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Harnessing nanoscale spatial effects in inner-modified zeolitic imidazolate framework-8 for enhanced Knoevenagel condensation reaction

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02190D, Research Article
Semi Kim, Seojeong Woo, Cheongwon Bae, Yuri Jeon, Yeeun Seong, Song Li, Juyeong Kim
Precise carving of ZIF nanocrystals generates heterogeneous internal mesoporosity, providing effective mass transport and uncoordinated active sites for enhanced heterogeneous catalysis.
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Sodium ion pre-intercalation regulates the electron density and structural stability of vanadium oxide nanowires for Ca–ion batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00218K, Research Article
Huajie Feng, Yize Wang, Wenda Qiu, Zixi Liu, Yaping Tao, Xihong Lu
Benefiting from the abundant resource, low cost, and high operating potential, calcium–ion batteries (CIBs) have attracted great attention as emerging energy storage devices over lithium-based systems.
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Tailoring two magic number Au13 nanoclusters with N-containing diphosphine ligands: a classical icosahedral core vs. an unprecedented UFO- shaped core

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00334A, Research Article
Jing Liu, Jia-Chuan Liu, Hai-Ling Wang, Pei-Yu Liao, Jian-Hua Jia, Ming-Liang Tong
Two magic number Au13 nanoclusters were tailored using two N-containing multidentate phosphine ligands with a classical icosahedral core and an unprecedented “UFO”-shaped polyhedral core, respectively.
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Adhesion, stability, structural and electronic properties of perovskite/BaWO4 heterostructures: first-principles and experimental characterizations

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00231H, Research Article
Yao Guo, Shiding Zhang, Zhaoyu Zhang, Yuanbin Xue, Jianxin Li, Haixiang Song, Yuhua Wang, Qing Shen
The interfacial behavior and mechanism of the CsPbBr3/BaWO4 and MAPbBr3/BaWO4 heterostructures have been extensively investigated by a combined first-principles and experimental analysis.
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Pb3.5GeS4Br3: the first phase-matching thiogermanate halide infrared nonlinear optical material

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00293H, Research Article
Jiazheng Zhou, Hongshan Wang, Junjie Liu, Xin Su, Yu Chu, Jiale Qu, Xiangzhan Jiang
Pb3.5GeS4Br3 is the first phase-matching thiogermanate halide infrared nonlinear optical material.
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Modulating Mn self-reduction and multimodal luminescence in CaSb2O6 through La3+ doping for quadruple-mode dynamic anti-counterfeiting and optical temperature sensing applications

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00493K, Research Article
Fenzhong Long, Lu Xie, Jiawei Fu, Kaian Shan, Huihui Fei, Xinmin Zhang
The co-doping La3+strategy was employed to modulate Mn self-reduction and multimodal luminescence in CaS2O6:Mn. CaS2O6:Mn has potential application in optical anti-counterfeiting and high-sensitivity temperature sensing applications.
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Rational design for broad near-infrared emission from a two-sited Rb2LiAlF6:Cr3+ phosphor with high efficiency and thermal stability for spectroscopic applications

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00429A, Research Article
Song Qing, Jing Wan, Tao Yang, Qiang Zhou, Yayun Zhou, Zhengliang Wang, Dawei Wen, Mingmei Wu
A comparative investigation of broadband near-infrared luminescence from two different occupation sites in Rb2LiAlF6:Cr3+ with high efficiency and excellent thermal stability.
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Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00254G, Research Article
Yan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng Yang
An adjustable template effect was employed to activate the evolution of polyoxovanadate-based metal–organic clusters, resulting in unprecedented structural archetypes as well as customized dye and iodine adsorption features.
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Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00462K, Research Article
Chun-Li Hu, Qian-Qian Chen, Fang Kong, Jiang-Gao Mao
The long-neglected stereochemically active lone pair groups ClO3 and BrO3 are demonstrated to be important UV NLO functional motifs based on the fact that AClO3 and ABrO3 possess high SHG effects and short λPM and are promising UV NLO materials.
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Yellow-Emissive Organic Copper(I) Halide Single Crystals with [Cu4I4] Cubane Unit as Efficient X-ray Scintillators

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00500G, Research Article
Qingzheng Kong, Xiaomei Jiang, Ying Sun, Jianguo Zhu, Xutang Tao
Recently, low-dimensional copper(I)-based halide is considered as a potential substitute for lead-based counterpart due to its environmental friendliness, facile preparation and superior luminescence performances. In particular, as a representative of...
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Efficient doped and non-doped light-emitting diodes based on a TADF-emitting Cu4Br4 cluster

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00210E, Research Article
Xin Lu, Shao-Jie Wu, Ya-Shu Wang, Shan-Yue Wei, Lingyi Meng, Xi-He Huang, Xu-Lin Chen, Can-Zhong Lu
A sublimable Cu4Br4 cluster, chelated by bidentate N^P ligands with a donor–acceptor configuration, realizes highly efficient doped and non-doped cluster light-emitting diodes.
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Solvent-modulated assembly of peptide and cerium functionalized gigantic {Mo120Ce6}2 dimers for high-efficiency photocatalytic oxidation

Inorg. Chem. Front., 2024, 11,2355-2364
DOI: 10.1039/D4QI00339J, Research Article
Dexiang Zhou, Bingbing Li, Qixin Zhao, Xinyu Tang, Tingya Lan, Heyang Su, Guoping Yang, Weimin Xuan
Two gigantic peptide and cerium functionalized {Mo120Ce6}2 dimers have been constructed via a solvent-modulated assembly and applied for effective photocatalytic aerobic oxidation of sulfides to sulfoxides.
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Regulation of polyaniline thickness and substitution position on Cu foams to optimize hydrogen evolution and ethanol oxidation performance

Inorg. Chem. Front., 2024, 11,2373-2383
DOI: 10.1039/D4QI00085D, Research Article
Haiqiang Mu, Pengyue Shan, Min Zhu, Zhenli Lv, Guorui Ma, Jiaxing Guo, Junzhuo Fang, Jin Zhang, Feng Li, Jing Li
The Cu foam decorated with integrated polyaniline (PANI/CF-210) based on direct electro-grafting technique has been successfully designed to develop for efficient hydrogen evolution and ethanol oxidation reaction.
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Deciphering the active species and reaction mechanism in water oxidation catalyzed by a copper complex with redox-active ligands

Inorg. Chem. Front., 2024, 11,2365-2372
DOI: 10.1039/D4QI00163J, Research Article
Qing Fan, Cong Yang, Mengdi Li, Chen Wang, Guixia Wang, Xiangfei Kong, Qiping Zhu
This theoretical study unveils active species and the reaction mechanism in electrochemical water oxidation catalyzed by a copper complex with redox-active ligands.
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Boosting structural variety and catalytic activity of porphyrinic metal–organic frameworks by harnessing bifunctional ligands

Inorg. Chem. Front., 2024, 11,2281-2289
DOI: 10.1039/D4QI00314D, Research Article
Wei Wu, Xiu-Liang Lv, Tao He, Guang-Rui Si, Hongliang Huang, Lin-Hua Xie, Yabo Xie, Jian-Rong Li
High catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.
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Achieving a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets by hydroiodic acid-assisted ligand treatment

Inorg. Chem. Front., 2024, 11,2392-2401
DOI: 10.1039/D4QI00168K, Research Article
Zongnan Li, Yusheng Song, Sheng Cao, Ke Xing, Zhentao Du, Bingsuo Zou, Jialong Zhao
We demonstrate a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets achieved through a hydroiodic acid-assisted ligand treatment strategy, showcasing their application in perovskite LEDs.
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Enhancing the separation of C2H4/C2H6 in customized MOR zeolites

Inorg. Chem. Front., 2024, 11,2427-2435
DOI: 10.1039/D4QI00236A, Research Article
Hongwei Chen, Binyu Wang, Bin Zhang, Yongheng Ren, Jiuhong Chen, Jiabao Gui, Xiufeng Shi, Wenfu Yan, Jinping Li, Libo Li
MOR zeolites synthesized with cost-effective, non-toxic materials enhance ethylene separation without Ag or Cu modification. The customized framework composition improves adsorptive properties economically.
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Selective syntheses of homoleptic Ir(III) complexes bearing di-CF3-functionalized benzoimidazol-2-ylidenes for generation of blue phosphorescence

Inorg. Chem. Front., 2024, 11,2413-2426
DOI: 10.1039/D4QI00454J, Research Article
Open Access
Jie Yan, Yi Pan, I-Che Peng, Wen-Yi Hung, Bingjie Hu, Guowei Ni, Shek-Man Yiu, Yun Chi, Kai Chung Lau
Di-CF3-functionalized benzo[d]imidazol-3-ium pro-chelates were employed in the selective syntheses of fac-coordinated Ir(III) carbene emitters for efficient blue electroluminescence and hyperphosphorescence.
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Electrochemical conversion of 5-hydroxymethylfurfural over CuNi bimetallic catalysts: the synergistic effect of interfacial active sites

Inorg. Chem. Front., 2024, 11,2479-2488
DOI: 10.1039/D4QI00145A, Research Article
Yiwei Zhao, Chao Zhang, Shuangxi Xing, Zuhang Jin, Tingting Xiao
ECO of HMF to FDCA and ECR to BHMF with high yield have been studied on CuNi-based bimetallic catalysts. The presence of the Cu–O–Ni interfacial area was beneficial for promoting the catalytic performance in ECO.
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sp2–sp cross-carbanion coupling at a rare-earth center leading to the formation of carbon–carbon double bonds

Inorg. Chem. Front., 2024, 11,2312-2318
DOI: 10.1039/D4QI00178H, Research Article
Zhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, Wen-Xiong Zhang
The reaction of rare-earth azametallacyclopentadienes with terminal alkynes provides rare-earth metallacycles with cumulated double bonds in three steps: alkynyl C–H bond activation, sp2–sp cross-carbanion coupling and subsequent isomerization.
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N-heterocyclic carbene-stabilized Cu9 clusters with combined thermally activated delayed fluorescence and phosphorescence

Inorg. Chem. Front., 2024, 11,2498-2507
DOI: 10.1039/D4QI00160E, Research Article
Lin-Mei Zhang, Mo Xie, Hui-Zhi Wei, Shang-Fu Yuan, Dong-Sheng Li, Tao Wu
Two NHC-stabilized Cu9 clusters showcase both TADF and direct phosphorescence in thermal equilibrium. The combined harvesting mechanism arises from the simultaneous presence of a small ΔE(S1 − T1) gap and relatively strong spin–orbit coupling.
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Nanocarbon armor reinforced Ag particles to build a high-rate and long-lifespan aqueous Zn2+/Cl− dual-ion battery

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00499J, Research Article
Wenbo Guo, Tianyuan Zhang, Guangchang Shu, Leiyu Fan, Zhouxiang Wu, Lei Yan, Liyuan Zhang, Haoxiang Yu, Ting-Feng Yi, Jie Shu
A high-performance aqueous Zn2+/Cl dual-ion battery is built by using nanocarbon armor reinforced Ag particles as the cathode, metallic Zn as the anode and ZnCl2 as the electrolyte.
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CDs "inserted" abundant FeB based electrode via "local photothermal effect" strategy toward efficient overall seawater splitting

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00415A, Research Article
Shiheng Liang, Liugang Wu, Yiming Wang, Yuqi Shao, Hongyuan Song, Ziliang Chen, Weiju Hao
Construction of high-efficiency, long-stable catalytic electrodes for hydrogen by seawater splitting is a huge challenge in the field of green hydrogen. Herein, a matrix-type titanium dioxide nanorod (Ti/TiO2) is constructed...
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A wheel-like polyoxometalate for haloperoxidase inspired antibiofouling with H2O2 in-situ provided by electrocatalysis

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00482E, Research Article
Yumeng Bian, Runze Wang, xinxin xu, Jin Chen, Qiang Wang
Biofouling is adhering of micro-organisms on submerged surfaces, which is a common phenomenon presents serious hazard to industry and public health. Nanozymes with haloperoxidase mimic activity are promising options to...
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Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt(IV) prodrugs for cancer treatment

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00386A, Research Article
Peng Sun, Jia-Qian Wang, Qiang Xie, Xuan-Lin Ren, Xin Qiao, Jing-Yuan Xu
Two multifunctional fibrate-Pt(IV) prodrugs, 1 and 3, bearing lipid-modulating agents, exhibited impressive anticancer activity by triggering ferroptosis and apoptosis.
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Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00200H, Research Article
Yong-Sheng Shi, Tong Xiao, Dong-Dong Yang, Xiangjun Zheng
A viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....
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An unprecedented {Y2 ⊂ Y10} type disk-like Y12 nanocluster featuring electroluminescence property in OLED device

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00635F, Research Article
Lin-Ping Shi, Wen-Liang Li, Pu-Yue Wang, Xiaoming Wu, Zhao-Quan Yao, Jiong-Peng Zhao, Fuchen Liu
Although great efforts have been made in exploring the exquisite rare-earth (RE) clusters, the design and construction of planar RE-clusters with disk-like geometrical features are still scarce. Herein, a novel...
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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
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Unleashing the power of directed electron transfer: unraveling the potential of {PV4}2 in heterogeneous photocatalysis

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00606B, Research Article
Xin Su, Yuzan He, Kunhong Li, Miao Wang, Wei Tang, Shihao Zhang, Pengtao Ma, Jingyang Niu, Jingping Wang
{PV4}2 unleash the power of directed electron transfer in heterogeneous photocatalysis reduction.
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Application of changing the valence state of metals through the reaction time for efficient oxygen evolution reaction

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00522H, Research Article
Ming Chen, Sha Luo, Zongyan Ma, Fei Yuan, Jing Chen, Linkun Dong, Weiwen Mao, Jiantai Ma
In this study, a novel FeNi sulfide catalyst loaded on carbon nanotubes (CNTs) (FeNiS/CNTs) shows excellent OER electrocatalytic performance in alkaline solutions.
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Tuning lithium–yttrium chloride local structure through coordination control and mixing during synthesis

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00559G, Research Article
Open Access
Teerth Brahmbhatt, Cheng Li, Mounesha N. Garaga, Wan-Yu Tsai, Steve G. Greenbaum, Jagjit Nanda, Robert L. Sacci
Synthesis of Li3YCl6 is facilitated by the addition of NH4Cl. Synthesis method affects local ordering and Li+ dynamics as determined by neutron diffraction, impedance and NMR spectroscopy.
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SEBI explores feasibility of introducing crude oil ETFs

Such ETFs own futures contracts on crude oil instead of the commodity itself. The ETF price will mimic the spot price.




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Optimism in global commodities market over Chinese measures may be short-lived, say analysts

Subdued demand, struggling property sector may exert downward pressure on metals




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Crude oil futures rise amid declining US inventories

December Brent oil futures rose to $74.37, while November WTI futures climbed to $70.59.




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Crude oil futures rise as US inventories decline 

Market players are also assessing the supply risks from West Asia following the tensions in the region




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Spinning mills in Gujarat, N. India seek quality cotton from Raichur region

Ongoing rains raise concern over quality, crop size across key producing regions




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Nickel prices likely to be under pressure on market surplus

Analysts peg its average price for 2024 at around $17,000/tonne




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Crude oil futures slip as industry data shows increase in US inventory 

US crude oil inventories rose by 1.64 million barrels for the week ended October 18. Market estimates had earlier pegged increase at 0.7 million barrels




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India defers plan to hike minimum selling price of sugar, for now

The agri costs panel had recommended regular revision of the minimum price




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India’s diesel consumption likely to surpass 93 mt in FY25

Both August and September this year have witnessed a fall in diesel usage




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Board to convene consumers meeting next week over falling natural rubber prices

Rubber Board officials said prices exceeded Rs₹200 on June 11 but plummeted 24 per cent to ₹187 per kg by October 21. The Board may ask consumers to proactively purchase in the domestic market




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Oil prices likely to fall after Israel shows restraint in strikes on Iran

Scores of Israeli jets completed three waves of strikes before dawn on Saturday against missile factories and other sites near Tehran and in western Iran, in the latest exchange in the escalating conflict between the Middle East rivals




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Crude oil futures dip after Israeli attack avoids Iranian oil facilities 

November natural gas futures were trading at ₹254.50 on MCX during the initial hour of trading on Monday against the previous close of ₹258.20, down by 1.43 per cent




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Why drugmakers are dialing C for current good manufacturing practices

For the industry under scrutiny over quality concerns, cGMP requires immediate attention




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Calisthenics, rock-climbing and laughter




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COPing with cascading health concerns that climate change brings to our doorstep

Climate and Health: A global challenge needs a local solution to build resilient health systems




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Drugmakers chart a specialised course to navigate choppy waters

India’s pharma industry is moving from volume to value, investing in quality manufacturing 




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A pitch to walk the fine line between innovation and access

 Ahead of USTR’s Special 301 report, India campaigns for flexibilities in international trade laws




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A decade of triumph: Polio-free India

This year marks a decade of a polio-free India — one of the country’s most profound public health achievements to date.