Disclosed is a method for removing weakly basic nitrogen compounds from a hydrocarbon feed stream by contacting the hydrocarbon feed stream with acidic clay to produce a hydrocarbon effluent stream having a lower weakly basic nitrogen compound content relative to the hydrocarbon feed stream. The hydrocarbon feed stream comprises an aromatic compound and a weakly basic nitrogen compound.

High octane unleaded aviation fuel compositions having high aromatics content and a CHN content of at least 97.2 wt %, less than 2.8 wt % of oxygen content, a T10 of at most 75° C., T40 of at least 75° C., a T50 of at most 105° C., a T90 of at most 135° C., a final boiling point of less than 190° C., an adjusted heat of combustion of at least 43.5 MJ/kg, a vapor pressure in the range of 38 to 49 kPa, freezing point is less than −58° C. is provided.

This invention relates to the oligomerization of olefinic compounds in the presence of an activated oligomerization catalyst. The invention also extends to a particular manner for providing an activated oligomerization catalyst. According to the present invention, there is provided a process for producing an oligomeric product by the oligomerization of at least one olefinic compound, the process including (a) providing an activated oligomerization catalyst by combining, in any order, iii) a source of chromium, ιv) a ligating compound of the formula (R1)mX1(Y)X2(R2)n wherein X1 and X2 are independently an atom selected from the group consisting of nitrogen, phosphorus, arsenic, antimony, bismuth, oxygen, sulphur and selenium or said atom oxidized by S, Se, N or O where the valence of X1 and/or X2 allows for such oxidation, Y is a linking group between X1 and X2 which linking group contains at least one nitrogen atom which is directly bonded to X1 or X2, m and n are independently 0, 1 or a larger integer, and R1 and R2 are independently hydrogen, a hydrocarbyl group, an organoheteryl group or a heterohydrocarbyl group, and the respective R1 groups are the same or different when m>1, and the respective R2 groups are the same or different when n>1, in) a catalyst activator which is an organoboron compound including a cation and a non-coordinating anion of the general formula [(R10)xL*-H]+[B(R20)4]− wherein L* is an atom selected from the group consisting of N, S and P, the cation [(R10)x L*-H]* is a Bronsted acid, x is an integer 1, 2 or 3, each R10 is the same or different when x is 2 or 3 and each is a —H, hydrocarbyl group or a heterohydrocarbyl group, provided that at least one of R10 comprises at least 6 carbon atoms and provided further that the total number of carbon atoms in (R10)x collectively is greater than 12, R20 independently at each occurrence is selected from the group consisting of hydride, dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, halosubstituted-hydrocarbyl radicals, halosubstituted-alkoxide, halosubstituted-aryloxide and a halosubstituted aromatic ring moiety with at least one halide substituent on the aromatic ring, and vi) an aliphatic solvent, and (b) contacting the at least one olefinic compound with the activated oligomerization catalyst to produce an oligomeric product.

A process is presented for quenching a process stream in a paraffin dehydrogenation process. The process comprises cooling a propane dehydrogenation stream during the hot residence time after the process stream leaves the catalytic bed reactor section. The process includes cooling and compressing the product stream, taking a portion of the product stream and passing the portion of the product stream to the mix with the process stream as it leaves the catalytic bed reactor section.

A method of creating a semiconductor device is disclosed. An end of a carbon nanotube is unzipped to provide a substantially flat surface. A contact of the semiconductor device is formed. The substantially flat surface of the carbon nanotube is coupled to the contact to create the semiconductor device. An energy gap in the unzipped end of the carbon nanotube may be less than an energy gap in a region of the carbon nanotube outside of the unzipped end region.

A molding composition formulation includes a thermoset cross-linkable 12 to 45 micron polymeric resin. Hollow glass microspheroids are present from 2 to 12 total weight percent. An article formed from such a composition is further strengthened by the addition of a surface activating agent bonded to the surface of the glass microspheroids. Conventional particulate fillers when added to an inventive formulation provide enhanced performance when the filler particle has a size sufficiently small to insert within adjacent microspheroid interstitial voids. An unsaturated polyester resin so formed is particularly well suited for the formation of sheet molding compound formulations.

Aqueous copolymer dispersions for a variety of uses, including coating compositions or binders for plasters and paints, are disclosed. The aqueous copolymer dispersions may comprise one or more silicon containing compounds, in particular hydrolyzable silane compounds without any additional reactive group.

The invention relates to a method for producing thermoplastic molding compounds, comprising: A) 40 to 99 wt % of at least one thermoplastic polymer, B) 1 to 60 wt % of a flame-proofing agent component containing an expandable graphite, and C) 0 to 60 wt % of further additives, by melt-mixing components A), B) and C) in a screw-type extruder, wherein the screw-type extruder, along the feed direction, comprises, in the following order, at least one dosing zone, a plastifying zone, a homogenizing zone, a second dosing zone, and a discharge zone, in that the dosing takes place into the screw-type extruder having the length L, wherein the length L is defined as the section starting with the first dosing unit for adding components A, B and/or C and ending, in the feed direction, at the discharge opening, a melt is generated after adding components A, B and C in the range of 0 liter to 0.15 liter in a first method step in the presence of component B1), and in a second method step, after the addition of component B1) in the range of 0.5 liter to 0.95 liter, component B1) is mixed into said melt, wherein said method offers technical advantages.

A facile synthesis of amphiphilic hyperbranched polymers consisting of poly(amic acid) and polyimide was developed via “A2+B3” approach from difunctional anhydride and trifunctional hydrophilic poly(oxyalkylene)triamine. Various amphiphilic hyperbranched poly(amic acid)s (HBPAAs) with terminal amine functionalities and amic acid structures were prepared through ring-opening polyaddition at room temperature, followed by thermal imidization process for the formation of hyperbranched polyimides (HBPIs), accordingly. The resulting HBPIs were analyzed by GPC, indicating the molecule weights of 5000˜7000 g/mol with a distribution of polydispersity between 2.0 and 3.8. The amine titration for HBPIs indicated the peripheral total-amine contents to be 8.32˜18.32 mequiv/g dependent on compositions.

A Test Wrapper and associated Test Access Mechanism (TAM) architecture for facilitating testing of IP blocks integrated on a System on a Chip (SoC). The TAM architecture includes a Test Controller and one or more Test Wrappers that are integrated on the SoC proximate to IP blocks. Test data and commands corresponding to input from an external tester are packaged by the Test Controller and sent to one or more Test Wrappers via an interconnect fabric. The Test Wrappers interface with one or more IP test ports to provide test data, control, and/or stimulus signals to the IP blocks to facilitate circuit-level testing of the IP blocks. Test results for the circuit-level tests are returned to the Test Controller via the fabric. Test Wrappers may be configured to pass through interconnect signals, enabling functional testing of IP blocks to be facilitated via test packages and test results transmitted between the Test Controller and the IP blocks via the fabric. Test wrappers may also be configured to test multiple IP blocks comprising a test partition.

Within a radio communication network infrastructure transmitting data organized into a sequence of symbols to a receiving device over a plurality of radio links, data to be transmitted is encoded according to an error correction coding scheme in order to produce a set of systematic symbols and a set of corresponding redundancy symbols; the systematic symbols and a first subset of the corresponding redundancy symbols are transmitted, over a first radio link among said plurality of radio links, in broadcast mode, and a second subset of the corresponding redundancy symbols, distinct from the first one, is transmitted over a second radio link among said plurality of radio links.

A logical operations functional block for an execution unit of a processor includes a first input data link for a first operand and a second input data link for a second operand. The execution unit includes a register connected to an error correction code detection unit. The logical operations functional block includes a look-up table configured to receive an error correction code syndrome from the error correction code detection unit. The logical operations functional block also includes a multiplexer configured to receive an output signal from the look-up table at a first input and the first operand at a second input, wherein an output of the multiplexer is coupled to the first input data link of a logical functional unit.

The present inventions are related to systems and methods for data processing, and more particularly to systems and methods for variable rate coding in a data processing system.

A wireless communication system including a sender apparatus having a plurality of transmitting antennas that performs MIMO transmission of a plurality of data blocks; and a receiver apparatus that receives the plurality of data blocks. The sender apparatus transmits a process number via a control channel different from a data channel to the receiver apparatus, and wherein when the MIMO diversity transmission is performed, the receiver apparatus performs HARQ processing in the received data blocks based on not a process number which prevents the data blocks from competing but the received process number from the sender apparatus.

Containers and methods for disposing unused pharmaceutical product are disclosed. Each container (100, 200, 300) may include a container body (104, 204, 304) with an internal chamber (116, 216, 316) for storing pharmaceutical product, along with a cover (124, 224, 324) for selectively limiting access to the chamber (116, 216, 316). An encapsulation component (128, 228, 328) may be selectively disposable within the chamber (116, 216, 316), and may be operable to encapsulate the pharmaceutical product within the container (100, 200, 300). For instance, the encapsulation component (128, 228, 328) may melt and/or flow into contact with the pharmaceutical product and thereafter solidify to encapsulate the pharmaceutical product. The encapsulation component (128, 228, 328) may melt and thereafter solidify between the cover (124, 224, 324) and shell (104, 204, 304) to limit removal of the cover (124, 224, 324) from the shell (104, 204, 304).

A treatment system and a method for removal of at least one halogenated compound, such as PCBs, found in contaminated systems are provided. The treatment system includes a polymer blanket for receiving at least one non-polar solvent. The halogenated compound permeates into or through a wall of the polymer blanket where it is solubilized with at least one non-polar solvent received by said polymer blanket forming a halogenated solvent mixture. This treatment system and method provides for the in situ removal of halogenated compounds from the contaminated system. In one embodiment, the halogenated solvent mixture is subjected to subsequent processes which destroy and/or degrade the halogenated compound.

A method for computer-implemented unit-conversion method, the method comprising identifying a first numerical value in a first system of units displayed on a computing device, converting the first numerical value in the first system of units into a second numerical value, and displaying the second numerical value and the second system of units on the computing device.

A circuit arrangement and method couple a hardware-based pseudorandom number generator (PRNG) to an execution unit in such a manner that pseudorandom numbers generated by the PRNG may be selectively output to the execution unit for use as an operand during the execution of instructions by the execution unit. A PRNG may be coupled to an input of an operand multiplexer that outputs to an operand input of an execution unit so that operands provided by instructions supplied to the execution unit are selectively overridden with pseudorandom numbers generated by the PRNG. Furthermore, overridden operands provided by instructions supplied to the execution unit may be used as seed values for the PRNG.

A communication device includes a storage unit to store quotients and remainders associated with multiplication values obtained by multiplying a specified integer number, which is expressed in a form of (2β+α) where β is a positive integer number and α is a positive integer number other than integral multiples of 2, respectively, the quotients and the remainders being obtained by dividing the multiplication values by 2β, respectively, a first unit to divide a dividend by 2βand calculate a quotient and a remainder, a second unit to obtain a quotient, which corresponds to the remainder from the storage unit, and a third unit to determine that the data length of the packet data is normal, when a combination of the quotient and the remainder calculated by the first unit is in the storage unit.

In this application, a set of orthogonal functions is introduced whose power spectral densities are all rectangular shape. To find the orthogonal function set, it was considered that their spectrums (Fourier transforms of the functions) are either real-valued or imaginary-valued, which are corresponding to even and odd real-valued time domain signals, respectively. The time domain functions are all considered real-valued because they are actually physical signals. The shape of the power spectral densities of the signals are rectangular thus, the Haar orthogonal function set can be employed in the frequency domain to decompose them to several orthogonal functions. Based on the inverse Fourier transform of the Haar orthogonal functions, the time domain functions with rectangular power spectral densities can be determined. This is equivalent to finding the time-domain functions by taking the inverse Fourier transform of the frequency domain Walsh functions. The obtained functions are sampled and truncated to generate finite-length discrete signals. Truncation destroys the orthogonality of the signals. The Singular Value Decomposition method is used to restore the orthogonality of the truncated discrete signals.

A system (200) and a method (100) of operating a computing device to perform memoization are disclosed. The method includes determining whether a result of a function is stored in a cache and, if so, retrieving the result from the cache and, if not, calculating the result and storing it in the cache. The method (100) includes transforming (104) by the computing device at least one selected from the input parameters and the output parameters of the function, the transforming being based on an analysis of the function and its input arguments to establish whether or not there is a possible relationship reflecting redundancy among the input parameters and output parameters of the function. The transforming may include at least one of: use of symmetry, scaling, linear shift, interchanging of variables, inversion, polynomial and/or trigonometric transformations, spectral or logical transformations, fuzzy transformations, and systematic arrangement of parameters.

A method of generating a code sequence in a wireless communication system is disclosed. More specifically, the method includes recognizing a desired length of the code sequence, generating a code sequence having a length different from the desired length, and modifying the length of the generated code sequence to equal the desired length. Here, the step of modifying includes discarding at least one element of the generated code sequence or inserting at least one null element to the generated code sequence.

Examples disclose a computing system comprising a computing device with a display surface to detect a selection of functionality from a list of functionalities to be disabled on a calculator. Further, the computing device creates a custom configuration based on the selected functionality. Additionally, the examples also disclose a calculator with a processor to integrate the custom configuration, the custom configuration restricts the selected functionality on the calculator.

The invention pertains to an oligomer or polymer substituted by one or more bisacylphosphine oxide moieties, characterized in that said bisacylphosphine oxide moiety is linked via the phosphorous atom, optionally via a spacer group, to the oligomer or polymer backbone; as well as to specifically functionalized bisacylphosphine oxides, suitable to prepare said polymers or oligomers.

In embodiments of driver interface functions to interface client function drivers, a set of serial communication protocol driver interfaces are exposed by a core driver stack, and the serial communication protocol driver interfaces include driver interface functions to interface with client function drivers that correspond to client devices configured for data communication in accordance with the serial communication protocol. A client function driver can check for the availability of a driver interface function before interfacing with the core driver stack via the serial communication protocol driver interfaces. A contract version identifier can also be received from the client function driver via an extension of the driver interface functions, where the contract version identifier indicates a set of operation rules by which the client function driver interfaces with the core driver stack.

In one exemplary embodiment, a computer-implemented method includes receiving, at a remote direct memory access (RDMA) device, a plurality of RDMA requests referencing a plurality of virtual pages. Data transfers are scheduled for the plurality of virtual pages, wherein the scheduling occurs at the RDMA device. The number of the virtual pages that are currently pinned is limited for the RDMA requests based on a predetermined pinned page limit.

A method of interacting with data at a wireless communication device is provided. The wireless communication device has access to a first set of capabilities. Data is received at the wireless communication device via a wireless transmission. The data represents visual content that is viewable via a display device. A graphical user interface, including a delayed action selector, is provided via the display device. An input is received within a limited period of time after displaying the delayed action selector. The input is associated with a command to delay execution of an action with respect to the data until the wireless communication device has access to a second set of capabilities. The action is not supported by the first set of capabilities but is supported by the second set of capabilities. An indication of receipt of the input is provided at the wireless communication device.

A processor having a streaming unit is disclosed. In one embodiment, a processor includes one or more execution units configured to execute instructions of a processor instruction set. The processor further includes a streaming unit configured to execute a first instruction of the processor instruction set, wherein executing the first instruction comprises the streaming unit loading a first data stream from a memory of a computer system responsive to execution of a first instruction. The first data stream comprises a plurality of data elements. The first instruction includes a first argument indicating a starting address of the first stream, a second argument indicating a stride between the data elements, and a third argument indicative of an ending address of the stream. The streaming unit is configured to output a second data stream corresponding to the first data stream.

A memory system includes a CPU that communicates commands and addresses to a main-memory module. The module includes a buffer circuit that relays commands and data between the CPU and the main memory. The memory module additionally includes an embedded processor that shares access to main memory in support of peripheral functionality, such as graphics processing, for improved overall system performance. The buffer circuit facilitates the communication of instructions and data between CPU and the peripheral processor in a manner that minimizes or eliminates the need to modify CPU, and consequently reduces practical barriers to the adoption of main-memory modules with integrated processing power.

Aspects of the invention relate generally to validating array bounds in an API emulator. More specifically, an OpenGL (or OpenGL ES) emulator may examine each array accessed by a 3D graphic program. If the program requests information outside of an array, the emulator may return an error when the graphic is drawn. However, when the user (here, a programmer) queries the value of the array, the correct value (or the value provided by the programmer) may be returned. In another example, the emulator may examine index buffers which contain the indices of the elements on the other arrays to access. If the program requests a value which is not within the range, the emulator may return an error when the graphic is drawn. Again, when the programmer queries the value of the array, the correct value (or the value provided by the programmer) may be returned.

A technique to enable efficient interrupt communication within a computer system. In one embodiment, an advanced programmable interrupt controller (APIC) is interfaced via a set of bits within an APIC interface register using various interface instructions or operations, without using memory-mapped input/output (MMIO).

A bridge includes a Peripheral Component Interconnect Express interface supporting at least two lanes, an Extensible Host Controller Interface, and a Universal Serial Bus 3.0 root hub. The Peripheral Component Interconnect Express interface is used for coupling to a host. Each lane of the at least two lanes provides a highest data transmission speed. The Extensible Host Controller Interface is coupled to the Peripheral Component Interconnect Express interface for storing data transmitted by the Peripheral Component Interconnect Express interface. The Universal Serial Bus 3.0 root hub includes a first controller and a second controller. The first controller and the second controller are used for controlling data transmission of four ports, and a highest data transmission speed provided by each port of the four ports is not more than the highest data transmission speed provided by the lane.

Various embodiments include apparatuses, stacked devices and methods of forming dice stacks on an interface die. In one such apparatus, a dice stack includes at least a first die and a second die, and conductive paths coupling the first die and the second die to the common control die. In some embodiments, the conductive paths may be arranged to connect with circuitry on alternating dice of the stack. In other embodiments, a plurality of dice stacks may be arranged on a single interface die, and some or all of the dice may have interleaving conductive paths.

A method of processing an electronic file by identifying portions of content data in the electronic file and determining if each portion of content data is passive content data having a fixed purpose or active content data having an associated function. If a portion is passive content data, then a determination is made as to whether the portion of passive content data is to be re-generated. If a portion is active content data, then the portion is analyzed to determine whether the portion of active content data is to be re-generated. A re-generated electronic file is then created from the portions of content data which are determined to be re-generated.

A liquid crystal compound having a high stability to heat, light and so forth, a high clearing point, a low minimum temperature of a liquid crystal phase, a small viscosity, a suitable optical anisotropy, a large dielectric anisotropy, a suitable elastic constant and an excellent solubility in other liquid crystal compounds, a liquid crystal composition containing the compound, and a liquid crystal display device including the composition. The compound is represented by formula (1): wherein, for example, R1 is fluorine or alkyl having 1 to 10 carbons; ring A1 and ring A2 are 1,4-phenylene, or 1,4-phenylene in which at least one of hydrogen is replaced by fluorine; Z1, Z2 and Z3 are a single bond; L1 and L2 are hydrogen or fluorine; X1 is fluorine or —CF3; and m is 1, and n is 0.

To provide a compound, when the compound has both a high clearing point and a low crystallization temperature, having a wide temperature range of a liquid crystal phase and also an excellent solubility in other liquid crystal compounds, and further having general physical properties necessary for the compound, namely, stability to heat, light and so forth, a suitable optical anisotropy and a suitable dielectric anisotropy. A compound is represented by formula (1): wherein, for example, Ra and Rb are alkyl having 1 to 10 carbons; A1, A2, A3 and A4 are 1,4-phenylene; Z1, Z2, Z3 and Z4 are a single bond or alkylene having 1 to 4 carbons; and m, n, q and r are independently 0, 1, or 2, and a sum of m, n, q and r is 1, 2, 3 or 4.

An optically active bisbenzyl compound or a racemic bisbenzyl compound represented by formula (2) that has axial chirality: where: R1 represents a halogen, or an optionally substituted: linear, branched, or cyclic C1-8 alkyl, C2-8 alkenyl, C2-8 alkynyl, C6-14 aryl, C3-8 heteroaryl, linear, branched, or cyclic C1-8 alkoxy, or C7-16 aralkyl;R21 each independently represents hydrogen, halogen, nitro, or an optionally substituted: linear, branched, or cyclic C1-8 alkyl, C2-8 alkenyl, C2-8 alkynyl, C6-14 aryl, linear, branched, or cyclic C1-8 alkoxy, or a C7-16 aralkyl;R3 represents hydrogen, or an optionally substituted: C6-14 aryl, a C3-8 heteroaryl, or a C7-16 aralkyl; andY2 represents a halogen, or an optionally substituted: C1-8 alkylsulfonyloxy, C6-14 arylsulfonyloxy, or C7-16 aralkylsulfonyloxy.

A novel organic compound suitable for emitting green light and an organic light-emitting device including the organic compound are provided. The organic compound is represented by general formula (1). In general formula (1), R1 to R18 are each independently selected from a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted amino group, a substituted or unsubstituted aryl group, and a substituted or unsubstituted heterocyclic group.

Disclosed are: a diaryliodonium salt mixture which is a precursor of a BF4 salt or the like of a diaryliodonium compound, can be produced in the form of crystals at ambient temperature, can be purified in a simple manner, can be produced with high efficiency, and can be induced into a BF4 salt or the like salt that has excellent solubility in a monomer or the like; and a process for producing the diaryliodonium salt mixture. Also disclosed is a production process which can achieve good yield and can produce reduced amounts of byproducts, and is therefore applicable to the industrial mass production of a diaryliodonium compound. The diaryliodonium salt mixture is characterized by containing at least two specific diaryliodonium salts.

A method of synthesizing an alkyl cyclopentadiene compound is disclosed. The method includes contacting at least one cyclopentadienyl anion source and at least one alkyl group source to form at least one alkyl cyclopentadiene compound. The method further includes extracting the alkyl cyclopentadiene compound with a hydrocarbon solvent. The alkyl cyclopentadiene compound may be converted to a metallocene catalyst compound.

The invention is to provide a new liquid crystal compound having a high clearing point, a good compatibility with other compounds, a small viscosity, and a high stability to heat, light and so forth; compound (1) is provided: R1CF2nR2 (1) wherein, for example, R1 is alkyl having 4 to 10 carbons or —(CH2)2—CH═CH2, R2 is alkyl having 2 to 10 carbons, n is 8, and R1 and R2 are not allowed to be straight-chain alkyl having an identical number of carbons.

The present invention relates to 1,4-diethynylbenzene derivatives having substituents in the 2,3-position (cf. formula I, Claims), to the use thereof for high-frequency components, to liquid-crystalline media comprising the compounds, and to high-frequency components, in particular antennae, especially for the gigahertz range, comprising these media. The liquid-crystalline media serve, for example, for the phase shifting of microwaves for tuneable ‘phased-array’ antennae.

The disclosure describes a process for dehalogenation of chlorofluorocompounds. The process comprises contacting a saturated chlorofluorocompound with hydrogen in the presence of a catalyst at a temperature sufficient to remove chlorine and/or fluorine substituents to produce a fluorine containing terminal olefin.

The subject of the invention is a process for the preparation of fluoroolefin compounds. It relates more particularly to a process for manufacturing a (hydro)fluoroolefin compound comprising (i) bringing at least one compound comprising from three to six carbon atoms, at least two fluorine atoms and at least one hydrogen atom, provided that at least one hydrogen atom and one fluorine atom are located on adjacent carbon atoms, into contact with potassium hydroxide in a stirred reactor, containing an aqueous reaction medium, equipped with at least one inlet for the reactants and with at least one outlet, in order to give the (hydro)fluoroolefin compound, which is separated from the reaction medium in gaseous form, and potassium fluoride, (ii) bringing the potassium fluoride formed in (i) into contact, in an aqueous medium, with calcium hydroxide in order to give potassium hydroxide and to precipitate calcium fluoride, (iii) separation of the calcium fluoride precipitated in step (ii) from the reaction medium and (iv) optionally, the reaction medium is recycled after optional adjustment of the potassium hydroxide concentration to step (i).

Provided is a process for making 2-chloro-1,1,1,2-tetrafluoropropane. The process has the step of hydrofluorinating 2-chloro-3,3,3-trifluoropropene in the presence of a catalyst selected from the group consisting of SbCl3, SbCl5, SbF5, TiCl4, SnCl4, Cr2O3, and fluorinated Cr2O3.

Methods for fluorinating organic compounds are described herein.

Particular compounds having a fluorene skeleton are superior in broad utility and stability, as a protecting reagent for liquid phase synthesis of amino acids and/or peptides.

A method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3(—CX2X2)nCX1═H2 (I) to at least one compound of formula (II): CF3(CX2X2)nCX1═H2 (II), where X1 is Cl, Br or I, each X2 is independently selected from the group consisting of H, Cl, F, Br or J, and n is 0, 1, or 2.

Methods of increasing the solubility of a base in supercritical carbon dioxide include forming a complex of a Lewis acid and the base, and dissolving the complex in supercritical carbon dioxide. The Lewis acid is soluble in supercritical carbon dioxide, and the base is substantially insoluble in supercritical carbon dioxide. Methods for increasing the solubility of water in supercritical carbon dioxide include dissolving an acid or a base in supercritical carbon dioxide to form a solution and dissolving water in the solution. The acid or the base is formulated to interact with water to solubilize the water in the supercritical carbon dioxide. Some compositions include supercritical carbon dioxide, a hydrolysable metallic compound, and at least one of an acid and a base. Some compositions include an alkoxide and at least one of an acid and a base.

This invention provides a method related to the preparation of derivatives of poly(ethylene glycol), wherein the method comprises increasing the pH of an aqueous composition comprising a poly(ethylene glycol) bearing a —O—(CH2)n—CO2R3 functional group to result in an aqueous composition comprising a poly(ethylene glycol) bearing a —O—(CH2)n—CO2H functional group, wherein R3 is alkyl and (n) in each instance is 1-6.