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Green Chemistry: Advancing Planetary Phosphorus Sustainability through the Synergy of Graphene Oxide Modified with Magnetic Nanoparticles (M@GO) for Extracting Tertiary Effluent Phosphorus in Sewage Treatment Plants.

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Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00859B, Paper
Open Access
Andrea Muñoz-Garcia, Pablo Montoro Leal, María Mar López Guerrero, Carlos Vereda-Alonso, Elisa Vereda Alonso
Securing the enduring sustainability of global phosphorus (P) utilization has become a key societal priority. The application of green chemistry and green engineering presents an opportunity to mitigate these challenges...
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Regulating the type of nitrogen to improve the performance of Co–N/C with a confinement effect in peroxymonosulfate activation for the effective degradation of organic pollutants

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00145A, Paper
Yanqing Cong, Lingjie Ye, Qiuang Zheng, Yudi Wang, Yifan Shao, Xuhua Ren, Shi-Wen Lv
Three Co–N/C-based catalysts with different types of nitrogen are prepared and employed to activate peroxymonosulfate for tetracycline degradation.
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Mycogenic silver nanoparticles from Penicillium citrinum IB-CLP11 – their antimicrobial activity and potential toxicity effects on freshwater organisms

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00002A, Paper
Arthur Pérez Aguiar, Cristiane Angélica Ottoni, Claudia de Lima Ramos Aquaroli, Evelyn Caroline Vicente Mendes, Ana Lúzia de Souza Araújo, Marta Filipa Simões, Edison Barbieri
Silver nanoparticles (AgNPs) are some of the most attractive nanomaterials for commercial applications, but they can also be a very challenging issue from the point of view of cytotoxicity and phytotoxicity as agents that damage genetic information.
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A multi-technique analysis of gelatin biodegradation on the surface of core–shell nanoparticles by Alteromonas macleodii extracellular proteases

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Environ. Sci.: Nano, 2024, 11,1429-1441
DOI: 10.1039/D3EN00523B, Paper
Sergio Fernández-Castillo Suárez, Cécile Courrèges, Javier Jiménez-Lamana, Simon Godin, Sophie Nolivos, Régis Grimaud, Luisa Ronga, Joanna Szpunar, Joachim Allouche
Multi-technique characterization at the nanoscale of gelatin biodegradation on the surface of core–shell nanoparticles by extracellular proteases.
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Effect of ZnMgO2 nanoparticles used as a nanofertilizer: promoting the growth activities of rice seedlings

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Environ. Sci.: Nano, 2024, 11,1571-1581
DOI: 10.1039/D3EN00770G, Paper
Sajid Mehmood, Niteesh Kumar, Aadil Mansoori, Madan Mohan, Anirudh Kumar, Tanmay Kumar Ghorai
Novel ZnMgO2 bimetallic nanoparticles were synthesized using Cinchona succirubra leaf extract and used as a nano fertilizer, promoting the growth activities of rice seedlings, α-amylase and antioxidant activity with average particle sizes of 24.8 nm.
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High-performance TiO2 catalyst composited with In–1,1,2,2-tetra(4-carboxylbiphenyl)ethylene for the efficient degradation of organic pollutants

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Environ. Sci.: Nano, 2024, 11,1533-1542
DOI: 10.1039/D3EN00820G, Paper
Xinyu Liu, Chenchen Li, Jian Nan, Ruike Liang, Huabin Wang, Rui Xu, Yong Zhang
A combination of metal–organic frameworks (MOFs) with TiO2 can improve the performance of TiO2 in the photocatalytic degradation of organic pollutants.
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Preparation of UV-responsive hydrogels based on nanocellulose and their utilization in fungicide delivery

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Environ. Sci.: Nano, 2024, 11,1442-1451
DOI: 10.1039/D3EN00910F, Paper
Chaoqun You, Xinyue Ji, Hanchen Lin, Ning Ma, Wei Wei, Lingfeng Long, Like Ning, Fei Wang
A stimuli-responsive hydrogel for fungicide delivery based on UV-sensitive molecular (AZO)-conjunct CNCs is successfully prepared.
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Fe–carbon nanofiber-modified Mo-MOF for the controlled release and translocation of micronutrients in plants

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Environ. Sci.: Nano, 2024, 11,1597-1611
DOI: 10.1039/D3EN00833A, Paper
Komal Pandey, Rishabh Anand Omar, Nishith Verma, Govind Gupta
Fe-CNF/Mo-MOF releases Mo and Fe in soil upon degradation by resident rhizobacteria and translocates the micronutrients to plant roots, shoots, and leaves.
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Applications of bismuth-based nanoparticles for the removal of pollutants in wastewater: a review

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Environ. Sci.: Nano, 2024, 11,1332-1367
DOI: 10.1039/D3EN00983A, Critical Review
Shan Jiang, Yihang Zhang, Jianyu Gong
This review discusses the characteristics and synthesis methods of Bi-based NPs. It delves into the removal efficiency in wastewater, emphasizing traditional/emerging strategies to enhance the performance, mechanisms, toxicology, and challenges.
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TiO2−x prepared by radio-frequency thermal plasma: optical switching of hydrophilicity and hydrophobicity used in the efficient recovery of photocatalysts

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Environ. Sci.: Nano, 2024, 11,1693-1700
DOI: 10.1039/D4EN00033A, Paper
Chang Liu, Huacheng Jin, Zongxian Yang, Yuge Ouyang, Fei Ding, Baoqiang Li, Fangli Yuan
A TiO2−x catalyst synthesized using radio-frequency thermal plasma can switch between hydrophilic and hydrophobic properties. Its dispersion and agglomeration can thus be adjusted so that it is dispersed evenly or forms floating balls, which is convenient for recycling.
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Biogenic synthesis of dual-emission chlorophyll-rich carbon quantum dots for detection of toxic heavy metal ions – Hg(II) and As(III) in water and mouse fibroblast cell line NIH-3T3

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Environ. Sci.: Nano, 2024, 11,1636-1653
DOI: 10.1039/D3EN00789H, Paper
Ravi Pratap, Nurul Hassan, Monika Yadav, Saurabh Kumar Srivastava, Shilpi Chaudhary, Anita Kamra Verma, Jayeeta Lahiri, Avanish S. Parmar
Due to the excessive residues and serious adverse effects, it is urgent to develop an efficient method to detect Hg2+ and As3+ in drinking water to protect human health.
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Understanding the active sites and associated reaction pathways of metal-free carbocatalysts in persulfate activation and pollutant degradation

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Environ. Sci.: Nano, 2024, 11,1368-1393
DOI: 10.1039/D3EN00988B, Critical Review
Huawen Hu, Dongchu Chen, Yaoheng Liang, Wenyi Wang, Yinlei Lin, Xuejun Xu, Xiaowen Wang, Kun Wang, Yuyuan Zhang, Jian Zhen Ou
Environmental remediation based on peroxomonosulfate- and peroxydisulfate-activation-enabled radical/non-radical oxidation has gained growing interest due to the strong oxidation power, long life of reactive oxygen species, and wide pH adaptability.
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Influence of time and ageing conditions on the properties of ferrihydrite

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Environ. Sci.: Nano, 2024, 11,1682-1692
DOI: 10.1039/D3EN00828B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Michel Sassi, Odeta Qafoku, Mark E. Bowden, Carolyn I. Pearce, Drew Latta, Quin R. S. Miller, Mavis D. Boamah, Alpha T. N'Diaye, Jade E. Holliman Jr., Elke Arenholz, Kevin M. Rosso
Storage conditions affect the initial tetrahedral iron and hydroxyl populations of ferrihydrite, both are correlated and decrease over time as function of ageing.
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Core–shell magnetic zinc-based molecularly imprinted polymer: a robust heterogeneous catalytic nanoreactor toward the CO2 fixation reaction

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Environ. Sci.: Nano, 2024, 11,1622-1635
DOI: 10.1039/D3EN00554B, Paper
Tahereh Nasiriani, Neda Adabi Nigjeh, Ahmad Shaabani
This study deals with the synthesis of a core–shell magnetic zinc-based molecularly imprinted polymer (M-Zn-MIP) as a robust heterogeneous catalytic nanoreactor. The catalytic activity of the M-Zn-MIP was explored in the CO2 fixation reaction.
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Utilization of lead-based saturated adsorbents for the fabrication of battery-like hybrid asymmetric supercapacitors

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Environ. Sci.: Nano, 2024, 11,1654-1670
DOI: 10.1039/D3EN00601H, Paper
Sourav Acharya, Shrabani De, Ayon Ganguly, Brijesh K. Mishra, Ganesh Chandra Nayak
In this study S-doped graphitic CN/ZIF-8 composite was fabricated to remove Pb from water which was anchored through heat treatment. This formed a composite of carbon, Zn-NCN, PbO and PbS and was used as supercapacitor anode.
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The effects of CdSe/ZnS quantum dots on autofluorescence properties and growth of algae Desmodesmus communis: dependence on cultivation medium

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Environ. Sci.: Nano, 2024, 11,1701-1712
DOI: 10.1039/D3EN00955F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Agnė Kalnaitytė-Vengelienė, Danguolė Montvydienė, Emilija Januškaitė, Živilė Jurgelėnė, Mindaugas Kazlauskas, Nijolė Kazlauskienė, Saulius Bagdonas
The cultivation media markedly influence the quantum dot induced effects on photosynthesis properties and growth of green freshwater microalgae.
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Rational construction of micro-plate-like iron oxide/aluminium oxide-fabricated screen-printed carbon electrode for the electrochemical detection of the antiandrogen drug

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Environ. Sci.: Nano, 2024, 11,1521-1532
DOI: 10.1039/D3EN00808H, Paper
Sivakumar Musuvadhi Babulal, Nandini Nataraj, Tse-Wei Chen, Shen Ming Chen, Bih-Show Lou, Arshad Mehmood Abbasi, Amal M. Al-Mohaimeed, Mohamed Soliman Elshikh, Jaysan Yu
An improved electrochemical sensing platform with a vital strategy for NTM antiandrogen drug detection in real environmental and biofluid samples.
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2023 Outstanding Papers published in the Environmental Science journals of the Royal Society of Chemistry

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Environ. Sci.: Nano, 2024, 11,1329-1331
DOI: 10.1039/D4EN90012J, Editorial
Zongwei Cai, Neil Donahue, Graham Gagnon, Kevin C. Jones, Célia Manaia, Elsie Sunderland, Peter J. Vikesland
The Editors-in-Chief of the Environmental Science journals introduce the Outstanding Papers of 2023.
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Magnetic and structural characteristics associated with the transformation of As(V)-coprecipitated ferrihydrite to hematite: implications for magnetic enhancement in soils and sediments

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00739A, Paper
Guoqing Zhang, Yixuan Tang, Jinru Lin, Jiaxing Xu, Zidan Yuan, Lingyun Chen, Fei Wu, Chengshuai Liu, Zongmin Zhu, Xiangyang Bi, Wei Zou, Zhiguo Cao, Kai Jiang, Yuanming Pan, Roman Chernikov, Yongfeng Jia, Shaofeng Wang
The transformation of metastable ferrihydrite to stable hematite has been linked to magnetic enhancement in soils and sediments.
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Mining, refining, and QSAR analysing the nanoinformatics in EPA NaKnowBase

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00619K, Paper
Paul Harten, Henry Helgen, Wilson Melendez, Bradley Beach, William K. Boyes, Iason Sotiropoulos, Pantelis Karatzas, Haralambos Sarimveis, Holly M. Mortensen
The EPA nanoQSAR model predicts the impacts of in vitro cell viability following exposure to certain nanomaterials.
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Functional silver-based nanomaterials affecting zebrafish development: the adverse outcomes in relation to the nanoparticle physical and chemical structure

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Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00813D, Paper
Open Access
Patrizia Bonfanti, Anita Colombo, Rossella Daniela Bengalli, Maurizio Gualtieri, Ilaria Zanoni, Magda Blosi, Anna Costa, Paride Mantecca
The growing demand for effective antimicrobials determined a significant increase of new nanoformulated materials to fight against bacteria and viruses, to be used in many industrial sectors including textiles, cosmetics,...
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Crystallinity regulation induced organics degradation on Ultra-thin 2D Co3O4/SiO2 Nanosheets: the critical trigger of oxygen vacancy

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Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D4EN00134F, Paper
Wenhui Bai, Hongze Lu, Yang Liu, Xue Yuan, Yuejie Ai, Lidong Wang, Zhe Chen
As an antibiotic drug, sulfamethoxazole (SMX) is a nitrogen-containing and sulfur-containing heterocyclic compound, which is an endocrine disruptor and difficult to be biodegraded. Not only can it exist stably in...
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Anatase TiO2 nanomaterials are much more effective in enhancing hydrolysis of organophosphorus compounds than their rutile counterparts

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00138A, Paper
Tong Li, Yiting Ju, Tingting Du, Chuanjia Jiang, Tong Zhang, Wei Chen
The crystalline phase significantly affects the efficiency of TiO2 nanomaterials in catalyzing hydrolysis reactions of organophosphates, primarily by modulating the surface Lewis acidity of TiO2.
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Co-transport of polybromodiphenyl ethers and soil nanoparticles in saturated porous media: implications for the risks of polybromodiphenyl ether spreading in groundwater

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00086B, Paper
Jiameng Liu, Tianchi Cao, Lin Duan, Shengkai Xu, Min Li, Tong Zhang, Wei Chen
This study demonstrates that PBDEs attached to soil nanoparticles can be highly mobile in saturated porous media, providing important insights on risk assessment of PBDEs contamination.
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Consequences of twisting of the flexible arms of imidazole-derived urea in zinc-dicarboxylate coordination polymers

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CrystEngComm, 2024, 26,1976-1985
DOI: 10.1039/D4CE00005F, Paper
Satyendra Verma, Rinki Brahma, Jubaraj B. Baruah
A semi-flexible imidazole-based urea ligand, 1-(3-(1H-imidazol-1-yl)propyl)-3-phenylurea, and three zinc-dicarboxylate coordination polymers possessing the ligand were synthesized and characterized.
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A facile synthesis of a Ce-based MOF at room temperature for effective adsorption of methylene blue

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CrystEngComm, 2024, 26,2009-2017
DOI: 10.1039/D4CE00096J, Paper
Yang Zhou, Dan Wang, Qiuxiang Feng, Qi Wu, Feng Cao, Li Jiang, Qianli Zhang, Jie Liu
Ce-UiO-66-NH2 was synthesized in water and ethanol at room temperature for effective removal of MB in aqueous solution.
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Rock-salt Ti1−xO → rutile TiO2−x transformation twinning via pulsed laser deposition – implications for the dense (hkl)-specific phase change and optoelectronic properties

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CrystEngComm, 2024, 26,1926-1939
DOI: 10.1039/D3CE01091K, Paper
Chang-Ning Huang, Jian-Yu Chen, Yu-Xuan Lin, Pouyan Shen
The R + r intimate intergrowth was found to form a butterfly twin following the optimum crystallographic orientation relationship [101]R//[11̄]r by the close-packed (̄11)R and (011)r planes as the twin boundary and phase interface, respectively.
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Effects of nucleating agents on the II–I transition of iPB-1

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CrystEngComm, 2024, 26,1940-1951
DOI: 10.1039/D3CE01303K, Paper
Zhiqi Li, Jingqing Li, Shichun Jiang
For iPB-1, II–I transition is of industrial importance; whereas, the traditional solid–solid II–I transition mechanism encountered challenges. It is form I formation in amorphous phase that triggers II-I transition with crystal reorganizations.
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“Feather-duster” like ZnIn2S4/TiO2 heterostructured nanocomposites with enhanced visible-light photocatalytic performance

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CrystEngComm, 2024, 26,2025-2032
DOI: 10.1039/D3CE01239E, Paper
Wenjie Liu, Lei Li, Jingru Li, Fang Wang, Chun-Shuai Cao, Jianzhou Gui, Alex T. Kuvarega, Bhekie B. Mamba, Dan Liu
The ZnIn2S4/TiO2 heterostructures show an increased surface area and strengthened interface contacts, facilitating efficient photogenerated carrier separation and leading to high photocatalytic performance under visible light irradiation.
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Synthesis, structure, and properties of helical bis-Zn(II) complexes of hexapyrrolic ligands

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00019F, Paper
Pinky Chauhan, Poornenth Pushpanandan, Mangalampalli Ravikanth
Bis(3-pyrrolyl BODIPY)s were used to prepare rare examples of hexapyrrolic ligands by demasking BF2 units. The hexapyrrolic ligands, without isolating, were used to prepare novel examples of double-stranded bis-Zn(II) helicate complexes.
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Modulating the active phase in perovskite LaCoO3 with B-site doping of Cu for efficient methanol reforming to produce hydrogen

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01268A, Paper
Weiling Zhang, Peiwei Han, Juan Li, Zizhen Niu, Guowei Wang, Nan Wang, Xiangnan Li, Lyumeng Ye, Xinjun Li
The structure transformation of Cu+–Ov–Co2+ and Cu2+–O–Co3+ on the efficient MSR reaction.
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Thermal fluctuation-induced selective CO2 uptake of seemingly nonporous N,C-protected dipeptide crystals as elucidated by in situ X-ray crystallographic analysis

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01018J, Paper
Kazuaki Yamanaka, Ryusei Oketani, Yuya Mori, Takashi Sato, Seiji Tsuzuki, Hiroki Takahashi, Hirohito Tsue
A novel N,C-protected dipeptide deposited nonporous but yet CO2-sorbing molecular crystals, of which the CO2 sorption state was disclosed.
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Synthesis and luminescent properties of three excellent yellow emissive Cu(I) complexes based on the diphosphine ligand and the diimine ligand

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00206G, Paper
Wen-Long Mou, Cheng-Jie Gao, Zi-Xi Li, Si-Jie Fan, Chuan-Bin Hou, Jing-Tong Zhao, Shuai Zhang, Zhong-Feng Li, Hong-Liang Han, Chun-Bo Duan, Guo Wang, Qiong-Hua Jin
High quantum yield (72–88%) yellow-emitting Cu(I) complexes obtained by tuning the nitrogen ligands and anions.
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Assessing aspects of solution-based chemical synthesis to convert waste Si solar cells into nanostructured aluminosilicate crystals

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00038B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Edita Garskaite, Math Bollen, Enock Mulenga, Mathis Warlo, Glenn Bark, Espen Olsen, Dalia Brazinskiene, Denis Sokol, Dietrich Buck, Dick Sandberg
An affordable, scalable, and easily adoptable solution-based processing route provides a potential way of converting waste Si solar cells into aluminosilicate minerals to contribute to sustainability in the solar energy value chain.
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Extended isomerism in heteronuclear metal-organic frameworks: synthetic strategies and crystal structures of lanthanide-cobalt-oxydiacetate systems

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00168K, Paper
Fernando Igoa, Agustín López Cabrera, Javier Gonzalez-Platas, Leopoldo Suescun, Carlos Kremer, Julia Torres
Here, we present the synthesis and crystal structure of a series of heteronuclear metal-organic frameworks, which consists of cobalt(II) and lanthanide(III) ions or yttrium(III), connected by oxydiacetato (oda2-) as ligand....
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New 8-hydroxy quinoline-polycyclic aromatic hydrocarbon (PAH) conjugates and their sulfonated derivatives: effects of sulfonation and PAH size on their structural, supramolecular and cytotoxic properties

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00105B, Paper
Suman Sehlangia, Surbhi Dogra, Prosenjit Mondal, Chullikkattil P. Pradeep
The ring size of polycyclic aromatic hydrocarbons (PAHs) and sulfonation affect the supramolecular interactions and cytotoxic properties of a new series of 8-hydroxy quinoline-PAH conjugates.
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Enantioselective enrichment of chiral 1-phenylethanol in the camphor-based chiral metal–organic framework CFA-22

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CrystEngComm, 2024, 26,2051-2055
DOI: 10.1039/D4CE00181H, Communication
Richard Röβ-Ohlenroth, Katharina Knippen, Maryana Kraft, Dirk Volkmer
The novel enantioselective CFA-22 metal–organic frameworks were successfully developed and investigated for chiral adsorption separation of e.g. racemic 1-phenylethanol.
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Using the nature of the achiral solvent to orient chiral resolution

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CrystEngComm, 2024, 26,2056-2059
DOI: 10.1039/D4CE00124A, Communication
Joséphine de Meester, Oleksii Shemchuk, Laurent Collard, Johan Wouters, Simon Baillieux, Koen Robeyns, Tom Leyssens
Both (R)- and (S)-Binol can be resolved from a racemic mixture using the same (R,R)-diamine resolving agent, merely adapting the nature of the solvent. This peculiarity is explained by the existence of both a diastereomeric as well as enantiospecific solvate cocrystal system.
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The structural evolution of CL-20-based energetic host–guest solvates at decomposition temperature according to the perceptions of THz spectroscopy

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01310C, Paper
Lu Shi, XiaoHui Duan, Hongzhen Li
This work employed variable-temperature THz spectroscopy to analyze the structural evolution of host–guest energetic CL-20/H2O2 and CL-20/H2O solvates, as well as the mechanism of intermolecular interactions using DFT calculation and MD simulation.
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Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic(V)-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper
Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
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AlN interlayer-induced reduction of dislocation density in the AlGaN epilayer

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00191E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David Maria Tobaldi, Luc Lajaunie, Arianna Cretì, Massimo Cuscunà, Iolena Tarantini, Marco Esposito, Gianluca Balestra, Mauro Lomascolo, Adriana Passaseo, Vittorianna Tasco
The emerging ultrawide-bandgap AlGaN alloy system holds promise for the development of advanced materials in the next generation of power semiconductor and UV optoelectronic devices. Within this context, heterostructures based...
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Local concentration controls the hydrate phase of calcium oxalate

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01286G, Paper
Zhaodong Wang, Lala Du, Qihang Wang, Jingjing Xie, Zhengyi Fu, Zhaoyong Zou
The calcium oxalate phase selection in supersaturated solution is determined by a combination of thermodynamic and kinetic factors.
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Highly enhanced cationic dye adsorption from water by nitro-functionalized Zn-MOF nano/microparticles and a biomolecular binder for improving the reusability

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00131A, Paper
Gunasekaran Arunkumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Savarimuthu Philip Anthony
Zn-MOF with a nitro-functionalized ligand exhibited enhanced cationic dye adsorption, and binder coating improved the reusability.
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3-(3,5-Dinitrophenyl)-5-amino-1,2,4-oxadiazole: synthesis, structure and properties of a novel insensitive energetic material

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00201F, Paper
Binshan Zhao, Baolong Kuang, Mou Sun, Tingwei Wang, Chao Zhang, Meiqi Xu, Cong Li, Zujia Lu, Jian-guo Zhang
A novel heat-resistant energetic compound 3-(3,5-dinitrophenyl)-5-amino-1,2,4-oxadiazole with low mechanical sensitivity on the basis of combining dinitrobenzene and aminooxadiazole was synthesized through a simple method in this work.
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Nitro group and K+-based secondary building units for the self-assembly of 3D coordination polymers built on dinuclear dianionic helicate connectors

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00255E, Paper
Open Access
Raúl Mendoza-Báez, Alan Molina-Renteria, Juan Olguín
Two dinuclear dianionic helicates, K2[MII2(L)3] M = MnII (1) and NiII (2), based on 2-hydroxy-5-nitrobenzaldehyde, self-assemble into novel 3D coordination polymers due to nitro groups acting as secondary assembly instruction.
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Synthesis and structural trends in a series of simple tetraalkylphosphonium salts

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00210E, Paper
Jakub Gawraczynski, Piotr J Leszczynski, Michal Ksawery Cyranski, Łukasz Dobrzycki, Wiktor Koźmiński, Karol J. Fijalkowski, Wojciech Grochala, Tomasz Jaroń
A series of sulfates (S) and hydrogen sulfates (HS) containing tetramethylphosphonium (TMP), tetraethylphosphonium (TEP) and tetrabutylphosphonium (TBP) cations have been prepared from the respective bromides using ion metathesis reactions. The...
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Synthesis and photophysical properties of charge transfer cocrystals based on TCNB and fluorene and its derivatives

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CrystEngComm, 2024, 26,2155-2165
DOI: 10.1039/D3CE01208E, Paper
Wenxiu Yao, Pengfei Wu, Yidan Xie, Xinyu Shen, Shuwei Xia, Liangmin Yu
A series of charge transfer cocrystals with fluorescence properties involving 1,2,4,5-tetracyanobenzene as acceptor, fluorene, 2-bromofluorene, carbazole and 2-bromocarbazole as donor were synthesized via cocrystal design strategies.
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Facile syntheses, structures and photocatalytic properties of 3D iodoargentate frameworks derived from TM-flexible-amino-ligand templates

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CrystEngComm, 2024, 26,2172-2179
DOI: 10.1039/D4CE00247D, Paper
Yan Gao, Xiao Yang, Taohong Ren, Dingxian Jia
3D iodoargentates [Co(en)3(Ag2I4)]n (1), [Fe(en)3(Ag2I4)]n (2) and [Co(dien)2(Ag2I4)]n·nH2O (3) were prepared by solvothermal methods. Compounds 1–3 were catalytic activity for photodegradation of crystal violet under visible light irradiation.
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The development of an approach for the precision determination of thermal strain tensor elements for single crystals using the example of t-Ag0.8Li0.2InSe2

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CrystEngComm, 2024, 26,2207-2218
DOI: 10.1039/D3CE01186K, Paper
Polina S. Serebrennikova, Sergey I. Lobanov, Alexander S. Sukhikh, Lyudmila I. Isaenko, Sergey A. Gromilov
A new approach to the precision determination of single-crystal unit cell parameters is proposed and demonstrated using tetragonal Ag0.8Li0.2InSe2.
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