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Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00254G, Research Article
Yan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng Yang
An adjustable template effect was employed to activate the evolution of polyoxovanadate-based metal–organic clusters, resulting in unprecedented structural archetypes as well as customized dye and iodine adsorption features.
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Near-infrared-photoinduced metamagnet based on a layered cyanido-bridged Co–W assembly with π–π interactions

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Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00511B, Research Article
Open Access
Kazuki Nakamura, Koji Nakabayashi, Shota Kobayashi, Shin-ichi Ohkoshi
A cyanido-bridged Co–W assembly with π–π interactions showed a thermal phase transition and a photo–induced metamagnetism based on a charge transfer–induced spin transition.
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Yellow-Emissive Organic Copper(I) Halide Single Crystals with [Cu4I4] Cubane Unit as Efficient X-ray Scintillators

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Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00500G, Research Article
Qingzheng Kong, Xiaomei Jiang, Ying Sun, Jianguo Zhu, Xutang Tao
Recently, low-dimensional copper(I)-based halide is considered as a potential substitute for lead-based counterpart due to its environmental friendliness, facile preparation and superior luminescence performances. In particular, as a representative of...
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Integrating multiple regulatory strategies: phase, morphology and interface engineering to construct a hierarchical Ni2P–MoS2/rGO heterostructure catalyst for efficient oxygen reduction reaction

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00262H, Research Article
Xinyi Wang, Jing Jin, Zeyuan Gao, Li Hou, Xiwen Tao, Jing Wang, Yueqi Zhao, Faming Gao
Two-dimensional (2D) molybdenum disulfide (MoS2) with a large surface area and unique electronic properties has emerged as a promising noble metal-free catalyst for electrochemical energy storage/conversion applications.
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Efficient doped and non-doped light-emitting diodes based on a TADF-emitting Cu4Br4 cluster

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00210E, Research Article
Xin Lu, Shao-Jie Wu, Ya-Shu Wang, Shan-Yue Wei, Lingyi Meng, Xi-He Huang, Xu-Lin Chen, Can-Zhong Lu
A sublimable Cu4Br4 cluster, chelated by bidentate N^P ligands with a donor–acceptor configuration, realizes highly efficient doped and non-doped cluster light-emitting diodes.
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Achieving high-sensitivity dual-mode optical thermometry via phonon-assisted cross-relaxation in a double-perovskite structured up-conversion phosphor

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00395K, Research Article
Houhe Dong, Zonghao Lei, Shikun Su, Wenhua Yang, Xuyang Zhang, Wenying Teng, Guangyue Zu, Bing Teng, Degao Zhong
By adjusting the phonon energy of the host crystal (Ca2+/Sr2+/Ba2+) LaLiTeO6:Yb3+, Tm3+ phosphor, combined with the cross-relaxation phenomenon, a high-sensitivity thermometer for dual-mode temperature measurement was constructed.
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Porphyrin-based MOFs for photocatalysis in water: advancements in solar fuels generation and pollutants degradation

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2212-2245
DOI: 10.1039/D3QI01996A, Review Article
Open Access
Fangbing Liu, Irene Rincón, Herme G. Baldoví, Amarajothi Dhakshinamoorthy, Patricia Horcajada, Sara Rojas, Sergio Navalón, Alexandra Fateeva
This review highlights the recent advances in the photocatalytic applications of porphyrin-based MOFs in aqueous environments for solar fuel generation and water remediation.
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Selenium doping induced phase transformation and interlayer expansion boost the zinc storage performance of molybdenum disulfide

By pubs.rsc.org
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Inorg. Chem. Front., 2024, 11,2272-2280
DOI: 10.1039/D4QI00344F, Research Article
Mengfan Niu, Wenli Xin, Lei Zhang, Min Yang, Yaheng Geng, Xilin Xiao, Hui Zhang, Zhiqiang Zhu
This work synthesized Se-doped MoS2 nanosheets as a cathode for aqueous zinc-ion batteries, and they exhibited largely improved electrochemical performance owing to their high content of the 1T phase (64%) and expanded interlayer spacing (0.65 nm).
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Solvent-modulated assembly of peptide and cerium functionalized gigantic {Mo120Ce6}2 dimers for high-efficiency photocatalytic oxidation

By pubs.rsc.org
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Inorg. Chem. Front., 2024, 11,2355-2364
DOI: 10.1039/D4QI00339J, Research Article
Dexiang Zhou, Bingbing Li, Qixin Zhao, Xinyu Tang, Tingya Lan, Heyang Su, Guoping Yang, Weimin Xuan
Two gigantic peptide and cerium functionalized {Mo120Ce6}2 dimers have been constructed via a solvent-modulated assembly and applied for effective photocatalytic aerobic oxidation of sulfides to sulfoxides.
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Achieving a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets by hydroiodic acid-assisted ligand treatment

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2392-2401
DOI: 10.1039/D4QI00168K, Research Article
Zongnan Li, Yusheng Song, Sheng Cao, Ke Xing, Zhentao Du, Bingsuo Zou, Jialong Zhao
We demonstrate a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets achieved through a hydroiodic acid-assisted ligand treatment strategy, showcasing their application in perovskite LEDs.
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Structural phase transition drives outright photoluminescence quenching and dielectric duple bistable switching

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2290-2299
DOI: 10.1039/D4QI00303A, Research Article
Open Access
Zhi-Jie Wang, Ming-Jing Shen, Zhi-Peng Rao, Pei-Zhi Huang, Meng-Meng Lun, Bo-Wen Deng, Jun-Yi Li, Chang-Feng Wang, Hai-Feng Lu, Da-Wei Fu, Yi Zhang
(TECA)PbBr3 and (TEBA)PbBr3 have a wide range of photoluminescence signals and undergo coupling of the structural phase transition and photoluminescence quenching.
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Bulk single crystal growth and optoelectronic properties of the quasi-two-dimensional perovskites (CH3NH3)3Bi2X9 (X− = Br− and I−)

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2442-2456
DOI: 10.1039/D3QI02687F, Research Article
Zhiyuan Li, Xiangjun Wang, Peng Zhao, Jingquan Liu, Xiangxin Tian
Single crystals of MA3Bi2X9 (X = Br, I) with quasi-two-dimensional structures were successfully grown and the relationship between the compositions, dimensionality, and properties were discussed.
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Perovskite photoinitiated RAFT-mediated polymerization-induced self-assembly for organic–inorganic hybrid nanomaterials

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Inorg. Chem. Front., 2024, 11,2471-2478
DOI: 10.1039/D4QI00233D, Research Article
Bingfeng Shi, Wanchao Hu, Shiyi Li, Zhinan Xia, Changli Lü
An efficient strategy is proposed to construct PQD/polymer organic–inorganic nanohybrids by PET-RAFT polymerization-mediated PISA and the nanohybrid assemblies can maintain excellent luminescence originating from PQDs with enhanced stability.
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A composite electrolyte based on aluminum oxide filler/polyester polymer via in situ thermal polymerization for long-cycle sodium metal batteries

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2300-2311
DOI: 10.1039/D4QI00391H, Research Article
Qiujun Wang, Xin He, Di Zhang, Zhaojin Li, Huilan Sun, Qujiang Sun, Bo Wang, Li-Zhen Fan
The introduction of Al2O3 regulates the solvation structure of Na+, which is conducive to the formation of inorganic-rich SEI. Na|THFA-5|Na cell maintains low polarization voltage, indicating that uniform Na depositions was successfully achieved.
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Energetic copper(II) quadridentate chelate: a novel green laser-sensitive primary explosive

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00489B, Research Article
Qi Zhang, Ruibing Lv, Ying Wang, Zhenghang Luo, Pengyang Pan, Tingwei Wang, Quancheng Liu
A copper(II)-based quadridentate chelate [Cu(BNATE)·2H2O] has been prepared and systematically studied. It has excellent near-infrared laser sensitivity and detonation performance, and low mechanical sensitivity.
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Stable Calcium Ellagate Metal-Organic Framework as High Performance Green Memorizer Bearing High Working Temperature

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00038B, Research Article
Ting-Bo Liu, Jing-Wen Deng, Li Yi, Hai-Ying Fu, Liang-Wen Shi, Shi-Ying Lin, Yue Liu, Hao-Hong Li, Jing-Bo Liu, Jian-Zhi Liu
The development of green memorizers with distinct mechanism is significant. In this work, renewable polyphenol ellagic acid (EA) and environmentally friendly calcium were used to construct a unique 3D interpenetrated...
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CDs "inserted" abundant FeB based electrode via "local photothermal effect" strategy toward efficient overall seawater splitting

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00415A, Research Article
Shiheng Liang, Liugang Wu, Yiming Wang, Yuqi Shao, Hongyuan Song, Ziliang Chen, Weiju Hao
Construction of high-efficiency, long-stable catalytic electrodes for hydrogen by seawater splitting is a huge challenge in the field of green hydrogen. Herein, a matrix-type titanium dioxide nanorod (Ti/TiO2) is constructed...
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Hafnia-based oxide enhanced Ga2O3-based photodetectors via band engineering with ultralarge responsivity

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00490F, Research Article
Han Wu, Jiaying Shen, Lincong Shu, Jie Dai, Shulin Sha, Zeng Liu, Weihua Tang, Yuehui Wang, Zhenping Wu, Kun Lin, Qiang Li, Jun Miao, Xianran Xing
β-Ga2O3 photodetectors achieve ultrahigh responsivity under low supply voltage and ultralow light intensity conditions via band engineering with polar Hf0.5Zr0.5O2 as an insert layer.
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A wheel-like polyoxometalate for haloperoxidase inspired antibiofouling with H2O2 in-situ provided by electrocatalysis

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00482E, Research Article
Yumeng Bian, Runze Wang, xinxin xu, Jin Chen, Qiang Wang
Biofouling is adhering of micro-organisms on submerged surfaces, which is a common phenomenon presents serious hazard to industry and public health. Nanozymes with haloperoxidase mimic activity are promising options to...
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Radiochromic Semiconductive MOF with High Sensitivity and Fast Photochromic Response for Dual-mode X-ray Direct Detection

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00771A, Research Article
Xuying Yu, Jia-Rong Mi, Qiu-Pei Qin, Xin-Ping Fang, Yong-Fang Han, Li-Zhen Cai, Ming-Sheng Wang, Guo-Cong Guo
X-ray direct detectors, which may directly convert X-rays into electrical signals through semiconductors, are highly desirable for early cancer screening and other applications. Prevailing commercial amorphous Se detectors still suffer...
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Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00519H, Research Article
Tianqi Nie, Guihao Liu, Ziheng Song, Tianyang Shen, Xiaoliang Sun, Tianrui Yu, Sha Bai, Lirong Zheng, Yu-Fei Song
By doping transition metals into CoOx, we can regulate the deintercalation capacity of OH−. The CoCuOx with enriched oxygen vacancies allowed the optimization of the competitive adsorption between HMF and OH−, and accelerated the kinetics of HMFOR.
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Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00200H, Research Article
Yong-Sheng Shi, Tong Xiao, Dong-Dong Yang, Xiangjun Zheng
A viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....
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Phase switching and shape-memory effect in a molecular material: revisiting the Werner complex [Ni(4-MePy)4(NCS)2]

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00636D, Research Article
Open Access
Shi-Qiang Wang, Shaza Darwish, Catiucia Matos, Zicong Marvin Wong, Anjaiah Nalaparaju, Yifei Luo, Jun Zhu, Xiaofei Zhang, Zhengtao Xu, Michael Zaworotko
Shape-memory effects and stimuli-induced phase transformations are observed across many types of materials but remain understudied in molecular materials. In this contribution, we revisit the Werner complex, [Ni(4-MePy)4(NCS)2] (4-MePy =...
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Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
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Unleashing the power of directed electron transfer: unraveling the potential of {PV4}2 in heterogeneous photocatalysis

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00606B, Research Article
Xin Su, Yuzan He, Kunhong Li, Miao Wang, Wei Tang, Shihao Zhang, Pengtao Ma, Jingyang Niu, Jingping Wang
{PV4}2 unleash the power of directed electron transfer in heterogeneous photocatalysis reduction.
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Asian rice prices drop after India eases export curbs

By www.thehindubusinessline.com
Published On :: Fri, 04 Oct 2024 19:49:50 +0530

FAO says market down by $10-72 a tonne, Thai cuts rates by 10%


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National Mission on Edible Oil to help increase production to 25 mt by 2030-31: SEA

By www.thehindubusinessline.com
Published On :: Fri, 04 Oct 2024 22:04:57 +0530

Over 60 per cent of edible oil requirement is now met through imports, which is a cause for concern, says SEA president Sanjeev Asthana


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India dominates global natural gas contracts in 2024, cornering 30% of share

By www.thehindubusinessline.com
Published On :: Tue, 08 Oct 2024 15:18:37 +0530

The Middle East, led by Qatar, was the primary exporter, while Asian countries, notably India and China, were key importers


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SEBI explores feasibility of introducing crude oil ETFs

By www.thehindubusinessline.com
Published On :: Tue, 08 Oct 2024 21:26:29 +0530

Such ETFs own futures contracts on crude oil instead of the commodity itself. The ETF price will mimic the spot price.


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Indian rice exports get delayed at ports as Customs officials hold up consignments

By www.thehindubusinessline.com
Published On :: Wed, 09 Oct 2024 18:52:39 +0530

Exporters say they incur $70/tonne additional costs; Customs officials playing safe to verify if shipments are white or parboiled rice


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Optimism in global commodities market over Chinese measures may be short-lived, say analysts

By www.thehindubusinessline.com
Published On :: Thu, 10 Oct 2024 16:03:50 +0530

Subdued demand, struggling property sector may exert downward pressure on metals


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Crude oil futures dip amid easing Middle East tensions

By www.thehindubusinessline.com
Published On :: Tue, 15 Oct 2024 10:12:40 +0530

Brent and WTI oil futures saw declines of over 3%, with MCX crude oil futures also experiencing significant drops.


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MCX launches cottonseed wash oil futures contract

By www.thehindubusinessline.com
Published On :: Tue, 15 Oct 2024 17:55:03 +0530

It will offer a robust price risk management solutions for the cottonseed oil industry


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Your cuppa to cost more as coffee roasters set to hike prices

By www.thehindubusinessline.com
Published On :: Tue, 15 Oct 2024 20:08:10 +0530

Auction prices have more than doubled since the beginning of the year as domestic prices tail global trend


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Aluminium futures retain positive bias

By www.thehindubusinessline.com
Published On :: Thu, 17 Oct 2024 16:17:26 +0530

The price region between ₹228 and ₹230 is a demand zone


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Kandla Customs Commissioner orders release of ship detained in organic rice export irregularities

By www.thehindubusinessline.com
Published On :: Thu, 17 Oct 2024 18:10:31 +0530

Tells Kandla traffic manager to allow another ship to set sail after getting release order from Gujarat HC


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Crude oil futures rise as US inventories decline 

By www.thehindubusinessline.com
Published On :: Fri, 18 Oct 2024 10:14:15 +0530

Market players are also assessing the supply risks from West Asia following the tensions in the region


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India decides to ease rice export curbs further

By www.thehindubusinessline.com
Published On :: Fri, 18 Oct 2024 20:37:24 +0530

High-level inter-ministerial meeting clears scrapping $490/t MEP on white rice, 10% export duty on parboiled rice


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SEA survey estimates 27% increase in Gujarat groundnut production this season

By www.thehindubusinessline.com
Published On :: Sat, 19 Oct 2024 17:01:27 +0530

Good rains this year and the increase in acreage might help Gujarat achieve a record groundnut production of 42.19 lakh tonnes this year, surpassing the previous record of 38.55 lakh tonnes set in 2021-22


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Crude oil futures rise as China cuts key lending rates

By www.thehindubusinessline.com
Published On :: Mon, 21 Oct 2024 10:18:13 +0530

In India, October crude oil futures traded slightly lower at ₹5,850


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Natural gas: Futures in bear grip

By www.thehindubusinessline.com
Published On :: Mon, 21 Oct 2024 13:40:02 +0530

Traders can consider going short 


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Crude oil futures slip as industry data shows increase in US inventory 

By www.thehindubusinessline.com
Published On :: Wed, 23 Oct 2024 10:44:12 +0530

US crude oil inventories rose by 1.64 million barrels for the week ended October 18. Market estimates had earlier pegged increase at 0.7 million barrels


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SEA asks members not to increase prices of old stock of edible oil

By www.thehindubusinessline.com
Published On :: Wed, 23 Oct 2024 17:46:06 +0530

Solvent extractors seek Centre’s help to export oilmeals


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India’s diesel consumption likely to surpass 93 mt in FY25

By www.thehindubusinessline.com
Published On :: Wed, 23 Oct 2024 21:51:03 +0530

Both August and September this year have witnessed a fall in diesel usage


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Crude oil trades higher as market monitors developments in West Asia 

By www.thehindubusinessline.com
Published On :: Fri, 25 Oct 2024 10:22:57 +0530

At 9.56 am on Friday, December Brent oil futures were at $74.50, up by 0.16 per cent, and December crude oil futures on WTI (West Texas Intermediate) were at $70.28, up by 0.13 per cent


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Easing West Asia tensions bring back overseas tea buyers to Kochi 

By www.thehindubusinessline.com
Published On :: Fri, 25 Oct 2024 18:34:43 +0530

Sales percentage increases as Russian buyers turn active


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CCI begins purchase of cotton for 2024-25 season at MSP from Telangana

By www.thehindubusinessline.com
Published On :: Mon, 28 Oct 2024 11:56:19 +0530

The Centre has declared an MSP of Rs ₹7,121 per quintal for the medium staple and Rs ₹7,521 per quintal for the longer variety for the 2024-25 cropping season, an increase of around 7 per cent over previous year


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Crude oil trades higher as industry data shows decrease in US inventories 

By www.thehindubusinessline.com
Published On :: Wed, 30 Oct 2024 10:14:13 +0530

Official data on crude oil inventory level in the US is expected later on Wednesday


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Praveena Rai takes charge as CEO of MCX

By www.thehindubusinessline.com
Published On :: Fri, 01 Nov 2024 10:04:07 +0530

Praveena Rai succeeds P S Reddy, who completed his five-year tenure in May 2024


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Crude oil futures rise as OPEC delays production output increase

By www.thehindubusinessline.com
Published On :: Mon, 04 Nov 2024 10:35:58 +0530

Increase in tensions in West Asia also boosted the price of the commodity. The latest developments in West Asia have created apprehensions in the market over possible crude oil supply disruptions from the region.


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