ical Magneto-optical properties of heavily Fe-doped GaAs: a density functional approach By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27510-27518DOI: 10.1039/D4CP03101F, PaperJ. Zarpellon, D. H. Mosca, J. VaraldaHeavily Fe-doped GaAs, investigated using a DFT approach, reveals a spin polarized electronic band structure correlated with magnetic circular dichroism and complex Kerr and Faraday rotation angles in agreement with some previous experiments.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Comparing coupled cluster and composite quantum chemical methods for computing activation energies and reaction enthalpies of radical propagation reactions By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27536-27543DOI: 10.1039/D4CP03676J, PaperTimothy B. Huber, Ralph A. WheelerThe accuracy of DLPNO-CCSD(T)/CBS and composite methods G3(MP2)-RAD and CBS-RAD is assessed against CCSD(T)/aug-cc-pVTZ for activation energies and reaction enthalpies in hydrocarbon radical addition reactions relevant to free radical polymerization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical An in-depth investigation of lead-free KGeCl3 perovskite solar cells employing optoelectronic, thermomechanical, and photovoltaic properties: DFT and SCAPS-1D frameworks By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27704-27734DOI: 10.1039/D4CP02974G, PaperMd. Tarekuzzaman, Mohammad Hasin Ishraq, Md. Shahazan Parves, M. A. Rayhan, Sohail Ahmad, Md. Rasheduzzaman, K A Al Mamun, M. Moazzam Hossen, Md. Zahid HasanCrystal structure of KGeCl3 and the design configuration of the KGeCl3-based PSC.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Electrochemical system of nitrogen-doped TiO2, Fe–N–C, and copper hexacyanoferrate electrodes for photo-assisted energy conversion in acidic wastewater treatment By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27498-27509DOI: 10.1039/D4CP02063D, PaperBianca Tainá Ferreira, Matheus Martins, Fritz HugueninThis study examines the electrochemical performance of nitrogen-doped TiO2, Fe–N–C, and CuHCF electrodes for energy conversion in acidic solution neutralization, capturing 62.9 kJ per mole of protons.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Experimental and theoretical study of the Sn–O bond formation between atomic tin and molecular oxygen By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27763-27771DOI: 10.1039/D4CP03687E, PaperIakov A. Medvedkov, Anatoliy A. Nikolayev, Shane J. Goettl, Zhenghai Yang, Alexander M. Mebel, Ralf I. KaiserIn this article, we combine state-of-art electronic structure calculations and crossed beam experiments to expose the reaction dynamics of 120Sn(3Pj) + 16O2(X3Σ−g) → 120Sn16O(X1Σ+) + 16O(3P) reaction that involve extensive ISC.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Fundamental basis of mechanochemical reactivity By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27245-27247DOI: 10.1039/D4CP90153C, EditorialAdam A. L. Michalchuk, Francesco DeloguThis themed collection includes a collection of articles on the fundamental basis of mechanochemical reactivity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Theoretical insight into photodeactivation mechanisms of adenine–uracil and adenine–thymine nucleobase pairs By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27807-27816DOI: 10.1039/D4CP02817A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kinga Szkaradek, Robert W. GóraAb initio calculations elucidate plausible intramolecular photoinduced relaxation pathways involving ring puckering and an efficient intersystem crossing in A–U and A–T base pairs, potentially hindering electron-driven proton transfer detection.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Hydrogen tunneling with an atypically small KIE measured in the mediated decomposition of the Co(CH3COOH)+ complex By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27741-27750DOI: 10.1039/D4CP02722A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Simon U. Okafor, Gabriele Pinto, Michael Brdecka, William Smith, Tucker W. R. Lewis, Michael Gutierrez, Darrin J. BellertRate-limiting hydrogen/deuterium tunneling rate constants are measured in the photon initiated decay of Co(CH3COOH)+ with small KIE values.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Insights of the peroxychloroformyl radical ClC(O)OO via microwave spectrum By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27669-27676DOI: 10.1039/D4CP03506B, PaperChing-Hua Chang, Wen Chao, Cheng-Han Tsai, Mitchio Okumura, Frank A. F. Winiberg, Yasuki EndoPure rotational spectra of trans-ClC(O)O2 (left) and cis-ClC(O)O2 (right), and the potential energy curve connecting the two conformers. The energy diagram and the observed transitions for the trans-ClC(O)O2 are also shown.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Strategy for predicting catalytic activity of catalysts with hierarchical nanostructures By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27371-27381DOI: 10.1039/D4CP03102D, PaperZidi Zhu, Daoming Huan, Jingchao Yuan, Dan Zhang, Aijun Li, Jiujun ZhangThis study constructs a multiphysics model that successfully replicates experimental results, introducing an improved Thiele modulus to enhance the prediction of catalytic activity in hierarchical nanostructured SOFC electrodes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Dynamics of ionic liquids by means of nuclear magnetic resonance relaxation – overview of theoretical approaches By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27248-27259DOI: 10.1039/D4CP03183K, Review ArticleDanuta Kruk, Elzbieta Masiewicz, Roksana Markiewicz, Rajendra Kumar SinghNuclear magnetic resonance relaxometry probes the translational and rotational dynamics of ionic liquids. To take advantage of this unique experimental potential, appropriate theoretical models are needed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical A theoretical investigation on the OER and ORR activity of graphene-based TM–N3 and TM–N2X (X = B, C, O, P) single atom catalysts by density functional theory calculations By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Advance ArticleDOI: 10.1039/D4CP03779K, PaperJiaxiang Wu, Erjun Kan, Cheng ZhanPromising ORR/OER single atom catalysts have been designed in the form of TM–N2X via DFT simulation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Mixed quantum/classical theory for rotationally inelastic scattering of identical collision partners revised By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27567-27582DOI: 10.1039/D4CP02806F, PaperD. Bostan, B. Mandal, D. BabikovWhen the tested system is artificially forced to follow the same collision path in indistinguishable and distinguishable treatments, all the differences between the results of the two treatments disappear.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Performance of functionalized graphene oxide with organic radical scavengers in proton exchange membranes By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27817-27828DOI: 10.1039/D4CP03151B, PaperYu Hu, Jiaxing Wang, Shuai Wang, Yuan FengA diazonium salt reaction is used to prepare benzoic acid-functionalized graphene oxide as a bi-functional filler for a Nafion membrane, and the corresponding composite membrane has improved chemical durability and proton conductivity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Exploring the valleytronic, optical, and piezoelectric properties of Janus MoBXY2 (X = N, P; Y = S, Se, Te) monolayers for multifunctional applications By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Advance ArticleDOI: 10.1039/D4CP03793F, PaperLuogang Xie, Lingli Wang, YanDong Ma, Hongyan Lu, Yang YangUnveiling novel Janus MoBXY2 monolayers with unique valleytronic, optical, and piezoelectric properties for multifunctional applications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical A combination of experimental and theoretical methods in evaluating triazole derivatives' mild steel corrosion inhibition ability in an acidic solution By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Advance ArticleDOI: 10.1039/D4CP03537B, PaperNgo Hong Cat Van, Nguyen Quang Trung, Pham Dinh Tu Tai, Pham Cam Nam, Dinh Quy HuongThe introduction of many nitrogen heteroatoms into inhibitor molecules improves corrosion inhibition efficiency.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Insight into physico-chemical properties of oxalatoborate-based ionic liquids through combined experimental-theoretical characterization By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Advance ArticleDOI: 10.1039/D4CP02296C, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Matteo Palluzzi, Giorgia Mannucci, Akiko Tsurumaki, Matteo Busato, Maria Assunta Navarra, Paola D’AngeloAn anion–anion attraction was inferred from the thermal behavior of oxalate-borate ionic liquids and confirmed through computational methods.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Exploring the electrochemical properties and lithium insertion mechanisms in akaganeite (β-FeOOH) – a combined DFT/experimental study By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Advance ArticleDOI: 10.1039/D4CP02947J, PaperPaulo Roberto Garcês Gonçalves, Heitor Avelino De Abreu, Luciano Andrey Montoro, Gabriela Cordeiro Silva, Angela de Mello Ferreira, Hélio Anderson DuarteUnveiling the unique charge/discharge characteristics of akaganeite offers valuable insights into electron transfer mechanisms through experimental and DFT calculations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical First-principles study on stability, electronic and optical properties of 2D SbXY (X=Se/Te, Y=I/Br)Janus layers By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Accepted ManuscriptDOI: 10.1039/D4CP04077E, PaperAnjana E Sudheer , Amrendra Kumar, Tejaswini G, Muthu Vallinayagam, Matthias Posselt, Matthias Zschornak, Chinnathambi Kamal, D. MuraliMotivated by the exceptional optoelectronic properties of 2D Janus layers (JLs), we explore the properties of group Va antimony-based JLs SbXY (X=Se/Te, Y=I/Br). From the Bader charges, the elec-tric dipole...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical A hydrogen passivation strategy for the electrocatalytic chlorine evolution reaction on metal–organic frameworks: a theoretical insight By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Advance ArticleDOI: 10.1039/D4CP03153A, PaperJiake Fan, Lei Yang, Hui Li, Zijian Sun, Mengyun Mei, Weihua ZhuThe chlorine evolution reaction (CER) is a crucial solution for treating chlorine-containing wastewater, a type of wastewater generated during the chemical production process.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Investigation on the combustion mechanism for NF3/H2 in DF/HF chemical lasers: a new perspective based on deep potential molecular dynamics simulations By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Advance ArticleDOI: 10.1039/D4CP03014A, PaperYinhua Ma, Dongmei Mu, Meiheng Lv, Nan Wang, Huaxin Liu, Fangjian Shang, Jianyong LiuCombustion-driven deuterium fluoride/hydrogen fluoride (DF/HF) lasers are a crucial type of chemical lasers.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Theoretical Insights into the Vibrational Spectra and Chemical Bonding of Ln(III) Complexes with a Tripodal N4O3 Ligand Along the Lanthanide Series By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Accepted ManuscriptDOI: 10.1039/D4CP03677H, PaperFrancielle C Machado, Mateus M Quintano, Carlos Vital dos Santos Junior, Albano Carneiro Neto, Elfi Kraka, Ricardo Luiz Longo, Renaldo Tenorio Moura Jr.{This study provides new theoretical insights into the vibrational spectra of Ln(III) complexes, along the lanthanide series by utilizing the LModeAGen protocol and integrating cutting-edge topological ideas. It provides a...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Intermolecular Hydrogen Bonding Delineates Stability of Non-canonical Adenine Base Pairs: A First-Principles Study By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Accepted ManuscriptDOI: 10.1039/D4CP02875A, PaperNicholas Adu-Effah, Nabanita SaikiaNon-canonical nucleobase pairs differ from canonical Watson-Crick (WC) pairs in their hydrogen bonding patterns. This study uses density functional theory with empirical dispersion correction to examine the stability and electronic...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Multi-scale study on the electrochemical behavior and corrosion mechanism of 5083 aluminum alloy with different microstructures in a NaCl environment By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Advance ArticleDOI: 10.1039/D4CP03380A, PaperZhijie Dai, Zhengbing Xiao, Dahong Zhao, Sunhang Xiao, Yuanchun Huang, Qingsong DaiMulti-scale study on the electrochemical behavior and corrosion mechanism of 5083 aluminum alloy with different microstructures in a NaCl environment.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Investigating Ni nanoparticles on CeO2 for methane dissociation: a comparative study of theoretical calculations and experimental insights By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Advance ArticleDOI: 10.1039/D4CP01324G, PaperTakaya Fujisaki, Yuta Tsuji, Phuc Hoan Tu, Tin Chanh Duc Doan, David S. Rivera Rocabado, Aleksandar Tsekov Staykov, Keiji Yashiro, Yusuke ShiratoriCeO2 supported with Ni nanoparticles has emerged as a promising catalyst for enhancing the efficiency of dry reforming of methane (DRM) reaction.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Deciphering the spectroscopic and thermodynamic aspects of binding of biologically important antioxidants with the alkali induced state of human serum albumin By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Advance ArticleDOI: 10.1039/D4CP03636K, PaperAnjali Maheshwari, Nand KishoreProtein–ligand interactions are crucial for developing and identifying novel therapeutic targets.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Deciphering nonlinear optical properties in functionalized hexaphyrins via explainable machine learning By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Advance ArticleDOI: 10.1039/D4CP03303E, PaperEline Desmedt, Michiel Jacobs, Mercedes Alonso, Freija De VleeschouwerThe NLO response of hexaphyrins is traced back to its driving forces using kernel ridge regression and explainable machine learning. Orbital and charge-transfer based features play a key role, as opposed to aromaticity and geometrical descriptors.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Annealing approach to form a nanotube from graphdiyne ribbon: A theoretical prediction By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Accepted ManuscriptDOI: 10.1039/D4CP03573A, PaperBo Song, Kun Cai, Jiao Shi, Qinghua QinA precisely controllable heat treatment process is critical for nanofabrication. We developed a two-step method to fabricate a graphdiyne nanotube (GNT) through heat treatment in an argon environment. Initially, we...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Magnetic field enhanced discharge and water activation of atmospheric pressure plasma jet: effect of assistance region and underlying physico-chemical mechanism By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Accepted ManuscriptDOI: 10.1039/D4CP03938F, PaperXiongfeng Zhou, Bin Chen, Hua Liao, Kun LiuMagnetic field-assistance holds the promise of becoming a new or complementary approach to enhance the efficiency of atmospheric pressure plasma jet (APPJ), but there is currently a lack of research...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Singer Dana Razik and her family feature in an original musical production, Rooh-E-Mardem By www.thehindu.com Published On :: Thu, 24 Oct 2024 22:11:06 +0530 Dana Razik and her family unite for an original music video Rooh-E-Mardem Full Article Life & Style
ical Radical reactions enabled by polyfluoroaryl fragments: photocatalysis and beyond By pubs.rsc.org Published On :: Chem. Soc. Rev., 2024, Advance ArticleDOI: 10.1039/D3CS00889D, Review ArticleMikhail O. Zubkov, Alexander D. DilmanThe review summarizes advances in the radical chemistry of polyfluorinated arenes under photocatalytic conditions. The fluoroaryl fragment serves as enabling motif for the reaction design and efficient generation of reactive intermediates.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Recent advances in super-resolution optical imaging based on aggregation-induced emission By pubs.rsc.org Published On :: Chem. Soc. Rev., 2024, 53,3350-3383DOI: 10.1039/D3CS00698K, Review ArticleFeng-Yu Zhu, Li-Jun Mei, Rui Tian, Chong Li, Ya-Long Wang, Shi-Li Xiang, Ming-Qiang Zhu, Ben Zhong TangFrom aggregation-induced emission to super-resolution imaging: the significance of reversible dynamic interaction.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Sixty years of electrochemical optical spectroscopy: a retrospective By pubs.rsc.org Published On :: Chem. Soc. Rev., 2024, 53,3579-3605DOI: 10.1039/D3CS00734K, Review Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chao-Yu Li, Zhong-Qun TianAfter sixty years of development, electrochemical optical spectroscopy has evolved from the early phase of proof-of-concept to an advanced phase with various spectroscopic modes and has contributed significantly to the field of electrochemistry.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Theoretical and computational methods for tip- and surface-enhanced Raman scattering By pubs.rsc.org Published On :: Chem. Soc. Rev., 2024, Advance ArticleDOI: 10.1039/D3CS01070H, Review ArticleSai Duan, Guangjun Tian, Yi LuoThe effective field Hamiltonian can rigorously treat the quantum interactions between all components of localized optical fields and molecules, which predicts the breakdown of diverse selection rules and extends the application of optical techniques.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Engineered two-dimensional nanomaterials based diagnostics integrated with internet of medical things (IoMT) for COVID-19 By pubs.rsc.org Published On :: Chem. Soc. Rev., 2024, 53,3774-3828DOI: 10.1039/D3CS00719G, Review ArticleMohd. Abubakar Sadique, Shalu Yadav, Raju Khan, Avanish K. SrivastavaEngineered 2D nanomaterials-based smartphone-assisted detection approaches integrated with IoMT, focusing on reliable, sensitive, and rapid diagnostics for COVID-19.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Electrochemical coupling in subnanometer pores/channels for rechargeable batteries By pubs.rsc.org Published On :: Chem. Soc. Rev., 2024, 53,3829-3895DOI: 10.1039/D3CS01043K, Review ArticleYao-Jie Lei, Lingfei Zhao, Wei-Hong Lai, Zefu Huang, Bing Sun, Pauline Jaumaux, Kening Sun, Yun-Xiao Wang, Guoxiu WangThis review categorizes subnanometer pores/channels (SNPCs) from structural perspective and demonstrates electrochemical couplings in SNPCs for batteries while proposing corresponding challenges and future research directions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Degradable biomedical elastomers: paving the future of tissue repair and regenerative medicine By pubs.rsc.org Published On :: Chem. Soc. Rev., 2024, 53,4086-4153DOI: 10.1039/D3CS00923H, Review ArticleBen Jia, Heyuan Huang, Zhicheng Dong, Xiaoyang Ren, Yanyan Lu, Wenzhi Wang, Shaowen Zhou, Xin Zhao, Baolin GuoThis review critically analyzes degradable biomedical elastomers, focusing on their degradation, synthesis, microstructure, and role in tissue repair. It guides experts in balancing degradation with tissue repair for improved applications.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Progress and perspectives on iron-based electrode materials for alkali metal-ion batteries: a critical review By pubs.rsc.org Published On :: Chem. Soc. Rev., 2024, 53,4154-4229DOI: 10.1039/D3CS00819C, Review ArticleJunzhe Li, Chao Wang, Rui Wang, Chaofeng Zhang, Guanjie Li, Kenneth Davey, Shilin Zhang, Zaiping GuoThis review critically evaluates recent advances in iron-based electrode materials and applications in alkali metal ion batteries, covering chemical synthesis, structural design, and modification strategies, with insights into future directions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical High Court tells CBSE to re-evaluate Political Science answer sheet By www.thehindu.com Published On :: Wed, 10 Aug 2016 00:00:00 +0530 Board against revaluation despite verification revealing that student had been marked wrongly Full Article Delhi
ical Mythical monsters of Greenland : a survival guide / by Maria Bach Kreutzmann ; illustrated by Maria Bach Kreutzmann and Coco Apunnguaq Lynge By darius.uleth.ca Published On :: Kreutzmann, Maria Bach, author Full Article
ical Funding ventures with vertical takeoffs By www.thehindubusinessline.com Published On :: Sun, 02 Jun 2024 20:58:00 +0530 Cornerstone Venture Partners on how specialisation can deepen a start-up’s value proposition Full Article Emerging Entrepreneurs
ical The synthesis of specifically isotope labelled fluorotryptophan and its use in mammalian cell-based protein expression for 19F-NMR applications By pubs.rsc.org Published On :: Chem. Commun., 2024, Advance ArticleDOI: 10.1039/D4CC04789C, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Giorgia Toscano, Martina Rosati, Letizia Barbieri, Katharina Maier, Lucia Banci, Enrico Luchinat, Robert Konrat, Roman J. LichteneckerCombining multistep organic synthesis with mammalian cell based protein overexpression leads to isolated 13C–19F spin systems in tryptophan side chains, which represent ideal sensors to probe protein interaction and dynamics using NMR spectroscopy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Synthesis of environmentally friendly energetic cocrystal derived from commodity chemicals By pubs.rsc.org Published On :: Chem. Commun., 2024, Advance ArticleDOI: 10.1039/D4CC04037F, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kazuki Inoue, Yosuke Nishiwaki, Mieko Kumasaki, Shinya Matsumoto, Ken OkadaAmmonium nitrate/glycine (2 : 1) energetic cocrystal was synthesized to address two drawbacks of ammonium nitrate: phase transitions and hygroscopicity. The cocrystal did not show phase transitions and exhibited decreased hygroscopicity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Direct alkene functionalization via photocatalytic hydrogen atom transfer from C(sp3)–H compounds: a route to pharmaceutically important molecules By pubs.rsc.org Published On :: Chem. Commun., 2024, Advance ArticleDOI: 10.1039/D4CC05026F, HighlightHangqian Fan, Yuxin Fang, Jingbo YuDirect functionalization of alkenes with C(sp3)–H substrates offers unique opportunities for the rapid construction of pharmaceuticals and natural products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Helical aromatic foldamers with tubular cavities capable of accommodating multiple halide ions By pubs.rsc.org Published On :: Chem. Commun., 2024, Advance ArticleDOI: 10.1039/D4CC05474A, CommunicationSeungwon Lee, Byeung Ju Lee, Geunmoo Song, Kyu-Sung JeongA series of pyridinium–indolocarbazole oligomers has been synthesized, which fold into helical structures with tubular cavities capable of accommodating up to four iodide ions in a linear arrangement.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Radical anions of 1,1-azoliumdithiocarboxylates By pubs.rsc.org Published On :: Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC05486E, CommunicationMartin Simon Luff, Kai Oppel, Ivo Krummenacher, Holger Braunschweig, Udo RadiusThe 1,1-azoliumdithiocarboxylate cAACMe-CS2 (1a) was prepared and its redox chemistry was evaluated and compared to NHC-based dithiocarboxylates IDipp CS2 (1b) and IMes-CS2 (1c). Radical anions [carbene CS2]·– were prepared by...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Boosting the electrochemical performance of Ni-rich LiNi0.96Co0.02Mn0.02O2 cathode by high-valence Zr/Mo dual-doping By pubs.rsc.org Published On :: Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04275A, CommunicationHongmei Cao, Yudong Zhang, Xunzhu Zhou, Jie Yu, Xiang Chen, Lin LiNi-rich oxides are attractive high-energy cathodes for lithium-ion batteries but suffer from inherent instability. Herein, we employed an ectopic Zr4+/Mo6+ dual-doping strategy to reinforce the layered structure through robust M-O...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Recent Advances in Photochemical Strain-Release Reactions of Bicyclo[1.1.0]butanes By pubs.rsc.org Published On :: Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC05108D, HighlightXiang Zhou, Ye Hu, Yao Huang, Yang XiongBicyclo[1.1.0]butanes (BCBs) are attractive compounds for their beautiful “butterfly” conformations, distinctive properties, and novel reactivities. As soon as the first example had been synthesized, a wide range of strain-release reactions...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Lipidic biomass as a renewable chemical building block for polymeric materials By pubs.rsc.org Published On :: Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04993D, Feature ArticleRafael Turra Alarcon, Gabriel Iago Iago, Caroline Gaglieri, Aniele De Moura, Éder Tadeu Gomes Cavalheiro, Gilbert BannachPolymers are intrinsically connected to our modern society and are found and used in different technologies. Although polymers are worthwhile, concerns about synthetic polymers from non-renewable sources have arisen. Therefore,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ical Sulfonated hierarchical ZSM-5 zeolite monoliths as solid acid catalyst for esterification of oleic acid By pubs.rsc.org Published On :: Chem. Commun., 2024, 60,13356-13359DOI: 10.1039/D4CC05044D, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Binhang Zhao, Pan Yang, Nan Zhang, Donald R. Inns, Elena F. Kozhevnikova, Alexandros P. Katsoulidis, Ivan V. Kozhevnikov, Alexander Steiner, Haifei ZhangSulfonated hierarchical H-ZSM-5 monoliths were synthesized via ice-templating as solid acid catalysts for biodiesel production.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article