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Solvent-polarity-controlled assembly of polynuclear titanium-calixarene complexes: constructing isolated {Ti7}, {Ti13}, {Ti24} and {Tb2Ti13} clusters

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01275A, Paper
Yanyan Wang, Ying Xiong, Wuping Liao
The assembly of polynuclear titanium-calixarene complexes is based on Ti4–C8A SBUs.
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Zn1−xMgxTe and P:Zn1−xMgxTe (x = 0.06–0.25) bulk crystals grown by travelling Te solution method

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00081A, Paper
Yuchen Song, Tingting Zhang, Jiahui Lv, Guorong Zhang, Changyou Liu, Tao Wang, Gangqiang Zha, Wanqi Jie
Zn1−xMgxTe and P:Zn1−xMgxTe (x = 0.06–0.25) bulk crystals were successfully grown by travelling Te solution method. The segregation of Mg with the growth of crystal is weaken and the as-grown crystal has high homogeneity.
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Co-doped modified LiLuF4:Eu microcrystalline scintillation with flexible film for high resolution X-ray imaging

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00211C, Paper
Xixi Huang, Jinhai Yang, Hao Lu, Xieming Xu, Shuaihua Wang, Shaofan Wu
X-ray detectors based on scintillators are widely used in the fields of medical imaging, high-energy physics, geological exploration, and industrial detection. The development of scintillation materials with different characteristics has...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis and luminescent properties of three excellent yellow emissive Cu(I) complexes based on the diphosphine ligand and the diimine ligand

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00206G, Paper
Wen-Long Mou, Cheng-Jie Gao, Zi-Xi Li, Si-Jie Fan, Chuan-Bin Hou, Jing-Tong Zhao, Shuai Zhang, Zhong-Feng Li, Hong-Liang Han, Chun-Bo Duan, Guo Wang, Qiong-Hua Jin
High quantum yield (72–88%) yellow-emitting Cu(I) complexes obtained by tuning the nitrogen ligands and anions.
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Assessing aspects of solution-based chemical synthesis to convert waste Si solar cells into nanostructured aluminosilicate crystals

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00038B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Edita Garskaite, Math Bollen, Enock Mulenga, Mathis Warlo, Glenn Bark, Espen Olsen, Dalia Brazinskiene, Denis Sokol, Dietrich Buck, Dick Sandberg
An affordable, scalable, and easily adoptable solution-based processing route provides a potential way of converting waste Si solar cells into aluminosilicate minerals to contribute to sustainability in the solar energy value chain.
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High-quality β-(AlxGa1-x)2O3 thin films on sapphire substrate by face-to-face annealing

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00263F, Paper
Songhao Wu, Chicheng Ma, Han Yang, Zichun Liu, Yuanxiao Ma, Ran Yao, Yiyun Zhang, Hua Yang, Xiaoyan Yi, Junxi Wang, Yeliang Wang
High-quality β-(AlxGa1-x)2O3 thin film is fabricated through a face-to-face annealing on sapphire substrate covered by epitaxial Ga2O3. Al atoms during the high-temperature annealing are uniformly diffused from the sapphire substrate...
The content of this RSS Feed (c) The Royal Society of Chemistry




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New 8-hydroxy quinoline-polycyclic aromatic hydrocarbon (PAH) conjugates and their sulfonated derivatives: effects of sulfonation and PAH size on their structural, supramolecular and cytotoxic properties

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00105B, Paper
Suman Sehlangia, Surbhi Dogra, Prosenjit Mondal, Chullikkattil P. Pradeep
The ring size of polycyclic aromatic hydrocarbons (PAHs) and sulfonation affect the supramolecular interactions and cytotoxic properties of a new series of 8-hydroxy quinoline-PAH conjugates.
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Gefitinib salts/cocrystals with phenolic acids as a promising solid-state approach to improve solubility

CrystEngComm, 2024, 26,2112-2122
DOI: 10.1039/D4CE00039K, Paper
Yao Zou, Xin Meng, Baoxi Zhang, Hongmei Yu, Guorong He, Ningbo Gong, Yang Lu, Guanhua Du
In this study, we designed and synthesized a series of gefitinib (GEF) salts and cocrystals with phenolic acids, comprising two salts, one cocrystal, and two salt cocrystals. All these forms exhibited significant improvements in solubility compared to pure GEF.
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Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn3B7O13Cl

CrystEngComm, 2024, 26,2060-2064
DOI: 10.1039/D4CE00060A, Communication
Haodong Li, Duo Zhang, Jiesen Guo, Qiangqiang Wang, Yuxin Ma, Munan Hao, Yuetong Wu, Fanshu Meng, Tianming Liu, Yibo Xu, Xu Chen, Changchun Zhao, Dezhong Meng, Zhiyuan Zheng, Ruijin Sun
High-quality single crystals of Mn3B7O13Cl have been successfully synthesized, to unravel the elusive mechanism behind its spontaneous polarization.
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Chemical solution deposition of a (GaAl)2O3 single layer with high thickness and silver-enhanced crystal quality

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00086B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiao Tang, Wesam A. AlQanbar, Mohamed Ben Hassine, Yi Lu, Haicheng Cao, Chuanju Wang, Zixian Jiang, Tingang Liu, Na Xiao, Mingtao Nong, Vishal Khandelwal, Xiaohang Li
A new study presents a revolutionary CSD method to create thick (180 nm) single-layer (GaAl)2O3 films with enhanced crystal quality through silver doping.
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Degradation of tetracycline by visible light using Ca2Nb2O7 composite oxides with perovskite and pyrochlore sub-crystalline phases

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00044G, Paper
Junwei Xu, Chengxin Lu, Xianfeng Zhang, Rumeng Ouyang, Xiuzhong Fang, Xianglan Xu, Xiang Wang
We synthesized two paramorphs of Ca2Nb2O7 for visible light degradation of tetracycline, and found that pyrochlore phase has better reactivity compared to perovskite phase, which is attributed to the intrinsic oxygen vacancies and lattice disorder of pyrochlore phase.
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Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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Noble-metal-free bimetallic nitride decorated CdS nanorods for photocatalytic hydrogen generation

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00216D, Paper
Lu Chen, Yu Zou Xia, Jiale Shi, Xiaohui Huang, Xiyao Liu, Guiyang Yan, Renkun Huang
Developing highly active and stable non-noble-metal cocatalyst-decorated semiconductors is desirable for the practical application of photocatalysis, which remains an open question. Herein, we report transition-metal nitride (Ni3FeN) loaded cadmium sulfide...
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Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic(V)-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper
Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
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Structural diversity and tetrel bonding significance in lead(II) complexes with pyrazoylisonicotinoylhydrazone and varied anionic co-ligands

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00325J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ghodrat Mahmoudi, Isabel Garcia-Santos, Roi Fernández-Vázquez, Rosa Maria Gomila, Alfonso Castineiras, Esmail Doustkhah, Ennio Zangrando, Antonio Frontera
Four lead(II) complexes featuring pyrazoylisonicotinoylhydrazone ligand paired with various anionic co-ligands (azido, thiocyanato, nitrito, and nitrato) were synthesized and thoroughly examined using structural, analytical, and spectroscopic techniques. These ligands, in...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Highly enhanced cationic dye adsorption from water by nitro-functionalized Zn-MOF nano/microparticles and a biomolecular binder for improving the reusability

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00131A, Paper
Gunasekaran Arunkumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Savarimuthu Philip Anthony
Zn-MOF with a nitro-functionalized ligand exhibited enhanced cationic dye adsorption, and binder coating improved the reusability.
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S-scheme heterojunction based on CuWO4/WO3 microspheres with improved photocatalytic property under visible light

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00301B, Paper
Yangang Sun, Jianhua Ge, jiaqi xu, Jinguo Wang
Dye wastewater green treatment has always been one of the research hotspots in the environmental protection and remediation field. The photocatalytic degradation and mineralization of organic dyes are considered to...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Structural chemistry of decalins and perfluorodecalins

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01117H, Paper
Bartłomiej Paska, Grzegorz Cichowicz, Patryk Rzepiński, Michał Ksawery Cyrański, Łukasz Dobrzycki, Roland Boese
Crystaline phases of decalins and perfluorodecalins.
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Orthogonal stimulation of structural transformations in photo-responsive MOF films through linker functionalization

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00221K, Communication
Open Access
Sumea Klokic, Benedetta Marmiroli, Denys Naumenko, Giovanni Birarda, Simone Dal Zilio, Miriam de J. Velásquez-Hernández, Paolo Falcaro, Lisa Vaccari, Heinz Amenitsch
Controlling the magnitude of structural dynamics in flexible MOF films by an applied stimulus is largely desired for specific applications such as energy storage.
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Nitro group and K+-based secondary building units for the self-assembly of 3D coordination polymers built on dinuclear dianionic helicate connectors

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00255E, Paper
Open Access
Raúl Mendoza-Báez, Alan Molina-Renteria, Juan Olguín
Two dinuclear dianionic helicates, K2[MII2(L)3] M = MnII (1) and NiII (2), based on 2-hydroxy-5-nitrobenzaldehyde, self-assemble into novel 3D coordination polymers due to nitro groups acting as secondary assembly instruction.
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Flux growth and characterization of gallium-rare earth borates

CrystEngComm, 2024, 26,2180-2189
DOI: 10.1039/D3CE01269G, Paper
Victor V. Maltsev, Elizaveta V. Koporulina, Elena A. Volkova, Diana D. Mitina, Anna I. Jiliaeva, Vladimir L. Kosorukov, Alexey E. Afanasev, Daniil A. Naprasnikov
YGa3(BO3)4 single crystals were grown from a K2Mo3O10-based flux, and also RGa3(BO3)4 (R = Y, Pr–Yb) spontaneous crystals (RGB) were obtained by a high-temperature flux growth technique from a complex R2O3–Bi2O3–B2O3–Ga2O3 solvent.
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Facile syntheses, structures and photocatalytic properties of 3D iodoargentate frameworks derived from TM-flexible-amino-ligand templates

CrystEngComm, 2024, 26,2172-2179
DOI: 10.1039/D4CE00247D, Paper
Yan Gao, Xiao Yang, Taohong Ren, Dingxian Jia
3D iodoargentates [Co(en)3(Ag2I4)]n (1), [Fe(en)3(Ag2I4)]n (2) and [Co(dien)2(Ag2I4)]n·nH2O (3) were prepared by solvothermal methods. Compounds 1–3 were catalytic activity for photodegradation of crystal violet under visible light irradiation.
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The development of an approach for the precision determination of thermal strain tensor elements for single crystals using the example of t-Ag0.8Li0.2InSe2

CrystEngComm, 2024, 26,2207-2218
DOI: 10.1039/D3CE01186K, Paper
Polina S. Serebrennikova, Sergey I. Lobanov, Alexander S. Sukhikh, Lyudmila I. Isaenko, Sergey A. Gromilov
A new approach to the precision determination of single-crystal unit cell parameters is proposed and demonstrated using tetragonal Ag0.8Li0.2InSe2.
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Effects of B2S3 additive on diamond crystallization at HPHT conditions

CrystEngComm, 2024, 26,2190-2196
DOI: 10.1039/D4CE00147H, Paper
Yong Li, Shuai Wang, Hongyu Xiao, Qiang Wang, Zhengguo Xiao, Yanchao She, Ying Wang
The color of the diamond obtained with the B2S3 additive changes from yellow to light blue and the resistivity of the synthesized diamond drops from 3.89 × 10 Ω cm to 2.51 × 10−1 Ω cm with the introduction of Ti/Cu into the synthetic cavity.
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Bilirubin and its crystal forms

CrystEngComm, 2024, 26,2136-2142
DOI: 10.1039/D4CE00123K, Paper
Open Access
Matthew L. Bracken, Manuel A. Fernandes, Sadhna Mathura
Bilirubin crystals in the gall bladder and urine are typical indicators of liver dysfunction. Examining the crystal structure of lipophilic bilirubin is thus of interest. We present crystal structures for three crystal forms of the bile pigment.
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Acoustic shock wave-induced phase transition in indium selenide: tuning band gap energy for solar cell applications

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00012A, Paper
S. Oviya, F. Irine Maria Bincy, S. Arumugam, K. Kamala Bharathi, Raju Suresh Kumar, P. Kannappan, Ikhyun Kim, S. A. Martin Britto Dhas
Acoustic shock wave loading experiment on indium selenide.
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Twitter lets users search for new lists to follow

Twitter launches the functionality for web users




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Snapchat reaches over 200 million monthly active users in India

Snapchat has over 750 million monthly active users globally




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WhatsApp to launch usernames for accounts like Instagram

WhatsApp is working to launch ‘usernames’ for users on Android.




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Twitter sued by music publishers for allowing copyrighted songs

Members of the National Music Publishers’ Association (NMPA) are seeking over $250 million in damages for alleged infringement of nearly 1,700 copyrights.




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Twitter applies temporary limit to address data scraping, system manipulation: Elon Musk

That comes after Twitter had announced that it will require users to have an account on the social media platform to view tweets.




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Musk sets tweet-viewing limits to combat data scraping from large AI companies

Temporary limits to address “extreme levels of data scraping and system manipulation”




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Twitter limits TweetDeck to verified members only

TweetDeck now supports full composer functionality, spaces, video docking, and polls




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Meta Threads is live now. Here’s how to register

Threads gains about 10 million signups within seven hours of the roll out




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Meta’s Threads draws millions seeking a Twitter alternative

On Threads, people can post text and links and reply to or repost messages from others




li

Meta's 'friendly' Threads collides with unfriendly internet

Mark Zuckerberg’s idealistic vision for Threads has been challenged from Day 1 by news junkies, politicians and other fans of rhetorical combat




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US willing to work with India on investment platform to deliver lower cost capital for energy transitionition

Following PM Narendra Modi’s recent visit, US Treasury Secretary Janet Yellen says that her country and India are among the closest partners in the world




li

Twitter’s blue bird flies off, Musk brings in the X factor

Twitter sees dramatic new updates that might change its entire character




li

Twitter turning into X is set to kill billions in brand value

Elon Musk’s vision for X includes audio, video, messaging, payments, and banking, but rebuilding brand equity and user trust may be challenging




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Elon Musk tests live video on X

Musk’s X platform also pledges to fund legal bills for individuals facing unfair treatment by employers due to their posts or likes on the platform




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Elon Musk says fight with Mark Zuckerberg will be live-streamed on X

Musk had tested a live video feature on X.




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Artists take government to court over 'chilling' tech laws

Kunal Kamra, who for nearly a decade has satirised politics and social norms in his routines, is fighting an amendment to the IT rules that allows the government to order social media platforms to take down any news that its fact-checking unit identifies as "fake or false or misleading"




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WhatsApp unveils Mac app with group calling

The new version enables users to make group calls, supporting up to eight people in video calls and up to 32 in audio calls.




li

Community norm violation: YouTube removed 1.9 million videos in Jan-Mar 2023 in India

In the same period, YouTube removed over 6.48 million videos globally for violation of the norms




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WhatsApp’s latest update: Undo feature empowers users with message deletion flexibility

This new functionality complements the existing “Delete for Everyone” option, allowing users to undo message deletions within a brief window of five seconds




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Centre extends deadline for Telangana millers for supply of rice to FCI

Asks State government to adhere to quality norms




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GST payers get communication to first show irreversible ITC and then reverse, experts advise caution in filing Nov GSTR-3B

In August 2022 this year, Central Board of Indirect Taxes & Custom (CBIC) issued a detailed clarification on reporting of information about reversal of ITC as well as ineligible ITC




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Can climate-resilient farming become a profitable venture?  

The mantra of climate-resilient farming was simple but difficult to digest for traditional farming households




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Strengthen panchayats to mobilise internal revenues: CFC member Lahiri

Two-day national conclave of SFC begins in Hyderabad




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Local manufacturing makes India sales resilient for Apple

‘Sale for Apple products will increase 15-16 per cent in fourth quarter of 2022’