3

Realty sector rises 63%, outshining Nifty50; more firms eye IPOs

The sector is attracting new entrants via record IPOs, with seven listings raising ₹13,550 crore in 2024, showing strong investor interest in this thriving market.




3

Iron-catalyzed thiolation of C(sp3)–H with sulfonyl chlorides via photoinduced ligand-to-metal charge transfer

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01488J, Research Article
Sheng-Ping Liu, Lan Yang, Yan-Hong He, Zhi Guan
A photoinduced FeCl3/HCl synergistic catalytic method enables C(sp3)–S bond formation via reductive cross-coupling of activated/inert C(sp3)–H and aryl/alkyl sulfonyl chlorides through ligand-to-metal charge transfer (LMCT).
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3

Photocatalytic arylation/alkylation of olefins/alkynes via halogen-atom transfer mediated by NHC-BH3

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01562B, Research Article
Xinhan Li, Yao Zhong, Fengsong Tan, Yusong Fei, Xiaohan Zhao, Jianbin Xu, Baomin Fan
A versatile method for radical reductive cross-coupling of iodides and activated olefins under mild conditions, facilitated by NHC-BH3 through photocatalysis, was developed.
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3

Chiral synthetic unprecedented spiro[indoline-2,3'-thiophen]-3-ones via an organocatalytic asymmetric sulfa-Michael/aldol cascade reaction

Org. Chem. Front., 2024, 11,6426-6436
DOI: 10.1039/D4QO01551G, Research Article
Mao Zhang, Xing-Hai Fei, Gui-Ping Yang, Cheng Lin, Wen-Jie Li, Ming-Liang Rao, Meng Zhou, Chong Zhao, Bin He, Yong-Long Zhao
A cinchona-derived squaramide-catalyzed asymmetric sulfa-Michael/aldol cascade reaction of 2-ylideneoxindoles with 1,4-dithiane-2,5-diol was developed to realize the chiral synthesis of spiro[indoline-2,3'-thiophen]-3-ones.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Visible light-induced aerobic photooxidative cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes

Org. Chem. Front., 2024, 11,6385-6392
DOI: 10.1039/D4QO01243G, Research Article
Jinyu Tang, Xi Zhao, Jinxuan Ni, Yanping Huo, Yang Gao, Xianwei Li, Yan Liu, Keiji Maruoka, Qian Chen
A cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes to aromatic aldehydes and ketones has been achieved via a visible light-induced photocatalysis.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Theoretical insights into Pd-catalyzed dual γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids: mechanistic pathways, substituent influence on product selectivity, diastereoselectivity, and additive effects

Org. Chem. Front., 2024, 11,6393-6410
DOI: 10.1039/D4QO01451K, Research Article
Jiaoyang Liu, Li-juan Huang, Zeang Sun, Juan Li
DFT calculations were employed to explore the detailed reaction mechanism and the origins of the experimentally observed product, regio-, and diastereoselectivities in the Pd-catalyzed dual-γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01388C, Research Article
Shanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian Cai
A two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.
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The content of this RSS Feed (c) The Royal Society of Chemistry




3

Enantioselective Addition of 3-hydroxyquinolin-2(1H)-one to Isatin and Pyrazole-4,5-dione Derived Ketimines

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01895H, Research Article
Yue Wei, Guishun Bai, Jiamin Wu, Yi Hua, Tao Zhang, Congyong Yue, Hong Wang, Xiaoze Bao
The enantioselective reactivity of 3-hydroxyquinolin-2(1H)-ones was developed through their addition to isatin and pyrazole-4,5-dione derived ketimines, affording novel architectures featuring multiple natural products scaffolds in high yield with excellent enantioselectivities....
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Facile single-step synthesis of pentaaryl-substituted pyrano[3,2-b]pyrrol-5(1H)-ones showing aggregation-induced emission

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01600A, Research Article
Yongfeng Wang, Ruijun Chu, Yanxiao Wang, Mengyuan Zhou, Yuan Chen, Cheng Xu, Jingyu Sun, Guodong Yin
A novel class of heterocyclic AIEgens has been synthesized via a multicomponent reaction of isatins, 2,3-diaryl cyclopropenones, and alkyl bromides.
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The content of this RSS Feed (c) The Royal Society of Chemistry




3

Metal–ligand cooperation and synergistic palladium catalysis for the dual ligand system [2,2'-bipyridin]-6(1H)–one/PCy3: milder conditions for the undirected C–H arylation of arenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01877J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Cintya Pinilla, Mario García-Zarza, Ana C. Albéniz
The mixture of Pd(OAc)2 and two ligands segregate into distinct active species working synergistically for the C–H arylation of simple arenes.
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The content of this RSS Feed (c) The Royal Society of Chemistry




3

Synthesis of oxa-bridged carbocycles via rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained carbocycles

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01831A, Research Article
Jiale Li, Lingfei Wang, Pei-Nian Liu, Xingguang Li
A method for cooperative rhodium/Lewis acid-catalyzed cycloadditions of carbonyl ylides with donor–acceptor (D–A) strained carbocycles is described. It affords structurally diverse oxa-bridged carbocycles with high efficiency and stereoselectivity.
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The content of this RSS Feed (c) The Royal Society of Chemistry




3

Transition-metal-free skeletal editing of benzoisothiazol-3-ones to 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01714E, Research Article
Ke Yang, Qin Li, Yanqi Luo, Dan Yuan, Chunjian Qi, Zhengyi Li, Bijin Li, Xiaoqiang Sun
Transition-metal-free ring expansion of benzoisothiazol-3-ones has been established to construct various 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion.
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The content of this RSS Feed (c) The Royal Society of Chemistry




3

PIFA-Mediated cyclization of methyl(2-(1-phenylvinyl)phenyl)sulfane for the concise, flexible, and scalable de novo synthesis of C3-arylated benzo[b]thiophenes

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01589D, Research Article
Xinya Liu, Olivier Provot, Christine Tran, Jean-Francois Soule, Abdallah Hamze
The well-decorated arylated benzo[b]thiophene scaffold is a pivotal structural motif with diverse applications in medicinal chemistry. This paper outlines a de novo synthesis of C3-arylated benzo[b]thiophenes, showcasing its flexibility and...
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Rhodium-catalyzed synthesis of N-substituted 3-acylpyrroles from enaminones and vinylene carbonate

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01816H, Research Article
Sheng-Jiao Yan, Jian-Bo Ma, Yi-Mai Yin, Xing-Mei Hu, Bi-Na Shao, Kun Huang, Qing-Sheng Zhao
Skeletal editing is a highly efficient strategy for modifying the core scaffolds of drug molecules, with multi-atomic editing as an emergent approach. Herein, we present a protocol for constructing N-substituted...
The content of this RSS Feed (c) The Royal Society of Chemistry




3

TGSRTC Karimnagar region to operate special buses to Arunachala Hill in Tamil Nadu on November 13




3

Congress shedding ‘çrocodile tears’ over BCs welfare: BJP leader Laxman




3

Ugandan woman sentenced to 13 years RI for smuggling drugs to Hyderabad

The woman was caught attempting to smuggle 3,900 grams of heroin, worth ₹25 crore, to Hyderabad




3

Hyderabad man loses ₹1.73 lakh trying to get 0% interest loan on insurance policy worth ₹10 lakh




3

32 STPs taken up by BRS govt. to cleanse Musi: MLAs

₹3.8k crore STP project was to protect Nalgonda ryots’ farm fields from sewage water




3

Telangana delegation to embark on 3-day study tour in Karnataka for fisheries development




3

Letters to the Editor dated July 3, 2024 




3

Letters to the Editor dated July 30, 2024




3

Letters to the Editor dated July 31, 2024




3

Letters to the Editor dated August 13, 2024




3

Letters to the Editor dated August 23, 2024 




3

Letters to the Editor dated August 30, 2024




3

Letters to the Editor dated September 3, 2024




3

Letters to the Editor dated September 13, 2024




3

Letters to Editor the editor dated September 23, 2024




3

Letters to the Editor dated September 30, 2024




3

Letters to the Editor dated October 3, 2024




3

Letters to the Editor dated October 23, 2024 




3

Ind vs NZ 3rd Test: India hand New Zealand control after batting flop show on Day 1

India’s batting collapse makes a comeback as they face the horror of a clean sweep at home against New Zealand.




3

India vs New Zealand, 3rd Test, Day 2: Spinners dominate, time for batters to salvage pride; Test poised for exciting finish

New Zealand ended day two with an overall lead of 143, which might look small but even a target in the vicinity of 150 will pose serious challenge for the Indian batters




3

IND vs NZ third Test Day 2: Chase won't be easy, we have to bat really well, says Ravichandran Ashwin

What surprised Ashwin is the nature of low bounce, not exactly synonymous with red soil Mumbai surfaces which helps the ball to fly.




3

Ind vs NZ 3rd Test: One of the better knocks I have played in Tests, says Shubman Gill

The conversation with the coach was just having more repetitions on what I think is the best idea for me to be able to play spinners, says Shubman Gill after the second day of the third test against New Zealand




3

Ind vs NZ 3rd Test: New Zealand scripts history as India suffers Test series whitewash

No team had been able to win all the Test matches in India in a series featuring three or more Test matches in nine decades.




3

India whitewashed 0-3 at home: I take full responsibility, says Rohit Sharma

Set a target of 147, India were all out for 121. The hosts also suffered embarrassing defeats in the first two Tests of the series




3

Ball-change controversy involving Kishan dominates India A's 7-wicket loss to Australia A

Resuming at the overnight score of 139 for 3 while chasing 225, skipper Nathan McSweeney (88 not out) and Beau Webster (61) remained unbeaten, stitching unconquered 141 runs for the fourth wicket to ensure the comfortable win for the hosts.




3

Wriddhiman Saha announces retirement from cricket after this year's Ranji Trophy

Veteran cricketer Wriddhiman Saha announces retirement, last season in Ranji Trophy, ending a cherished journey in cricket




3

Shami's return to competitive cricket delayed; not to play for Bengal against Karnataka, M.P.

Other than Shami, Bengal will also miss the services of prolific opener Abhimanyu Easwaran, wicketkeeper batter Abhishek Porel and pacer Mukesh Kumar, who are with India A squad in Australia.




3

KL Rahul's form and batting number in focus as India A gets 'G' experience

With Boland, one of Australia's senior reserve pacers steaming in and hitting the deck, it will be a stern test for the likes of Abhimanyu Easwaran, Ruturaj Gaikwad, B Sai Sudharsan and Devdutt Padikkal




3

James Anderson wants to grow his 'knowledge of the game' through IPL

In a surprising move, James Anderson, who last played a T20 match in 2014 and never played a match in the IPL, registered himself for the auction




3

Koushik’s five-for helps Karnataka dismiss Bengal for 301

Abhinav Manohar, who scored his maiden First Class 50, and Shreyas Gopal steady the ship for the home side after some initial stutters




3

Bonding with one's student

Teachers need to master two secrets to be successful in their careers.




3

'Lengthy' physics section kept students on tenterhooks

Many of them said they had not prepared thoroughly for AIPMT as it was only ‘an option’




3

'Don'ts' at the interview

There are pointers on what one must do while preparing for an interview. Here is what one should avoid.




3

Ramanuja's respect for women



  • History & Culture

3

Desika's haven of peace on the other side of the cauvery

This year the Vedanta Desika festival will be celebrated on November 13 in Satyagalam, Karnataka.




3

On 'kaniyan koothu', an art form dedicated to the graveyard god

Sudalai Madan was banished to earth after it was discovered that he preferred eating human flesh to divine nectar