Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00925H, Paper

George E. P. O'Connell, Richard F. Webster, Elise Elkington, Rose Amal, Jason Scott, Emma C. Lovell
Introducing light to thermal DRM may be an effective strategy to improve catalyst stability, but light's role in the stability mechanism is not well understood.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00974F, Paper

Melanie A. Kascoutas, Alison Sy-min Chang, Kiana E. Kawamura, Gabriela M. Bailey, Parker T. Morris, Elizabeth A. Borst, Lilliana H. Granados, Amanda K. Cook
A modular Ni(0)/silane E-selective alkene isomerization system has been developed with air-tolerant reagents.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01028K, Paper

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Dominik Neukum, Maya Eyleen Ludwig, Georgios Uzunidis, Ajai Raj Lakshmi Nilayam, Baerbel Krause, Silke Behrens, Jan-Dierk Grunwaldt, Erisa Saraçi
The synthesis of renewable bio-based monomers, like 2,5-furandicarboxylic acid (FDCA), is of high interest in the shift toward a circular economy. Bimetallic catalysts offer the variation of different properties, enabling...
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00987H, Paper

Juanjo Mateu-Campos, María Gutiérrez-Blanco, Eva Guillamón, Vicent S. Safont, Rosa Llusar
Air-stable diamino Mo₃S₄ clusters are efficient catalysts for the late-stage functionalization of drugs and other valuable products containing sulfide moieties.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00971A, Paper

Qianqian Shang, Hongbing Wang, Changjie Kan, Rui Ding, Yankai Li, Shiva Pandeya, Ziliang Li, Mahesh Kumar Joshi
Exfoliation and hetero-element doping are common procedures for band gap engineering and enhancing the photocatalytic properties of g-C₃N₄.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01031K, Paper

Xinwan Zhao, Minjun Lei, Guangbo Liu, Zhiliang Jin, Noritatsu Tsubaki
A fundamental strategy for enhancing the performance of photocatalytic water-splitting catalysts is to facilitate the efficient migration of photogenerated charge carriers to establish a heterojunction.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01132E, Paper

Zaili Xiong, Jijun Guo, Yuwen Deng, Meirong Zeng, Zhandong Wang, Zhongyue Zhou, Wenhao Yuan, Fei Qi
This study investigates the oxidative coupling of methane (OCM) using a Li/MgO catalyst in a packed bed reactor.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00703D, Paper

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Anna Vidal-López, Estefanía Díaz López, Aleix Comas-Vives
First-principles calculations show the crucial role of the Cu/Mo₂CO_x interface in enabling low-energy pathways for CO₂/CO hydrogenation to methanol via successive heterolytic H₂ cleavages.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00821A, Review Article

Toyese Oyegoke, Franck Dumeignil, Baba E.-Yakubu Jibril, Carine Michel, Robert Wojcieszak
This review explores the mechanisms and factors influencing the selective oxidation of HMF and furfural into valuable products using gold, platinum, and palladium catalysts.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00995A, Paper

Tiantian Liu, Kang Lv, Xiaoguang Bao
A detailed computational study was performed to shed light on the mechanistic differences between the Ru(II) and Zn(II)-catalyzed cross-coupling of cyclopropenes with diazo compounds.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00685B, Paper

Ray Miyazaki, Somayeh Faraji, Sergey V. Levchenko, Lucas Foppa, Matthias Scheffler
Vibrational frequencies can be utilized as a reference to assess the reliability of the exchange–correlation functionals.
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Catal. Sci. Technol., 2024, 14,6186-6197
DOI: 10.1039/D4CY00693C, Paper

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Abdulrhman Moshantaf, Michael Wesemann, Simeon Beinlich, Heinz Junkes, Julia Schumann, Baris Alkan, Pierre Kube, Clara Patricia Marshall, Nils Pfister, Annette Trunschke
Digitalisation in experimental catalysis research: we are introducing machine-readable standard operating procedures combined with automated data acquisition, storage and sharing to improve research efficiency and reproducibility.
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Catal. Sci. Technol., 2024, 14,6331-6337
DOI: 10.1039/D4CY01046A, Paper

Ling Ding, Lou Gao, Di Pan, Ke Du, Jiayu Yu, Wanyi Li, Yahong Zhang, Yi Tang
Efficiently reduce the formation of meso-lactide from racemic lactic acid by utilizing H-Beta zeolite shape selectivity towards lactic acid dimers.
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Catal. Sci. Technol., 2024, 14,6298-6306
DOI: 10.1039/D4CY00657G, Paper

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Diana A. Amariei, Julia Tenhaef, Thomas Classen, Benoit David, Tobias M. Rosch, Holger Gohlke, Stephan Noack, Jörg Pietruszka
The engineering of stereoselective C-methyltransferase PsmD through saturation mutagenesis led to improved activity for larger substrates. An automated process was designed and successfully applied for the mutant library production and screening.
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Catal. Sci. Technol., 2024, 14,6247-6258
DOI: 10.1039/D4CY00741G, Paper

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Clément Molinet-Chinaglia, Elizabeth Vera, Philippe Vernoux, Laurent Piccolo, Stéphane Loridant
H₂ reducing pretreatment at 500 °C promotes the activity of low-Pt-content Pt/CeO₂ catalysts by increasing the number of active Pt⁰ NPs. A 12 h oxidative post-treatment at 500 °C which forms PtO_x species easily activated also leads to improvement.
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Catal. Sci. Technol., 2024, 14,6286-6297
DOI: 10.1039/D4CY00755G, Paper

Yuzheng Li, Xianbao Duan, Zhang Liu, Caoran Li, Fangwen Ye, Zhihong Zhang, Liuqing Chen, Chun Du, Qingbo Wang, Bin Shan
Pt–Rh alloy nanoparticles featuring surfaces with both Pt and Rh atoms are poised to demonstrate bifunctional catalytic prowess in the NO + CO reaction.
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Catal. Sci. Technol., 2024, 14,6207-6214
DOI: 10.1039/D4CY00564C, Paper

Kio Kawata, Shoji Iguchi, Shimpei Naniwa, Tsunehiro Tanaka, Masamu Nishimoto, Kentaro Teramura
Towards the realisation of carbon neutrality by utilising renewable energy sources, the photocatalytic conversion of CO₂ with H₂O—known as artificial photosynthesis—is important.
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Catal. Sci. Technol., 2024, 14,6411-6419
DOI: 10.1039/D4CY00808A, Paper

Manish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. Ghorai
A metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O₂ is reported.
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Catal. Sci. Technol., 2024, 14,6270-6277
DOI: 10.1039/D4CY00502C, Paper

Yao Ning, Yuqi Yang, Dongming Shan, Shuxing Mei, Yibai Yan, Linjie Ding, Ying Zhang
Ethylene oligomerization plays an important role in industrial production.
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Catal. Sci. Technol., 2024, 14,6363-6371
DOI: 10.1039/D4CY00912F, Paper

Junchao Huang, Borui Li, Jiaxing Yu, Zhan Shu, Ming Li
The Z-scheme three-dimensional flower-like shape BiOBr/ZnIn₂S₄ showed excellent efficiency to degrade Congo red.
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Catal. Sci. Technol., 2024, 14,6321-6330
DOI: 10.1039/D4CY00807C, Paper

Andrija Kokanović, Dunja Pupavac, Stéphane Chenot, Stéphane Guilet, Igor M. Opsenica, Slavica Stankic
In this study, we explore the catalytic activity of highly pure PdZn–ZnO nanopowder, synthesized via an innovative metal–organic chemical vapor synthesis (MOCVS) method.
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Catal. Sci. Technol., 2024, 14,6198-6206
DOI: 10.1039/D4CY00945B, Paper

Jinwon Choi, Amol Pophali, Byeongseok Kim, Kwangsuk Yoon, Thomas You-Seok Kim, Hocheol Song, Sang Eun Shim, Jaewoo Kim, Taejin Kim
RuO_x/BNNT catalysts were prepared with varying metal loadings and under oxidation and reduction conditions. RuO_x/BNNT showed superior catalytic activity than Ru/BNNT. The catalyst will be favorable to the ER mechanism over the LH mechanism.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00979G, Paper

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Peixue Wang, Shimin Liu, Xinjiang Cui, Feng Shi
Effectively synthesis of methyl ethyl carbamate from dimethyl carbonate and ethanol using 14 wt% KATriz/Al₂O₃ in fixed bed mode.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00779D, Paper

Suchitra N. Sapakal, Arvind Singh, Ayesha Khan, Mayur Gaikwad, Jin H. Kim, Anamika Kadam
HER: overpotential for HER, OER: overpotential for OER; R_s: solution resistance, R_ct: charge transfer resistance. The comparison of various parameters of the MoO₂@Fe₂O₃ electrode in KOH and H₂SO₄ electrolytes.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01007H, Paper

Andrew C. Chien, Corinna C. Chi
The La/Ni/SDC catalyst from one pot microwave-heating gives higher methanation activity than La–Ni/SDC and Ni–La/SDC from stepwise heating.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01061B, Paper

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Joachim Pasel, Johannes Häusler, Ralf Peters, Detlef Stolten
The uniqueness and innovation of the Ni₉₉Pt₁/C catalyst lies in the fact that a promising activity for iso-butanol synthesis was already observed at a low temperature of 165 °C in methanolic solution and at a very low precious metal mass fraction.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01035C, Paper

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Matthew E. Potter, Lucas Spiske, Philipp N. Plessow, Evangeline B. McShane, Marina Carravetta, Alice E. Oakley, Takudzwa Bere, James H. Carter, Bart D. Vandegehuchte, Kamila M. Kaźmierczak, Felix Studt, Robert Raja
Using a model microporous catalyst, the influence of acid site density and partial pressure is explored in alkane isomerisation. Combining with DFT calculations shows the role of olefins in this industrially important catalytic process.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01140F, Paper

Meiyan Guo, Wanxiang Yang, Yi Li, Yongfan Zhang, Wei Lin
Cadmium sulfide (CdS) exhibits remarkable light absorption capabilities and is widely employed in photocatalytic reduction of CO2. Nevertheless, the role of crystal facet effects on the micro-scale mechanisms governing CO2...
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01098A, Paper

Luohe Wang, Junnan E, Xiubin Bu, Jing Zeng, Xiaobo Yang, Hua Fu, Zhen Zhao
RhCOF-SYNU-1 serves as a transition-metal catalyst, photocatalyst, and metal ligand, enabling regioselective C(sp²)–H bond functionalization and offering a sustainable approach for Rh(III) catalysis.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00981A, Paper

Yufeng Wu, Jiajie Kang, Li Jianing, Mingshu Bi, Qingwei Meng
Debenzylations are widely used in fields such as pharmaceuticals and fine chemicals. In this study, metal-free tubular carbon nitride (CN-T) was prepared and used to the photocatalytic debenzylations with molecular...
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Catal. Sci. Technol., 2024, 14,6573-6583
DOI: 10.1039/D4CY00969J, Paper

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Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-Ochoa
The study utilizes density functional theory to enhance the design and efficiency of coordination polymers for sustainable photocatalytic applications.
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Catal. Sci. Technol., 2024, 14,6537-6549
DOI: 10.1039/D4CY00679H, Paper

Luliang Liao, Kunlei Wang, Guangfu Liao, Muhammad Asif Nawaz, Kun Liu
The transformative power of CO₂ methanation can efficiently transform greenhouse gases into high-value products, aligning with the carbon neutrality goals.
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Catal. Sci. Technol., 2024, 14,6550-6560
DOI: 10.1039/D4CY00559G, Paper

Ting-Hao Liu, Shuai Fu, Jin-Tao Gou, Yin-Sheng Zhang, Chang-Wei Hu, Hua-Qing Yang
Over Pt₁/Nb₂O₅, oxygen vacancy increases the catalytic activity, while the strong Lewis acidity of Nb₂O₅ selectively promotes the hydrogenolysis of the –CH₂OH group rather than the hydrogenation of the –CHO group.
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Catal. Sci. Technol., 2024, 14,6651-6661
DOI: 10.1039/D4CY01000K, Paper

Jonathan Y. C. Ting, George Opletal, Amanda S. Barnard
The structural patterns and catalytic activities of the surface atoms of simulated metal nanoparticles are characterised by an automatable data-driven unsupervised machine learning approach.
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Catal. Sci. Technol., 2024, 14,6513-6523
DOI: 10.1039/D4CY00702F, Paper

Niladri Maity, Samiyah A. Al-Jendan, Samir Barman, Nagendra Kulal, E. A. Jaseer
Heteroatom (N, S) assisted CeO₂ nanorod materials exhibited enhanced catalytic efficiency in the synthesis of dimethyl carbonate from CO₂ and methanol, attributed to their superior surface acidity, basicity, Ce³⁺ concentration, and oxygen vacancies.
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Catal. Sci. Technol., 2024, 14,6670-6677
DOI: 10.1039/D4CY00949E, Paper

Chandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook Baeg
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO₂. The CO₂ conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
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Catal. Sci. Technol., 2024, 14,6710-6719
DOI: 10.1039/D4CY00739E, Paper

Charlotte David, Stephane Grolleau, Denys Grekov, Aydar Rakhmatullin, Errol Blart, Valerie Hequet, Yann Pellegrin
A perylene-doped mesoporous silica material is used as a photocatalyst to produce H₂O₂ from aerated polluted water samples under light soaking.
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Catal. Sci. Technol., 2024, 14,6621-6640
DOI: 10.1039/D4CY00930D, Paper

Bin Guan, Junyan Chen, Zhongqi Zhuang, Zhan Gao, Zeren Ma, Xuehan Hu, Chenyu Zhu, Sikai Zhao, Kaiyou Shu, Hongtao Dang, Tiankui Zhu, Zhen Huang
As a promising future energy material, g-C₃N₄ as a CO₂ photo-thermal-reduction catalyst can effectively convert CO₂ to renewable fuel, but the low yield and low product selectivity significantly limit its further development and application.
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Catal. Sci. Technol., 2024, 14,6678-6691
DOI: 10.1039/D4CY00936C, Paper

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Beatrice Senoner, Andrea Osti, Antonella Glisenti
How to enhance DRM and NO carbon-assisted coupling using a support?
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Catal. Sci. Technol., 2024, 14,6720-6720
DOI: 10.1039/D4CY90084G, Correction

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Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-Ochoa
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