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Tin based organic-inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01401J, Paper
Zhenhong Wei, Xiuli You, Jiaojiao Yao
Organic−inorganic hybrid materials with perovskite structure have recently attracted tremendous interest due to their structural tunability and rich functional properties, such as phase transition and photoelectric properties. Within this context,...
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Oxacalix[4]arene Derived Dual Sensing Fluorescence Probe for the Detection of As (V) and Cr (VI) Oxyanions in Aqueous Media

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00452A, Paper
Shuvankar Dey, Anshu Kumar, Pradip Mondal, Krunal M. Modi, Deepak Chopra, Vinod K. Jain
An oxacalix[4]arene-Ce (III) complex viz. L-Ce(III) has been introduced for selective detection of As (V) and Cr (VI) oxyanions in aqueous medium. Binding mode of L-Ce(III) + AsO43-/ CrO42- was...
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Double addition of phenylacetylene onto the mixed bridge phosphinito–phosphanido Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)](Pt–Pt)

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00923G, Paper
Stefano Todisco, Mario Latronico, Vito Gallo, Nazzareno Re, Alessandro Marrone, Iogann Tolbatov, Piero Mastrorilli
Double addition of phenylacetylene onto the Pt(I)–Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)] (Pt–Pt) affords the η1-alkenyl-μ,η12-alkynyl complex [(η1-trans-(Ph)HCCH)(PHCy2)Pt(μ-PCy2)(μ,η12-PhCC)Pt{κP-P(O)Cy2}(PHCy2)].
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A molecular boron cluster-based chromophore with dual emission

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00826E, Paper
Kierstyn P. Anderson, Mary A. Waddington, Gary J. Balaich, Julia M. Stauber, Nicholas A. Bernier, Justin R. Caram, Peter I. Djurovich, Alexander M. Spokoyny
Bromination of the luminescent borane, anti-B18H22, via electrophilic substitution using AlCl3 and Br2, yields the monosubstituted derivative 4-Br-anti-B18H21 as an air-stable crystalline solid.
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Crystal structure, chemical bonding, and electrical and thermal transport in Sc5Rh6Sn18

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00324G, Paper
Manuel Feig, Lev Akselrud, Walter Schnelle, Vadim Dyadkin, Dmitry Chernyshov, Alim Ormeci, Paul Simon, Andreas Leithe-Jasper, Roman Gumeniuk
Single crystals of the superconductor Sc5Rh6Sn18 were grown from Sn-flux.
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Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) as necroptosis and ferroptosis inducers

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00168F, Paper
Daniel Baecker, Benjamin N. Ma, Jessica Sagasser, Lukas Schultz, Carina Hörschläger, Maria Weinreich, Lucy Steiner, Brigitte Kircher, Ronald Gust
Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) were synthesized and characterized as necroptosis and ferroptosis inducers using the acute myeloid leukemia cell line HL-60.
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Reactive metallocene cations as sensitive indicators of gas-phase oxygen and water

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00798F, Paper
Anuj Joshi, Sofia Donnecke, Ori Granot, Dongju Shin, Scott Collins, Irina Paci, J. Scott McIndoe
Gas-phase oxidation of air-sensitive organometallic compounds does not proceed to a significant extent in mass spectrometric analysis unless a vacant coordination site is generated, making nitrogen generators a suitable source of desolvation gas.
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Two [Ln4] molecular rings folded as compact tetrahedra

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01259A, Paper
Guillem Aromi, Olivier Roubeau, Leoní Alejandra Barrios, Jorge Salinas-Uber
The design of photoactive ligands may provide an entry into multifunctional molecular nanomagnets. We report here the design and synthesis of a new multitopic chelating ligand, 1,2-bis-(5-(N’-(pyridine-2-yl-methylene)-carbohydrazide)-3-methyl-thien-3-yl)-cyclopentene (H2L), bearing a...
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Heat-resistant Pb(II)-based X-ray scintillating metal-organic frameworks for sensitive dosage detection via the aggregation-induced luminescent chromophore

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00974A, Communication
Jian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng, Guo-Cong Guo
The synergy of unusual X-aggregation induced luminescent chromophores and heavy Pb(II) ions has facilitated excellent X-ray scintillation of two structurally similar Pb-SMOFs, which are heat-resistant due to solvent-free lattices. Owing...
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High Pressure and Elastic properties of a Guanidinium -formate Hybrid Perovskite

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/C9DT04805G, Paper
Hong-Qiang Gao, Chao Li, Lin-Sui Li, Wen-Juan Wei, Yu-hui Tan, Yun Zhi Tang
The high pressure and elastic properties in a hybrid ABX3-type perovskite, [C(NH2)3][Cd(HCOO)3] (CdGF), based on the A-site guest molecular is revealed via combining the high-pressure synchrotron X-ray diffraction experiments with...
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Spin-frustration with two quasi-degenerated spin states of a copper(II) heptanuclear complex obtained from an amino acid ligand

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/C9DT04501E, Paper
Catiúcia Rodrigues Marcelino Oliveira Matos, Henrique Silva Jr, Dayenny D’Amato, Guilherme Guedes, Glaucio Braga Ferreira, Odivaldo Cambraia Alves, Filipe Barra de Almeida, Sergio Pinheiro, Acácio Souza, Flavio Garcia, Célia Machado Ronconi
The Cu(II) heptanuclear complex (Cu7atac) was synthesised using the hydrated amino acid ligand 2-(5-amino-1H-1,2,4-triazol-3-yl)acetic acid (Hatac.H2O). Single crystal X-ray diffraction analysis revealed a μ3-hydroxo bridged Cu(II) heptanuclear complex, consisting of...
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Photophysical, photodynamical, redox properties and BSA-interactions of novel isomeric tetra-cationic peripheral palladium(II)-bipyridyl porphyrins

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01063D, Paper
Fabiano S Santos, Carolina H. da Silveira, Fabio Souza Nunes, Daniele Ferreira, Henrique Victória, Klaus Krambrock, Otávio Augusto Chaves, Fabiano Severo Rodembusch, Bernardo Almeida Iglesias
New isomeric tetra-cationic porphyrins containing peripheral [Pd(bpy)Cl]+ units attached at pyridyl substituents were synthetized and fully characterized. The porphyrins present an intense Soret band located in the blue spectral region...
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Impacts of hydrogen bonding interactions with Np(V/VI)O2Cl4 complexes: vibrational spectroscopy, redox behavior, and computational analysis

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00848F, Paper
Mikaela M. Pyrch, Jennifer L. Bjorklund, James M. Williams, Daniel L. Parr IV, Sara E. Mason, Johna Leddy, Tori Z. Forbes
Crystallization of neptunyl(V) tetrachlorides over neptunyl(VI) species occurs simultaneously with charge assisted hydrogen bonding in our solid state materials, which we explored by DFT calculations, cyclic voltammograms, and Raman spectroscopy.
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The differential magnetic relaxation behaviours of slightly distorted triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compounds

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00990C, Paper
An-Qi Xue, Yang-Yu Liu, Jia-Xin Li, Yan Zhang, Yin-Shan Meng, Wen-Hua Zhu, Yi-Quan Zhang, Hao-Ling Sun, Fei Wang, Guan-Xia Qiu, Lu-Yu Liang, Xiang Wang, Song Gao
Differential magnetic properties were observed for triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compound.
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d

Rhenium and technetium-complexed silicon rhodamines as near-infrared imaging probes for bimodal SPECT- and optical imaging

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01084G, Communication
Thines Kanagasundaram, Carsten Sven Kramer, Eszter Boros, Klaus Kopka
Radiolabelled fluorescent dyes are decisive for bimodal imaging and currently in demand for scintigraphic and optical imaging. This powerful method allows the combination of nuclear imaging (e.g. SPECT-imaging) and optical...
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A Review: Recent Advances in Preparations and Applications of Heteroatom-Doped Carbon Quantum Dots

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01004A, Perspective
Xiaoli Kou, Shicui Jiang, Soo-Jin Park, Long-Yue Meng
Carbon quantum dots (CQDs) are widely used in optoelectronic catalysis, biological imaging, and ion probes owing to their low toxicity, stable photoluminescence, and ease of chemical modification. However, the low...
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Highly cytotoxic gold(I)-phosphane dithiocarbamate complexes trigger an ER stress-dependent immune response in ovarian cancer cells

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01411G, Paper
Hai Van Le, Maria Babak, Muhammad Ali Ehsan, Mohammad Altaf , Lisa Reichert, Artem Gushchin, Wee Han Ang, Anvarhusein Isab
Ovarian cancer is a highly aggressive disease which is treated by surgery and platinum chemotherapy. However, a significant proportion of treated patients develop resistance to platinum treatment resulting in tumor...
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d

Platinum Complexes of a Boron-Rich Diphosphine Ligand

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00963F, Paper
Marcus W. Drover, Eric G Bowes, Maeve C Dufour, Lindsay Lesperance-Nantau
Herein, we describe the preparation, characterization, and reactivity of two PtIIbis-hydrocarbyl complexes containing the 1,2-bis(di(3-dicyclohexylboraneyl)propylphosphino)ethane (P2BCy4) ligand. These scaffolds are readily accessed from four-fold hydroboration of 1,2-bis(diallylphosphino)ethane PtII precursors....
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Dual-fixations of europium cation and TEMPO species on metal-organic frameworks for aerobic oxidation of alcohols

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01324B, Paper
Seongwoo Kim, Jooyeon Lee, Sungeun Jeoung, Hoi Ri Moon, Min Kim
The efficient and selective aerobic oxidation of alcohols has been investigated with judicious combinations of europium-incorporated and/or TEMPO ((2,2,6,6-tetramethylpiperidin-1-yl)oxyl)-functionalized zirconium-based porous metal-organic frameworks (MOFs). Although MOFs are well-known catalytic platform...
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d

Sequenced cooking that really works

I went to a talk by a cookbook author who said she’d figured out a system for efficient home cooking: big pots of beans and soup, dishes that could be frozen and reheated. The concepts would have been obvious to any old-fashioned cook, and they are good, practical concepts. But her specific advice was so

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d

What is a “third place,” and do you have one?

The term “happy place” is not in the Oxford English Dictionary (though “happy slap” is), but I’ve been hearing the term a lot. There’s even a new shop in Great Barrington called HappyPlace Berkshires. I first dismissed it as therapeutic slang, but discovered that the concept actually goes back to the Greeks: a utopia is

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The Spirit of Sustainability: print or digital, which is “greener”?

When we published the Encyclopedia of Sustainability in 2012, a librarian wrote, “That goes against the spirit of sustainability.” I got a similar response this week, so I want to explain why we publish in print and online, and why online is not “green.” An ebook probably kills more trees through deforestation than an equivalent print book,

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d

First Look at the T S Eliot – Emily Hale Letters (podcast)

In what one scholar called “the literary event of the decade,” on 2 January 2020, Princeton University Library opened up more than 1,100 letters that the Nobel-Prize-winning poet T.S. Eliot wrote over the course of three decades to an American speech professor and amateur actress named Emily Hale. The day became even more

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Tyrannical Leadership

"Tyrannical Leadership" from Berkshire Publishing's Encyclopedia of Leadership. Ed. George R. Goethals, Georgia J. Sorenson, and James MacGregor Burns. Vol. 4. Thousand Oaks, CA: Sage Reference, 2004. Click to view or purchase. For customized collections of material from the Encyclopedia of Leadership, contact cservice@berkshirepublishing.com. Tyrants, as the Greek philosopher Plato defined them in The Republic, are

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Gastrodiplomacy in China; T S Eliot’s Love Letters

Chinese food, anyone? I'll be co-presenting a program about gastrodiplomacy at Schwarzman College in Beijing next month, and I am looking for stories to share, from history as well as personal experience. Schwarzman College 苏世民书院 is a residential college at Tsinghua University. Schwarzman scholarships are modeled on the Rhodes Scholarships at Oxford. The one-year MA

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  • Seeing the World

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Letter from Beijing: Love in the Time of COVID-19

My son Tom works in healthcare finance, and has lived in China since graduating from college. He was quarantined in Lanzhou during the 2009 swine flu epidemic, and now he's experiencing the semi-quarantine of 2020. In fact, I expected to be there right now and was looking forward to time with him and his wife

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Tom’s 2nd letter from Beijing

This Princess and Prince Party is sure to be canceled. I'm delighted to report that the Train Campaign projects were included in the governor's bond bill last week, and the bills I filed by petition (a unique Massachusetts citizen right) have been favorably reported on. Read about A Great Week for Train Advocates

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COVID-19 is here (& where has all the toilet paper gone?)

We lived through the ‘80s. We lived through the ‘90s. We lived through the ‘00s. We lived through the ‘10s. And we’ve lived through March. Most of us, that is, have lived. I’m still coming to terms with what is happening. It’s like grief. I go about my day, getting absorbed in work, or a

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T.S. Eliot “Got Cheese” Campaign Announced

Great Barrington, MA - COVID-19 has delayed the launch of a record-setting marketing deal expected to boost international appreciation of English and European cheeses. The image and words of the Nobel Prize winning poet T S Eliot, as well as characters from the musical Cats, will be used to promote cheese and cheese products throughout the world.

The post T.S. Eliot “Got Cheese” Campaign Announced appeared first on Berkshire Publishing.




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Berkshire Joins COVID-19 Support Efforts With JStor, EBSCO, ProQuest

We want to make sure you know about some of the ways in which publishers - including Berkshire - are making our books and reference publications available online at reduced cost, or even free, during the COVID-19 crisis. We're well aware that taking classes and doing research papers online is a huge challenge for many

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d

A Letter is Better: Love and Remembrance

Messenger of Sympathy and Love Servant of Parted Friends Consoler of the Lonely Bond of the Scattered Family Enlarger of the Common Life Carrier of News and Knowledge Instrument of Trade and Industry Promoter of Mutual Acquaintance Of Peace and of Goodwill Among Men and Nations. A business consultant once passed around copies of the

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d

Do exclusionary rules ensure a fair trial?: a comparative perspective on evidentiary rules / Sabine Gless, Thomas Richter, editors

Online Resource




d

Selma and the Liuzzo murder trials: the first modern civil rights convictions / by James P. Turner

Dewey Library - KF224.K7 T87 2018




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Artist, authorship & legacy: a reader / edited by Daniel McClean

Rotch Library - KF3050.A78 2018




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First: Sandra Day O'Connor / Evan Thomas

Dewey Library - KF8745.O25 T46 2019




d

Our selfish tax laws: toward tax reform that mirrors our better selves / Anthony C. Infanti

Dewey Library - KF6289.I49 2018




d

The World Bank policy for projects on international waterways: an historical and legal analysis / Salman M.A. Salman

Online Resource




d

Real estate finance in a nutshell / Vada Waters Lindsey, Associate Professor of Law, Marquette University Law School

Rotch Library - KF695.Z9 L56 2018




d

Many nations under many gods: public land management and American Indian sacred sites / Todd Allin Morman

Rotch Library - KF5605.M67 2018




d

Free speech in the digital age/ Edited By Susan J. Brison And Katharine Gelber

Dewey Library - K3254.F73 2019




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Implementing environmental constitutionalism: current global challenges / edited by Erin Daly, James R. May

Rotch Library - K3585.I596 2018




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Decarcerating America: from mass punishment to public health / edited by Ernest Drucker

Dewey Library - KF9730.D43 2018




d

Practitioner's guide to project-based vouchers: a successor to the Beginner's guide / Sarah Molseed and Julie S. McGovern

Rotch Library - KF5735.M654 2018




d

No property in man: slavery and antislavery at the nation's founding / Sean Wilentz

Hayden Library - KF4545.S5 W59 2018




d

Religious exemptions / edited by Kevin Vallier and Michael Weber

Dewey Library - K3258.R453 2018




d

Networked press freedom: creating infrastructures for a public right to hear / Mike Ananny

Dewey Library - K3255.A958 2018




d

Separate: the story of Plessy v. Ferguson, and America's journey from slavery to segregation / Steve Luxenberg

Hayden Library - KF223.P56 L88 2019




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The essential guide to intellectual property / Aram Sinnreich

Dewey Library - K1401.S56 2019




d

Gender quotas in South America's big three: national and subnational impacts / Adriana Piatti-Crocker, Gregory D. Schmidt, and Clara Araujo

Dewey Library - KH136.W64 P53 2017




d

Winning together: the natural resource negotiation playbook / Bruno Verdini Trejo

Dewey Library - KZ6047.V47 2017