Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00905A, Paper

Lei-Lei Li, Hong-Dan Su, Shuang Liu, Wen-Zhen Wang
Upon changing the employed halide ions as counterions, U_eff increases from 290 K to 320 K in two Ho^III-SIMs with pentagonal-bipyramidal structures.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01031F, Paper

Pavel S. Kulyabin, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Jo Ann M. Canich, John R. Hagadorn
Pyridylamido hafnium complexes with a silylene bridge were synthesized, characterized with X-ray crystal structure analysis and shown to polymerize 1-hexene and propene and copolymerize ethylene and 1-octene.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04837E, Paper

Nanxi Lin, Shengnan Zhang, Haixin Chen, Yunjin Chen, Xin Chen, Yongfan Zhang, Xiaolin Hu, Naifeng Zhuang
Orthorhombic CeFeO₃ is optimized to be cubic perovskite with high compatibility with Si substrate by introducing Sr, V ions into lattice. Cubic Sr,V:CeFeO₃ film exhibit strong magneto-optical effect due to spin-coupling hybrid of Ce 4f with Fe/V 3d.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01001D, Paper

Tsukasa Abe, Yoshihito Shiota, Shinobu Itoh, Kazunari Yoshizawa
DFT calculations are carried out to investigate the geometric effects of the supporting ligands in the relative energies of the (μ–η²:η²-peroxido)Cu^IICu^II complex 1 and the bis(μ-oxido)Cu^IIICu^III complex 2.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00156B, Paper

Cheng-Chang Chiu, Ming-Chuan Cheng, Sheng-Hsiang Lin, Cheng-Wei Yan, Gene-Hsiang Lee, Mu-Chieh Chang, Tien-Sung Lin, Shie-Ming Peng
A novel heteroheptanuclear metal string complex was synthesized by using nickel and ruthenium metal ions to explore the electronic structure and magnetic property.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01241F, Paper

Jingjing Liu, Lydia E. Nodaraki, Philip J. Cobb, Marcus J. Giansiracusa, Fabrizio Ortu, Floriana Tuna, David P. Mills
Two families of lanthanide(III) phospholyl borohydride complexes are reported (carbon = grey, hydrogen = white, oxygen = red, boron = yellow, phosphorus = magenta, potassium = blue, lanthanides = teal; only BH₄ hydrogens are shown for clarity).
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00496K, Paper

Ke Shan, Zhong-Zhou Yi, Xi-Tao Yin, Davoud Dastan, Hamid Garmestani
First-principles calculations were used to explore the effect of various Y-doping levels on the electrical conductivity of SrTiO₃.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01177K, Paper

To Van Nguyen, Le The Son, Vu Van Thuy, Vu Dinh Thao, Masahito Hatsukano, Koichi Higashimine, Shinya Maenosono, Sang-Eun Chun, Tran Viet Thu
We report the synthesis of manganese-doped nickel cobalt oxide (Mn-doped NiCo₂O₄) nanoparticles (NPs) by an efficient hydrothermal and subsequent calcination route.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00844C, Paper

Juliane N. B. D. Pelin, Charlotte J. C. Edwards-Gayle, Herculano Martinho, Barbara B. Gerbelli, Valeria Castelletto, Ian W. Hamley, Wendel A. Alves
We show that arginine/phenylalanine based peptides can be used to control the aggregation of gold nanoparticles in different ways. The arrangement provides a colorimetric approach to detect Cu²⁺ ions in water.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01287D, Paper

Jacqueline Gianino, Seth N. Brown
Describing the π bonding in ruthenium and osmium iminoxolenes as highly covalent allows one to experimentally dissect the electron distribution in these compounds.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00726A, Paper

Hart Plommer, Laura Stein, Jennifer N. Murphy, Nduka Ikpo, Nelaine Mora-Diez, Francesca M. Kerton
Five aluminum catalysts demonstrated different selectivity and activity during reactions of carbon dioxide and epoxides.
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01340D, Communication

Ya-Liang Lai, Xue-Zhi Wang, Rui-Rong Dai, Yong-Liang Huang, Xian-Chao Zhou, Xiao-Ping Zhou, Dan Li
Two mixed-valent CuII/CuI and two heterometallic CuII/AgI metallocycles have been synthesized by the assembly of designed metalloligands and CuI/AgI ions, respectively. The CuII/CuI metallocycle can catalyze oxidation of alcohols to...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00618A, Paper

Hengbin Xu, Zhenyuan Bai, Milin Zhang, Jun Wang, Yongde Yan, Min Qiu, Jiaming Chen
With the depletion of uranium terrestrial deposits, researchers have focused on the development of adsorbents to extract radioactive uranium from seawater/wastewater. However, there are still considerable challenges to manipulate this...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00824A, Paper

Mengke Cai, Qinglin Liu, Yiyue Zhao, Zhenyu Wang, Yinle Li, Guangqin Li
Owing to coordinating of intriguing activity and conductivity, the hybrid compositions of layered double hydroxides (LDHs) and carbon-based materials have been extensively and widely applied to evolve oxygen gas for...
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00978D, Paper

Ji-Min Yang, Wei Zhang, Run-Zhi Zhang, Meng-Xuan Tong
MIL-101-SO₃H analogues functionalized with –SO₃H groups exhibited superior CR, MO and AC adsorption capacities because of their distinct adsorption mechanisms.
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01325K, Paper

Shi-Rui Kang, Qin Zi Zhou, Chang-Fang Xiong, Bin Liu, John E. McGrady, Mohammed Obies, Chao Liu, Piao He, Xiao-Yi Yi
A family of Ru2 dimers, [Ru₂(μ-κ₂N,N’:κ₂N’,N’’-dpp)2(μ-X)(X)₂]^q+ (X = Cl, Br, q = 0 and X = I, q = 1) is synthesized from a [Ru₂(OAc)₄Cl] paddlewheel starting material. The neutral...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01483D, Communication

Xuefeng Zou, Qin Hu, Hengxiu Yang, Feng Chen, Bin Xiang, Xinyue Liang, Qibing Wu, Hujun Shen
Here we report an ultra-effective, reliable pathway to reduce GO into graphene by an about 4-seconds flame-assisted microwave process. A holey graphene with a C/O atom ratio of 31.1, a...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00866D, Paper

Jun Tao, Yue Li, Min Liu, Zi-Shuo Yao
Hofmann-type spin-crossover (SCO) frameworks attract much attention due to their predictable structures and diverse SCO behaviours. In this paper, we report two isostructural two-dimensional (2D) Hofmann-type SCO frameworks [FeII(ppe)2MII(CN)4]·3H2O (ppe...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01130D, Paper

Huiling Zhang, Dengwen Yuan, Xiaoyun Mi, Xiuling Liu, Jun Lin
A series of Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) phosphors were prepared via high-temperature solid-state reaction process. The X-ray diffraction and Rietveld refinements were used to verify the incorporations of...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01223H, Paper

Tomohiro Sugahara, Arturo Espinosa Ferao, Alicia Rey, Jing-Dong Guo, Shin Aoyama, Kazunobu Igawa, Katsuhiko Tomooka, Takahiro Sasamori, Daisuke Hashizume, Shigeru Nagase, Norihiro Tokitoh
1,2-insertion reactions of alkynes into the Ge–C bonds in dibromodigermenes afford stable crystalline bromovinylgermylenes. In contrast to previously reported Lewis-base-supported vinylgermylenes, the bromovinylgermylene obtained from reaction of the bromogermylene with...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00735H, Paper

Jie Chen, Yixin Gao, Haifeng Jiang, Yan Liu, Zhaohui Jin
Optimizing structure and varing doped ions are two main strategies to obtain excellent luminescence performance. Spherical morphology is considered to be the most ideal phosphor structure due to the least...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01132K, Paper

María Joaquina Beltrán Leiva, Eduardo Solis Céspedes, Dayan Paez-Hernandez
A fragmentation scheme combined with a series of theoretical approximations like TD-DFT, and multiconfigurational CASSCF/NEVPT2 methods, have been used to describe the photophysical phenomena associated with the antenna effect and...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01321H, Paper

Tatiane Strelow Lilge, Adriano Borges Andrade, Claudiane dos Santos Bezerra, Giordano Frederico da Cunha Bispo, Zélia Soares Macedo, Mario Lucio Lúcio Moreira, Mário Ernesto Giroldo Valerio
Inorganic hybrid materials are promising applications in absorbers and photon harvesting of solar irradiation, such as DSSC cell photoanodes. Moreover, the investigation of the interaction between the photoanode constituent materials...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01044H, Paper

Carsten Schlüsener, Dustin Nils Jordan, Mergime Xhinovci, Tobie J. Matemb Ma Ntep, Alexa Schmitz, Beatriz Giesen, Christoph Janiak
We report the systematic study on the possibility of forming mixed-linker MOFs spanning between the aluminum metal-organic frameworks CAU-23 and MIL-160 with their 2,5-thiophenedicarboxylate (TDC) and 2,5 furandicarboxylate (FDC) linkers,...
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00568A, Paper

Anastasia I. Solomatina, Kirill M. Kuznetsov, Vladislav V. Gurzhiy, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov, Sergey P. Tunik
New N^N and N^C luminescent ligands with solvatochromic behavior and their iridium complexes were synthesized, characterized and investigated.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01054E, Paper

Sankar Das, Arnab Samanta, Kanika Kole, Gautam Gangopadhyay, Subhra Jana
MnO2 flowery nanocomposites were explored as a novel and cost effective nanoadsorbent for the fast and efficient extraction of toxic inorganic contaminants from aqueous solution.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01070G, Paper

Ming Wen, Cong Hu, Hongping Wu, Zhihua Yang, Xiaohong Wu, Shilie Pan
We reported the synthesis, structure, characterization and first-principles calculations of diphosphates, α-Li₂Na₂P₂O₇, Li₈Pb₃Ba(P₂O₇)₄ and Li₇Rb(P₂O₇)₂, and studied the influences of co-substitution on the crystal structure.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01058H, Paper

Magdalena Ceglarska, Olaf Stefańczyk, Shin-ichi Ohkoshi, Anna M. Majcher-Fitas
Dilution with diamagnetic species in a SIM solid solution leads to an increase in relaxation times at low temperatures and monotonously reduces the probability of quantum tunneling of magnetization and the direct process.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00466A, Paper

Manas Khatua, Bappaditya Goswami, Subhas Samanta
A Ni(II)-template directed dehydrogenative imine formation reaction via ligand reduction leading to the formation of new pincer-like azo imine ligands is described.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00863J, Frontier

Papri Sutar, Tapas Kumar Maji
In this article, we reviewed recent advances in coordination-driven polymeric gels and highlighted their design and applications in various fields.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00033G, Paper

Xiao-Quan Zhu, Wen-Hai Cao, Shao-Dong Su, Xin-Tao Wu, Tian-Lu Sheng
The SMM behavior weakens until its disappearance with the substituent changing from Br, H to OMe in the quinonoid-bridged dicobalt compounds [(N₄Co)₂LX](ClO₄)₂, (X = H, Cl, Br, and OMe).
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04755G, Paper

Xuerui Yi, Xiaobo He, Fengxiang Yin, Biaohua Chen, Guoru Li, Huaqiang Yin
The electrodeposition of amorphous Ni–Fe–Se hollow nanospheres as a highly efficient bifunctional catalyst for the sustainable production of hydrogen.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01227K, Communication

Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka
A triplatinum complex with chelating NHC ligands reacts with Ag(I) and affords a heptanuclear cluster bearing four Ag–Pt bonds.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01240H, Paper

Zihao Wang, Zongzhe Li, Marcus Ng, Phillip J. Milner
We describe the mechanochemical, solvent-free synthesis of metal–organic frameworks using liquid organic base for the first time.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01510E, Paper

Nikita V. Shvydkiy, Egor A. Dlin, Klimentiy V. Ivanov, Anastasiya G. Buyanovskaya, Yulia V. Nelyubina, Dmitry S. Perekalin
The reaction of NiBr₂ with 3-hexyne provides new access to various cyclobutadiene nickel complexes.
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00444H, Paper

Jingyang Niu, Hui Kong, Peipei He, Zongfei Yang, Qiaofei Xu, Jiawei Wang, Ran Ban, Pengtao Ma, Jingping Wang
Three sandwich-type TM-containing (TM = transition metal) organophosphonate-based polyoxotungstate clusters, [TM(H2O)4(SeW6O21)2{Co(OOCCH2NCH2PO3)2}3]12– (TM = Co, Ni), have been successfully synthesized, which is the first reported TMs-containing organophosphonate-based selenotungstates. They were structurally...
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01034K, Paper

Katherine R. Johnson, Sebastian B. Vittardi, Manuel A. Gracia-Nava, Jeffrey J. Rack, Ana de Bettencourt-Dias
A new pyridine-bis(carboxamide)-based ligand with a bithiophene pendant, 2Tcbx, was synthesized.
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01295E, Paper

Rui Feng, Rong Wu, Yuncheng Cao, Xiaolin Guo, Xu Ma
Molybdenum selenide has great potential for degradation of water pollutants，but its performance is limited by the active sites and recombination of photogenerated electron-hole pairs. In this study, amorphous Co-doped MoSex...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01401J, Paper

Zhenhong Wei, Xiuli You, Jiaojiao Yao
Organic−inorganic hybrid materials with perovskite structure have recently attracted tremendous interest due to their structural tunability and rich functional properties, such as phase transition and photoelectric properties. Within this context,...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00452A, Paper

Shuvankar Dey, Anshu Kumar, Pradip Mondal, Krunal M. Modi, Deepak Chopra, Vinod K. Jain
An oxacalix[4]arene-Ce (III) complex viz. L-Ce(III) has been introduced for selective detection of As (V) and Cr (VI) oxyanions in aqueous medium. Binding mode of L-Ce(III) + AsO₄^3-/ CrO₄^2- was...
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00923G, Paper

Stefano Todisco, Mario Latronico, Vito Gallo, Nazzareno Re, Alessandro Marrone, Iogann Tolbatov, Piero Mastrorilli
Double addition of phenylacetylene onto the Pt(I)–Pt(I) complex [(PHCy₂)Pt(μ-PCy₂){κ²P,O-μ-P(O)Cy₂}Pt(PHCy₂)] (Pt–Pt) affords the η¹-alkenyl-μ,η¹:η²-alkynyl complex [(η¹-trans-(Ph)HCCH)(PHCy₂)Pt(μ-PCy₂)(μ,η¹:η²-PhCC)Pt{κP-P(O)Cy₂}(PHCy₂)].
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00826E, Paper

Kierstyn P. Anderson, Mary A. Waddington, Gary J. Balaich, Julia M. Stauber, Nicholas A. Bernier, Justin R. Caram, Peter I. Djurovich, Alexander M. Spokoyny
Bromination of the luminescent borane, anti-B₁₈H₂₂, via electrophilic substitution using AlCl₃ and Br₂, yields the monosubstituted derivative 4-Br-anti-B₁₈H₂₁ as an air-stable crystalline solid.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00324G, Paper

Manuel Feig, Lev Akselrud, Walter Schnelle, Vadim Dyadkin, Dmitry Chernyshov, Alim Ormeci, Paul Simon, Andreas Leithe-Jasper, Roman Gumeniuk
Single crystals of the superconductor Sc₅Rh₆Sn₁₈ were grown from Sn-flux.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00168F, Paper

Daniel Baecker, Benjamin N. Ma, Jessica Sagasser, Lukas Schultz, Carina Hörschläger, Maria Weinreich, Lucy Steiner, Brigitte Kircher, Ronald Gust
Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) were synthesized and characterized as necroptosis and ferroptosis inducers using the acute myeloid leukemia cell line HL-60.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00798F, Paper

Anuj Joshi, Sofia Donnecke, Ori Granot, Dongju Shin, Scott Collins, Irina Paci, J. Scott McIndoe
Gas-phase oxidation of air-sensitive organometallic compounds does not proceed to a significant extent in mass spectrometric analysis unless a vacant coordination site is generated, making nitrogen generators a suitable source of desolvation gas.
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01259A, Paper

Guillem Aromi, Olivier Roubeau, Leoní Alejandra Barrios, Jorge Salinas-Uber
The design of photoactive ligands may provide an entry into multifunctional molecular nanomagnets. We report here the design and synthesis of a new multitopic chelating ligand, 1,2-bis-(5-(N’-(pyridine-2-yl-methylene)-carbohydrazide)-3-methyl-thien-3-yl)-cyclopentene (H2L), bearing a...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00974A, Communication

Jian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng, Guo-Cong Guo
The synergy of unusual X-aggregation induced luminescent chromophores and heavy Pb(II) ions has facilitated excellent X-ray scintillation of two structurally similar Pb-SMOFs, which are heat-resistant due to solvent-free lattices. Owing...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/C9DT04805G, Paper

Hong-Qiang Gao, Chao Li, Lin-Sui Li, Wen-Juan Wei, Yu-hui Tan, Yun Zhi Tang
The high pressure and elastic properties in a hybrid ABX3-type perovskite, [C(NH2)3][Cd(HCOO)3] (CdGF), based on the A-site guest molecular is revealed via combining the high-pressure synchrotron X-ray diffraction experiments with...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/C9DT04501E, Paper

Catiúcia Rodrigues Marcelino Oliveira Matos, Henrique Silva Jr, Dayenny D’Amato, Guilherme Guedes, Glaucio Braga Ferreira, Odivaldo Cambraia Alves, Filipe Barra de Almeida, Sergio Pinheiro, Acácio Souza, Flavio Garcia, Célia Machado Ronconi
The Cu(II) heptanuclear complex (Cu7atac) was synthesised using the hydrated amino acid ligand 2-(5-amino-1H-1,2,4-triazol-3-yl)acetic acid (Hatac.H2O). Single crystal X-ray diffraction analysis revealed a μ3-hydroxo bridged Cu(II) heptanuclear complex, consisting of...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01063D, Paper

Fabiano S Santos, Carolina H. da Silveira, Fabio Souza Nunes, Daniele Ferreira, Henrique Victória, Klaus Krambrock, Otávio Augusto Chaves, Fabiano Severo Rodembusch, Bernardo Almeida Iglesias
New isomeric tetra-cationic porphyrins containing peripheral [Pd(bpy)Cl]+ units attached at pyridyl substituents were synthetized and fully characterized. The porphyrins present an intense Soret band located in the blue spectral region...
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