me Switchable, chiral aluminium catalysts for ring opening polymerisations By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02831G, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.David T. Jenkins, Elizabeth C. Trodden, John M. Andresen, Stephen M. Mansell, Ruaraidh D. McIntoshA switchable, solvent-free catalytic system was developed in which Al catalysts selectively initiate either the formation of polyether or polycarbonate through the application of a PPNCl (bis(triphenylphosphine)iminium chloride) cocatalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Ionic-liquid Functionalized Metal-organic Framework and Its High Performance Solid Electrolyte for Lithium-ion Conduction By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02756F, PaperXiang Kun Cui, Yu Ding, Li Feng, Li Ming Chen, Yang Mei Hu, Hui Chen, Chong-Qing WanHerein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me A highly sensitive ratiometric optical thermometer based on Sr2MgWO6 double perovskite doped with Dy3+ exploiting thermally coupled and uncoupled levels By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02940B, PaperThi Hong Quan Vu, Bartosz Bondzior, Dagmara Stefanska, Shovan Dan, Przemysław Jacek DereńThe increasing demand for highly sensitive optical thermometers operating within a wide temperature range necessitates the development of new phosphors. In this work, the potential of temperature sensing performance of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me β-Cyclodextrin and cucurbit[7]uril as protective encapsulation agents of the CO-releasing molecule [CpMo(CO)3Me] By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT01863J, PaperRodrigo P. Monteiro, Isabel B. Calhau, Ana C. Gomes, André D. Lopes, José P. Da Silva, Isabel S. Gonçalves, Martyn PillingerFor inclusion compounds between the complex [CpMo(CO)3Me] (1) and β-cyclodextrin or cucurbit[7]uril, the macrocyclic hosts modulate to different degrees the UV light-mediated CO release from encapsulated 1.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Highly selective organo-gallium hydroxamate mediated inhibition of antibiotic resistant Klebsiella pneumoniae By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02440K, PaperRebekah N. Duffin, Jenisi Kelderman, Megan Herdman, Philip Craig AndrewsFive complexes of gallium derived from hydroxamic acids have been synthesised, characterised, and their anti-bacterial activity and mammalian cell toxicity established. These are three metal-organic complexes; [Ga(BPHA]3 1, [Ga(BHA-H]3 2,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Advances in metal–organic frameworks for optically selective alkaline phosphatase activity monitoring: a perspective By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17742-17755DOI: 10.1039/D4DT01727G, PerspectiveEduarda Andrade, Filipe A. Almeida Paz, Flávio FigueiraMOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18003-18012DOI: 10.1039/D4DT02285H, PaperAnupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti GhoshalAn ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me BODIPY dyes for optical limiting applications on the nanosecond timescale By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17766-17771DOI: 10.1039/D4DT02505A, FrontierJohn Mack, Gugu Kubheka, Aviwe May, Bokolombe P. Ngoy, Tebello NyokongRecent research at the Institute for Nanotechnology Innovation at Rhodes University exploring the utility of BODIPY and azaBODIPY dyes for optical limiting of incident nanosecond laser pulses in the visible region is described.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17918-17933DOI: 10.1039/D4DT02542C, PaperKrishnendu M. Nair, Pavithra Shankar, Selvaraju ThangaveluElectrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Construction of oxygen-rich vacancies and heterojunctions coupled with different morphologies of CeO2/mesoporous TiO2 framework structures for efficient photocatalytic CO2 reduction performance By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17963-17975DOI: 10.1039/D4DT02014F, PaperMorigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin ZhaoConstruction of oxygen-rich vacancies and heterojunction-coupled CeO2/mesoporous TiO2 framework structures with different morphologies and efficient photocatalytic CO2 reduction performance.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Direct O2 mediated oxidation of a Ni(II)N3O structural model complex for the active site of nickel acireductone dioxygenase (Ni-ARD): characterization, biomimetic reactivity, and enzymatic implications By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17852-17863DOI: 10.1039/D4DT02538E, PaperKelsey E. Kirsch, Mary E. Little, Thomas R. Cundari, Emily El-Shaer, Georgia Barone, Vincent M. Lynch, Santiago A. ToledoA structural and functional biomimetic Ni(II)N3O complex, capable of O2 mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Asymmetric magnetic nanosnowman loaded with AgPd nanocage toward NIR-enhanced catalytic activity By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17864-17879DOI: 10.1039/D4DT02425G, PaperJie Jin, Haoran Li, Hongfa Wang, Qunling Fang, Yunqi Xu, Weili Kong, Xia Chen, Ken Cham-Fai Leung, Hailong Wang, Shouhu XuanAn asymmetric Fe3O4@AgPd/PDA nanosnowman embedded with an AgPd nanocage shows significantly enhanced catalytic activity under near-infrared (NIR) light.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Imine bond-directed assembly of polyoxometalate-based metal–organic frameworks By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17902-17908DOI: 10.1039/D4DT02609H, PaperXiang Yu, Xinyu Xu, Lei Gao, Rengan Luo, Yi-Fan Liu, Yu-Hao Gu, Shuai YuanA series of isostructural polyoxometalate-based MOFs were constructed by linking polyoxometalates and metal clusters with imine bonds under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Ruthenium, copper and ruthenium–copper complexes of an unsymmetrical phosphino pyridyl 1,8-naphthyridine PNNN ligand By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18037-18046DOI: 10.1039/D4DT02755H, PaperJingyun Wu, Michael A. Stevens, Michael G. Gardiner, Annie L. ColebatchA new unsymmetrical dinucleating PNNN ligand is reported, the versatility of which is demonstrated by formation of heterobimetallic, homobimetallic and monometallic complexes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17948-17962DOI: 10.1039/D4DT02118E, PaperAnandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel ElumalaiWe disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18027-18036DOI: 10.1039/D4DT02642J, PaperAlexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. SukhikhBased on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17934-17947DOI: 10.1039/D4DT01996B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara MachuraThe impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Catalytic partial oxidation of methane over oxide-ion-conductive lanthanum silicate apatites By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18021-18026DOI: 10.1039/D4DT02421D, PaperAfif Pamungkas, Yuta Goto, Kazumasa Murata, Saburo Hosokawa, Satoshi Ogawa, Kosaku Ohishi, Tomohiro Matsumoto, Miwa Saito, Teruki MotohashiThe oxide-ion-conductive lanthanum silicate La9.33Si6O26 with an apatite-type structure exhibits high activity for the catalytic partial oxidation of methane (CPOX).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17893-17901DOI: 10.1039/D4DT02111H, PaperYunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo LuAn acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02873B, PaperSofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. IversenBy investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02452D, PaperJing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang YangThis study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02589J, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef HolubThe objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02420F, Frontier Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yohei Kametani, Yoshihito ShiotaMechanistic analysis of nitrite (NO2−) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02258K, PaperCeyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. YilmazHighly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02652G, CommunicationYue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng ChengIsomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02655A, PaperZ. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun XuFour BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02573C, FrontierPrashanta Pal, Mahasweta NandiTwo dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02621G, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro MarronePaddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02605E, PaperJunxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining SunPhotodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
me Media invited but not welcomed! By www.thehindubusinessline.com Published On :: Fri, 19 Apr 2013 15:11:49 +0530 Full Article Siddhartha P Saikia
me Media & Freebies: a murky connection By www.thehindubusinessline.com Published On :: Fri, 31 May 2013 16:21:44 +0530 Full Article Siddhartha P Saikia
me Of govt departments and RTI By www.thehindubusinessline.com Published On :: Tue, 03 Sep 2013 16:52:44 +0530 Full Article S Madhavan
me The show off syndrome By www.thehindubusinessline.com Published On :: Mon, 23 Sep 2013 12:04:00 +0530 Full Article S Madhavan
me Samen delen across the fence By www.thehindu.com Published On :: Sun, 11 Aug 2024 01:16:00 +0530 Striking a rapport with neighbours in the Netherlands Full Article Open Page
me Moving house and memories By www.thehindu.com Published On :: Sun, 18 Aug 2024 01:20:00 +0530 When life’s imprints tumble out of closets and into oblivion Full Article Open Page
me It’s time to unwind By www.thehindu.com Published On :: Sun, 25 Aug 2024 02:30:00 +0530 Make the most of the silver years as it is the most relaxing phase of life Full Article Open Page
me Thriving technology, waning memory By www.thehindu.com Published On :: Sun, 25 Aug 2024 03:33:00 +0530 Too many digital nannies are robbing us of the power of memory Full Article Open Page
me Women at the receiving end By www.thehindu.com Published On :: Sun, 01 Sep 2024 04:54:00 +0530 They are the worst affected by alcoholism among men Full Article Open Page
me When homes turn hell By www.thehindu.com Published On :: Sun, 01 Sep 2024 05:40:00 +0530 Domestic violence takes a psychological, emotional, financial and physical toll Full Article Open Page
me Nothing has changed for women in India By www.thehindu.com Published On :: Sun, 22 Sep 2024 01:15:00 +0530 From Nirbhaya to Abhaya, violence continue to be perpertrated against women in the country Full Article Open Page
me Talking about menopause By www.thehindu.com Published On :: Sun, 29 Sep 2024 00:44:31 +0530 Media explore gender disparity largely, but it has failed to explicitly probe this transformative stage in a woman’s life Full Article Open Page
me Complete actor vs method hero By www.thehindu.com Published On :: Sun, 29 Sep 2024 02:50:00 +0530 When Sivaji Ganesan fans locked horns with Dilp Kumar admirers Full Article Open Page
me A strong memory By www.thehindu.com Published On :: Sun, 06 Oct 2024 01:55:32 +0530 The mind can be a double-edge sword, serving up both good and bad memories Full Article Open Page
me Building mental reserves By www.thehindu.com Published On :: Sun, 13 Oct 2024 03:44:00 +0530 Treat mental health like an “account” with regular deposits of nurturing habits, thoughts, and actions Full Article Open Page
me A women-only conversation, but for all By www.thehindu.com Published On :: Sun, 13 Oct 2024 04:13:00 +0530 Why do we descend to the misogynistic use of ‘girlish’ and ‘womanly’ as labels to demean some of the complex disciplines? Full Article Open Page
me What’s in a name? By www.thehindu.com Published On :: Sun, 20 Oct 2024 02:50:00 +0530 Much, if it’s of the place you have grown up in Full Article Open Page
me Permeating partiarchy By www.thehindu.com Published On :: Sun, 20 Oct 2024 03:05:00 +0530 It’s no longer about confining women to the kitchen; it subtly disguises itself as praise for how well women juggle careers and family Full Article Open Page
me Celebrate menopause By www.thehindu.com Published On :: Sun, 20 Oct 2024 03:35:00 +0530 Recognise it as the beginning of a new chapter in a woman’s life Full Article Open Page
me Apparel oft proclaims the times By www.thehindu.com Published On :: Sun, 27 Oct 2024 01:37:00 +0530 Sartorial preferences change from one era to another Full Article Open Page
me Women and travel By www.thehindu.com Published On :: Sun, 27 Oct 2024 02:38:00 +0530 Whether working or not working, during daytime or at night, indoors or outdoors, they have the right to life and dignity Full Article Open Page
