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Enhanced photocatalytic CO2 reduction by controlled oxygen vacancy generation and co-constructed heterojunction strategy for Pd/CeO2

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00581C, Research Article
Fanlin Kong, Xiaoyan Lu, Jing Xie, Zhenjiang Lu, Jindou Hu, Yali Cao
Rational control of Vo concentration and the construction of a heterojunction strategy enable Pd/CeO2-Vo(r) to exhibit excellent photocatalytic CO2RR activity. The presence of COOHcreates favorable conditions for CO formation and desorption.
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Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00200H, Research Article
Yong-Sheng Shi, Tong Xiao, Dong-Dong Yang, Xiangjun Zheng
A viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....
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Insights into the modulation mechanisms of multiple active sites in a conjugated small molecule towards organic cathode capacity from first-principles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00547C, Research Article
Zhaopeng Sun, Hao Tian, Meng Zhang, Yi Zhang, Zhiping Li, Weiwei Huang
The modulation mechanisms of Na+ within the redox-active sites of the two-dimensional conjugated organic small-molecule 3BQ, and their impact on the initial capacity of a 3BQ cathode for Na-ion batteries, were investigated using first-principles calculations.
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Structural and electrochemical properties of Tan+1Cn MXene anode materials for metal-ion batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02335D, Research Article
Jiayi Guo, Danni Hu, Chenqi Bai, Lina Xu, Hongping Xiao, Qian Shi, Xinhua Li, Xi'an Chen, Yingjin Ma, Guoyong Fang
Density functional theory calculations show that Tan+1Cn and Tan+1CnO2 MXenes have excellent open circuit voltages and maximum storage capacities for use in alkali metal-ion batteries.
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An unprecedented {Y2 ⊂ Y10} type disk-like Y12 nanocluster featuring electroluminescence property in OLED device

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00635F, Research Article
Lin-Ping Shi, Wen-Liang Li, Pu-Yue Wang, Xiaoming Wu, Zhao-Quan Yao, Jiong-Peng Zhao, Fuchen Liu
Although great efforts have been made in exploring the exquisite rare-earth (RE) clusters, the design and construction of planar RE-clusters with disk-like geometrical features are still scarce. Herein, a novel...
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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
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Advances in technical strategies for monitoring the reduction of platinum(IV) complexes

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00459K, Review Article
Open Access
Shu Chen, Qiyuan Zhou, Ka-Yan Ng, Zoufeng Xu, Weikang Xu, Guangyu Zhu
The reduction of Pt(IV) complexes can be monitored by various analytical techniques. These techniques hold significant promise in elucidating the mechanisms of Pt(IV) prodrug activation, aiding in the rational design of novel Pt(IV) prodrugs.
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Application of changing the valence state of metals through the reaction time for efficient oxygen evolution reaction

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00522H, Research Article
Ming Chen, Sha Luo, Zongyan Ma, Fei Yuan, Jing Chen, Linkun Dong, Weiwen Mao, Jiantai Ma
In this study, a novel FeNi sulfide catalyst loaded on carbon nanotubes (CNTs) (FeNiS/CNTs) shows excellent OER electrocatalytic performance in alkaline solutions.
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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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NaVSeO5: Synergistic Combinations to Excellent Birefringent Materials

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00513A, Research Article
Qiuyuan Feng, Jialong Wang, Changyou Liu, Qun Jing, Xiaoyu Dong
The novel NaVSeO5 birefringent crystals were successfully synthesized using a multifunctional group synergistic strategy, which combines a two-dimensional layered structure, consisting of stereochemically active lone pairs [SeO3], and anomalous [VO6]...
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Trifluoroacetic acid molecules confined into/onto metal–organic frameworks using H2btzip for efficiently improving proton conductivity using a synergistic effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00605D, Research Article
Xiaoxue Ma, Xin Li, Xueke Han, Lu Zhang, Ronghua Liu, Hongguo Hao, Hui Yan, Xin Zhao, Xiangjin Kong, Huawei Zhou, Xia Li, Hongjie Zhu, Suna Wang, Yunwu Li, Dichang Zhong, Fangna Dai
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
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ICRIER study explores untapped potential of India’s turmeric sector

Offers roadmap as the country dominates the global market with 70% market share




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Asian rice prices drop after India eases export curbs

FAO says market down by $10-72 a tonne, Thai cuts rates by 10%




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Indian rice exports get delayed at ports as Customs officials hold up consignments

Exporters say they incur $70/tonne additional costs; Customs officials playing safe to verify if shipments are white or parboiled rice




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Your cuppa to cost more as coffee roasters set to hike prices

Auction prices have more than doubled since the beginning of the year as domestic prices tail global trend




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Global Organic Textiles Standards bans 5 Indian cotton firms for faking documents

Two firms used non-existent shipping firms to show transactions, the others submitted fake transaction certificates




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Kandla Customs Commissioner orders release of ship detained in organic rice export irregularities

Tells Kandla traffic manager to allow another ship to set sail after getting release order from Gujarat HC




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India’s rice procurement drops by a half during October 1-15

Purchases for buffer stocks hit by storage and other issues in Punjab and Haryana




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India decides to ease rice export curbs further

High-level inter-ministerial meeting clears scrapping $490/t MEP on white rice, 10% export duty on parboiled rice




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Spinning mills in Gujarat, N. India seek quality cotton from Raichur region

Ongoing rains raise concern over quality, crop size across key producing regions




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Nickel prices likely to be under pressure on market surplus

Analysts peg its average price for 2024 at around $17,000/tonne




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Global oil prices should hopefully come down, says Oil Minister Puri

One thing that is very clear is there is no shortage of oil in the world, said Puri




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SEA asks members not to increase prices of old stock of edible oil

Solvent extractors seek Centre’s help to export oilmeals




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India defers plan to hike minimum selling price of sugar, for now

The agri costs panel had recommended regular revision of the minimum price




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Board to convene consumers meeting next week over falling natural rubber prices

Rubber Board officials said prices exceeded Rs₹200 on June 11 but plummeted 24 per cent to ₹187 per kg by October 21. The Board may ask consumers to proactively purchase in the domestic market




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Festivals, agriculture, elections set to boost India's oil demand: S&P Global Commodity Insights

According to the commodities information services provider, India's oil demand decreased in September on a yearly basis, due to above normal rainfall, which affected road movement, construction, and mining activities




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Oil prices likely to fall after Israel shows restraint in strikes on Iran

Scores of Israeli jets completed three waves of strikes before dawn on Saturday against missile factories and other sites near Tehran and in western Iran, in the latest exchange in the escalating conflict between the Middle East rivals




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Fuel price update: Jet fuel sees 3.3% hike; commercial LPG rates rise by ₹62

In contrast, domestic LPG rates remain unchanged at ₹803 for a 14.2-kg cylinder




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Manufacturing method of lab grown diamonds should be declared before export and import: CBIC

The new norms, which will help in quick processing and inspection of consignments, are to be effective from December 1




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Crude oil gains as market analyses Trump’s victory in US Presidential election

The Trump administration could stimulate economic growth in the US, which could help boost consumption demand in that country, say analysts




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Trump effect: Base metal prices surge on demand spike after slumping post-Trump win

Aluminium, zinc and copper futures climb on November 7, the day after Trump’s election, say PTI reports




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Down the AI rabbit hole, strewn with health benefits and ethical pitfalls 

Regulatory frameworks covering AI need fine-tuning to harness its potential without halting growth 




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Why drugmakers are dialing C for current good manufacturing practices

For the industry under scrutiny over quality concerns, cGMP requires immediate attention




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Calisthenics, rock-climbing and laughter




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Making the right choice on organs — ‘pass it on’

Organ Donation: A tightly regulated practice tainted by acts of fraud, gifts someone a chance at a better health




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Crystal-ball gazing: Diagnostics, faster & more precise

Comprehensive remote monitoring has the potential to revolutionise healthcare




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Medication safety

Patient harm due to unsafe care is a leading cause of death and disability worldwide




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Cricket, cooking and the classics to unwind

Director and CEO of Sahyadri Hospitals on finding joy in cricket, cooking, gym, and movies for relaxation and wellness




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PLI, plugging chinks in the country’s manufacturing armour for drugs and devices

 Call for simplification of licencing regimes gets louder even as benefits become tangible 




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The rising global tide of genomics for public health

Genomics is advancing our understanding of the genetic basis of health and disease and shaping strategies to promote population health.




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Making India a go-to for medical treatment

India stands at the crossroads of innovation and tradition, offering medical solutions for the world, where life-saving treatments are delivered with precision and care




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Redefining the regulatory pathway for nutraceutical and pharmaceutical products

As the nutraceutical landscape grows, experts call for clarity in the manufacturing debate




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Breaking down ‘patent thickets’ without smothering innovation

With recent patent-linked rejections, governments push back on big pharma’s strategy




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Trust instincts, avoid quick fixes

Amit Saneja, CEO, Educate Online, on his exercise routine, mindful eating and ways to sustainable health.




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Reviewing TRIPS, an opportunity for evidence-based policies

Colombia calls for review of TRIPS Agreement implementation, highlighting need for evidence-based IP law and policy




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Clinical trial waiver, a step to improve patient access, in need of guardrails

Experts call for ensuring patient safety while expanding access to new drugs




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Paralympic’s equity campaign

The World Health Organization and International Paralympic Committee have launched the ‘Equipped for equity’ campaign at the Paris 2024 Paralympic Games




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Code grey: Hospitals as safe zones for medical practitioners, patients

Amid rising violence, medicos call for a stringent Central Act to ensure safe workspaces and speedy action




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Golf, gluten-free diet, and music

Personal fitness diary