study of negative thermal expansion (NTE). Among the diverse organic ligands, the...
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High-Entropy Materials for Thermoelectric Applications: Towards Performance and Reliability

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02181E, Review Article
NOUREDINE OUELDNA, Noha Sabi, Hasna Aziam, Vera Trabadelo, Hicham Ben youcef
High-entropy materials (HEMs), including alloys, ceramics and other entropy-stabilized compounds, have attracted considerable attention in different application fields. This is due to their intrinsically unique concept and properties, such as...
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Giant auxetic behavior in remote-plasma synthesized few-layer tungsten semicarbide

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH02193A, Communication
Noah B. Stocek, Farman Ullah, Giovanni Fanchini
We show how remote-plasma synthesis far from thermodynamic equilibrium yields unprecedented 2D crystals and demonstrates the first synthesis of 2D tungsten semicarbide, which was known from theoretical predictions to exhibit giant auxetic behavior.
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Atomic Scale Quantum Anomalous Hall Effect in Monolayer Graphene/MnBi2Te4 Heterostructure

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00165F, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yueh-Ting Yao, Su-Yang Xu, Tay-Rong Chang
The two-dimensional quantum anomalous Hall (QAH) effect is direct evidence of non-trivial Berry curvature topology in condensed matter physics. Searching for QAH in 2D materials, particularly with simplified fabrication methods,...
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Photochemical engineering unsaturated Pt islands on supported Pd nanocrystals for a robust pH-universal hydrogen evolution reaction

Mater. Horiz., 2024, 11,1964-1974
DOI: 10.1039/D3MH02041J, Communication
Yidan Liu, Nuttapon Yodsin, Ting Li, Haocheng Wu, Rongrong Jia, Liyi Shi, Zhuangchai Lai, Supawadee Namuangruk, Lei Huang
Novel core–shell Pd7@Ptx heterostructured nanocrystals with Pt-islands shell of unsaturated coordination edges could be directly photodeposited on a reduced graphene oxide support as a highly efficient HER electrocatalyst in a wide pH range.
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