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Mild boroxazolidone formation and dissociation: Application toward target identification of bioactive molecules

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05370B, Communication
Toya Tabei, Kyoko Nagasawa-Goto, Yohei Saito
We successfully found that boroxazolidone can dissociate under aqueous conditions, which were applicable to a solution containing proteins. The immobilization of a newly synthesized diarylborinic acid on beads enabled the...
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Synthesis of heteroleptic bis-phosphine bis-NHC iron (0) complexes: a strategy to enhance small molecule activation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05463F, Communication
Open Access
Christian M. Andre, Nathaniel K. Szymczak
We report low-valent iron complexes containing bis-NHC and bis-phosphine donor ligands that coordinate and strongly activate N2 and CO.
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Separation of Rare Earth Elements and Nickel Harnessing Electrochemistry and Reactive CO2 Capture and Mineralization

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04632C, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Akanksha Srivastava, Prarabdh Jain, Greeshma Gadikota, Prince Ochonma, Christopher Noe, Tianhe Yin
The aim is to probe the chemical mechanisms underlying the use of multifunctional solvents to simultaneously capture and convert CO2 into insoluble Rare Earth Element (REE)-carbonates, while forming soluble complexes...
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Composition tunable and stable spontaneous emission and lasing in Cd-alloyed perovskite microdisks

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04488F, Communication
Dmitry A. Tatarinov, Elizaveta V. Sapozhnikova, Daria Khmelevskaia, Yangyang Ju, Dmitriy M. Dolgintsev, Elena V. Bodyago, Alexandr A. Marunchenko, Alexey E. Zhukov, Haizheng Zhong, Ivan G. Scheblykin, Anatoly P. Pushkarev
All-inorganic Cd-alloyed perovskite microdisks were synthesized by pressure-assisted high temperature recrystallization. The microdisks showed composition tunable and temporally stable photoluminescence.
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Bidirectional strain release in a thermosalient organic salt crystal induced by anisotropic thermal expansion and phase transformation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04764H, Communication
Priyasha Harsha, Dinabandhu Das
Two-way release of strain followed by jumping in an organic salt crystal can be attributed to the anisotropic thermal expansion by heating and phase transformation followed by shear deformation of the crystals by cooling.
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Alkenylation of unactivated alkanes: synthesis of Z-alkenes via dual Co-TBADT catalysis

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04651J, Communication
Vetrivelan Murugesan, Anagha Syam, Guru Vigknesh Anantharaj, Ramesh Rasappan
Hydroalkylation of terminal alkynes using unactivated alkanes under dual Co-TBADT catalysts is reported. Our cobalt-HAT catalysis achieves the desired Z alkene with excellent regio- and diastereoselectivity via C–H activation.
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Visible light-activated polyphenol–Al3+ coordination for ambient and quantitative xylose-to-furfural conversion

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04899G, Communication
Jinshu Huang, Qizhi Luo, Tengyu Liu, Song Yang, Hu Li
Visible light-enhanced coordination of polyphenol–Al3+ is uncovered to switch Lewis/Brønsted acid sites for room-temperature cascade upgrading of xylose to furfural in ultrahigh yields.
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Interlayer spacing expansion for V2O5 towards ultra-stable zinc anode-based flexible electrochromic displays in Zn2+/Li+-PC organic electrolyte

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04974H, Communication
Zhe Li, Zhaoyang Song, Linhua Liu, William Yu, Jingwei Chen, Qianqian Zhu, Haizeng Li
To enhance the electrochemical stability and kinetics of V2O5, 3,4-ethylenedioxythiophene (EDOT) was in-situ polymerized within V2O5 interlayers, rendering PEDOT@V2O5 with enlarged layer spacing, increased stability in organic electrolyte, superior electrochemical...
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Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05173D, Communication
Bing Zeng, Yuexin Wang, Kanghui Xiong, Keke Zhang, Siyu Zhang, Xianjun Lang
A catalytic amount of TEMPO, mobile in the reaction medium, enhances the hole transfer of NU-1003 photocatalysis for blue light-powered oxidation of organic sulfides with O2.
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Tunable synthesis of magnetoelectric CoFe2O4–BaTiO3 core–shell nanowires

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03701D, Communication
Noah D. Ferson, John R. Ganiban, David P. Arnold, Jennifer S. Andrew
CoFe2O4–BaTiO3 core–shell nanowires with tunable magnetic anisotropy and magnetoelectric coupling are generated using a template-assisted synthetic procedure providing composition control.
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Revealing the structural influence mechanism of intrinsic potassium/calcium elements on bio-waste-derived hard carbon for sodium-ion batteries

Chem. Commun., 2024, 60,13380-13383
DOI: 10.1039/D4CC03546A, Communication
Yinghao Zhang, Chun Wu, Qinghang Chen, Chuangchuang Li, Wenjie Huang, Qianxiong Wen, Xiang-Xi He, Xingqiao Wu, Shu-Lei Chou
The evolution mechanism of hard carbon structures in terms of graphitization and pore structure caused by K/Ca has been clarified.
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Mn and Mo co-doped NiS nanosheets induce abundant Ni3+–O bonds for efficient electro-oxidation of biomass

Chem. Commun., 2024, 60,13392-13395
DOI: 10.1039/D4CC04818K, Communication
Pengfei Ren, Zixuan Wang, Wenchao Zhang, Fang Duan, Shuanglong Lu, Mingliang Du, Han Zhu
MnMo–NiS were synthesized for electro-oxidizing ethylene glycol (EG), glycerol (GLY), and 5-hydroxymethylfurfural (HMF), achieving faradaic efficiencies of 97.5%, 98.6%, and 99.2%, and yield rates of 615.7, 475.5, and 333.9 μmol h−1 cm−2.
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A polychloride-enabled synthesis of [NEt3Me][PCl6] serving as a potential PCl3-storage and PCl5-reagent

Chem. Commun., 2024, 60,13372-13375
DOI: 10.1039/D4CC04319G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Moritz J. Ernst, Merlin Kleoff, Patrick Voßnacker, Günther Thiele, Christian Müller, Sebastian Riedel
The reaction of the ionic liquid [NEt3Me][Cl3] with white phosphorus (P4) gives, quantitatively, hexachlorophosphate [NEt3Me][PCl6], which shows similar reactivity as PCl5 and can be used as a potential PCl3-storage material.
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PVDF nanocomposites with aligned boron nitride nanosheets and dispersed BaTiO3@PEG nanoparticles by a superspreading strategy towards high energy density

Chem. Commun., 2024, 60,13344-13347
DOI: 10.1039/D4CC04430D, Communication
Dajun Hou, Jingjing Zhou, Wen Chen, Jing Zhou, Pengchao Zhang
The limited improvement in discharge energy density (Ue) of polyvinylidene fluoride (PVDF) nanocomposites filled with low-dielectric-constant (εr) nanosheets has been addressed by using a superspreading layering strategy.
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Solution plasma synthesis of α-amino acids

Chem. Commun., 2024, 60,13408-13411
DOI: 10.1039/D4CC04482G, Communication
Changhua Wang, Yutong Zhang, Yuanyuan Li, Yinhe Rong, Xintong Zhang
This work uses solution plasma for easier control of amino acid synthesis, successfully producing rare serine, achieving green and low-carbon synthesis from small molecules to amino acids.
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Universal synthesis of pure-phase IB-group Sn-based alloys with modulable electrocatalytic CO2 reduction products

Chem. Commun., 2024, 60,13436-13439
DOI: 10.1039/D4CC05317F, Communication
Luyao Yang, Wenqing Zhang, Ximei Lv, Qianqian Zhao, Xiaojing Liu, Shulin Zhao, Yuhui Chen
A universal method for synthesizing a range of pure-phase IB-group Sn-based alloy catalysts (Cu3Sn, Ag4Sn, and AuSn) for electrochemical reduction of CO2.
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Solid-state synthesis of ligand-assisted lead halide nanoclusters

Chem. Commun., 2024, 60,13396-13399
DOI: 10.1039/D4CC04623D, Communication
David C. Zeitz, Kai-Chun Chou, Jin Z. Zhang
A solid-state synthesis of blue-emitting lead halide nanoclusters has been demonstrated for the first time.
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Atomistic insight into the promising thermoelectric performance of the copper-based ternary phosphide CaCuP

Chem. Commun., 2024, 60,13400-13403
DOI: 10.1039/D4CC04660A, Communication
Un-Gi Jong, Chol Ryu, Ji-Min Hwang, Su-Hyang Kim, Il-Gwang Ju, Chol-Jun Yu
We provide a valuable atomistic insight into the thermoelectric properties of hexagonal CaCuP, revealing that nano-structuring can double the thermoelectric figure of merit by further reducing lattice thermal conductivity.
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Bioinspired hydrogels: polymeric designs towards artificial photosynthesis

Chem. Commun., 2024, 60,13314-13324
DOI: 10.1039/D4CC04033C, Feature Article
Open Access
Reina Hagiwara, Ryo Yoshida, Kosuke Okeyoshi
This Feature Article outlines the design of polymer networks for water splitting induced by visible light to develop artificial chloroplasts. The network serves as a mediator for photoinduced electron transfer among precisely organised molecules.
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Intramolecular cyclization of N-aryl amides for the synthesis of 3-amino oxindoles

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05259E, Communication
Haitao Yang, Yu Pan, Yijing Tian, Kaili Yu, Yifeng Bai, Yonggang Jiang, Hongbin Zhang, Guogang Deng, Xiaodong Yang
A mild and efficient strategy to synthesize pharmaceutically important 3-amino oxindoles from readily available N-aryl amides has been developed.
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A MOF-derived CuO/TiO2 photocatalyst for methanol production from CO2 reduction in an AI-assisted continuous flow reactor

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05008H, Communication
Bhavya Jaksani, Ruchi Chauhan, Switi Dattatraya Kshirsagar, Abhilash Rana, Ujjwal Pal, Ajay K. Singh
An AI-assisted continuous flow reactor for CO2 reduction to methanol using a MOF-derived CuO/TiO2 photocatalyst.
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Origin of anisotropic thermal transport in CsPbBr3

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05037A, Communication
Open Access
Wilarachchige D. C. B. Gunatilleke, Oluwagbemiga P. Ojo, George S. Nolas
We reveal the specific structural and bonding features that result in anisotropic thermal transport for CsPbBr3 by directional single-crystal measurements and elucidate the bases for the low Debye temperature and speed of sound.
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Synthesis of substituent-free dioxadiaza[8]circulene to investigate intermolecular interactions and photophysical properties

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05539J, Communication
Aoi Nakagawa, Wataru Ota, Takumi Ehara, Yusuke Matsuo, Kiyoshi Miyata, Ken Onda, Tohru Sato, Shu Seki, Takayuki Tanaka
Substituent-free dioxadiaza[8]circulene has been synthesized and its dense packing structure and optical properties were analyzed in detail.
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Metal-free photocatalysts with charge-transfer excited states enable visible light-driven atom transfer radical polymerization

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04470C, Communication
Yuchen Huang, Yangxin Liu, Yingde Yan, Yanjun Gong, Yifan Zhang, Yanke Che, Jincai Zhao
Photoredox-catalyzed atom transfer radical polymerization (O-ATRP) offers powerful tools for the precise control of polymer synthesis. Metal-free photocatalysts are particularly desirable due to their high level of control in O-ATRP...
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Base-Promoted Cascade 5-exo-dig Annulation/Carboxylation of o-(1-Alkynyl)benzenesulfonamides with CO2: Divergent Synthesis of Mono- or Gem-dicarboxylic Esters

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05239K, Communication
Yang Yao, Junxue Bai, Peidong Cheng, Han Yang, Jianwei Sun, Song Sun
A base-promoted cascade 5-exo-dig cyclization/carboxylation of o-alkynylsulfamides with CO2 has been accomplished, furnishing a variety of benzosultams-containing acrylates in good yields by using CO2 as the carboxylic source. Notably, in...
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Machine Learning Directed Discovery and Optimisation of a Platinum-Catalysed Amide Reduction

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05273K, Communication
Open Access
Eleonora Casillo, Benon Maliszewski, Cesar Blanco, Thomas Scattolin, Catherine Cazin, Steven P Nolan
The discovery and optimisation of reaction conditions leading to the reduction of amides, a fundamental large-scale industrial reaction, is achieved using a machine learning (ML) platform and a platinum catalyst....
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Synthesis of Aryl Fluorocyclopropanes from Aryl Fluorodiazirines and Alkenes in Continuous Flow

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC01881H, Communication
Hoang-Minh To, Shima Mirakhorli, Thierry Ollevier
Photochemically induced generation of aryl fluorocarbene from arylfluorodiazirines and their subsequent [2 + 1] cycloaddition with alkenes was developed in continuous flow. The in situ generated electrophilic aryl fluorocarbene reacted...
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The wonders of veganism

The latest trend in the food space is going off milk and meat. Read on and find out where Bengaluru stands on this




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Feeling peckish?

Head to the Bird on Tree and choose from a variety of cuisines




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‘Our food is about love’

Osama Jalali says plating and presentation were not the focus of traditional Indian cuisine




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The takeaway is taste

RAHUL VERMA finds a cold weather friend in Mayur Vihar!




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Going bullish

Café Dalal Street issues new currency in the menu!




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Salt baked fish at its heart

The Drawing Room charms with fancy seafood set to Bohemian décor




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Moringa honey: How Italian bees are helping farmers in sweet enterprise

Moringa honey is among the most popular varieties of floral nectar in the food sector. Farmer and beekeeper N Dhandayuthapani is one of those in the Cauvery delta reaping the benefit of combining apiary with agriculture




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Reconsider decision to distribute fortified rice through PDS in Wayanad: Shreyams Kumar

Health issues, social impact not considered, says LJD State president




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With pop-up restaurants, chefs discover the joys of cooking flexible, seasonal menus

A pandemic-prompted wave of pop-up kitchens has now become a creative way for independent chefs and edgy restaurants to travel, experiment and connect with diners



  • Life & Style

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Theobroma, Mumbai’s popular patisserie, opens its first outlet in Chennai

After 100 outlets across the country, Theobroma opens its first patisserie in the city, in Anna Nagar. The second will open in Nungambakkam next week and feature all the favourites



  • Life & Style

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Cloud kitchens make a mark in Thiruvananthapuram with pocket-friendly food and a wide range of cuisines

Still ordering in, though lockdowns are over? You are not alone. As cloud kitchens juggle cuisines and experiment with new dishes from a single space, takeaway in Thiruvananthapuram gets more interesting every day




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Take home a piece of heritage at this Visakhapatnam sweet store

Sarvani Sweets launches its series sweet boxes featuring some iconic heritage spots of Visakhapatnam




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Bengaluru hosts Indian Cacao & Craft Chocolate Festival this weekend

The upcoming craft chocolate fest promises to be an eye-opener on the entire bean-to-bar experience




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Visiting Abu Dhabi this holiday season? Get a sense of the city’s growing luxury dining scene

Abu Dhabi is rising as a culinary destination with an emphasis on luxury dining offering cuisine from across the globe




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Artisanal craft chocolates made in Rajahmundry

An artisanal craft chocolate named Bon Fiction is made from cacao beans grown here



  • Life & Style

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Home bakers and chefs in Thiruvananthapuram have spread out a delectable platter for Christmas

Cakes, cookies, puddings and more are in the Christmas hampers sold by home cooks




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Goa’s latest fine dining restaurant White Plate serves familiar flavours with a modern twist

Chef Jason DeSouza’s White Plate serves glocal food with the theatrics of molecular gastronomy wrapped in marble and crystal chandeliers




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Six millet-based recipes to try this Pongal

This pongal, help yourself to healthy servings of Foxtail Poli and Little Millet pepper pongal While Pongal meals have traditionally been a rice-dominant affair, give Foxtail Poli and Little Millet pepper pongal a try




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A four-day Wild Food Festival in the Nilgiris puts the spotlight on sustainability

Climate crisis is real. It’s time to switch the narrative towards seasonal, locally available produce for sustainability, say speakers at the recently-concluded four-day Nilgiris Wild Food Festival




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Chef Manu Chandra opens LUPA, an oasis on Bengaluru’s busy MG road

LUPA, the flagship restaurant of chef Manu Chandra, will take you far from the madding crowd




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How Pune is becoming a dining destination, drawing cosmopolitan bar hoppers

With a heady mix of craft beer, high energy spaces and unique cocktail programmes, Pune cracks the cocktail code




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On a Ramzan food trail in Visakhapatnam

From the creamy slow-cooked haleem to paya nihari and sheer kurma, restaurants and hotels in Visakhapatnam are offer an array of Ramzan delicacies




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At Kraft, a concept store in Chennai, shop for pendant lights and wall art over a meal of crispy keema dosas and Korean burgers

Shop, eat, and try your hand at games at Kraft, the concept store that showcases around 60 different types of furniture and decor