as A pillar[5]arene-based three-component supramolecular copolymer for the fluorescence detection of spermine By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6293-6303DOI: 10.1039/D4QO01470G, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Martina Mazzaferro, Daniele Crisafulli, Francesca Mancuso, Marco Milone, Fausto Puntoriero, Anna Irto, Salvatore Patanè, Valentina Greco, Alessandro Giuffrida, Ilenia Pisagatti, Anna Notti, Melchiorre F. Parisi, Giuseppe GattusoA supramolecular copolymer, composed of a bis-pillar[5]arene diacid and complementary alkylidene- and perylene-bisimide-bis-imidazole comonomers, acts as an OFF/ON luminescent sensor for spermine.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Design, synthesis and application of bipyridine-N,N'-dioxide catalysts in asymmetric synthesis of chiral cyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6470-6476DOI: 10.1039/D4QO01532K, Research ArticleXiaoying Cao, Xue Tian, Minmin Liu, Shi-Wu LiA novel type of highly efficient chiral C2-symmetric bipyridine-N,N'-dioxide ligands was prepared and successfully applied in the synthesis of optically pure 1,2,3-trisubstituted cyclopropanes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Activation of donor–acceptor cyclopropanes under basic conditions: ring opening of 2-(p-siloxyaryl)cyclopropane 1,1-dicarboxylates with nitro compounds and other C-nucleophiles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6483-6494DOI: 10.1039/D4QO01472C, Research ArticleYulia A. Antonova, Andrey A. TabolinA new activation mode for donor–acceptor cyclopropanes was proposed and implemented in their reaction with nitro compounds and other common C-nucleophiles.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6510-6517DOI: 10.1039/D4QO01517G, Research ArticleYu Sun, Yi Wang, Zhijun ZuoA novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Anomalous magnetic behaviour induced by a structural phase transition with anisotropic thermal expansion in a spirodiradical By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6495-6502DOI: 10.1039/D4QO01098A, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Takuya Kanetomo, Daigo Matsunaga, Shinichi Ogawa, Masaya EnomotoA Ge-centred spirodiradical exhibited anomalous magnetic behaviour, influenced by two key structural factors: negative thermal expansion and a structural phase transition.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Dendron-mediated control over self-assembly of chlorophyll rosettes into columnar vs. discrete aggregates By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6304-6310DOI: 10.1039/D4QO01629G, Research Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ryo Kudo, Hiroki Hanayama, Balaraman Vedhanarayanan, Hitoshi Tamiaki, Nobuyuki Hara, Sarah E. Rogers, Martin J. Hollamby, Biplab Manna, Koji Harano, Shiki YagaiBy controlling the π-π stacking of chlorophyll supramolecular rosettes through steric hindrance of alkyl dendrons, it become possible to create chlorophyll tubes and discrete rings that resemble to natural chlorophyll assemblies.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Recent advances in asymmetric synthesis of chiral benzoheterocycles via Earth-abundant metal catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6534-6557DOI: 10.1039/D4QO01686F, Review ArticleJinhui Cai, Wenting Zhang, Usman Muhammad, Weishuang Li, Yanjun XieThis review mainly focus on the assembly of chiral benzoheterocycles, such as dihydrobenzofurans, chromans, indolines, tetrahydroquinolines, etc., via Earth-abundant metal-catalyzed (Cu, Fe, Ni, and Ti) asymmetric synthesis in the last few decades.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01388C, Research ArticleShanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian CaiA two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Copper(II)-catalyzed synthesis of sulfonyl-functionalized quinone-fused cyclopenta[b]indoles via four-component cascade annulation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01560F, Research ArticleHong Xu, Jie Liao, Fei Ren, Chuan-Rong Zhou, Xiao-Zhuo Liu, Yao Xiao, Dong-Wei Hang, Fuyu Li, Bei Wang, Ji-Yu WangThrough crucial selective radical tandem process and intramolecular nucleophilic addition, a facile copper-catalyzed four-component cascade has been realized to selectively construct novel sulfonyl-functionalized quinone-fused cyclopenta[b]indole.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Catalytic asymmetric synthesis of chiral sulfilimines via S-C bond formation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01963F, HighlightYingying Shi, Shuiyun Zheng, Jiapian Huang, Fu-Sheng He, Min Yang, Jie WuAs the aza-analogues of sulfoxides, sulfilimines bearing S(IV) stereogenic centers hold tremendous potential in synthetic chemistry and medicinal chemistry. However, the catalytic asymmetric synthesis of chiral sulfilimines are much less...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Nickel-catalyzed reductive 1,2-alkylarylation of alkenes via a 1,5-hydrogen atom transfer (HAT) cascade By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01875C, Research ArticleXi Chen, Qiang Wang, Xiao-Ping Gong, Rui-Qiang Jiao, Xue-Yuan Liu, Yong-Min LiangA nickel-catalyzed 1,2-alkylarylation of alkenes has been developed, leveraging amidyl radical-triggered 1,5-HAT with electrophiles as functionalizing reagents.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01771D, Research ArticleBendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin QiuAn efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Integrating electrocatalysis with biocatalysis for asymmetric synthesis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01899K, HighlightYuqi Lin, Jiage Yu, Ke-Yin YeThis highlight presents recent advances in asymmetric synthesis that integrate electrocatalysis with biocatalysis and discusses future development directions in this field.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Visible-light responsive defluorination-acyl fluoride exchange for photoclick labeling based on phenoxazine chromophores By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01870B, Research ArticleLijun Deng, Sitong Li, Cefei Zhang, Yuqiao Zhou, Zhishan Su, Changwei Hu, Xiaohu Zhao, Zhipeng YuWe developed a new generation of photo-DAFEx reagents to realize photoaffinity labeling for drug discovery under 405 nm light control.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids for the synthesis of fused isoquinolinones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01573H, Research ArticleZhaolin Quan, Yubo Duan, Zhengkai ChenA straightforward approach for the preparation of fused isoquinolinone derivatives via palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids is described.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Rh-Catalysed Hydroacyloxylation of Cyclopropenes: Regio- and Diastereoselective Synthesis of Acyloxycyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01810A, Research ArticleÁngel Manu Martínez, Gema Domínguez, Ines Alonso, Marta Palaín, Javier Perez-CastellsCyclopropyl carboxylates are essential building blocks in biological and medicinal chemistry. However, their accessibility is severely limited by the need to pre-synthesise highly reactive cyclopropane derivatives. Herein, we report an...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Influence of hydrogen bonds and π-π stacking on the self-assembly of aryldipyrrolidones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01577K, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pedro Ximenis, Llorenç Rubert, Heike Ehmann, Bartolome SoberatsWe report on the self-assembly behaviour in solution and solid-state of two newly designed bisdendronized aryldipyrrolidones (BDP and NDP) dyes with two free N-H at the lactam positions. Interestingly, while...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01641F, Research ArticlePeng Wang, Qiang Wang, Meng Wang, Liang Wang, Lubin Xu, Xiong-Li Liu, Fangzhi Hu, Shuai-Shuai LiAn FeCl3-catalyzed cross-dehydrogenative coupling reaction for the construction of various types of C–Y (Y = C, N, O, S) bonds with air as a green oxidant.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Hemilabile P,N-Ligand-Assisted Gold Catalyzed Hiyama Allylation to Access Allylarenes and 1,4-Dienes Derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01879F, Research ArticleYuanhao He, Wanping Ma, Yu Zhong, Yanfei Hu, Mingou Li, Fen Zhao, Zhonghua Xia, Baomin FanOxidant-free gold-catalyzed reactions are emerging as a novel synthetic tool for organic transformations. Here in, we reported a hemilabile P,N-ligand-assisted gold-catalyzed Hiyama cross coupling reaction of aryl and alkenyl iodides...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
as Usha Rk on the visual splendour of Adi Shankaracharya’s Ashtakams By www.thehindu.com Published On :: Thu, 07 Nov 2024 16:31:17 +0530 Usha Rk, former director of Jawaharlal Nehru Cultural Center (JNCC) of the Embassy of India in Moscow, shares her vision of bringing Adi Shankaracharya’s Ashtakams to life through a dance form Full Article Entertainment
as Telangana pharmaceutical industries logged 97 major fire accidents in past decade: Fire Services Director-General Y. Nagi Reddy By www.thehindu.com Published On :: Thu, 07 Nov 2024 18:58:18 +0530 The new government would like to decentralise and set up pharma villages, in 10 clusters, Special Chief Secretary Jayesh Ranjan said Full Article Telangana
as GHMC official sentenced to one-year RI in ACB case By www.thehindu.com Published On :: Thu, 07 Nov 2024 20:18:55 +0530 Full Article Telangana
as Mother-daughter duo to showcase Andhra Natyam and Perini Tandavam in Hyderabad By www.thehindu.com Published On :: Fri, 08 Nov 2024 15:20:10 +0530 Duvvuri Vathsalendra redefines tradition by mastering Perini Thandavam and sharing its power on stage with her daughter Abhimanika Full Article Entertainment
as ‘Rahasyam Idham Jagath’ movie review: Earnest but far from engrossing By www.thehindu.com Published On :: Fri, 08 Nov 2024 15:36:40 +0530 Director Komal R Bharadwaj’s Telugu indie ‘Rahasyam Idham Jagath’ is ambitious in using science, technology and stories from the Indian epics for an adventure drama, but falls short in its execution Full Article Movies
as Man arrested for sexually assaulting mother-in-law in Balapur By www.thehindu.com Published On :: Fri, 08 Nov 2024 21:13:40 +0530 Full Article Telangana
as 32 STPs taken up by BRS govt. to cleanse Musi: MLAs By www.thehindu.com Published On :: Sat, 09 Nov 2024 19:00:05 +0530 ₹3.8k crore STP project was to protect Nalgonda ryots’ farm fields from sewage water Full Article Telangana
as Ponnam criticises BJP leader Laxman’s comments on caste census By www.thehindu.com Published On :: Sat, 09 Nov 2024 20:06:17 +0530 Full Article Telangana
as Telangana govt. urged to release caste survey forms in English and Urdu By www.thehindu.com Published On :: Sat, 09 Nov 2024 20:26:10 +0530 Full Article Telangana
as Mental health and resilience in higher education institutions as a mission By www.thehindu.com Published On :: Sat, 09 Nov 2024 21:10:51 +0530 A two-day conclave started at IIT Hyderabad with an aim to foster healthy and harmonious environment in higher education institutions with the goal of reducing suicide rates and enhancing student and faculty wellbeing Full Article Telangana
as Man arrested for kidnapping, marrying, sexually assaulting minor By www.thehindu.com Published On :: Sat, 09 Nov 2024 21:24:54 +0530 Full Article Telangana
as Apprehensions aplenty in Hyderabad about caste survey By www.thehindu.com Published On :: Sat, 09 Nov 2024 23:51:46 +0530 Many residents refuse to share details, with some regarding questions too intrusive and some wary about data privacy and identity of enumerators in the backdrop of rising scams; officials face public ire over unfulfilled government promises and outcome of ‘Praja Palana’ applications Full Article Telangana
as Trust deficit exists between citizens and healthcare system: former IAS officer By www.thehindu.com Published On :: Sun, 10 Nov 2024 18:23:49 +0530 Full Article Hyderabad
as Telangana State Cyber Security Bureau nabbed 165 cyber criminals involved in 795 cases in last six months By www.thehindu.com Published On :: Sun, 10 Nov 2024 19:58:22 +0530 45% fraudsters are either graduates or post-graduates; indulge in crime due to peer pressure and for easy money, says data Full Article Telangana
as Minister Ponnam Prabhakar urges caste associations to support ongoing comprehensive survey in Telangana By www.thehindu.com Published On :: Sun, 10 Nov 2024 23:47:20 +0530 Full Article Telangana
as Pending bills paid to contractors, but situation of BC students remains unchanged: National BC welfare association chief By www.thehindu.com Published On :: Mon, 11 Nov 2024 11:34:20 +0530 He demanded Telangana government to immediately release reimbursement and scholarship dues amount to about ₹4,000 crore Full Article Telangana
as Telangana’s Dhanalakota Vaikuntam Nakash’s journey with Cheriyal art By www.thehindu.com Published On :: Mon, 11 Nov 2024 14:30:09 +0530 The 64-year-old artist adapts to the times to narrate stories in the 400-year-old Cheriyal artform in new mediums Full Article Art
as Hyderabad-based Raghu Vamsi Group acquires British precision machining firm PMC Group By www.thehindu.com Published On :: Mon, 11 Nov 2024 14:55:02 +0530 The Hyderabad-based MSME, Raghu Vamsi Group, has completed the acquisition of British precision machining firm PMC GGroup, that traces its roots to over 100 years Full Article Hyderabad
as Agitated villagers chase govt officials over proposed pharma plant in Vikarabad By www.thehindu.com Published On :: Mon, 11 Nov 2024 16:09:21 +0530 The villagers have been protesting for several weeks against the proposed pharma company Full Article Telangana
as Nodal officers appointed for the caste survey in Greater Hyderabad By www.thehindu.com Published On :: Mon, 11 Nov 2024 20:44:47 +0530 Full Article Telangana
as SRIRAM’s IAS launches coaching centre in Hyderabad By www.thehindu.com Published On :: Mon, 11 Nov 2024 20:49:07 +0530 Full Article Telangana
as KTR’s Delhi visit to lobby with BJP to save him in Formula-E race case: Congress By www.thehindu.com Published On :: Tue, 12 Nov 2024 00:42:43 +0530 Full Article Telangana
as Maamaas studio inaugurated in Kukatpally By www.thehindu.com Published On :: Tue, 12 Nov 2024 12:08:31 +0530 Full Article Telangana
as People’s committee slams BJP, BRS for ‘opposing’ caste survey in Telangana By www.thehindu.com Published On :: Tue, 12 Nov 2024 12:53:21 +0530 Full Article Telangana
as India cancel intra-squad match to prioritise net practice ahead of Border-Gavaskar Trophy By www.thehindu.com Published On :: Fri, 01 Nov 2024 13:39:48 +0530 India cancels intra-squad match with ‘A’ side in Australia tour for more net practice, focusing on Test series preparation Full Article Cricket
as I will prove my that my retention was right decision: Shashank By www.thehindu.com Published On :: Fri, 01 Nov 2024 16:16:44 +0530 Shashank established himself as a fine finisher for Punjab Kings in the last season where he was their top run-getter with 354 runs at a strike rate of 164.65. He averaged 44.25. Full Article Cricket
as IND vs NZ third Test Day 2: Chase won't be easy, we have to bat really well, says Ravichandran Ashwin By www.thehindu.com Published On :: Sat, 02 Nov 2024 18:03:18 +0530 What surprised Ashwin is the nature of low bounce, not exactly synonymous with red soil Mumbai surfaces which helps the ball to fly. Full Article Cricket
as Livingstone rises to the occasion as England levels ODI series against West Indies By www.thehindu.com Published On :: Sun, 03 Nov 2024 09:23:28 +0530 England finished its successful run chase on 329-5 in the second one-day international with 15 balls remaining Full Article Cricket
as Ind vs NZ 3rd Test: New Zealand scripts history as India suffers Test series whitewash By www.thehindu.com Published On :: Sun, 03 Nov 2024 09:58:39 +0530 No team had been able to win all the Test matches in India in a series featuring three or more Test matches in nine decades. Full Article Cricket
as India whitewashed 0-3 at home: I take full responsibility, says Rohit Sharma By www.thehindu.com Published On :: Sun, 03 Nov 2024 15:24:00 +0530 Set a target of 147, India were all out for 121. The hosts also suffered embarrassing defeats in the first two Tests of the series Full Article Cricket
as BCCI to discuss New Zealand whitewash, some senior players could be phased out post-Australia series By www.thehindu.com Published On :: Sun, 03 Nov 2024 18:27:36 +0530 There is a high possibility that the five-match Test series against Australia could be the final one for at least two of the four seniors among Rohit Sharma, Virat Kohli, Ravindra Jadeja and Ravichandran Ashwin. Full Article Cricket
