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Merging nucleophilic phosphine catalysis and photocatalysis for the rapid assembly of 2-oxabicyclo-[2.1.1]hexane scaffolds from feedstock allyl alcohols

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06684G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David M. Whalley, Luca Carlino, Okky Dwichandra Putra, Niall A. Anderson, Susannah C. Coote, Olivier Lorthioir
A synthesis of 2-oxabicyclo-[2.1.1]hexanes from readily available allyl alcohols and electron-poor arylalkynes. The transformation utilises phosphine catalysis and energy transfer catalysis for rapid assembly of these diverse scaffolds.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




2

Tailoring Hierarchical MnO2 Nanostructures on Self-Supporting Cathodes for High-Mass-Loading Zinc-Ion Batteries

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06182A, Edge Article
Open Access
Weijie Zheng, Zhibiao Cui, Cong Liu, Libei Yuan, Shengsong Li, Lilin Lin, Tao Meng, Liangui Yang, Yexiang Tong, Dong Shu
Aqueous zinc-ion batteries (AZIBs) with MnO2 cathodes have promising application prospects, however, their performance is hindered by their low efficiency and insufficient life. By leveraging the nanomicellar properties of cetyltrimethylammonium...
The content of this RSS Feed (c) The Royal Society of Chemistry




2

Spin State Modulation and Kinetic Control of Thermal Contraction in a [Fe2Co2] Discrete Prussian Blue Analogue

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05792A, Edge Article
Open Access
Jyoti Yadav, Sanjit Konar
Stimuli-responsive switchable molecules represent an important category of magnetic materials with significant potential for functional devices. However, engineering complexes with controlled switchability remains challenging due to their sensitivity to lattice...
The content of this RSS Feed (c) The Royal Society of Chemistry




2

12/14:46 EST Heatwave Warning (QLD)




2

13/09:26 EST Minor Flood Warning for the Bremer River and Warrill Creek




2

Subdued 62nd birthday for Kamal Haasan




2

Dear Zindagi music: Déjà vu with a hint of new

Amit Trivedi returns as a composer for the new Gauri Shinde film with a bunch of feel-good tracks




2

IFFI 2016: all eyes on S. Korea

What makes South Korean cinema so special on the global map? With a great line-up of its contemporary films, IFFI's 47th edition, could be the place to find the answer




2

Share Market Highlights 18 April 2024: Sensex falls 330 pts, Nifty at 22,000; media, metal stocks shine, FMCG, healthcare drag

Sensex, Nifty updates on 18th April 2024: Equity benchmarks BSE Sensex and NSE Nifty extended losses on Thursday. As per provisional figures, BSE Sensex fell 332.23 pts or 0.46 per cent to trade at 72,611.45 as of 3.35 pm and Nifty 50 declined 103.70 pts or 0.47 per cent to trade at 22,044.20., Bharti Airtel, Power Grid Corp, M&M, BPCL, and Tata Steel were the top gainers, while Nestle, Apollo Hospitals, Axis Bank, HCL Technologies, and ONGC were the major laggards. The stocks that hit a 52-week high on the NSE include AAA Tech (19.33 per cent), Just Dial (12.95 per cent), Indo Tech (10 per cent) and Hi-Tech Gear (10 per cent).




2

Three key MF inflow trends in May 2024

Monthly investments via SIPs crossed the ₹20,000-crore mark for the second successive month.




2

Navi Nifty 500 Multicap 50:25:25 Index Fund: Should you subscribe?

The only fund tracking the Nifty 500 Multicap 50:25:25 Index till date. But does it offer some unique value proposition?




2

This value fund has just completed 20 years: Should you invest?

As benchmarks rise and broader markets correct, a portfolio anchored in strong value-based stock-selection criteria may work well for investors




2

20 landmark verdicts delivered by CJI Chandrachud




2

PM Modi participates in 200th year celebrations of Shree Swaminarayan Mandir in Gujarat




2

Secrets of the Red Lantern Chosen One of The Best Cookbooks of 2008

Secrets of the Red Lantern by Pauline Nguyen has been chosen by NPR food writer Susie Chang as one of the Best Cookbooks of 2008.

An interview with Susie about her selections is tentatively scheduled for Weekend Edition the weekend of November 22, with two recipes and images from the book planned for npr.org.

• Secrets of the Red Lantern will also be on the year’s top cookbook lists of the Chicago Tribune and the Atlanta Journal-Constitution.

Overflowing with sumptuous but simply prepared dishes that have been passed down through generations of the Nguyen family, Secrets of the Red Lantern is part Vietnamese cookbook and part family memoir.

More than 275 traditional Vietnamese recipes are presented alongside a visual narrative of food and family photographs that follows the family's escape from war-torn Vietnam to the successful founding of the Red Lantern restaurant.




2

Secrets of the Red Lantern Named Best Asian Cookbook of 2008

Secrets of the Red Lantern: Stories and Vietnamese Recipes from the Heart
by Pauline Nguyen has been named Best Asian Cookbook of 2008 by epicurious.com:


BEST ASIAN
Secrets of the Red Lantern
by Pauline Nguyen (Andrews McMeel Publishing)
Recipe to try: Salt and Pepper Tofu

Whether you want amazingly accessible Vietnamese recipes or just a good, honest family story with food, this Sydney restaurateur delivers. Her family memoir is a great tale of what immigrants both give up and gain in choosing (or not) to pack up and try another country, and if it's not always pretty, it is inspiring, especially with both vintage photos and pictures of the contemporary food Nguyen creates. The book is so beautiful you can almost taste the braised duck with ginger and scallions or the banana fritters.

http://www.epicurious.com/articlesguides/howtocook/cookbooks/bestof2008




2

AOL Food Names The Art & Soul of Baking One Of The Best Cookbooks of 2008

The editors of AOL Food included The Art and Soul of Baking by Sur La Table with Cindy Mushet on their list of the Best Cookbooks of 2008:

http://food.aol.com/holidays/most-sought-after-cookbooks

The Art and Soul of Baking by Cindy Mushet

Cindy Mushet, a pastry chef at the legendary Chez Panisse and a culinary instructor at Le Cordon Bleu in Los Angeles, reveals the science behind baking in a language the home cook can understand. Take the time to read through the Baker's Pantry, which provides useful tips.

Recipes to try: Baci Tart with Frangelico Cream and Herbed Chicken Pot Pie





2

Dilbert 2.0 Creator Scott Adams Interviewed By Barron's

No Laughing Matter By JIM MCTAGUE
Cartoonist and blogger Scott Adams is outspoken about economics, politics and more -- but tight-lipped about Dilbert, hero to cubicle jockeys.

JUST WHEN YOU THOUGHT THE ECONOMY COULDN'T POSSIBLY get worse comes this disturbing news: Dilbert's mismanaged high-tech company is foundering, jeopardizing the lovable cartoon character's oppressive but steady job as an electrical engineer in a stuffy cubicle, where he's manufactured laughs about illogical and inhumane corporate managers for nearly 20 years.

Barron's won't divulge the climax of the current plot. During a recent interview, Dilbert's creator, Scott Adams, asked that we merely hint at what lies ahead for the cylinder-headed nerd with the upturned, clip-on tie. But read the daily Dilberts carefully over the next few days or weeks; clues abound and they don't point to a happy conclusion.

That's fitting because, as Adams notes in Dilbert 2.0, his $85, 576-page 20th-anniversary collection of 4,000 of his more than 8,000 cartoon strips (plus a DVD): "Dilbert is most popular when the workplace is at its worse." In fact, the strip, a window on workplace absurdity, took off during the downsizing binge of the early 1990s. In one memorable sequence from that period, Dilbert competes with a monkey to keep his engineering job. Dilbert wins, but his victory jig is short-circuited by his pointy-haired boss' decision to place the monkey on the upper-management fast track. Sounds like a telling commentary on the corporate world of 21st century's first decade, too.

Adams' current strips and very funny blog (http://www.dilbert.com/blog/), which often feature the cartoonist's insightful economic and stock-market commentaries, provide more hints about Dilbert's fate. A Dec. 12 blog argues that the recession is anything but temporary: "I think we are on the verge of a change as profound as the Industrial Revolution. Society will have to retool its expectations to meet the reality that there just won't be enough money to provide necessary services if we insist on consuming in an inefficient way."

One clue about Dilbert's fate appeared on Dec. 13 in newspapers around the world (Dilbert is published in 70 countries and 25 languages) in what turned out to be one of the most popular episodes in the strip's history: A financial adviser recommends that Dilbert's pointy-haired boss invest all of the company's funds in sick livestock. Don't buy just one sick cow, the adviser urges; buy an entire herd, because by aggregating sick cows, the risk goes away. "It's called math," the adviser adds, in a send-up of the asset-backed securitizations that have helped topple the global economy.

The financial adviser, by the way, is a malicious canine. In his blogs, Adams is equally unkind to real advisers and money managers. In his view, formed long before the disrobing of Bernie Madoff, they're always conniving to steal investors' money. Perhaps this depiction is payback: Adams lost a bundle following advice during the tech bubble, which also convinced him that investing in individual stocks and "professionally managed" funds is a losers' game. His advisers put half of his portfolio into WorldCom, Enron and other sure things and lost 40% of his invested cash, he says. He managed the other half and lost 20% in the tech wreck.

"Most of the investments I made in individual stocks went bad because managements were lying. They are the source of the information for the markets." His conclusion: "It is even dumber to pay an expert to talk to the liar for you and charge you 1% of your portfolio." Some folks who bought funds of funds that invested with Madoff surely would agree.

Read entire article: http://online.barrons.com/article/SB123094660981850775.html




2

President Obama Election 2008 Named Best Seller

The New York Times Book Review of January 18, 2009 features President Obama Election 2008: A Collection of Newspaper Front Pages Selected by the Poynter Institute at #28 on the Paperback NonFiction Best Seller List

The election of Barack Obama as the first African-American president of the United States was a worldwide historic event resulting in perhaps some of the most important front pages in US history. President Obama Election 2008 is a collection of over seventy November 5th, 2008 newspaper front pages from around the world. There is no better statement of the emotion, excitement, and significance of this moment in history.

During his campaign for the White House, Barack Obama garnered an almost frenzied following. President Obama Election 2008 will be a cherished keepsake or gift for any of the millions of Americans who cast their vote for the 44th President of the United States. Here is the must-have commemorative book on this historic event.

  • Features over 70 historic newspaper front-pages from the day after the election, including international, campus, and ethnic publications.
  • Includes an introduction by Doonesbury creator Garry Trudeau.
  • Compiled by The Poynter Institute, a non-profit, non-partisan school of journalism.

About The Poynter Institute

Founded in 1975, The Poynter Institute is a school dedicated to teaching and inspiring journalists and media leaders. It promotes excellence and integrity in the practice of craft and in the practical leadership of successful businesses. It stands for a journalism that informs citizens and enlightens public discourse. It carries forward Nelson Poynter's belief in the value of independent journalism in the public interest. As a financially independent, nonprofit organization, The Poynter Institute is beholden to no interest except its own mission: to help journalists seek and achieve excellence.

To purchase: http://www.andrewsmcmeel.com/products/?isbn=0740784803



  • President Obama Election 2008
  • The New York Times Book Review
  • The Poynter Institute

2

The Art and Soul of Baking a 2009 IACP Cookbook Awards Winner

The Art and Soul of Baking is a 2009 IACP Cookbook Awards Winner

Winners were announced at the 2009 International Association of Culinary Professionals Conference (IACP) International in Denver on April 4.

Art and Soul of Baking won in the cookbook/baking category!

Sur La Table teamed with pastry chef and baking teacher Cindy Mushet to bring you the ultimate guide to baking. Beautiful photographs and more than 250 easy-to-follow recipes lead you into a world of alluring aromas and light, flaky pastries. Illustrated asides take you step by step through important techniques, from carmelizing sugar to working with croissant dough. Plus, you'll find invaluable information on over 100 ingredients and 50 baker's tools. A true pleasure for anyone who loves to bake.

The cookbook is also nominated for a 2009 James Beard Foundation Award.



  • IACP
  • The Art and Soul of Baking

2

Man accused in 25 cases arrested for attempted theft at magistrate’s house in Ernakulam




2

Over 12,000 dengue cases reported in Ernakulam since January

Sources include illegal waste dumping sites, vacant plots, and mosquito-breeding grounds like discarded containers, used tyres, and pots




2

Kerala School Sports & Games 2024: Athletics events to start on Thursday




2

Road safety class mandatory for driving licence applicants in Ernakulam from Dec. 2

“The sessions will include new road safety guidelines in keeping with advancements in automobiles and road construction and also amendments made to the Motor Vehicles Act in the recent past”




2

Union Minister Suresh Gopi inaugurates ‘Confluence-24’ in Kochi




2

Kerala State Sports & Games 2024: curiosity pulls in more people to baseball games

Though not a very popular game like cricket, more youngsters are getting drawn into the sport, says a baseball coach




2

Tom Cruiser wins Mysore Dasara Sprint Championship-2024




2

JSK1 Golconda St. Leger to be run on Oct. 28




2

Mandarino claims the Cubic Mysore Derby 2024




2

Geographique should score a hat-trick in the Teena Katrak Memorial R.W.I.T.C. Ltd Trophy (Gr. 2)




2

Cabinet clears ₹2,254 crore for national forensic infra enhancement scheme

Under this scheme, the MHA will establish campuses of the National Forensic Sciences University and central forensic science laboratories in the country




2

Union Cabinet announces economic decisions worth over ₹2.88-lakh crore

These include the MSP hike for 14 Kharif crops, Varanasi airport expansion, and a new major port at Vadhavan




2

Centre notifies new Telecom Act effective June 26, replaces 138-year-old Telegraph Act

Key provisions include user protection, reforms in the right of way, optimal spectrum utilisation, and the introduction of biometric identification for new SIMs




2

Interest subsidy scheme for exporters extended for 2 months for MSMEs

Claims of non-MSME exporters not to be entertained beyond June 30, 2024, says DGFT




2

On eve of Modi’s Moscow visit, Indo-Russia JV delivers 35,000 AK-203s to Indian Army

The Indo-Russian Rifles Private Ltd, a joint venture between India and Russia, has production facility at Amethi, UP and is expected to manufacture more than 600,000 rifles as per a deal between the two sides




2

Budget 2024: ₹5,000 monthly internship allowance announced for 1 crore youth

Internship scheme aims to create job opportunities in top 500 companies over next five years




2

Union Budget 2024-25: India slashes aid to Maldives, boosts support for Sri Lanka and Mauritius

Aid to the Maldives has been cut by 48%, reducing the grant from ₹770 crore to ₹400 crore, reflecting strained diplomatic ties following the election of pro-China President Mohamed Muizzu.




2

Entering a decade of financial inclusion: PMJDY reaches 53 crore beneficiaries and ₹2.28 lakh crore in deposits

The scheme has largely been women-centric with 29.48 crore beneficiaries while 35.27 crore of total accounts are from rural and semi-urban branches




2

Cabinet approves e-auction to roll out FM Radio stations in 234 new cities

The Cabinet also clears the proposal to change annual licensing fee conditions




2

A dozen industrial smart cities worth ₹28,602 cr get CCEA approval

Projects to be completed by 2027, attract investment of ₹1.5 lakh crore, general 10 lakh direct jobs, says Piyush Goyal




2

India enforces mandatory CCI approval for M&As over ₹2,000 crore under new regulations

The updated regulations define ‘India nexus’ criteria, including user metrics and turnover, and introduce a ₹500 crore monetary threshold.  




2

Chennai Metro Phase 2 now a ‘Central Sector’ project, Centre to fund 65% of costs

The decision shifts financial responsibility largely to the central government, freeing up state resources and triggering loan renegotiations with international agencies. 




2

India’s new biodiversity strategy aims to protect 30% of ecosystems, restore degraded habitats by 2030

This plan aligns with the global targets set by the Kunming-Montreal Global Biodiversity Framework.




2

PM E-DRIVE: Government starts disbursal of incentives amounting to ₹320 crore in first month of scheme

Total 28,81,436 units of EVs to be incentivised with an outlay of ₹10,900 crore in the next 2 years




2

2024 Land Rover Discovery Sport launched




2

BMW 620d M Sport Signature launched

Priced at ₹78.90 lakh, ex-showroom, the tech-laden car is powered by a 2-litre diesel engine




2

Coupé de Inde

New Entrant: The upcoming Citroen C3-based Basalt promises to bring coupe aesthetics to the compact SUV segment




2

Quarter-litre crisis: Bajaj Pulsar N250

While there’s no crisis in the 250 cc space, Bajaj appears to have devised a great solution anyway




2

2024 Porsche Panamera makes its Indian debut

The Panamera benefits from a new cabin, complete with a 12.6-inch instrument panel, a 10.9-inch touchscreen, and a passenger display