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Enhanced photocatalytic CO2 reduction by controlled oxygen vacancy generation and co-constructed heterojunction strategy for Pd/CeO2

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00581C, Research Article
Fanlin Kong, Xiaoyan Lu, Jing Xie, Zhenjiang Lu, Jindou Hu, Yali Cao
Rational control of Vo concentration and the construction of a heterojunction strategy enable Pd/CeO2-Vo(r) to exhibit excellent photocatalytic CO2RR activity. The presence of COOHcreates favorable conditions for CO formation and desorption.
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Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00200H, Research Article
Yong-Sheng Shi, Tong Xiao, Dong-Dong Yang, Xiangjun Zheng
A viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....
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Insights into the modulation mechanisms of multiple active sites in a conjugated small molecule towards organic cathode capacity from first-principles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00547C, Research Article
Zhaopeng Sun, Hao Tian, Meng Zhang, Yi Zhang, Zhiping Li, Weiwei Huang
The modulation mechanisms of Na+ within the redox-active sites of the two-dimensional conjugated organic small-molecule 3BQ, and their impact on the initial capacity of a 3BQ cathode for Na-ion batteries, were investigated using first-principles calculations.
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An unprecedented {Y2 ⊂ Y10} type disk-like Y12 nanocluster featuring electroluminescence property in OLED device

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00635F, Research Article
Lin-Ping Shi, Wen-Liang Li, Pu-Yue Wang, Xiaoming Wu, Zhao-Quan Yao, Jiong-Peng Zhao, Fuchen Liu
Although great efforts have been made in exploring the exquisite rare-earth (RE) clusters, the design and construction of planar RE-clusters with disk-like geometrical features are still scarce. Herein, a novel...
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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
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Advances in technical strategies for monitoring the reduction of platinum(IV) complexes

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00459K, Review Article
Open Access
Shu Chen, Qiyuan Zhou, Ka-Yan Ng, Zoufeng Xu, Weikang Xu, Guangyu Zhu
The reduction of Pt(IV) complexes can be monitored by various analytical techniques. These techniques hold significant promise in elucidating the mechanisms of Pt(IV) prodrug activation, aiding in the rational design of novel Pt(IV) prodrugs.
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Unleashing the power of directed electron transfer: unraveling the potential of {PV4}2 in heterogeneous photocatalysis

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00606B, Research Article
Xin Su, Yuzan He, Kunhong Li, Miao Wang, Wei Tang, Shihao Zhang, Pengtao Ma, Jingyang Niu, Jingping Wang
{PV4}2 unleash the power of directed electron transfer in heterogeneous photocatalysis reduction.
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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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Trifluoroacetic acid molecules confined into/onto metal–organic frameworks using H2btzip for efficiently improving proton conductivity using a synergistic effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00605D, Research Article
Xiaoxue Ma, Xin Li, Xueke Han, Lu Zhang, Ronghua Liu, Hongguo Hao, Hui Yan, Xin Zhao, Xiangjin Kong, Huawei Zhou, Xia Li, Hongjie Zhu, Suna Wang, Yunwu Li, Dichang Zhong, Fangna Dai
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
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ICRIER study explores untapped potential of India’s turmeric sector

Offers roadmap as the country dominates the global market with 70% market share




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National Mission on Edible Oil to help increase production to 25 mt by 2030-31: SEA

Over 60 per cent of edible oil requirement is now met through imports, which is a cause for concern, says SEA president Sanjeev Asthana




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Crude Check: More gains projected

Retain the futures buy position




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Indian rice exports get delayed at ports as Customs officials hold up consignments

Exporters say they incur $70/tonne additional costs; Customs officials playing safe to verify if shipments are white or parboiled rice




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Optimism in global commodities market over Chinese measures may be short-lived, say analysts

Subdued demand, struggling property sector may exert downward pressure on metals




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Edible oil import down by 6% in 11 months

India imported 145.35 lakh tonnes (lt) of edible oil during the first 11 months of the oil year 2023-24, against 154.68 lt in the corresponding period of the previous oil year




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MCX launches cottonseed wash oil futures contract

It will offer a robust price risk management solutions for the cottonseed oil industry




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Kandla Customs Commissioner orders release of ship detained in organic rice export irregularities

Tells Kandla traffic manager to allow another ship to set sail after getting release order from Gujarat HC




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Weather experts divided over emergence of La Nina

APEC Climate Centre predicts the weather event from December




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SEA asks members not to increase prices of old stock of edible oil

Solvent extractors seek Centre’s help to export oilmeals




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Storage in key Indian reservoirs unchanged for 3rd week in a row

They are higher than normal, filled to 87 per cent of the 180.852 BCM capacity




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Part of India’s sugar export quota to Maldives ‘diverted’ to Sri Lanka, Malaysia

Though exports are banned, shipments of 64,000 tonnes were allowed under special bilateral pact




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Manufacturing method of lab grown diamonds should be declared before export and import: CBIC

The new norms, which will help in quick processing and inspection of consignments, are to be effective from December 1




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Coconut water, evening walks & meditation




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Golden morning, balanced diet & tennis




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Drugmakers chart a specialised course to navigate choppy waters

India’s pharma industry is moving from volume to value, investing in quality manufacturing 




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Medication safety

Patient harm due to unsafe care is a leading cause of death and disability worldwide




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In need of a cell therapy revolution

Indian biotech sector poised for growth with cell and gene therapies revolutionising healthcare, positioning India as a global leader




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Tobacco exposed

May 31 is World No Tobacco Day




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Green shoots of expectations on health, from newly-minted govt

As political tides change, the public sets sights on inclusive and robust healthcare reforms




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Making India a go-to for medical treatment

India stands at the crossroads of innovation and tradition, offering medical solutions for the world, where life-saving treatments are delivered with precision and care




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Redefining the regulatory pathway for nutraceutical and pharmaceutical products

As the nutraceutical landscape grows, experts call for clarity in the manufacturing debate




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Data integrity alarm sounded for CROs, the backbone to pharma industry

USFDA cautions CROs; says such incidents “undermine the reputation of generic industry”




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Reviewing TRIPS, an opportunity for evidence-based policies

Colombia calls for review of TRIPS Agreement implementation, highlighting need for evidence-based IP law and policy




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Clinical trial waiver, a step to improve patient access, in need of guardrails

Experts call for ensuring patient safety while expanding access to new drugs




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Lung cancer, in need of local research

Lung cancer in India presents unique challenges, with different patterns, genetics, and treatment options compared to the western world.




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Code grey: Hospitals as safe zones for medical practitioners, patients

Amid rising violence, medicos call for a stringent Central Act to ensure safe workspaces and speedy action




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Advent of an assisted baby boom

How IVF clinics in India are plotting healthy growth plans amid falling fertility rates 




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HML succeeds in bringing back workers to Wayanad tea plantations 

This is evident from the number of workers in the tea estates of the hill district rose by five per cent to 40 per cent during the past two months




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Centre launches mobile app for grievance redressal of rice millers

Move to enchance transparency, accountability




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Subdued blenders’ demand hits Coonoor tea auctions sales 

Sales drop to less than 70 per cent in leaf and dust




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High moisture content leaves cotton growers worried in some Indian States

Telangana and Maharashtra badly hit as CCI looks for low moisture content




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UPL recognised as top patent applicant in agro-chemical research

This recognition comes from the Global Innovation Index (GII) 2024, which annually ranks the world’s economies based on their innovation capabilities




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CMFRI develops eco-friendly fish feed from black soldier fly larvae 

CMFRI transferred the technology to Amala Ecoclean, a start-up focusing on sustainable waste management and environmental solutions, for large-scale commercial production




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Storage in India’s key reservoirs unchanged for 4th week in a row

The 155 major reservoirs were filled to 87 per cent of capacity; level in 4 States below normal




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Blue Pearl, a new fish farmer producer company launched in Kodungallur

Highlighting the rapid growth of the fisheries sector, the Minister said the Centre has outlined several schemes dedicated to strengthening the fisheries sector




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Stanford Blade named interim D-G of ICRISAT

Blade, currently the Deputy Director General (Research) at the institute, will lead the institute until the new Director General, Himanshu Pathak, assumes the position next year




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South Peninsula records 7% above normal rainfall so far, poised to get even more from later this week

Easterly to north-easterly flows starting to rebuild after being scattered by severe cyclone Dana over the Bay




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Crystal Crop Protection acquires I&B Seeds

Diversifies into flower and vegetable seeds with the latest buyout




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SEA urges govt to re-evaluate ban on export of de-oiled rice bran

In a letter to various Central ministers, SEA said that this decision could have far-reaching negative consequences for multiple sectors