3

Gold prices anticipated to surpass $3,000 per ounce: Citi report

The report attributes this projection to the weakening US labour market, disinflation, and the Federal Reserve’s dovish pivot at the upcoming July FOMC meeting



  • Gold & Silver

3

RBI to redeem 30 gold bonds from October 11

Window for redemption of SGBs issued between 2017 and 2020




3

Gold may sustain its current rally to top $3,000/oz, say analysts

US Fed rate cut, weak dollar and rising geopolitical tension to aid the precious metal’s surge



  • Gold & Silver

3

India’s Q3 gold demand surges 18% as prices fall post duty cut

The value of gold demand also increased dramatically by 54% to ₹1.65 lakh crore.



  • Gold & Silver

3

Recipe Collecting Shípǔ 食谱

Abstract: In Chinese history, the practice of collecting recipes evolved along two parallel but interacting trends. The first placed food within a medical context in order to nourish the body and heal different ailments. The second was concerned with technical aspects as well as the aesthetic enjoyments of food. Beginning with twenty recipes found

The post Recipe Collecting Shípǔ 食谱 appeared first on Berkshire Publishing.




3

LDH-derived Co0.5Ni0.5Te2 Dispersed in 3D Carbon Sheets as Separator Modifier to Enable Kinetics-Accelerated Lithium-Sulfur Batteries

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02619E, Paper
Chunmei Li, kan Mi, Kai Xu, Zhuo Jia, Xiaolei Jiang, Huili Peng, Xiuwen Zheng, Hongjiao Nie
Lithium-sulfur battery is considered as a powerful candidate for the next generation of advanced energy storage systems relying on its high energy density and theoretical specific capacity. However, its practical...
The content of this RSS Feed (c) The Royal Society of Chemistry




3

An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02690J, Communication
Alexey Bilyachenko, Victor N Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel Dorovatovskii, Elena Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim G. Rahimov, Di Sun
First metallasilsesquioxane bearing pyrazolylpyridine ligands, Cu8-based complex 1, adopts cage structure with two zigzag-like copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. Four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual...
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Zn(II) coordination influences the secondary structure, but not antimicrobial activity of the N-terminal histatin 3 hydrolysis product

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02274B, Paper
Emilia Dzień, Joanna Wątły, Aleksandra Hecel, Aleksandra Mikołajczyk, Agnieszka Matera-Witkiewicz, Miquel Adrover, Miquel Barceló-Oliver, Alicia Domínguez-Martín, Magdalena Rowińska-Żyrek
Histatin 3 and 4 have greater activity against Gram(+) than Gram(−) bacteria, and Cu(II) or Zn(II) binding can moderately increase their antimicrobial activity. The N-terminal part of histatin 3 becomes α-helical upon Zn(II) binding.
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The content of this RSS Feed (c) The Royal Society of Chemistry




3

The mechanism of Mo-nitrogenase: from N2 capture to first release of NH3

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02606C, Paper
Ian Dance
I describe how nitrogenase catalyses N2 → HNNH → HNNH2 → NH3 + NH and how the calculated dynamics explain recent kinetics data.
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3

Hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand with abrupt spin-crossover with T1/2=340 K and wide hysteresis loop of 45 K

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02901A, Paper
Maxim Andreevich Blagov, Alexander V. Akimov, Anatoly S Lobach, Leokadiya Zorina, Sergey Simonov, Konstantin Zakharov, Alexander Vasiliev, Natalia Spitsyna
The hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand [FeIII(Hthpy)(thpy)]·H2O (1) was synthesized and characterized using FT-IR spectroscopy, powder and single-crystal X-ray diffraction, dc magnetic measurements, EPR...
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Fe/Fe3C particles encapsulated in hollow carbon nanoboxes for high performance zinc–air batteries

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02396J, Paper
Chuyun Huang, Wenyuan Zhang, Xuezhi Hu, Shiliang Fei, Fhulufhelo Nemangwele, Nnditshedzeni Eric Maluta, Yangsen Hu, Hui Lv, Pei Hu, Zhuo Peng
Zinc–air batteries are recognized for their environmental friendliness and high energy density; however, the slow kinetics of the oxygen reduction reaction (ORR) at the air electrode hinder their commercial viability.
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3

Extended investigation of the conductive characteristics of monoclinic tungstates with a Bi3.24Ln2W0.76O10.14 (Ln = La, Pr or Nd) composition

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02462A, Paper
Ekaterina I. Orlova, Yelizaveta A. Morkhova, Nikolay V. Lyskov, Anastasia V. Egorova, Egor D. Baldin, Artem A. Kabanov, Elena P. Kharitonova, Valentina I. Voronkova
More extensive conductivity studies have been carried out on the Bi3.24Ln2W0.76O10.14 (Ln = La, Pr or Nd) Watanabe phases, resulting in a detailed understanding of the predominant oxygen-ion migration.
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3

Morphology-dependent Li+ ion dynamics in X-ray amorphous and crystalline Li3PS4 prepared by solvent-assisted synthesis

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02636E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jonas Spychala, Christoph Mandl, Katharina Hogrefe, H. Martin R. Wilkening, Bernhard Gadermaier
Ionic conductivity of Li3PS4 if synthesized by a solvent-assisted method strongly depends on overall and surface morphology. Amorphous Li3PS4 shows a rather high conductivity which is only slightly enhanced when going to the (nano-)crystalline form.
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3

One-pot facile synthesis of rod-like Bi2S3 particles in deep eutectic solvent and their ppb-level selective H2S gas detection

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT03006K, Communication
Reiko Furukawa, Takuya Hasegawa, Ayahisa Okawa, Shu Yin
Rod-like Bi2S3 particles were synthesized by one-pot reactions with choline chloride-based DESs, and showed sub-ppm level selective H2S gas detection. Acetamide-based DES yielded uniform particles with excellent gas sensitivity.
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3

The preparation of CuM/SiO2 (M=Bi, Mg, Mn) catalysts applied in ethynylation of formaldehyde for 1,4‑butynediol synthesis: the positive interface effect of CuO and Bi2O3

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02616K, Paper
Jiali Chen, Guihua Yang, Feng Gao, Rui Wang
The ethynylation of formaldehyde reaction catalyzed by Cu-based catalysts is an important synthesis method for 1,4-butynediol relating to high value-added chemicals. In this work, a series of CuM/SiO2 ( M=Bi,...
The content of this RSS Feed (c) The Royal Society of Chemistry




3

A highly sensitive ratiometric optical thermometer based on Sr2MgWO6 double perovskite doped with Dy3+ exploiting thermally coupled and uncoupled levels

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02940B, Paper
Thi Hong Quan Vu, Bartosz Bondzior, Dagmara Stefanska, Shovan Dan, Przemysław Jacek Dereń
The increasing demand for highly sensitive optical thermometers operating within a wide temperature range necessitates the development of new phosphors. In this work, the potential of temperature sensing performance of...
The content of this RSS Feed (c) The Royal Society of Chemistry




3

β-Cyclodextrin and cucurbit[7]uril as protective encapsulation agents of the CO-releasing molecule [CpMo(CO)3Me]

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT01863J, Paper
Rodrigo P. Monteiro, Isabel B. Calhau, Ana C. Gomes, André D. Lopes, José P. Da Silva, Isabel S. Gonçalves, Martyn Pillinger
For inclusion compounds between the complex [CpMo(CO)3Me] (1) and β-cyclodextrin or cucurbit[7]uril, the macrocyclic hosts modulate to different degrees the UV light-mediated CO release from encapsulated 1.
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The content of this RSS Feed (c) The Royal Society of Chemistry




3

Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents

Dalton Trans., 2024, 53,18003-18012
DOI: 10.1039/D4DT02285H, Paper
Anupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti Ghoshal
An ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Direct O2 mediated oxidation of a Ni(II)N3O structural model complex for the active site of nickel acireductone dioxygenase (Ni-ARD): characterization, biomimetic reactivity, and enzymatic implications

Dalton Trans., 2024, 53,17852-17863
DOI: 10.1039/D4DT02538E, Paper
Kelsey E. Kirsch, Mary E. Little, Thomas R. Cundari, Emily El-Shaer, Georgia Barone, Vincent M. Lynch, Santiago A. Toledo
A structural and functional biomimetic Ni(II)N3O complex, capable of O2 mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation

Dalton Trans., 2024, 53,18047-18053
DOI: 10.1039/D4DT02567A, Paper
Hui Li, He Zheng
Insights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Synthesis and relaxivity of gadolinium-based DOTAGA conjugated 3-phosphoglycerate

Dalton Trans., 2024, 53,17777-17782
DOI: 10.1039/D4DT02766C, Communication
Open Access
Andrew R. Brotherton, Shifa Noor Mohamed, Thomas J. Meade
A Gd-DOTAGA based MR contrast agent conjugated to 3-phosphoglycerate for enhanced relaxivity and investigation into its metabolism.
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02655A, Paper
Z. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun Xu
Four BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...
The content of this RSS Feed (c) The Royal Society of Chemistry




3

Study of CanUO2(CO3)3(4–2n)– complexes using CE-ICP-MS with polyetheretherketone (PEEK) capillaries

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02781G, Paper
Ruopei Sun, Erwan Dupuis, Jean Aupiais, Pascal Reiller
The formation constants of CanUO2(CO3)3(4–2n)– complexes have been determined directly using capillary electrophoresis coupled with inductively coupled plasma mass spectrometry (CE-ICP-MS) in 0.1 M NaCl and at room temperature. Instead...
The content of this RSS Feed (c) The Royal Society of Chemistry




3

It's all in the interpretation




3

Developing the world's first full-body PET scanner

Simon Cherry explains why the EXPLORER project will revolutionize medical imaging




3

Siddaramaiah to launch projects in Mysuru on November 12 and 13




3

Chunchankatte Jalapatotsava to be held on Nov. 30, Dec. 1




3

Messi's Miami stunned by Atlanta in MLS

Miami were overwhelming favourites to win it all after producing a league record 74 points in the regular season but could not keep the momentum after Matias Rojas' close-range goal in the 17th minute and Messi's score in the 65th minute.




3

Vinicius 'tricks' Real Madrid to win!

Real Madrid forward Vinicius Jr scored a hat-trick to help the LaLiga champions snap a two-game winless run in all competitions.




3

'Messi has been the boost MLS needed'

Lionel Messi has more than proven his worth for the league and his team at a vitally important time for the sport in North America, where the FIFA World Cup will be staged in 2026.




3

Music resistance from 1900 to the present / edited by Igor Contreras Zubillaga, Helena Martín-Nieva.

Turnhout : Brepols, 2022.




3

Winter's end [electronic resource] : dementia and dying well / Lewis Cohen.

New York, NY : Oxford University Press, [2024]




3

Sacred cow, mad cow : a history of food fears / Madeleine Ferrières ; translated by Jody Gladding

New York : Columbia University Press, c2006




3

Ketamine [electronic resource] : the story of modern psychiatry's most fascinating molecule / by Keith G. Rasmussen.

Washington, DC : American Psychiatric Association Publishing, [2024]




3

Over nine crore voters to decide Maha's fate on Nov 20




3

Boozers beware: Maharashtra orders sophisticated surveillance of 'watering holes'




3

Mumbai artist's diamond portrait of Ratan Tata to be sold for his charities




3

Maharashtra key to India's growth story being scripted in Modi 3.0: EAM Jaishankar




3

EAM Jaishankar says success of Central govt's policies linked to state's intentions




3

Nov 20 Maharashtra election: 4,140 candidates in fray; 2,938 withdraw nominations




3

PMAY beneficiaries in Maharashtra's Beed thank PM Modi for affordable housing




3

8 parties in tough fight on Mumbai's 36 seats ahead of civic body polls




3

Morning Digest: NSCN-IM threatens armed violence for first time since 2015 agreement; Article 370 cannot be restored by anyone, says PM Modi, and more

Here is a select list of stories to start the day




3

'Achieved everything I can', says Cavendish ahead of last race

Mark Cavendish, the world's most decorated sprinter, announced his retirement last year before reversing that decision and breaking the all-time record for most stage wins at the Tour de France during this year's race




3

Kiran George's Korea Masters run ends in semifinals with loss to Kunlavut

Kiran George, who trains at the Prakash Padukone Badminton Academy (PPBA), had earlier registered a fine win over fifth seed Takuma Obayashi of Japan in the quarterfinals




3

Don't judge Kohli on current form, Australia series could change it all: Ricky Ponting

The much-awaited series against Pat Cummins' Australia will commence in Perth on November 22 and Kohli, as always, will be a vital cog in India's scheme of things if they are to retain the prestigious trophy




3

Vinícius nets hat trick in win as three Real Madrid players go down injured; Militão tears ACL

Vinícius Júnior shines with hat trick in Real Madrid win overshadowed by Militão ACL injury in La Liga.




3

Morning Digest: Unidentified terrorist killed in encounter in J&K’s Sopore; Biden, Trump to meet in the White House on November 13, and more

Here is a select list of stories to start the day




3

Ponting should be concerned about Australian cricket, not India's: Gautam Gambhir

Gambhir defends Kohli against Ponting’s criticism, emphasising confidence in Indian batters ahead of Australia series




3

Shubhankar Sharma finishes 32nd as Paul Waring grabs title in Abu Dhabi

After 71-73 on the first two days, Shubhankar Sharma had a great weekend as his final two rounds of 66 and 65 had an eagle each