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Electrodeposited Superaerophobic Nickel Catalyst on Pencil-Drawn Paper: A Novel Approach for Highly Efficient and Stable Hydrogen Evolution

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00101J, Research Article
Qian Sun, Xiaoyu Hao, Tianyi Zhang, Zelin Ma, Kui Hu, Ming Yang, Xiaolei Huang, Xuqing Liu
Electrocatalytic water splitting stands at the forefront of advancing renewable energy technologies. A critical challenge in this realm is the detrimental effect of gas bubble adhesion on electrode surfaces, which...
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Hafnia-based oxide enhanced Ga2O3-based photodetectors via band engineering with ultralarge responsivity

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00490F, Research Article
Han Wu, Jiaying Shen, Lincong Shu, Jie Dai, Shulin Sha, Zeng Liu, Weihua Tang, Yuehui Wang, Zhenping Wu, Kun Lin, Qiang Li, Jun Miao, Xianran Xing
β-Ga2O3 photodetectors achieve ultrahigh responsivity under low supply voltage and ultralow light intensity conditions via band engineering with polar Hf0.5Zr0.5O2 as an insert layer.
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Homochiral Dy2 single-molecule magnets with strong magneto-optical Faraday effect and strong third-harmonic generation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00691G, Research Article
Cai-Ming Liu, Rong Sun, Xiang Hao, Xi-Li Li, Bingwu Wang
Four pairs of homochiral Dy2 complexes were directionally prepared using homochiral β-diketone ligands {D-Htfc/L-Htfc = (+)/(−)-3-trifluoroacetyl camphor, D-Hpfc/L-Hpfc = 3-(perfluorobutyryl)-(+)/(−)-camphor} and hydrazone Schiff base bridging ligands {H2L1 = (E)-N'-(2-hydroxy-3-methoxybenzylidene)pyrazine-2-carbohydrazide, H2L2...
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Radiochromic Semiconductive MOF with High Sensitivity and Fast Photochromic Response for Dual-mode X-ray Direct Detection

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00771A, Research Article
Xuying Yu, Jia-Rong Mi, Qiu-Pei Qin, Xin-Ping Fang, Yong-Fang Han, Li-Zhen Cai, Ming-Sheng Wang, Guo-Cong Guo
X-ray direct detectors, which may directly convert X-rays into electrical signals through semiconductors, are highly desirable for early cancer screening and other applications. Prevailing commercial amorphous Se detectors still suffer...
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Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00519H, Research Article
Tianqi Nie, Guihao Liu, Ziheng Song, Tianyang Shen, Xiaoliang Sun, Tianrui Yu, Sha Bai, Lirong Zheng, Yu-Fei Song
By doping transition metals into CoOx, we can regulate the deintercalation capacity of OH. The CoCuOx with enriched oxygen vacancies allowed the optimization of the competitive adsorption between HMF and OH, and accelerated the kinetics of HMFOR.
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Post-synthetic modification of a covalent organic framework via a thiol–ene reaction for improving fluorescence detection and removal of cationic crystal violet carcinogenic dye

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00419A, Research Article
Ke Li, Bing Yan
Based on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.
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Enhanced photocatalytic CO2 reduction by controlled oxygen vacancy generation and co-constructed heterojunction strategy for Pd/CeO2

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00581C, Research Article
Fanlin Kong, Xiaoyan Lu, Jing Xie, Zhenjiang Lu, Jindou Hu, Yali Cao
Rational control of Vo concentration and the construction of a heterojunction strategy enable Pd/CeO2-Vo(r) to exhibit excellent photocatalytic CO2RR activity. The presence of COOHcreates favorable conditions for CO formation and desorption.
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Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00200H, Research Article
Yong-Sheng Shi, Tong Xiao, Dong-Dong Yang, Xiangjun Zheng
A viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....
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Phase switching and shape-memory effect in a molecular material: revisiting the Werner complex [Ni(4-MePy)4(NCS)2]

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00636D, Research Article
Open Access
Shi-Qiang Wang, Shaza Darwish, Catiucia Matos, Zicong Marvin Wong, Anjaiah Nalaparaju, Yifei Luo, Jun Zhu, Xiaofei Zhang, Zhengtao Xu, Michael Zaworotko
Shape-memory effects and stimuli-induced phase transformations are observed across many types of materials but remain understudied in molecular materials. In this contribution, we revisit the Werner complex, [Ni(4-MePy)4(NCS)2] (4-MePy =...
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Structural and electrochemical properties of Tan+1Cn MXene anode materials for metal-ion batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02335D, Research Article
Jiayi Guo, Danni Hu, Chenqi Bai, Lina Xu, Hongping Xiao, Qian Shi, Xinhua Li, Xi'an Chen, Yingjin Ma, Guoyong Fang
Density functional theory calculations show that Tan+1Cn and Tan+1CnO2 MXenes have excellent open circuit voltages and maximum storage capacities for use in alkali metal-ion batteries.
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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
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Tuning lithium–yttrium chloride local structure through coordination control and mixing during synthesis

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00559G, Research Article
Open Access
Teerth Brahmbhatt, Cheng Li, Mounesha N. Garaga, Wan-Yu Tsai, Steve G. Greenbaum, Jagjit Nanda, Robert L. Sacci
Synthesis of Li3YCl6 is facilitated by the addition of NH4Cl. Synthesis method affects local ordering and Li+ dynamics as determined by neutron diffraction, impedance and NMR spectroscopy.
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Row over ISMA’s suggestion to regulate khandsari units

Opposing curbs, traditional sweeteners body BHAKTI says Centre should not be swayed by false narratives




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Global Organic Textiles Standards bans 5 Indian cotton firms for faking documents

Two firms used non-existent shipping firms to show transactions, the others submitted fake transaction certificates




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Kandla Customs Commissioner orders release of ship detained in organic rice export irregularities

Tells Kandla traffic manager to allow another ship to set sail after getting release order from Gujarat HC




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Global steel demand to drop a tad in 2024, rebound in 2025: worldsteel

Ongoing weakness in housing construction, driven by tight financing conditions and high costs, cited as reason for the fall in demand




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Crude oil down due to concerns over slowing demand in China 

Market is also cautious about a potential increase in global oil supply as the OPEC+ is planning to restore production output in December




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Diesel, petrol demand to grow 50,000-55,000 barrels per day Y-o-Y in Oct-Dec

India’s appetite for oil products in October-December is set to get a boost from the upcoming festival season as well as the agricultural season




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Festivals, agriculture, elections set to boost India's oil demand: S&P Global Commodity Insights

According to the commodities information services provider, India's oil demand decreased in September on a yearly basis, due to above normal rainfall, which affected road movement, construction, and mining activities




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India’s iron ore, manganese, aluminium output rises in H1 FY25 amid strong demand

Iron ore production rose by 5.5% to 135 million tonnes, while manganese ore output increased by 6.2% to 1.7 million tonnes




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Manufacturing method of lab grown diamonds should be declared before export and import: CBIC

The new norms, which will help in quick processing and inspection of consignments, are to be effective from December 1




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Trump effect: Base metal prices surge on demand spike after slumping post-Trump win

Aluminium, zinc and copper futures climb on November 7, the day after Trump’s election, say PTI reports




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Down the AI rabbit hole, strewn with health benefits and ethical pitfalls 

Regulatory frameworks covering AI need fine-tuning to harness its potential without halting growth 




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Calisthenics, rock-climbing and laughter




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Balancing innovation and access to healthcare

The draft Patent (Amendment) Rules, 2023, have prompted extensive discussion and debate, drawing attention to India’s pivotal role in providing affordable medicines, especially to those in need




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Mountain rides, mindfulness and insightful reading

Start your day with InsuranceDekho CTO Ish Babbar’s morning mindfulness routine: deep breathing, stretching, running & more




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Counting calories, steps and taking off-road rides

Varun Madan, Founder and CEO, Salad Days, on food, fitness, travel and much more.




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A pitch to walk the fine line between innovation and access

 Ahead of USTR’s Special 301 report, India campaigns for flexibilities in international trade laws




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Sport, me-time and a mindful diet

Chief product officer of Adroit Vantage on consistent exercise, prioritising sport and mental health for a balanced and satisfying fitness journey




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Morning run, nutritious meals and unwinding

Prioritise mornings with running, balanced diet, revitalizing workouts and meditation for mental health, says Nishant Pitti, CEO and Co-Founder, EaseMyTrip




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Jal neti kriya, nature treks and Kulfi

Dhiraj Singh, CEO, SIS Group on energising morning routines, nature treks, quality sleep and a healthy diet for overall well-being




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Cricket, cooking and the classics to unwind

Director and CEO of Sahyadri Hospitals on finding joy in cricket, cooking, gym, and movies for relaxation and wellness




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PLI, plugging chinks in the country’s manufacturing armour for drugs and devices

 Call for simplification of licencing regimes gets louder even as benefits become tangible 




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Tennis, yoga and unwinding with a book

Ritesh Kumar’s daily routine includes yoga, a plant-based diet, contemplation, tennis, and unwinding with a good book.




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Health and climate @work

April 28 is World safety and health at work day




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Pharmacies journey through litigations and another election

Chemists’ manifesto: Call for fair play gets louder amidst deep discounts from online pharmacies




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MMA, Wim Hof breathing and intermittent fasting

Boost your day with Wim Hof breathing, meditation, MMA, fasting, and outdoor exercise for optimal health and wellness




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Walks, conscious nutrition and switching off with Buzo

Akshay Chaturvedi, Founder CEO of Leverage.biz, shares tips on health, fitness and his beloved German shepherd




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Mountain hikes, for fitness and zen

Uma R Krishnan, MD, Optum India, on her exercise routine, favourite cuisines and tips to manage stress




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Redefining the regulatory pathway for nutraceutical and pharmaceutical products

As the nutraceutical landscape grows, experts call for clarity in the manufacturing debate




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Flying, cooking and caring for cows

Goldi Solar’s Founder & MD on his passion for wheels, meditation and Gaukalyanam




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Health and climate meet

The ‘Health argument for climate action’ meet on the sidelines of the High-Level Political Forum on Sustainable Development (July 9) — will review SDG Goal 13




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Pranayam, veggie smoothies and adventure sports

Dr Sanjay Katkar on staying active, healthy eating and meditation for a balanced lifestyle




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Dial M for mental health support and ring-in resilience

From workplace woes to societal pressures, it’s time mental health became a priority




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Mindful eating, short walks and melatonin window of sleep

Founder & CEO, Khyaal, Hemanshu Jain, on his exercise routine, practising mindful eating and more.




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Golf, gluten-free diet, and music

Personal fitness diary




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Maharashtra’s sugar mills warn of potential halt to cane crushing season over MSP and ethanol price stalemate

Despite annual hikes in the Fair and Remunerative Price (FRP) for sugarcane, the MSP of sugar has remained unchanged since 2019




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Subdued blenders’ demand hits Coonoor tea auctions sales 

Sales drop to less than 70 per cent in leaf and dust




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Helping lift economic status of rural women — the Kissandhan way!

The SLCM subsidiary offers short-term loans, plans new products with longer term